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The Mars Phoenix Thermal Evolved-Gas Analysis: The Role of an Organic Free Blank in the Search for Organics

The Thermal Evolved-Gas Analyzer (TEGA) instrument onboard the 2007 Phoenix Lander will perform differential scanning calorimetry (DSC) and evolved-gas analysis of soil samples collected from the surface. Data from the instrument will be compared with Mars analog mineral standards, collected under TEGA Mars-like conditions to identify the volatile-bearing mineral phases [1] (e.g., Fe-oxyhydroxides, phyllosilicates, carbonates, and sulfates) found in the Martian soil. Concurrently, the instrument will be looking for indications of organics that might also be present in the soil. Organic molecules are necessary building blocks for life, although their presence in the ice or soil does not indicate life itself. The spacecraft will certainly bring organic contaminants to Mars even though numerous steps were taken to minimize contamination during the spacecraft assembly and testing. It will be essential to distinguish possible Mars organics from terrestrial contamination when TEGA instrument begins analyzing icy soils. To address the above, an Organic Free Blank (OFB) was designed, built, tested, and mounted on the Phoenix spacecraft providing a baseline for distinguishing Mars organics from terrestrial organic contamination. Our objective in this report is to describe some of the considerations used in selecting the OFB material and then report on the processing and analysis of the final candidate material

Lauer, H. V., Jr.↗

Aerothermodynamic Design of the Mars Science Laboratory Heatshield

Aerothermodynamic design environments are presented for the Mars Science Laboratory entry capsule heatshield. The design conditions are based on Navier-Stokes flowfield simulations on shallow (maximum total heat load) and steep (maximum heat flux, shear stress, and pressure) entry trajectories from a 2009 launch. Boundary layer transition is expected prior to peak heat flux, a first for Mars entry, and the heatshield environments were defined for a fully-turbulent heat pulse. The effects of distributed surface roughness on turbulent heat flux and shear stress peaks are included using empirical correlations. Additional biases and uncertainties are based on computational model comparisons with experimental data and sensitivity studies. The peak design conditions are 197 W/sq cm for heat flux, 471 Pa for shear stress, 0.371 Earth atm for pressure, and 5477 J/sq cm for total heat load. Time-varying conditions at fixed heatshield locations were generated for thermal protection system analysis and flight instrumentation development. Finally, the aerothermodynamic effects of delaying launch until 2011 are previewed.

Edquist, Karl T.↗

Carbon and Oxygen Stable Isotope Measurements of Martian Atmospheric CO2 by the Phoenix Lander

Precise stable isotope measurements of the CO2 in the martian atmosphere have the potential to provide important constraints for our understanding of the history of volatiles, the carbon cycle, current atmospheric processes, and the degree of water/rock interaction on Mars [1]. The isotopic composition of the martian atmosphere has been measured using a number of different methods (Table 1), however a precise value (<1%) has yet to be achieved. Given the elevated Delta(sup 13)C values measured in carbonates in martian meteorites [2-4] it has been proposed that the martian atmosphere was enriched in 13C [8]. This was supported by measurements of trapped CO2 gas in EETA 79001[2] which showed elevated Delta(sup 13)C values (Table 1). More recently, Earth-based spectroscopic measurements of the martian atmosphere have measured the martian CO2 to be depleted in C-13 relative to CO2 in the terrestrial atmosphere[ 7, 9-11]. The Thermal and Evolved Gas Analyzer (TEGA) instrument on the Mars Phoenix Lander [12] included a magnetic-sector mass spectrometer (EGA) [13] which had the goal of measuring the isotopic composition of martian atmospheric CO2 to within 0.5%. The mass spectrometer is a miniature instrument intended to measure both the martian atmosphere as well as gases evolved from heating martian soils.

Niles, Paul B.↗

Abundances of Jupiter's Trace Hydrocarbons from Voyager and Cassini

The flybys of Jupiter by the Voyager spacecraft in 1979, and over two decades later by Cassini in 2000, have provided us with unique datasets from two different epochs, allowing the investigation of seasonal change in the atmosphere. In this paper we model zonal averages of thermal infrared spectra from the two instruments, Voyager 1 IRIS and Cassini CIRS, to retrieve the vertical and meridional profiles of temperature, and the abundances of the two minor hydrocarbons, acetylene (C2H2) and ethane (C2H6). The spatial variation of these gases is controlled by both chemistry and dynamics, and therefore their observed distribution gives us an insight into both processes, We find that the two gases paint quite different pictures of seasonal change. Whilst the 2-D cross-section of C2H6 abundance is slightly increased and more symmetric in 2000 (northern summer solstice) compared to 1979 (northern fall equinox), the major trend of equator to pole increase remains. For C2H2 on tile other hand, the Voyager epoch exhibits almost no latitudinal variation, whilst the Cassini era shows a marked decrease polewards in both hemispheres. At the present time, these experimental findings are in advance of interpretation, as there are no published models of 2-D Jovian seasonal chemical variation available for comparison.

Nixon, C. A.↗

A Possible Organic Contribution to the Low Temperature CO2 Release Seen in Mars Phoenix Thermal and Evolved Gas Analyzer Data

Two of the most important discoveries of the Phoenix Mars Lander were the discovery of approx.0.6% perchlorate [1] and 3-5% carbonate [2] in the soils at the landing site in the martian northern plains. The Thermal and Evolved Gas Analyzer (TEGA) instrument was one of the tools that made this discovery. After soil samples were delivered to TEGA and transferred into small ovens, the samples could be heated up to approx.1000 C and the gases that evolved during heating were monitored by a mass spectrometer. A CO2 signal was detected at high temperature (approx.750 C) that has been attributed to calcium carbonate decomposition. In addition to this CO2 release, a lower temperature signal was seen. This lower temperature CO2 release was postulated to be one of three things: 1) desorption of CO2, 2) decomposition of a different carbonate mineral, or 3) CO2 released due to organic combustion. Cannon et al. [3] present another novel hypothesis involving the interaction of decomposition products of a perchlorate salt and calcium carbonate.

Archer, P. D. Jr.↗

NASA/Goddard Thermal Technology Overview 2014

This presentation summarizes the current plans and efforts at NASA Goddard to develop new thermal control technology for anticipated future missions. It will also address some of the programmatic developments currently underway at NASA, especially with respect to the Technology Development Program at NASA. While funding for basic technology development is still scarce, significant efforts are being made in direct support of flight programs. New technology development continues to be driven by the needs of future missions, and applications of these technologies to current Goddard programs will be addressed. Many of these technologies also have broad applicability to DOD, DOE, and commercial programs. Partnerships have been developed with the Air Force, Navy, and various universities to promote technology development. In addition, technology development activities supported by internal research and development (IRAD) program, the Small Business Innovative Research (SBIR) program, and the NASA Engineering and Safety Center (NESC), are reviewed in this presentation. Specific technologies addressed include; two-phase systems applications and issues on NASA missions, latest developments of electro-hydrodynamically pumped systems, development of high electrical conductivity coatings, and various other research activities. New Technology program underway at NASA, although funding is limited center dot NASA/GSFC's primary mission of science satellite development is healthy and vibrant, although new missions are scarce - now have people on overhead working new missions and proposals center dot Future mission applications promise to be thermally challenging center dot Direct technology funding is still very restricted - Projects are the best source for direct application of technology - SBIR thermal subtopic resurrected in FY 14 - Limited Technology development underway via IRAD, NESC, other sources - Administrator pushing to revive technology and educational programs at NASA - new HQ directorate established

Cooling↗

Remote Recession Sensing of Ablative Heat Shield Materials

Material recession and charring are two major processes determining the performance of ablative heat shield materials. Even in ground testing, the characterization of these two mechanisms relies on measurements of material thickness before and after testing, thus providing only information integrated over the test time. For recession measurements, optical methods such as imaging the sample surface during testing are under investigation but require high alignment and instrument effort, therefore being not established as a standard measurement method. For char depth measurements, the most common method so far consists in investigation of sectioned samples after testing or in the case of Stardust where core extractions were performed to determine char information. In flight, no reliable recession measurements are available, except total recession after recovering the heat shield on ground. Developments of mechanical recession sensors have been started but require substantial on board instrumentation adding mass and complexity. In this work, preliminary experiments to evaluate the feasibility of remote sensing of material recession and possibly char depth through optically observing the emission signatures of seeding materials in the post shock plasma is investigated. It is shown that this method can provide time resolved recession measurements without the necessity of accurate alignment procedures of the optical set-up and without any instrumentation on board of a spacecraft. Furthermore, recession data can be obtained without recovering flight hardware which would be a huge benefit for inexpensive heat shield material testing on board of small re-entry probes, e.g. on new micro-satellite re-entry probes as a possible future application of Cubesats or RBR

instrumentation↗

Reconciling the Differences between the Measurements of CO2 Isotopes by the Phoenix and MSL Landers

Precise stable isotope measurements of the CO2 in the martian atmosphere have the potential to provide important constraints for our understanding of the history of volatiles, the carbon cycle, current atmospheric processes, and the degree of water/rock interaction on Mars. There have been several different measurements by landers and Earth based systems performed in recent years that have not been in agreement. In particular, measurements of the isotopic composition of martian atmospheric CO2 by the Thermal and Evolved Gas Analyzer (TEGA) instrument on the Mars Phoenix Lander and the Sample Analysis at Mars (SAM) instrument on the Mars Science Laboratory (MSL) are in stark disagreement. This work attempts to use measurements of mass 45 and mass 46 of martian atmospheric CO2 by the SAM and TEGA instruments to search for agreement as a first step towards reaching a consensus measurement that might be supported by data from both instruments.

Niles, P. B.↗

TIRS Cryocooler: Spacecraft Integration and Test and Early Flight Data

The Thermal Infrared Sensor (TIRS) is an instrument on Landsat 8, launched in February 2013. The focal plane is cooled by a two-stage Ball Aerospace Stirling cycle cryocooler, with a coldfinger operating at 40K. This paper describes events during the spacecraft integration and test program, and results from early orbit operation of the cryocooler.

Boyle, R.↗

Small Rocket/Spacecraft Technology (SMART) Platform

The NASA Goddard Space Flight Center (GSFC) and the Department of Defense Operationally Responsive Space (ORS) Office are exercising a multi-year collaborative agreement focused on a redefinition of the way space missions are designed and implemented. A much faster, leaner and effective approach to space flight requires the concerted effort of a multi-agency team tasked with developing the building blocks, both programmatically and technologically, to ultimately achieve flights within 7-days from mission call-up. For NASA, rapid mission implementations represent an opportunity to find creative ways for reducing mission life-cycle times with the resulting savings in cost. This in tum enables a class of missions catering to a broader audience of science participants, from universities to private and national laboratory researchers. To that end, the SMART (Small Rocket/Spacecraft Technology) micro-spacecraft prototype demonstrates an advanced avionics system with integrated GPS capability, high-speed plug-and-playable interfaces, legacy interfaces, inertial navigation, a modular reconfigurable structure, tunable thermal technology, and a number of instruments for environmental and optical sensing. Although SMART was first launched inside a sounding rocket, it is designed as a free-flyer.

Esper, Jaime↗

Detailed Design of an Earth Entry Vehicle for Comet Surface Sample Return

The 2013 Decadal Survey for New Frontiers missions identifies several high-value science missions, including Comet Surface Sample Return (CSSR). A CSSR mission will advance the scientific community's fundamental understanding of the origin of the solar system and the contribution of comets to the volatile inventory of the Earth. An entry capsule, or earth entry vehicle (EEV), is be required to protect the scientific payload from the extreme conditions of atmospheric entry, descent, and landing. The Decadal Survey Mission Concept Study along with an APL (Johns Hopkins University Applied Physics Lab) 2007-2008 Comet Surface Sample Mission Study details several of the driving requirements for a CSSR EEV; these include a payload volume and mass and inertial entry velocity of 9 kilometers per second. The mission concept study selected a Multi-Mission Earth Entry Vehicle (MMEEV) design concept derived from the Mars Sample Return (MSR) entry capsule design because of its increased reliability over a parachute-based vehicle. This presentation will explore detailed design of a CSSR-capable Earth Entry Vehicle, including trajectories, aeroheating predictions and associated thermal protection system masses, and onboard instrumentation for entry science.

Trajectory Analysis↗

Working Fluid Trade Study for a Two-Phase Mechanically Pumped Loop Thermal Control System

NASA Jet Propulsion Laboratory is investigating a two-phase mechanically pumped fluid loop (MPFL) technology for spacecraft thermal control for future planetary space science mission concepts. The two-phase technology combines the potential of single-phase MPFL and the passive two-phase heat pipe systems. Previous two-phase MPFL studies at JPL have identified an evaporator system with a separated flow architecture as providing a robust light mass thermal control system with very high spatial and temporal thermal stability required by the science instruments on these missions. These studies have further identified the thermophysical properties of the working fluid to be key to the performance of a two-phase fluid loop. This paper describes the methodology used in the selection of the working fluids for optimizing the performance of the two-phase MPFL. A high level model was developed that includes the constraints and boundaries driven by the system components. The performance of fluids from the REFPROP database are investigated and rated for this system. The working fluid attributes such as cost, hazardous properties, and heritage were taken into account in this selection. A typical spacecraft dissipating 1000 W and a fluid loop consisting of an evaporator, accumulator, radiator, and associated tubing components is used as an example in this study.

Daimaru, Takuro↗

Working Fluid Trade Study for a Two-Phase Mechanically Pumped Loop Thermal Control System

NASA Jet Propulsion Laboratory is investigating a two-phase mechanically pumped fluid loop (MPFL) technology for spacecraft thermal control for future planetary space science mission concepts. The two-phase technology combines the potential of single-phase MPFL and the passive two-phase heat pipe systems. Previous two-phase MPFL studies4,5 at JPL have identified an evaporator system with a separated flow architecture as providing a robust light mass thermal control system with very high spatial and temporal thermal stability required by the science instruments on these missions. These studies have further identified the thermophysical properties of the working fluid to be key to the performance of a two-phase fluid loop. This paper describes the methodology used in the selection of the working fluids for optimizing the performance of the two-phase MPFL. A high level model was developed that includes the constraints and boundaries driven by the system components. The performance of fluids from the REFPROP database were investigated and rated for this system. The working fluid attributes such as cost, hazardous properties, and heritage were taken into account in this selection. A typical spacecraft dissipating 1000 W and a fluid loop consisting of an evaporator, accumulator, radiator, and associated tubing components was used as an example in this study.

Daimaru, Takuro↗

Maintenance-optimized Modular Robotic Concepts for Planetary Surface ISRU Excavators

Modular robotic concepts are identified and evaluatedover the design and operations/maintenance lifecycle forautonomous Lunar, Mars, and partial gravity planetary surfaceexcavation and in-situ earthworks equipment. In-Situ ResourceUtilization (ISRU) is the exploitation of available resources at thesite of a landed spacecraft on the surface of another planetary body.It is intended that this ISRU excavator concept be capable ofmaterial extraction from native regolith, and will be able to operatein a variety of planetary surface environments after initial shakedownon the moon. Using heritage from highly multi-functional,reconfigurable robotic systems like the All-Terrain Hex-LimbedExtra-Terrestrial Explorer (ATHLETE), Regolith AdvancedSurface Systems Operations Robot (RASSOR), and Marsexploration rovers, we propose a flexible maintenance-optimizedmobility platform concept with quick-connect/disconnect featuresfor robotically swappable excavation implements. Dust toleranttorque transmission, power & data docking, thermal fluidconnectors, and modular avionics and instrumentation will allow forautonomous swapping of tools, replacement of spares, and longtermmaintenance of robotic excavators. The architecture includesmodular tools for conventional excavate / scoop / haul / dump /process functions of a terrestrial mining operation on Earth, but alsowill have the capability to operate and robotically maintain itselfwithout human intervention. The concepts described in this studywill provide a suite of technologies, configurations, and operationsready for inclusion into a final flight-ready excavator system.

Schuler, Jason↗

Lessons Learned from Aerothermal Flight Data on NASA Mars Entry Vehicles

The NASA Mars Science Laboratory (MSL) and Mars 2020 entry vehicles included temperature measurements inside and direct heat flux on the surface of the thermal protection system (TPS) material. The instrumentation was included to begin addressing predictive capabilities for aerodynamic heating and ablative TPS material response. The MSL aeroshell included temperature measurements at seven heatshield locations, from which total aerodynamic heating was reconstructed. The Mars 2020 instrumentation suite included eleven heatshield measurement locations and new backshell measurements at nine locations: six with temperature sensors, two with sensors to directly measure total heat flux, and one to measure radiative heat flux. Both instrumentation suites returned full sets of data, with all temperature sensors nearest to the surface surviving entry, indicating minimal material recession. Heatshield boundary layer transition (BLT) was observed for both vehicles prior to the time of peak heating, with transition starting near the shoulder and progressing towards the stagnation area. MSL’s higher speed on approach to Mars resulted in higher total heating compared to Mars 2020, with the maximum occurring near the heatshield’s leeside shoulder. The Mars 2020 backshell heating data indicate significant contributions from shock layer radiation. Heating from Navier-Stokes flowfield calculations are in family with reconstructed heating. The paper covers the instrumentation, BLT and reconstructed heating on both heatshields, backshell heating for Mars 2020, TPS performance, and predicted versus reconstructed heat fluxes. Opportunities for improved design approaches for future Mars missions are discussed, especially for the upcoming Mars Sample Return mission.

Mars Science Laboratory↗

Lessons Learned from Aerothermal Flight Data on NASA Mars Entry Vehicles

The NASA Mars Science Laboratory (MSL) and Mars 2020 entry vehicles included temperature measurements inside and direct heat flux on the surface of the thermal protection system (TPS) material. The instrumentation was included to begin addressing predictive capabilities for aerodynamic heating and ablative TPS material response. The MSL aeroshell included temperature measurements at seven heatshield locations, from which total aerodynamic heating was reconstructed. The Mars 2020 instrumentation suite included eleven heatshield measurement locations and new backshell measurements at nine locations: six with temperature sensors, two with sensors to directly measure total heat flux, and one to measure radiative heat flux. Both instrumentation suites returned full sets of data, with all temperature sensors nearest to the surface surviving entry, indicating minimal material recession. Heatshield boundary layer transition (BLT) was observed for both vehicles prior to the time of peak heating, with transition starting near the shoulder and progressing towards the stagnation area. MSL’s higher speed on approach to Mars resulted in higher total heating compared to Mars 2020, with the maximum occurring near the heatshield’s leeside shoulder. The Mars 2020 backshell heating data indicate significant contributions from shock layer radiation. Heating from Navier-Stokes flowfield calculations are in family with reconstructed heating. The paper covers the instrumentation, BLT and reconstructed heating on both heatshields, backshell heating for Mars 2020, TPS performance, and predicted versus reconstructed heat fluxes. Opportunities for improved design approaches for future Mars missions are discussed, especially for the upcoming Mars Sample Return mission.

Mars Science Laboratory↗

MODIS TEB Electronic Crosstalk Correction Update and Impact on L1B Product Uncertainty

The MODIS instruments onboard the Terra and Aqua satellites have been in operation for over22 and 20 years, respectively. The instruments’ calibration accuracy has been maintained, even with instrument degradation. Electronic crosstalk in the thermal emissive bands (TEB) is a known issue with an increasing impact on the calibration and product. The Terra MODIS photovoltaic (PV) longwave infrared (LWIR) bands crosstalk corrections have been applied in Collection 6.1 (C6.1). However, the electronic crosstalk contamination for some detectors in the mid-wave infrared (MWIR) bands and the Aqua PVLWIR bands affect the Level-1B (L1B) product’s measurement accuracy and image quality. In Collection 7 (C7), crosstalk corrections for select detectors in the Terra and Aqua MWIR and Aqua PV LWIR bands are applied. The entire mission crosstalk coefficients for the select detectors and bands are derived from scheduled lunar observations and populated in the form of look-up tables (LUTs). The Aqua PV-LWIR bands exhibit similar downward crosstalk trends as the Terra PV-LWIR bands, especially in recent years. The crosstalk coefficients and their trends provide a guideline for the correction application. Earth measurement analyses before and after the correction provide contamination and correction assessments. It has been shown that the product quality is enhanced with the crosstalk correction applied in C7. For C7, the crosstalk coefficient uncertainty is derived from the fit residuals between the measured values and a linear fit over a three-year sliding window. The uncertainty propagation is modeled and applied in the total uncertainty calculation intheL1B product. The TEB electronic crosstalk LUTs have been processed over the entire Terra and Aqua MODIS missions. This paper presents the C7 crosstalk correction, as well as its assessment and uncertainty propagation algorithm to the TEB uncertainty.

Tiejun Chang↗