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At least 829 records · Page 46

A technique to measure the thermal diffusivity of high T(sub c) superconductors

High T(sub c) superconducting electrical current leads and ground straps will be used in cryogenic coolers in future NASA Goddard Space Flight Center missions. These superconducting samples will be long, thin leads with a typical diameter of two millimeters. A longitudinal method is being developed to measure the thermal diffusivity of candidate materials for this application. This technique will use a peltier junction to supply an oscillatory heat wave into one end of a sample and will use low mass thermocouples to follow the heat wave along the sample. The thermal diffusivity will be calculated using both the exponential decay of the heat wave and the phase shift of the wave. Measurements will be done in a cryostat between 10 K and room temperature.

Powers, Charles E.↗

Grain orientation studies in superconductors

Grain oriented fabrication of ceramics utilizes the presence of some form of anisotropy in the particles of the starting material to obtain textured microstructures. The molten salt, or flux method, a popular technique for growing crystals and particles with anisotropic morphology, is utilized in this study. The formation of Ba2YCu3O(7-x) in the presence of molten salts of Na, K, Li belonging to chloride and sulfate systems does not appear feasible in the temperature range up to 900 C. Researchers also present the results of studies in using BaY2CuO5 as seed crystals in the formation of Ba2YCu3O(7-x) wherein BaY2CuO5 has been observed to have better stability in water and against most of the salts as compared to Ba2YCu3O(7-x). Additional results of molten salt processing of bismuth systems are also presented.

Gopalakrishnan, Sudhakar↗

Construction and performance of a high-temperature-superconductor composite bolometer

A high-Tc superconducting bolometer has been constructed using a YBa2Cu3O(x) thin-film meander line 20 microns wide and 76,000 microns long, deposited on a SrTiO3 substrate. Radiation is absorbed by a thin film of Bi with well-characterized absorption properties deposited on a Si substrate in contact with the SrTiO3. At 1.8 Hz the measured bolometer response to a 500-K blackbody is 5.2 V/W (820 V/W extrapolated to dc). The impact of apparent nonohmic behavior at the transition is discussed, as are ways of reducing the observed 1/f noise. The response time is 32 s and is dominated by the heat capacity of the SrTiO3 substrate.

Brasunas, J. C.↗

Low-resistance noble metal contacts to high-temperature superconductors

Low-resistance contacts were made to both YBa2Cu3O(7-x) and Bi2BaSr2Cu2O8, and to related superconducting compounds by melting gold or silver pads onto the samples before the final oxygen treatment. Scanning electron microscope studies show that both gold and silver do not diffuse far from the contact area. The surface contact resistivity of the best contacts made by the melting technique has an upper limit value in the 10 to the -8th ohm sq cm range at 77 K. This contact resistivity shows no significant change in its value over a period of 17 months. Furthermore, an electron radiation dose of 5.7 x 10 to the 17th electron/sq cm only doubled the contact resistivity.

Selim, R.↗

Processing and properties of high Tc oxide/silver matrix composite superconductors

This paper describes the processing conditions for the formation of strong flux pinning high-Tc (REE)1Ba2Cu3O7/AgO (RE-123/AgO) composites with the RE-123:AgO ratio of 3:1 and presents the magnetization and critical field data on these composites. The results obtained indicate that proper processing conditions are critical to the formation of strong flux pinning RE-123/AgO composites. Resistance measurements in a magnetic field show that the upper critical field in Y-123/AgO is about three times larger than that of the Y-123 compound.

Curreri, P. A.↗

High Tc composite silver/oxide superconductors

Factors involved in the strong flux pinning effect of high-Tc YBa2Cu3O7/AgO (Y-123/AgO) composite and other REE-123/AgO composites were investigated. Samples of superconducting REE-123 and REE-123/AgO (where REE was Nd, Sm, Eu, Gd, Dy, Ho, Er, or Y) were prepared and used to obtain magnetic moments, critical field, and microstructure data. The optimum heat treatment conditions for the formation of strong flux-pinning REE-123/AgO composites were found to be different for different REE-123 compounds. It was found that the annealing temperature depends on the ionic size of the REE, with larger rare-earth ions requiring higher temperature. It was also found that strong flux-pinning REE-123/AgO composites form only in a narrow annealing temperature range.

Curreri, P. A.↗

Thin films of the Bi2Sr2Ca2Cu3O(x) superconductor

Using RF sputtering technique, thin films of near single phase Bi2Sr2Ca2Cu3O(x) were successfully prepared on SrTiO3(100), MgO(100), and LaAlO3(012) substrates. Zero resistance of these films occurred in the range of 90-105 K.

Mei, YU↗

Emerging applications of high temperature superconductors for space communications

Proposed space missions require longevity of communications system components, high input power levels, and high speed digital logic devices. The complexity of these missions calls for a high data bandwidth capacity. Incorporation of high temperature superconducting (HTS) thin films into some of these communications system components may provide a means of meeting these requirements. Space applications of superconducting technology has previously been limited by the requirement of cooling to near liquid helium temperatures. Development of HTS materials with transition temperatures above 77 K along with the natural cooling ability of space suggest that space applications may lead the way in the applications of high temperature superconductivity. In order for HTS materials to be incorporated into microwave and millimeter wave devices, the material properties such as electrical conductivity, current density, surface resistivity and others as a function of temperature and frequency must be well characterized and understood. The millimeter wave conductivity and surface resistivity were well characterized, and at 77 K are better than copper. Basic microwave circuits such as ring resonators were used to determine transmission line losses. Higher Q values than those of gold resonator circuits were observed below the transition temperature. Several key HTS circuits including filters, oscillators, phase shifters and phased array antenna feeds are feasible in the near future. For technology to improve further, good quality, large area films must be reproducibly grown on low dielectric constant, low loss microwave substrates.

Heinen, Vernon O.↗

Effects of antimony substitution on bismuth based superconductors

The effect of Sb substitution and simultaneous substitution of Pb and Sb on the superconducting transition temperatures in the BiSrCaCuO system is investigated. The 2:2:2:3 phase is of particular interest since any small increase in the transition temperature could be of great interest. More that 90 different samples were prepared based on 2:2:2:3 stoichiometry in the BiSrCaCuO system. After this preliminary attempt, four different families of samples were investigated. In the first family of samples, Bi was substituted by Sb to form Bi(1.9)Sb(0.1)Sr2Ca2Cu3O(y). The second group of samples were prepared by simultaneous addition of Pb and Sb with nominal composition Bi(1.8)Pb(0.1)Sb(0.1)Sr2Ca2Cu3O(y). The third and fourth groups were prepared to determine the effect created when the Pb concentration is increased with the nominal compositions being Bi(1.7)Pb(0.1)Sr2Ca2Cu3O(y) and Bi(1.6)Sb(0.1)Sr2Ca2Cu3O(y). The results of these investigations are presented with a discussion.

Barrientos, Alfonso↗

High T(sub c) superconductors: Are they magnetic

The objective is to demonstrate the magnetic characteristics of the new superconducting oxides with transition temperatures above liquid nitrogen temperature (77 K). The first task was to find out whether YBa2Cu3O7-x is magnetic at liquid nitrogen temperature, and if so, what the sign of its magnetic susceptibility is. Details of the experimental procedure are given.

Shull, Robert D.↗

Melt-processed bulk superconductors: Fabrication and characterization for power and space applications

Melt-process bulk superconducting materials based on variations on the base YBa2Cu3O(x) were produced in a variety of shapes and forms. Very high values of both zero-field and high-field magnetization were observed. These are useful for levitation and power applications. Magnetic measurements show that the effects of field direction and intensity, temperature and time are consistent with an aligned grain structure with multiple pinning sites and with models of thermally activated flux motion.

Hojaji, Hamid↗

Influence of field dependent critical current density on flux profiles in high Tc superconductors

The field distribution for superconducting cylinders and slabs with field dependent critical current densities in combined DC and AC magnetic fields and the corresponding magnetic fluxes are calculated. It is shown that all features of experimental magnetic-field profile measurements can be explained in the framework of field dependent critical current density. Even the quantitative agreement between the experimental and theoretical results using Kim's model is very good.

Takacs, S.↗

Femtosecond optical absorption studies of nonequilibrium electronic processes in high T(c) superconductors

The results are reported of femtosecond optical transient absorption experiments performed on the superconducting compounds YBa2Cu3O(7-x) (x about 0) and Bi2Sr2Ca2Cu3O(10+delta) (delta about 0) and nonsuperconducting YBa2Cu3O(6+y) (y less than 0.4) for sample temperatures ranging from about 7 K to room temperature. Nonequilibrium heating was found to occur on a subpicosecond time scale. A distinct, dramatic increase in the relaxation time was observed for the superconducting samples as the sample temperature was lowered below the critical temperatures of the respective films. Accompanying the increase in relaxation time was an increase in the peak fractional transmissivity change. No such changes were observed for the nonsuperconducting YBCO sample.

Chwalek, J. M.↗

Preparation of 110K (Bi, Pb)-Sr-Ca-Cu-O superconductor from glass precursor

The Bi1.5Pb0.5Sr2Ca2Cu3O(x) glass, prepared by rapid quenching of the melt, showed T(sub g) of 383 C, crystallization temperature of approx. 446 C, melting temperature of approx. 855 C, and bulk density of 5.69 g/cu. cm. in air. The as-quenched glass was oxygen deficient. On heating in O2, it showed a slow, irreversible, and continuous weight gain starting at approx. 530 C. The influence of annealing conditions on the formation of various phases was investigated by XRD and electrical resistivity measurements. The 110K-T(sub c) phase did not form below 840 C. The amount of this phase increased with the sintering time at 840 C. A sample annealed at 840 C for 243 h in air and furnace cooled showed the highest T(sub c) (R=0) of 107.2 K and transition width delta T(sub c) (10 to 90 percent) of approx. 2 K.

Bansal, Narottam P.↗

Shielding and flux trapping properties of high temperature superconductors in the shape of hollow cylinders

Allowing for a field-dependent critical current density, the authors calculate the magnetic field that can be supported by hollow cylinders of varying wall thickness. An adiabatically stable field of 1.0 T can be shielded by or trapped in a cylinder with a wall thickness of 0.4 cm if the critical current density varies linearly with magnetic field and has a value of 104 A/sq cm at a field of 1.0 T. Such a current density appears to be within reach of present state-of-the-art melt-processed YBa2Cu3O7 (123) materials.

Israelsson, U. E.↗

Upcoming planetary missions and the applicability of high temperature superconductor bolometers

Past and present planetary exploration is briefly reviewed, and the planned 1996 Cassini mission to Saturn and Titan is examined. The CIRS experiment aboard Cassini, which will retrieve information on the atmospheres of Titan and Saturn, is discussed. Ongoing efforts to build a high-sensitivity, high-Tc bolometer that would greatly improve detection in Titan's atmosphere are addressed.

Brasunas, J.↗

Design and performance of a high-Tc superconductor coplanar waveguide filter

The design of a coplanar waveguide low-pass filter made of YBa2Cu3O(7-delta) (YBCO) on an LaAlO3 substrate is described. Measurements were incorporated into simple models for microwave CAD analysis to develop a final design. The patterned and packaged coplanar waveguide low-pass filter of YBCO, with dimensions suited for integrated circuits, exhibited measured insertion losses when cooled in liquid nitrogen superior to those of a similarly cooled thin-film copper filter throughout the 0 to 9.5 GHz passband. Coplanar waveguide models for use with thin-film normal metal (with thickness either greater or less than the skin depth) and YBCO are discussed and used to compare the losses of the measured YBCO and copper circuits.

Chew, Wilbert↗

NASA Space applications of high-temperature superconductors

The application of superconducting technology in space has been limited by the requirement of cooling to near liquid helium temperatures. The only means of obtaining these temperatures has been with cryogenic fluids which severely limit mission lifetime. The development of materials with superconducting transition temperatures above 77 K has made superconducting technology more attractive and feasible for employment in aerospace systems. Here, potential applications of high temperature superconducting technology in cryocoolers, remote sensing, communications, and power systems are discussed.

Heinen, Vernon O.↗