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At least 829 records · Page 46

Atmospheric water on Mars, energy estimates for extraction

The Mars atmosphere is considered as a resource for water to support a human expedition. Information obtained from the Viking mission is used to estimate the near-surface water vapor level. The variability over the diurnal cycle is examined and periods of greatest water abundance are identified. Various methods for extracting atmospheric water are discussed including energy costs and the means for optimizing water extraction techniques.

Meyer, Tom↗

Integrating Water Supply Constraints into Irrigated Agricultural Simulations of California

Simulations of irrigated croplands generally lack key interactions between water demand from plants and water supply from irrigation systems. We coupled the Water Evaluation and Planning system (WEAP) and Decision Support System for Agrotechnology Transfer (DSSAT) to link regional water supplies and management with field-level water demand and crop growth. WEAP-DSSAT was deployed and evaluated over Yolo County in California for corn, rice, and wheat. WEAP-DSSAT is able to reproduce the results of DSSAT under well-watered conditions and reasonably simulate observed mean yields, but has difficulty capturing yield interannual variability. Constraining irrigation supply to surface water alone reduces yields for all three crops during the 1987-1992 drought. Corn yields are reduced proportionally with water allocation, rice yield reductions are more binary based on sufficient water for flooding, and wheat yields are least sensitive to irrigation constraints as winter wheat is grown during the wet season.

Agriculture; Irrigation; Water Resources Managemen↗

Aconcagua Basin Agriculture: Analyzing Hydrological Norms, Evapotranspiration, and Soil Moisture to Assess Crop Water Demand and Water Usage in Chile’s Aconcagua River Basin

The Aconcagua basin has experienced a prolonged drought since 2010, posing a significant concern to the agricultural sector, which contributes to 12% of the national agriculture output. Reduced precipitation and warmer conditions have led to water constraints for agricultural activities. As the agriculture sector relies more on irrigation, there has been a decline in surface water availability and a shrinking groundwater supply, both primarily sourced from snow and glacial melt. This study focuses on evaluating crop water demand and water usage in the Aconcagua Basin, leveraging in-situ and available satellite data from Aqua and Terra Moderate Resolution Imaging Spectroradiometer (MODIS), 1-km downscaled Soil Moisture Active Passive (SMAP), Global Precipitation Measurement Mission IMERG (GPM), and Landsat 8 Operational Land Imager (OLI). Remote sensing hydrologic norms from pre- and intra-drought conditions provided a baseline for our water use analysis. We have identified areas of the basin where water usage is exaggerated compared to other regions by analyzing soil moisture, evapotranspiration, and vegetation index trends across agricultural lands. The study highlights the presence of irrigation and exaggerated water usage categorized by crop type while normalizing the data by the quantity of water allocation (m3/s) to each subregion. The findings have the potential to assist our partners, the Centro de Información de Recursos Naturales (CIREN) and the Ministry of Agriculture, in refining water allocation approaches; showcasing the feasibility of leveraging remote sensing and earth observation datasets to monitor agricultural practices within the context of water scarcity.

Remote sensing↗

Relevant satellites for the WEF Nexus

This presentation provides an overview of Earth observation satellites relevant to water management issues. It discusses precipitation the most as this is the most mature measurement, but others such as surface water extent, snowpack, and ground water are also mentioned. As well, practicalities of using satellite data are raised and URLs for the various datasets are summarized.

WEF Nexus↗

Forensic tracers of exposure to produced water in freshwater mussels: a preliminary assessment of Ba, Sr, and cyclic hydrocarbons

Hydraulic fracturing is often criticized due in part to the potential degradation of ground and surface water quality by high-salinity produced water generated during well stimulation and production. This preliminary study evaluated the response of the freshwater mussel, Elliptio complanata, after exposure to produced water. A limited number of adult mussels were grown over an 8-week period in tanks dosed with produced water collected from a hydraulically fractured well. The fatty tissue and carbonate shells were assessed for accumulation of both inorganic and organic pollutants. Ba, Sr, and cyclic hydrocarbons indicated the potential to accumulate in the soft tissue of freshwater mussels following exposure to diluted oil and gas produced water. Exposed mussels showed accumulation of Ba in the soft tissue several hundred times above background water concentrations and increased concentrations of Sr. Cyclic hydrocarbons were detected in dosed mussels and principle component analysis of gas chromatograph time-of-flight mass spectrometer results could be a novel tool to help identify areas where aquatic organisms are impacted by oil and gas produced water, but larger studies with greater replication are necessary to confirm these results.

54 ENVIRONMENTAL SCIENCES↗

Search for Chemically Bound Water in the Surface Layer of Mars Based on HEND/Mars Odyssey Data

This study is emphasized on search for signatures of chemically bound water in surface layer of Mars based on data acquired by High Energy Neutron Detector (HEND) which is part of the Mars Odyssey Gamma Ray Spectrometer (GRS). Fluxes of epithermal (probe the upper 1-2 m) and fast (the upper 20-30 cm) neutrons, considered in this work, were measured since mid February till mid June 2002. First analysis of this data set with emphasis of chemically bound water was made. Early publications of the GRS results reported low neutron flux at high latitudes, interpreted as signature of ground water ice, and in two low latitude areas: Arabia and SW of Olympus Mons (SWOM), interpreted as 'geographic variations in the amount of chemically and/or physically bound H2O and or OH...'. It is clear that surface materials of Mars do contain chemically bound water, but its amounts are poorly known and its geographic distribution was not analyzed.

Basilevsky, A. T.↗

Water Indicators in Sirenum Terra and Around the Argyre Impact Basin, Mars

This study examines the relationships between three temporally distinct indicators of water on Mars: ancient craters with fluidized ejecta, relatively more recent gullies inside those craters, and current abundance of near surface hydrogen around those craters. We find an association between gully occurrence and large-scale geologic features; analysis indicates unique depth/diameter ratios for gullied craters in Sirenum Terra. Numerical comparisons of fluidized and non-fluidized, gullied and non-gullied craters suggest that the Argyre region could have had a near-surface water table that receded before recent times, while Sirenum Terra may have had an ancient water table that persists to this day.

Stern, J. G.↗

Data Assimilation of Terrestrial Water Storage to Adjust Precipitation Fluxes

The Gravity Recovery and Climate Experiment (GRACE) mission has provided unprecedented observations of terrestrial water storage (TWS) dynamics at basin to continental scales. TWS is defined as the sum of groundwater, soil moisture, snow, surface water, ice and biomass water. Data assimilation of GRACE TWS observations has been shown to improve simulation of groundwater, streamflow, and snow water equivalent, and has also proven useful for drought monitoring and identifying human impacts on the water cycle. From a modeling perspective, the TWS components are defined as "prognostic hydrological states". Existing GRACE data assimilation schemes update these prognostic states directly. In this work, we propose an alternate approach in which precipitation fluxes are adjusted in order to achieve the desired change in the hydrological prognostic states. Limitations of such an approach include the assumption that all errors in TWS originate from errors in precipitation. Nonetheless, benefits comprise (1) the water balance is maintained, as opposed to having to add increments to the water budget components, (2) the model automatically determines how to distribute the updates among the TWS prognostic states, and (3) it is not necessary to know the exact time of the observation TWS, because the TWS change timing is determined by the precipitation forcing.

Girotto, Manuela↗

Carbon dioxide catastrophes: Past and future menace

Carbon dioxide is important in its role as coupler of the terrestrial biosphere to inorganic chemical processes and as the principal greenhouse gas controlling Earth's surface temperature. The hypothesis that atmospheric CO2 levels have diminished with time, with the resulting cooling effect offsetting an increase in the solar constant, seems firmly established, and it is shown that feedback mechanisms exist which can maintain the terrestrial surface in a relatively narrow temperature range over geological time. Of the factors involved in such CO2 variation, the oceanic reservoir appears the most important. Surface waters are probably in approximate equilibrium with regard to CO2 exchange with the ambient atmosphere in most regions, but data from deep-ocean water sampling indicates that such waters are somewhat undersaturated in the sense that they would tend to absorb CO2 from the atmosphere if brought to the surface without change in composition or temperature. If major impacts into the ocean can result in loss of a substantial portion of the atmospheric CO2 reservoir, then any such future event could imperil the continuation of most higher forms of life on Earth. The most likely candidate for an inverse Nyos global event in previous Earth history is the Cretaceous-Tertiary terminal extinction event. The Cretaceous was characterized by warm, equable temperatures presumably indicative of relatively high CO2 levels and an intense greenhouse heating. Cooling of the oceans in absence of massive transfer of CO2 to the oceanic reservoir in itself would promote a condition of CO2 undersaturation in abyssal waters, and this is made even more extreme by the pattern of ocean water circulation. It is possible to envision a situation in which deep ocean waters were at least occasionally profoundly undersaturated with regard to CO2. Turnover of a major fraction of such an ocean would then remove, on a very short time scale, as much as 90 percent of the atmospheric CO2 inventory.

Baur, Mario E.↗

Evaluating Rock Pool Hydroperiod Fluctuation using Climate Variables to Inform Habitat Monitoring and Protection in the Western Sonoran Desert

As warming and drying trends continue to impact the greater American Southwest, effective ecosystem management increasingly relies upon understanding the relationships between climate and water resources. Ephemeral freshwater rock pools, known as tinajas, have great ecological and cultural importance as some of the only sources of surface water in the western Sonoran Desert (WSD). Tinaja flooding and drying cycles, known as hydroperiods, vary based on meteorologic and climatologic conditions; however, a lack of extensive research relating climatic impacts to tinajas puts these critical ecosystems further at risk. Tinajas throughout the WSD are monitored by the National Park Service (NPS) using resource intensive strategies including in situ trail camera observation and direct measurement. To aid NPS monitoring efforts, this research used remotely sensed climate data to analyze spatiotemporal climate trends and relationships between climate variables and tinaja hydroperiods in the WSD between 1979–2022. Using Aqua and Terra Moderate Resolution Imaging Spectroradiometers (MODIS), University of Idaho Gridded Surface Meteorological Dataset (gridMET), and OpenET data, the project analyzed land surface temperature, evapotranspiration, precipitation, wind velocity, and solar radiation. The team generated climate anomaly time series and climate normal maps for the WSD, identifying statistically significant spatial and temporal trends. These data were then compared to daily, qualitative in situ hydroperiod observations taken between 2019–2022. This work will be used by the NPS to inform the monitoring and protection of tinajas in the WSD. Findings contribute to a limited body of research concerning climate and tinajas, which are often overlooked despite their disproportionate ecological importance.

Annie Britton↗

The general circulation and meridional heat transport of the subtropical South Atlantic determined by inverse methods

The circulation and meridional heat transport of the subtropical South Atlantic Ocean are determined through the application of the inverse method of Wunsch (1978) to hydrographic data from the IGY and METEOR expeditions. Meridional circulation results of the two data sets agree on a northward mass transport of about 20 million metric tons/sec for waters above the North Atlantic Deep Water (NADW), and a comparable southward transport of deep waters. Additional gross features held in common are the Benguela, South Equatorial and North Brazilian Coastal currents' northward transport of the Surface Water, and the deflection of the southward-flowing NADW from the South American Coast into the mid ocean by a seamount chain near 20 deg S. Total heat transport is equatorward, with a magnitude of 0.8 X 10 to the 15th W near 30 deg S and indistinguishable from zero near 8 deg S.

Fu, L.-L.↗

The plume of the Yukon River in relation to the oceanography of the Bering Sea

The ecosystem of the northern Bering-Sea shelf was studied using data from the NOAA Very High Resolution Radiometer and AVHRR and the Landsat MSS and Thematic Mapper (TM) in conjunction with shipboard measurements. Emphasis was placed on the influence of the Yukon River on this inner shelf environment and on the evaluation of the utility of the new Landsat TM data for oceanography. It was found that the patterns of water mass distribution obtained from satellite images agreed reasonably well with the areal patterns of temperature, salinity, and phytoplankton distributions. The AVHRR, MSS, and TM data show that the Yukon-River discharge is warmer and more turbid than the surrounding coastal water that originates to the south; thus, the Yukon water contributes to the higher temperatures and lower transmissivity of the coastal water. The high resolution of the TM thermal IR band made it possible to observe complex patterns and structures in the surface water that could not be resolved on previous data sets.

Dean, Kenneson G.↗

Stable isotopic biogeochemistry of carbon and nitrogen in a perennially ice-covered Antarctic lake

Lake Hoare (77 degrees 38' S, 162 degrees 53' E) is an amictic, oligotrophic, 34-m-deep, closed-basin lake in Taylor Valley, Antarctica. Its perennial ice cover minimizes wind-generated currents and reduces light penetration, as well as restricts sediment deposition into the lake and the exchange of atmospheric gases between the water column and the atmosphere. The biological community of Lake Hoare consists solely of microorganisms -- both planktonic populations and benthic microbial mats. Lake Hoare is one of several perennially ice-covered lakes in the McMurdo Dry Valleys that represent the end-member conditions of cold desert and saline lakes. The dry valley lakes provide a unique opportunity to examine lacustrine processes that operate at all latitudes, but under an extreme set of environmental conditions. The dry valley lakes may also offer a valuable record of catchment and global changes in the past and present. Furthermore, these lakes are modern-day equivalents of periglacial lakes that are likely to have been common during periods of glacial maxima at temperate latitudes. We have analyzed the dissolved inorganic carbon (DIC) of Lake Hoare for delta 13C and the organic matter of the sediments and sediment-trap material for delta 13C and delta 15N. The delta 13C of the DIC indicates that 12C is differentially removed in the shallow, oxic portions of the lake via photosynthesis. In the anoxic portions of the lake (27-34 m) a net addition of 12C to the DIC pool occurs via organic matter decomposition. The dissolution of CaCO3 at depth also contributes to the DIC pool. Except near the Canada Glacier where a substantial amount of allochthonous organic matter enters the lake, the organic carbon being deposited on the lake bottom at different sites is isotopically similar, suggesting an autochthonous source for the organic carbon. Preliminary inorganic carbon flux calculations suggest that a high percentage of the organic carbon fixed in the water column is remineralized as it falls through the water column. At nearby Lake Fryxell, the substantial (relative to Lake Hoare) glacial meltstream input overprints Fryxell's shallow-water biological delta 13C signal with delta 13C-depleted DIC. In contrast, Lake Hoare is not significantly affected by surface-water input and mixing, and therefore the delta 13C patterns observed arise primarily from biological dynamics within the lake. Organic matter in Lake Hoare is depleted in 15N, which we suggest is partially the result of the addition of relatively light inorganic nitrogen into the lake system from terrestrial sources.

NASA Program Exobiology↗

Modelling Freshwater Resources at the Global Scale: Challenges and Prospects

Quantification of spatially and temporally resolved water flows and water storage variations for all land areas of the globe is required to assess water resources, water scarcity and flood hazards, and to understand the Earth system. This quantification is done with the help of global hydrological models (GHMs). What are the challenges and prospects in the development and application of GHMs? Seven important challenges are presented. (1) Data scarcity makes quantification of human water use difficult even though significant progress has been achieved in the last decade. (2) Uncertainty of meteorological input data strongly affects model outputs. (3) The reaction of vegetation to changing climate and CO2 concentrations is uncertain and not taken into account in most GHMs that serve to estimate climate change impacts. (4) Reasons for discrepant responses of GHMs to changing climate have yet to be identified. (5) More accurate estimates of monthly time series of water availability and use are needed to provide good indicators of water scarcity. (6) Integration of gradient-based groundwater modelling into GHMs is necessary for a better simulation of groundwater-surface water interactions and capillary rise. (7) Detection and attribution of human interference with freshwater systems by using GHMs are constrained by data of insufficient quality but also GHM uncertainty itself. Regarding prospects for progress, we propose to decrease the uncertainty of GHM output by making better use of in situ and remotely sensed observations of output variables such as river discharge or total water storage variations by multi-criteria validation, calibration or data assimilation. Finally, we present an initiative that works towards the vision of hyper resolution global hydrological modelling where GHM outputs would be provided at a 1-km resolution with reasonable accuracy.

Global hydrological model↗

Experimental Characterization of Additively Manufactured Nickel-Titanium Shape Memory Alloy Heat Pipes

Shape memory alloys (SMA) have been identified for use in spacecraft components as replacement for conventional deployment mechanisms. They may be used in thermal management components such as radiators to create self-deploying radiators. One SMA, NiTi, has also been developed for additive manufacturing processes. Heat pipes are a common way to create highly effective and lightweight spaceflight radiators, and heat pipes can also be made from NiTi and related alloys. The wick is the critical element of a functioning heat pipe, and recent progress over the past years has led to the development of additively manufactured heat pipe wicks in various materials. The combination of these efforts is the focus of this project: creating an additively manufactured, shape memory alloy self-deploying heat pipe radiator. This paper will focus on the experimental characterization of these additively manufactured NiTi heat pipes. The heat pipe coupons were additively manufactured by direct metal laser sintering (DMLS), with an integral liquid cooled condenser. Heat is input to the heat pipe via a thin film heater. Thermocouples were spot welded to the heat pipes to measure temperature at several axial locations. The heat pipes were tested with two working fluids: water and ethanol. Ethanol is not an ideal working fluid for heat pipes but is useful in characterizing them because it wets well to a wide variety of surfaces. Water is in general a superior working fluid for heat pipes, but its contact angle and therefore wicking performance strongly depends on the surface chemistry of the surface it is in contact with. A particular measurement of interest in this test is the evaporator to condenser thermal conductance, which will be compared in the full paper to recently published correlations for additively manufactured heat pipes. Experimental results for two straight geometry and one bellows geometry heat pipe will be presented. The bellows geometry is of interest for condenser of the self-deploying radiator design.

Additive manufacturing↗

Enhancement of a global lake and reservoir database to aid climate studies and resource monitoring utilizing satellite radar altimetry

Here, we describe the expansion and enhancement of a large (surface area ≥100 sq. km) lake and reservoir database (1.GREALD). These efforts have also resulted in the spin-off of two additional databases, one containing lakes and reservoirs (2.GREALD, area 10–99 sq. km), and the other containing ephemeral lakes (3.GELD, area ≥100 sq. km). These databases are unique sources for projects that utilize satellite radar altimeter data to monitor surface water levels. While 1.GREALD aims to be a complete catalog, 2.GREALD focuses on reservoirs in response to applied sciences programs that monitor water and energy resources. The creation of 3.GELD has climate change objectives as well as water resources and ecosystem conservation applications. The recording of information pertaining to the potential overpasses (waterbody crossings) of the current and archive satellite altimeters is a primary objective as is the need to highlight any form of controlled water level variation. The permanent water databases now contain 6282 entries, half experience some form of anthropogenic influence and ∼430 have been identified as potential climatically sensitive terminal lakes. The revised integral surface area distribution is a power law with exponent −1.016. Statistics reveal that with altimetric repeat visit times of 10-day to monthly, at least 80% of the permanent water bodies (≥10 sq. km) have been overflown at some period since the 1990s. Current information on water use and reservoir formation date show that the primary use of the reservoir class is hydroelectric power, and that China, Brazil, India, Turkey, and Vietnam dominate the dam building in recent decades.

Charon M. Birkett↗

Ethane Dehydrogenation on Single and Dual Centers of Ga-modified γ-Al 2 O 3

Density-functional theory calculations and microkinetic analysis are used to investigate the efficacy of Ga-modified γ-Al 2 O 3 (110) surfaces for the catalytic dehydrogenation of ethane and elucidate the synergy between Ga and Al sites. The model surfaces are modified by either Ga grafting or doping. We consider and analyze numerous active sites and rank them using microkinetic analysis. The kinetic parameters obtained from microkinetic modelling are compared with experimental values for ethane dehydrogenation over Ga 2 O 3 -Al 2 O 3 mixed oxides prepared by co-precipitation. The dominant reaction pathway proceeds via heterolytic C-H bond dissociation to a surface proton and a metal-carbanion intermediate that undergoes β-hydride elimination. We find that grafted Ga sites are catalytically inactive. In contrast, Ga-doped sites exhibit fivefold enhancement in catalytic activity when compared to the sites on pristine Al 2 O 3 , owed to the synergy between neighboring AlIII and GaIV sites. Furthermore, we model and investigate the effect of surface hydroxylation, demonstrate how surface water interferes with the aforementioned synergy between AlIII and GaIV sites and discuss the implications for the catalytic activity of the modified surfaces. Here, an increase in the partial pressure of H 2 O significantly increases the apparent activation energies of dehydrogenation and interestingly changes the most active site.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Some confusion factors in radar image interpretation

Geologic interpretation of radar imagery for land use applications is discussed with reference to its dependence on classification of the radar return into categories related to some training area within the image. It is shown that such interpretation relies on the assumption that surface characteristics of areas with similar returns are truly similar. It is further shown that this may not always be true over water surfaces due to the influence of system parameters on the radar return. In imagery over land, both system parameters and scene parameters may lead to ambiguous returns which can ultimately lead to misinterpretation.

Blanchard, B. J.↗