Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “structural evolution”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 829 records · Page 46
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Operando Freezing Cryogenic Electron Microscopy of Active Battery Materials

Abstract Understanding structural and chemical evolution of battery materials during operation is critical to achieving safe, efficient, and long-lasting energy storage. Cryogenic electron microscopy (cryo-EM) has become a valuable tool in battery characterization, leveraging low temperatures to improve stability of sensitive materials under electron beam irradiation. However, typical cryo-EM sample preparations leave extended time between the electrochemical point of interest and ex situ freezing of samples, during which active structures may relax, degrade, or otherwise evolve. Here, we detail a method for operando freezing cryo-EM to preserve and characterize native electrode and interfacial structures that arise during battery cycling, based on an operando plunge freezer and cold sample removal process. We validate the method on multiple electrode materials and quantify and discuss the freezing rate achieved. Operando freezing cryo-EM can be used to directly visualize transient features that arise at active electrochemical interfaces, to enable deeper understanding of structural evolution and interfacial chemistry in batteries and other electrochemical systems.

25 ENERGY STORAGE↗
NASA NTRSDate not supplied

Understanding thermal stability in doped zirconia aerogels for high temperature applications

The high porosities and low densities of ceramic aerogels offer outstanding insulative performance in applications where weight is a critical factor. The high surface-to-volume ratios and specific surface areas provide extremely low thermal conductivity, but also contribute to rapid densification of the pore structure at elevated temperatures. This densification diminishes their favorable properties and inhibits use of aerogels in high temperature applications. The purpose of this work is the establishment of a design framework for thermally stable, highly porous materials. Here we will review our recent studies on the effects of synthetic parameters and dopant chemistry on the evolution of zirconia-based aerogels. The structural evolution was studied to 1200 °C using nitrogen physisorption, scanning and transmission electron microscopy, and x-ray diffraction. The role of dopant identity and concentration in thermal stability was elucidated. In context of the design framework, dopant chemistry is an aggregate for many closely related material properties, each of which may contribute to aerogel structural evolution. To develop a truly predictive design framework for ceramic-based aerogels, systematic and comprehensive evaluation of thermodynamic and kinetic properties must be performed in conjunction with studies on structural evolution.

aerogel↗
NASA NTRS1989

Explosive east coast cyclogenesis over the west-central North Atlantic Ocean - A composite study derived from ECMWF operational analyses

This paper describes the observational aspects of explosive east-coast cyclogenesis using composites constructed from the daily global analyses generated and archived by ECMWF. An explosively deepening storm or bomb is defined as an extratropical cyclone whose mean sea-level pressure falls at least 1 mb/h for 24 h. The ECMWF data sets are used to examine the three-dimensional kinematic and thermodynamic structure of bombs over the entire depth of the troposphere. The evolution and structure of the composite bomb is diagnosed using a moving coordinate system consisting of a box with dimensions of 35 x 35 deg of latitude-longitude. The results reveal that explosive cyclogenesis is a baroclinic phenomenon in which the rapid development in the presence of strong upper tropospheric forcing is most likely enhanced by a highly destabilized lower troposphere.

Manobianco, John↗
NASA NTRS2002

The Evolution of Dust in the Multiphase Interstellar Medium

Interstellar dust has a profound effect on the structure and evolution of the interstellar medium (ISM) and on the processes by which stars form from it. Dust obscures regions of star formation from view, and the uncertain quantities of elements in dust makes it difficult to measure accurately the abundances of the elements in low density regions. Despite the central importance of dust in astrophysics, we cannot answer some of the most basic questions about it: Why is it that most of the refractory elements are in dust grains? What determines the sizes of interstellar grains? In our theoretical investigations we have addressed these questions by studying the destruction of interstellar grains. We describe here the investigations that we have completed to date. As part of our original proposal we proposed additional projects that have not been completed. We are requesting a no-cost extension to carry out those investigations and describe those in our request.

Slavin, J.↗
NASA NTRS2003

The Evolution of Dust in the Multiphase Interstellar Medium

Interstellar dust has a profound effect on the structure and evolution of the interstellar medium (ISM) and on the processes by which stars form from it. Dust obscures regions of star formation from view, and the uncertain quantities of elements in dust makes it difficult to measure accurately the abundances of the elements in low density regions. Despite the central importance of dust in astrophysics, we cannot answer some of the most basic questions about it: Why is it that most of the refractory elements are in dust grains? What determines the sizes of interstellar grains? It has been the goal of our proposed theoretical investigations to address these questions by studying the destruction of interstellar grains, and to develop observational diagnostics that can test the models we develop.

Oliversen, Ronald J.↗
NASA NTRS2006

Vertical Moist Thermodynamic Structure and Spatial-Temporal Evolution of the MJO in AIRS Observations

The atmospheric moisture and temperature profiles from the Atmospheric Infrared Sounder (AIRS)/Advanced Microwave Sounding Unit on the NASA Aqua mission, in combination with the precipitation from the Tropical Rainfall Measuring Mission (TRMM), are employed to study the vertical moist thermodynamic structure and spatial-temporal evolution of the Madden-Julian oscillation (MJO). The AIRS data indicate that, in the Indian Ocean and western Pacific, the temperature anomaly exhibits a trimodal vertical structure: a warm (cold) anomaly in the free troposphere (800-250 hPa) and a cold (warm) anomaly near the tropopause (above 250 hPa) and in the lower troposphere (below 800 hPa) associated with enhanced (suppressed) convection. The AIRS moisture anomaly also shows markedly different vertical structures as a function of longitude and the strength of convection anomaly. Most significantly, the AIRS data demonstrate that, over the Indian Ocean and western Pacific, the enhanced (suppressed) convection is generally preceded in both time and space by a low-level warm and moist (cold and dry) anomaly and followed by a low-level cold and dry (warm and moist) anomaly. The MJO vertical moist thermodynamic structure from the AIRS data is in general agreement, particularly in the free troposphere, with previous studies based on global reanalysis and limited radiosonde data. However, major differences in the lower-troposphere moisture and temperature structure between the AIRS observations and the NCEP reanalysis are found over the Indian and Pacific Oceans, where there are very few conventional data to constrain the reanalysis. Specifically, the anomalous lower-troposphere temperature structure is much less well defined in NCEP than in AIRS for the western Pacific, and even has the opposite sign anomalies compared to AIRS relative to the wet/dry phase of the MJO in the Indian Ocean. Moreover, there are well-defined eastward-tilting variations of moisture with height in AIRS over the central and eastern Pacific that are less well defined, and in some cases absent, in NCEP. In addition, the correlation between MJO-related mid-tropospheric water vapor anomalies and TRMM precipitation anomalies is considerably more robust in AIRS than in NCEP, especially over the Indian Ocean. Overall, the AIRS results are quite consistent with those predicted by the frictional Kelvin-Rossby wave/conditional instability of the second kind (CISK) theory for the MJO.

troposhere↗
DOE OSTI2026

EEPD1 evolved a unique DNA clamping dimer protecting reversed replication forks

Exonuclease/endonuclease/phosphatase (EEP)-fold hydrolases are canonically monomeric phosphodiesterases exemplified by APE1, DNase I, and TDP2 nucleases. While EEP family domain containing protein 1 (EEPD1) acts in DNA stress responses, its proposed nuclease activities are enigmatic. Here, we integrate hybrid structural methods, evolution, biochemistry, cancer genomics, plus molecular and cell biology to define EEPD1 structure, assembly, and function at stalled DNA replication forks. Results imply EEPD1 surprisingly requires both unique EEP domain dimer and distinctive tandem Helix-hairpin-Helix [(HhH) 2 ] domains to clamp double-stranded (ds) DNA at reversed DNA replication forks for fork protection. Small-angle X-ray Scattering (SAXS), crystal, and cryo-EM structures unveil an unprecedented tryptophan handshake dimer, conserved interface di-Trp-Pro pocket, and adjustable “wrist” enabling an open-closed conformational switch. EEPD1 dimer cooperatively binds complex dsDNA replication fork intermediates but alone lacks nuclease activity due to loss of key EEP catalytic residues during Metazoan evolution and atmospheric oxygen buildup. Instead, EEPD1 prevents nucleolytic degradation of reversed replication forks by MRE11. Furthermore, cancer bioinformatics support oxidative damage-dependent EEPD1 association as a significant modulator of overall patient survival. Collective findings uncover unexpected EEP dimer and fork protection function in clamping, not cleaving, reversed replication forks for metazoan oxidative stress responses controlling genome stability and cancer outcomes.

Shen, Runze [Univ. of Texas, Houston, TX (United S↗
DOE OSTI2020

Evolution of the Kondo lattice electronic structure above the transport coherence temperature

Significance The temperature ( T )-dependent evolution of the Kondo lattice electronic structure is a long-standing topic of theoretical and experimental investigation, still lacking a truly microscopic theory that agrees with a full experimental characterization. Here multiple characteristic T scales of the interaction of localized f moments with conduction electrons in the Kondo lattice CeCo I n 5 are identified and investigated using angle-resolved photoemission measurements that substantiate dynamical mean-field theory which newly includes the full realism of crystalline electric-field (CEF) f splittings. Thereby errors in the itinerant versus localized f -state classification from standard density functional theory are corrected, microscopic insight into the broad T -range crossover of f -hybridization effects is gained, and a prediction of CEF degeneracy crossover below the lattice coherence T is made.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS2003

Structures and Materials Technologies for Extreme Environments Applied to Reusable Launch Vehicles

This paper provides an overview of the evolution of structures and materials technology approaches to survive the challenging extreme environments encountered by earth-to-orbit space transportation systems, with emphasis on more recent developments in the USA. The evolution of technology requirements and experience in the various approaches to meeting these requirements has significantly influenced the technology approaches. While previous goals were primarily performance driven, more recently dramatic improvements in costs/operations and in safety have been paramount goals. Technologies that focus on the cost/operations and safety goals in the area of hot structures and thermal protection systems for reusable launch vehicles are presented. Assessments of the potential ability of the various technologies to satisfy the technology requirements, and their current technology readiness status are also presented.

Scotti, Stephen J.↗
NASA NTRS2022

Correlated Spatio-temporal Evolution of Extreme-Ultraviolet Ribbons and Hard X-Rays in a Solar Flare

We analyze the structure and evolution of ribbons from the M7.3 SOL2014-04-18T13 flare using ultraviolet images from the Interface Region Imaging Spectrograph and the Solar Dynamics Observatory (SDO)/Atmospheric Imaging Assembly (AIA), magnetic data from the SDO/Helioseismic and Magnetic Imager, hard X-ray (HXR) images from the Reuven Ramaty High Energy Solar Spectroscopic Imager, and light curves from the Fermi/Gamma-ray Burst Monitor, in order to infer properties of coronal magnetic reconnection. As the event progresses, two flare ribbons spread away from the magnetic polarity inversion line. The width of the newly brightened front along the extension of the ribbon is highly intermittent in both space and time, presumably reflecting nonuniformities in the structure and/or dynamics of the flare current sheet. Furthermore, the ribbon width grows most rapidly in regions exhibiting concentrated nonthermal HXR emission, with sharp increases slightly preceding the HXR bursts. The light curve of the ultraviolet emission matches the HXR light curve at photon energies above 25 keV. In other regions the ribbon-width evolution and light curves do not temporally correlate with the HXR emission. This indicates that the production of nonthermal electrons is highly nonuniform within the flare current sheet. Our results suggest a strong connection between the production of nonthermal electrons and the locally enhanced perpendicular extent of flare ribbon fronts, which in turn reflects the inhomogeneous structure and/or reconnection dynamics of the current sheet. Despite this variability, the ribbon fronts remain nearly continuous, quasi-one-dimensional features. Thus, although the reconnecting coronal current sheets are highly structured, they remain quasi-two-dimensional and the magnetic energy release occurs systematically, rather than stochastically, through the volume of the reconnecting magnetic flux.

S. J. Naus↗
NASA NTRSDate not supplied

Correlated Spatiotemporal Evolution of Extreme-Ultraviolet Ribbons and Hard X-rays in a Solar Flare

We study the structure and evolution of solar flare ribbons in the chromosphere to infer properties of magnetic reconnection that occurs in the corona. We analyze the imaging observations of the M7.3 SOL2014-04-18T13 flare obtained by IRIS in both the near and far ultraviolet passbands and by SDO/AIA in the 1600A passband. Two flare ribbons are observed to spread away from the magnetic polarity inversion line as the flare progresses. Using the high-resolution IRIS observations, we measure the width of the newly brightened ribbon front along the extension of the ribbon, which maps the feet of magnetic field lines reconnecting in the current sheet in the corona. We find that the width of the ribbon front is highly structured, possibly reflecting corresponding structure in the coronal current layer. Further the ribbon grows most rapidly with time in regions where non-thermal hard X-ray (HXR) emission is concentrated (Brosius, et al. 2015). The light curve of the ultraviolet emissions in this region, as measured by IRIS and AIA, also well matches the HXR light curve at photon energies above 25 keV. In contrast, the ribbon-width evolution and light curves in other regions along the ribbons do not correlate well with the HXR emission. These results suggest that there is a strong connection between the production of non-thermal electrons and locally enhanced perpendicular extent of flare ribbon fronts, which reflect the inhomogeneous structure and/or reconnection dynamics of the flare current sheet in the corona.

Stephen Naus↗
NASA NTRS1990

Numerical study of subcritical flow with fluid injection

It is suggested that the study of synthetic flows, where controlled experiments can be performed, is useful in understanding turbulent flow structures. The early states of formation of hairpin structures in shear flows and the subsequent evolution of these structures is studied in shear flows and the subsequent evolution of these structures is studied through numerical simulations, by developing full-time dependent three-dimensional flow solution of an initially laminar (subcritical) flow in which injection of fluid through a narrow streamwise slot from the bottom wall of a plate is carried out. Details of the numerical approach and significance of the present findings are reported in this work.

Balasubramanian, R.↗
DOE OSTI2021

Insights into the Rich Polymorphism of the Na + Ion Conductor Na 3 PS 4 from the Perspective of Variable-Temperature Diffraction and Spectroscopy

Solid electrolytes are crucial for next-generation solid-state batteries, and Na 3 PS 4 is one of the most promising Na + conductors for such applications, despite outstanding questions regarding its structural polymorphs. In this contribution, we present a detailed investigation of the evolution in structure and dynamics of Na 3 PS 4 over a wide temperature range 30 < T T < 500 °C, which we attribute to dynamic local tetragonal distortions. The first-order phase transition to the mesophasic high-temperature polymorph (γ, Fddd ) is associated with a sharp volume increase and the onset of liquid-like dynamics for sodium-cations (translational) and thiophosphate-polyanions (rotational) evident by inelastic neutron and Raman spectroscopies, as well as pair-distribution function and molecular dynamics analyses. Overall, these results shed light on the rich polymorphism of Na 3 PS 4 and are relevant for a range host of high-performance materials deriving from the Na 3 PS 4 structural archetype.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1980

The photometric properties of brightest cluster galaxies. II - SIT and CCD surface photometry

Surface photometry of the first-ranked galaxy in 108 Abell clusters is presented. Galaxy structure, as parameterized by simple Hubble law models, is found to correlate with galaxy absolute magnitude and cluster structure. All the structure data support the dynamical friction evolution model. Twenty-eight percent of the galaxies have multiple component nuclei; the short lifetimes of such systems provide the best available evidence that ongoing evolution actually occurs. Average magnitude and structure evolution rates are derived from the data.

Hoessel, J. G.↗
NASA NTRS2005

Full-Field Measurements of Self-Excited Oscillations in Momentum-Dominated Helium Jets

Flow structure of momentum-dominated helium jets discharged vertically into ambient air was investigated using a high-speed rainbow schlieren deflectometry (RSD) apparatus operated at up to 2000 Hz. The operating parameters, i.e., Reynolds number and Richardson number were varied independently to examine the self-excited, flow oscillatory behavior over a range of experimental conditions. Measurements revealed highly periodic oscillations in the laminar region at a unique frequency as well as high regularity in the flow transition and initial turbulent regions. The buoyancy was shown to affect the oscillation frequency and the distance from the jet exit to the flow transition plane. Instantaneous helium concentration contours across the field of view revealed changes in the jet flow structure and the evolution of the vortical structures during an oscillation cycle. A cross-correlation technique was applied to track the vortices and to find their convection velocity. Time-traces of helium concentration at different axial locations provided detailed information about the oscillating flow.

Yildirim, B. S.↗
DOE OSTI2020

Hierarchically-Structured Ti/TiO 2 Electrode for Hydrogen Evolution Synthesized via 3D Printing and Anodization

Hierarchically-structured, electro-catalysts consisting of a titanium core with controlled macro-porosity and a thin titania surface-layer with controlled nano-porosity were synthesized via combination of additive manufacturing and in-situ anodization. The electrodes were tested for hydrogen evolution reaction and depicted competitive electro-catalytic activities, with Tafel slopes between 40 and 56 mV dec -1 . The electrodes also depicted competitive onset and over potentials when compared with other electrode alternatives. The synthesis approach for the electro-catalysts reported in this work is being extended to other metal/metal-oxide pairs and applications.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Effect of Thermal Oxidation on the Structure, Surface Texturing, and Microstructure Evolution in Nanocrystalline Ga-O-N Films

An extensive examination of the nanoscale, crystallographic growth dynamics of the system, which is impacted by the thermal energy given to the GaN, is carried out to derive a deeper understanding of the growth kinetics, morphology and microstructure evolution, chemical bonding, and optical properties of Ga-O-N films. Thermal annealing of GaN films is performed in the temperature range of 900–1200 °C. Crystal structure, phase formation, chemical composition, surface morphology, and microstructure evolution of Ga-O-N films are investigated as a function of temperature. Increasing temperature induces surface oxidation, which results in the formation of stable β-Ga2O3 phase in the GaN matrix, where the overall film composition evolves from nitride (GaN) to oxynitride (Ga-O-N). While GaN surfaces are smooth, planar, and featureless, oxidation induced granular-to-rod shaped morphology evolution is seen with increasing temperature to 1200 °C. The considerable texturing and stability of the nanocrystalline Ga-O-N on Si substrates can be attributed to the surface and interface driven modification because of thermal treatment. Corroborating with structure and chemical changes, Raman spectroscopic analyses also indicate that the chemical bonding evolution progresses from fully Ga-N bonds to Ga-O-N. While the GaN oxidation process starts with the formation of β-Ga 2 O 3 at an annealing temperature of 1000 °C, higher annealing temperatures induce structural distortion with the potential formation of Ga-O-N bonds. The structure-phase-chemical composition correlation, which will be useful for nanocrystalline materials for selective optoelectronic applications, is established in Ga-O-N films made by thermal treatment of GaN.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Enhanced Electrocatalytic Hydrogen Evolution Activity in Single-Atom Pt-Decorated VS 2 Nanosheets

Enhancing catalytic activity by decorating noble metals in catalysts provides an opportunity for promoting the electrocatalytic hydrogen evolution reaction (HER) application. However, there are few systematic studies on regulating the structures of noble metals in catalytic materials and investigating their influence on HER. Herein, Pt catalysts with different structures including single atoms (SAs), clusters, and nanoparticles well-controllably anchored on VS 2 nanosheets through a cost-effective optothermal method are reported, and their HER performance is studied. The most efficient Pt-decorated VS 2 catalyst (with both Pt SAs and clusters) delivers an overpotential of 77 mV at 10 mA cm –2 , close to that of Pt/C (48 mV). However, the optimal mass activity of Pt (normalizing to Pt content) is obtained from only SA Pt-decorated VS 2 (i.e., 22.88 A mg Pt –1 at 200 mV) and is 12 times greater than that of the Pt/C (1.87 A mg Pt –1 ), attributed to the greatly enhanced Pt utilization. Additionally, the theoretical simulations reveal that Pt SA decoration makes the adsorption free energy of H* closer to the thermoneutral value and improves the charge-transfer kinetics, significantly enhancing HER activity. Furthermore, this work offers a pathway to prepare the desired catalyst based on synergy of Pt structures and VS 2 and reveals the intrinsic mechanism for enhancing catalytic activity, which is important for HER applications.

36 MATERIALS SCIENCE↗