The 5520 A band of ammonia in the spectrum of Jupiter
Equivalent line widths of 5520 A ammonia band in Jupiter spectrum
Owen, T.↗
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Relative rates and their dependence on kinetic energy for ion-molecule reactions in ammonia
Kinetic energy dependent charge transfer rates for ion-molecule reactions in ammonia, using cyclotron ejection and impulse methods
Elleman, D. D.↗
The effect of methane, ammonia, and silicates on the 3.07-micron ice absorption in interstellar grains
Methane, ammonia and silicate effects on 3.07 micron ice absorption in interstellar grains, using cesium iodide window deposited sample measurements
Donn, B.↗
Shapes and widths of ammonia lines collision-broadened by hydrogen.
Measurement of half-widths and shapes of several rotational lines in nu sub 2 bands of ammonia, collision-broadened by hydrogen. The measurements were made at room temperature with a spectral resolution of 0.15 per cm. Line intensities and self-broadened half-widths were also measured. From the line-intensity data, an estimate of S sub band = 600 plus or minus 30 per sq cm per atm has been derived for the absolute intensity of the pair of bands. Hydrogen-broadened half-widths of all the lines have been found to be equal to 0.075 plus or minus 0.004 per cm per atm. For all the lines measured, shapes of the lines in NH3-H2 collisions seem to conform to the super-Lorenz line shape proposed by Varanasi et al. (1972) for dipole quadrupole collisions.
Varanasi, P.↗
Rapid gas-phase reactions - The reaction of ammonia and the methylamines with boron trifluoride. III - Pressure dependence of rate constant.
A steady-state flow apparatus, shown earlier to be suitable for the study of rapid gas reactions, has been used to determine the pressure dependence of the relative quasi-bimolecular rate constants for the reactant pairs ammonia (AM)-trimethylamine (TMA) and dimethylamine (DMA)-trimethylamine in reaction with boron trifluoride. The pressure dependence of the former was determined in the range 0.03-75 torr and that of the latter in the range 0.02-720 torr.
Glicker, S.↗
Product distributions and rate constants for ion-molecule reactions in water, hydrogen sulfide, ammonia, and methane
The thermal energy, bimolecular ion-molecule reactions occurring in gaseous water, hydrogen sulfide, ammonia, and methane have been identified and their rate constants determined using ion cyclotron resonance methods. Absolute rate constants were determined for the disappearance of the primary ions by using the trapped ion method, and product distributions were determined for these reactions by using the cyclotron ejection method. Previous measurements are reviewed and compared with the results using the present methods. The relative rate constants for hydrogen-atom abstraction, proton transfer, and charge transfer are also determined for reactions of the parent ions.
Huntress, W. T., Jr.↗
The abundance of ammonia on Jupiter, Saturn and Titan
From recent spectra of Jupiter, Saturn and Titan in the 6450-A band of NH3, new values of the abundance of ammonia are derived for Jupiter and Saturn. NH3 abundances of 13 plus or minus 3 m-Am on Jupiter and 2 plus or minus 1 m-Am on Saturn were found. High resolution profiles of NH3 lines on Jupiter are used to estimate a pressure of 2.1 atm at the line formation level in the Jovian atmosphere. In the case of Titan, an NH3 abundance of less than 2 m-Am was found. The implications of these results are discussed.
Encrenaz, T.↗
Optical constants of solid ammonia in the infrared
No direct measurements of the refractive index for solid ammonia could be obtained because of failures in attempts to map the reflection spectrum. Kramers-Kronig techniques were, therefore, used in the investigation. The subtractive Kramers-Kronig techniques employed are similar to those discussed by Ahrenkiel (1971). The subtractive method provides a more-rapid convergence than the conventional techniques when data are available over a limited spectral range.
Robertson, C. W.↗
Ultraviolet optical constants of water and ammonia ices
A method reported by Tempelmeyer and Mills (1968) for the determination of real refractive indices of transparent films was used in the investigation. It was found that the fringe period for a transparent film can be used to approximate the period for a semitransparent film near its extremum. The experimental apparatus is discussed along with details regarding the employed technique. Graphs are presented concerning the refractive index and the absorption coefficients for amorphous water ice and amorphous ammonia ice.
Browell, E. V.↗
Shuttle ECLSS ammonia delivery capability
The possible effects of excessive requirements on ammonia flow rates required for entry cooling, due to extreme temperatures, on mission plans for the space shuttles, were investigated. An analysis of worst case conditions was performed, and indicates that adequate flow rates are available. No mission impact is therefore anticipated.
Source record↗
Measurement of hydrogen- and self-broadened half-widths of ammonia at 200 and 300 K
The hydrogen- and self-broadened half-widths have been measured for the (nu1 + nu2) and (nu2 + nu3) bands of ammonia at 300 and 207 K. Measurement of hydrogen-broadened widths has been restricted to J and K values not exceeding 6, but that of self-broadened widths is done for a few lines outside that range. Assuming a power-law dependence of half-width on temperature, the average value of the index alpha for the lines measured is found to be 0.57 for hydrogen broadening.
Margolis, J. S.↗
Spectral properties of hydrogen, helium, methane, and ammonia at thermal infrared wavelengths
The paper presents some results of a theoretical and laboratory program to determine the thermal infrared spectral properties of the principal gaseous constituents of the atmosphere of Jupiter. Birnbaum (1975) has measured laboratory spectra in the 16- to 1000-micron wavelength range for hydrogen and hydrogen-helium mixtures at Jovian temperatures. These are compared with theoretically computed spectra in order to determine the temperature dependence of the line strengths in the pressure-induced rotational band and the overlap parameters from the translational band. Existing spectral data for methane do not agree well with measurements of the nu 4 band at room temperature. A revised allocation of line intensities is proposed. Existing data for the nu 2 (10-micron) band of ammonia agree reasonably well with measurements at room temperature and at -77 C, but there are some important discrepancies which remain to be explained.
Taylor, F. W.↗
Ammonia-compatible elastomers and alloys
Study examines and reports positive findings from suitability tests of metal alloys, Inconel 718 and Ti-6A1-4V and elastomers, Ethylene propylene terpolymer rubbers, for utilization in storage vessels, fluid lines, and other system components subjected to continuous immersion in liquid anhydrous ammonia.
Bantrell, M. T.↗
Infrared heterodyne spectrometer measurements of vertical profile of tropospheric ammonia and ozone
Remote sensing of the concentration and vertical distribution of atmospheric gases has been carried out using a dual CO2 laser multichannel infrared heterodyne spectrometer (IHS). The high specificity and nearly quantum-noise-limited sensitivity of the IHS provide the capability of scanning individual signature lines of selected atmospheric constituents in the 9 to 11 micron region. A comprehensive investigation of the spectral overlap between CO2 laser local oscillator transitions and selected atmospheric constituents was performed; measurements of the atmospheric absorption of solar radiation from the ground were carried out at selected laser transitions for ammonia and ozone.
Peyton, B. J.↗
Analysis of the nu3 + nu4 band of ammonia
The 2-micron band of ammonia has been studied in the laboratory with a spectral resolution of 0.05/cm. Most of the strong lines, belonging to the nu3 + nu4 (perpendicular) band have been identified and spectroscopic constants have been derived.
Sarangi, S.↗
Effect of ammonia on Swiss albino mice
Times to incapacitation and death and LC /50/ values were determined for Swiss albino male mice exposed to different concentrations of ammonia in a 4.2 liter hemispherical chamber. The LC/50/ for a 30 minute exposure was 21,430 ppm.
Hilado, C. J.↗
Measurement of solar radiation at ground level in the region 1950-2150 A using ammonia actinometry
The use of ammonia as an actinometer for measurement of the solar flux in the region 1950-2150 A is presented. The solar flux was found to be 270 million photons/sq cm per sec at ground level in this wavelength interval in an area with minimum overhead ozone concentration. The advantages of this method over previously used methods are discussed, and the results are related to the present estimates of the tropospheric photodissociation rates for the freons CFCl3 and CF2Cl2 by radiation in this wavelength region.
Knoot, P.↗
A determination of Jovian ammonia abundance based on a 2 micron spectrum
A spectrum of Jupiter in the two-micron region has been analyzed to determine the Jovian ammonia abundance. The result is approximately 4 cm-amagat, assuming an airmass factor of 2.5 and a single effective reflecting layer for this wavelength. This is compared with the abundances observed at other wavelengths.
Sarangi, S.↗