Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “solution processable”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 829 records · Page 46

Imide Oligomers Containing Pendent and Terminal Phenylethynyl Groups-2

As part of a program to develop high-performance/high-temperature structural resins for aeronautical applications, imide oligomers containing pendent and terminal phenylethynyl groups were prepared, characterized and the cured resins evaluated as composite matrices. The oligomers were prepared at a calculated number-average molecular weight of 5000 g/mol and contained 15-20 mol% pendent phenylethynyl groups. In previous work, an oligomer containing pendent and terminal phenylethynyl groups exhibited a high glass transition temperature (approximately 313 C), and laminates therefrom exhibited high compressive properties, but processability, fracture toughness, microcrack resistance and damage tolerance were less than desired. In an attempt to improve these deficiencies, modifications in the oligomeric backbone involving the incorporation of 1,3-bis(3-aminophenoxy)benzene were investigated as a means of improving processability and toughness without detracting from the high glass transition temperature and high compressive properties. The amide acid oligomeric solutions were prepared in N-methyl-2-pyrrolidinone and were subsequently processed into imide powder, thin films, adhesive tape and carbon fiber prepreg. Neat resin plaques were fabricated from imide powder by compression moulding. The maximum processing pressure was 1.4 MPa and the cure temperature ranged from 350 to 371 C for 1 h for the mouldings, adhesives, films and composites. The properties of the 1,3-bis(3-aniinophenoxy)benzene modified cured imide oligomers containing pendent and terminal phenylethynyl groups are compared with those of previously prepared oligomers containing pendent and terminal phenylethynyl groups of similar composition and molecular weight.

Connell, J. W.↗

Direct solution for thermal stresses in a nose cap under an arbitrary axisymmetric temperature distribution

The design of a nose cap for a hypersonic vehicle is an iterative process requiring a rapid, easy to use and accurate stress analysis. The objective of this paper is to develop such a stress analysis technique from a direct solution of the thermal stress equations for a spherical shell. The nose cap structure is treated as a thin spherical shell with an axisymmetric temperature distribution. The governing differential equations are solved by expressing the stress solution to the thermoelastic equations in terms of a series of derivatives of the Legendre polynomials. The process of finding the coefficients for the series solution in terms of the temperature distribution is generalized by expressing the temperature along the shell and through the thickness as a polynomial in the spherical angle coordinate. Under this generalization the orthogonality property of the Legendre polynomials leads to a sequence of integrals involving powers of the spherical shell coordinate times the derivative of the Legendre polynomials. The coefficients of the temperature polynomial appear outside of these integrals. Thus, the integrals are evaluated only once and their values tabulated for use with any arbitrary polynomial temperature distribution.

Davis, Randall C.↗

JASON-1 Precise Orbit Determination (POD) Through the Combination and Comparison of GPS, SLR, DORIS and Altimeter Crossover Data

Jason-1, launched on December 7,2001, is continuing the time series of centimeter level ocean topography observations as the follow-on to the highly successful TOPEX/POSEIDON (T/P) radar altimeter satellite. The precision orbit determination (POD) is a critical component to meeting the ocean topography goals of the mission. T P has demonstrated that the time variation of ocean topography can be determined with an accuracy of a few centimeters, thanks to the availability of highly accurate orbits based primarily on SLR+DORIS tracking. The Jason-1 mission is intended to continue measurement of the ocean surface with the same, if not better accuracy. Fortunately, Jason- 1 POD can rely on four independent tracking data types available including near continuous tracking data from the dual frequency codeless BlackJack GPS receiver. Orbit solutions computed using individual and various combinations of GPS, SLR, DORIS and altimeter crossover data types have been determined from over 100 days of Jason-1 tracking data, The performance of the orbit solutions and tracking data has been evaluated. Orbit solution evaluation and comparison has provided insight into possible areas of refinement. Several aspects of the POD process are examined to obtain orbit improvements including measurement modeling, force modeling and solution strategy. The results of these analyses will be presented.

Luthcke, Scott B.↗

JASON-1 Precise Orbit Determination (POD) Through the Combination and Comparison of GPS, SLR, DORIS and Altimeter Crossover Data

Jason-1, launched on December 7, 2001, is continuing the time series of centimeter level ocean topography observations as the follow-on to the highly successful TOPEX/POSEIDON (T/P) radar altimeter satellite. The precision orbit determination (POD) is a critical component to meeting the ocean topography goals of the mission. T/P has demonstrated that the time variation of ocean topography can be determined with an accuracy of a few centimeters, thanks to the availability of highly accurate orbits based primarily on SLR+DORIS tracking. The Jason-1 mission is intended to continue measurement of the ocean surface with the same, if not better accuracy. Fortunately, Jason-1 POD can rely on four independent tracking data types available including near continuous tracking data from the dual frequency codeless BlackJack GPS receiver. Orbit solutions computed using individual and various combinations of GPS, SLR, DORIS and altimeter crossover data types have been determined from over 100 days of Jason-1 tracking data. The performance of the orbit solutions and tracking data has been evaluated. Orbit solution evaluation and comparison has provided insight into possible areas of refinement. Several aspects of the POD process are examined to obtain orbit improvements including measurement modeling, force modeling and solution strategy. The results of these analyses will be presented.

Luthcke, S. B.↗

Comparison of EKF and UKF for Robotic Missions to Mars

The batched Kalman lter works well for a wide variety of orbit determination scenarios but requires linearized approximations to the underlying dynamical system. Furthermore, implementation depends on the computation of partial derivatives for all measurements and parameters used in the lter, a non-trivial task even when analytical derivations are possible. To address these limitations, many extensions and modi - cations to the linear Kalman lter have been proposed over the years since Kalman's initial publication. Our investigation examines two popular variants of the Kalman lter, namely the Extended Kalman Filter (EKF) and Unscented Kalman Filter (UKF), within the context of spacecraft missions to Mars. The EKF relies on the same mathematical basis as the classic version of the lter, however it sequentially updates the linearization as the ltering process is conducted. In contrast, the UKF is built upon the unscented transform which samples the nearby solution space and numerically propagates perturbed trajectories as part of the update / estimation process. We assess the performance of the ltering algorithms under a variety of mission scenarios with the goal of establishing decision criteria for which implementation to use under di ering circumstances.

Ely, Todd↗

A multi-fluid model of an H2O-dominated dusty cometary atmosphere

The solution of the simultaneous set of differential equations representing conservation of number density, momentum, and energy, together with solar radiation transfer in streams that are responsible for major photolytic processes and nucleus heating, yields a self-consistent multifluid solution for the thermal and dynamical structure of an H2O-dominated, two-phase dusty gas cometary atmosphere, whose validity is restricted to the collision-dominated region where ions and neutrals are assumed to achieve a common temperature and velocity. The model is transonic, due to the dust in the inner coma, and involves the subsonic expansion of the ions and neutrals from the nucleus until, in the outermost part of the collision-dominated coma, temperatures of 300-400 K are reached due to UV pyrolytic heating.

Marconi, M. L.↗

Improved DORIS Reference Frame Solution from NASA GSFC

At GSFC, since 2008, we have been routinely processing data to DORIS and SLR satellites from 1993. A SINEX time series, based on processing of DORIS data from 1993 to 2008 (designated wd10) was included in the IDS combination for ITRF2008 (Le Bail et al., 2010; Valette et al., 2010). We have updated this series with the addition of new satellites Cryosat2 and Jason-2, and the new series (designated wd12) is routinely submitted to the IDS combination center for inclusion in the DORIS operational combination. In preparation for an eventual reprocessing of all the DORIS data for eventual inclusion in a new ITRF we are now updating our processing standards. As a first step, we update to the ITRF2008 reference frame as expressed through DPOD2008. In addition, we apply the GMF and GPT models for the troposphere, and we update the modeling for the change in pitch of SPOT-5 solar arrays after January 2008. Finally, we consider updated standards for static and time-variable gravity modeling. With this base series, we compute cumulative solution, expressed in ITRF2008, and examine the week-by-week station solution parameters, in particular scale, WRMS and Helmert transformation parameters. Finally we consider a joint solution with SLR, where the DORIS system is tied to SLR in two ways, first through the orbit computations using satellites tracked by both SLR and DORIS (e.g. TOPEX, Envisat, Jason-2, Cryosat2), and second through explicit ties at collocated sites. As one of the means of testing of these DORIS-only and SLR+DORIS solutions, we examine the vertical rates at sites in the vicinity of tide gauges.

Lemoine, Frank↗

PMR polyimides with improved high temperature performance

Studies were performed to investigate the effect of substituting a hexafluoro isopropyl idene connecting group for a carbonyl group of a PMR polyimide monomeric reactant on the thermo-mechanical properties processability of graphite fiber reinforced PMR polyimide composites. Composites were fabricated utilizing PMR methodology. Monomeric reactant solutions of various stoichiometric ratios were used to impregnate Hercules HTS graphite fiber. The processing characteristics and elevated temperature (600 F) mechanical properties of the composites are described.

Vannucci, R. D.↗

Photodeposition of amorphous polydiacetylene films from monomer solutions onto transparent substrates

Polydiacetylenes are a very promising class of polymers for both photonic and electronic applications because of their highly conjugated structures. For these applications, high-quality thin polydiacetylene films are required. We have discovered a novel technique for obtaining such films of a polydiacetylene derivative of 2-methyl-4-nitroaniline using photodeposition from monomer solutions onto UV transparent substrates. This heretofore unreported process yields amorphous polydiacetylene films with thicknesses on the order of I micron that have optical quality superior to that of films grown by standard crystal growth techniques. Furthermore, these films exhibit good third-order nonlinear optical susceptibilities; degenerate four-wave mixing experiments give x(3) values on the order of 10(exp -8) - 10(exp -7) esu. We have conducted masking experiments which demonstrate that photodeposition occurs only where the substrate is directly irradiated, clearly indicating that the reaction occurs at the surface. Additionally, we have also been able to carry out photodeposition using lasers to form thin polymer circuits. In this work, we discuss the photodeposition of polydiacetylene thin films from solution, perform chemical characterization of these films, investigate the role of the substrate, speculate on the mechanism of the reaction, and make a preliminary determination of the third-order optical nonlinearity of the films. This simple, straightforward technique may ultimately make feasible the production of polydiacetylene thin films for technological applications.

Paley, M. S.↗

Synthetic aperture radar signal processing on the MPP

Satellite-borne Synthetic Aperture Radars (SAR) sense areas of several thousand square kilometers in seconds and transmit phase history signal data several tens of megabits per second. The Shuttle Imaging Radar-B (SIR-B) has a variable swath of 20 to 50 km and acquired data over 100 kms along track in about 13 seconds. With the simplification of separability of the reference function, the processing still requires considerable resources; high speed I/O, large memory and fast computation. Processing systems with regular hardware take hours to process one Seasat image and about one hour for a SIR-B image. Bringing this processing time closer to acquisition times requires an end-to-end system solution. For the purpose of demonstration, software was implemented on the present Massively Parallel Processor (MPP) configuration for processing Seasat and SIR-B data. The software takes advantage of the high processing speed offered by the MPP, the large Staging Buffer, and the high speed I/O between the MPP array unit and the Staging Buffer. It was found that with unoptimized Parallel Pascal code, the processing time on the MPP for a 4096 x 4096 sample subset of signal data ranges between 18 and 30.2 seconds depending on options.

Ramapriyan, H. K.↗

The Fractional Step Method Applied to Simulations of Natural Convective Flows

This paper describes research done to apply the Fractional Step Method to finite-element simulations of natural convective flows in pure liquids, permeable media, and in a directionally solidified metal alloy casting. The Fractional Step Method has been applied commonly to high Reynold's number flow simulations, but is less common for low Reynold's number flows, such as natural convection in liquids and in permeable media. The Fractional Step Method offers increased speed and reduced memory requirements by allowing non-coupled solution of the pressure and the velocity components. The Fractional Step Method has particular benefits for predicting flows in a directionally solidified alloy, since other methods presently employed are not very efficient. Previously, the most suitable method for predicting flows in a directionally solidified binary alloy was the penalty method. The penalty method requires direct matrix solvers, due to the penalty term. The Fractional Step Method allows iterative solution of the finite element stiffness matrices, thereby allowing more efficient solution of the matrices. The Fractional Step Method also lends itself to parallel processing, since the velocity component stiffness matrices can be built and solved independently of each other. The finite-element simulations of a directionally solidified casting are used to predict macrosegregation in directionally solidified castings. In particular, the finite-element simulations predict the existence of 'channels' within the processing mushy zone and subsequently 'freckles' within the fully processed solid, which are known to result from macrosegregation, or what is often referred to as thermo-solutal convection. These freckles cause material property non-uniformities in directionally solidified castings; therefore many of these castings are scrapped. The phenomenon of natural convection in an alloy under-going directional solidification, or thermo-solutal convection, will be explained. The development of the momentum and continuity equations for natural convection in a fluid, a permeable medium, and in a binary alloy undergoing directional solidification will be presented. Finally, results for natural convection in a pure liquid, natural convection in a medium with a constant permeability, and for directional solidification will be presented.

Westra, Douglas G.↗

Demonstration of Data Processing and Fusion from Distributed Radars for AAM Surveillance

Advanced Air Mobility (AAM) is an active area of development which foresees the integration of autonomous uncrewed aircraft into the civil airspace for air transportation of people and cargo. Safe integration requires significant technological developments and extensive testing phases of sensing and surveillance strategies in dense airspace. Compared to well-assessed manned aviation systems scenarios, surveillance strategies in the AAM and small Uncrewed Aircraft Vehicles (UAVs) context need to detect smaller platforms flying at lower altitude against cluttered backgrounds in dense airspace. Fusion of data provided by a network of distributed sensing nodes is a powerful tool to enable detection and tracking in such complex conditions. This paper contributes to this research direction by proposing a surveillance strategy for the AAM environment based on sensor fusion of data acquired by distributed ground-based radars. Specifically, experimental data collected with three independent radars, observing the flight of two small UAVs, are used. Data fusion at tracking level is based on a leader-helper strategy where the leader radar uses the helper’s measurements to increase the lifespan of its generated tracks. This solution shows promising results with a 10% increase in track coverage with respect to the standalone leader radar tracking solution. The paper also proposes an interference removal processing method which is applied on the data collected by two of the radars.

Federica Vitiello↗

Temperature dependence of protein solubility-determination, application to crystallization, and growth kinetics studies

A scintillation method was developed for determinations of the temperature dependence of the solubility, and of nucleation induction times of proteins, in 50-100 mu(l) volumes of solution. Solubility data for lysozyme and horse serum albumin were obtained for various combinations of pH and precipitant concentrations. These data and the nucleation induction information were used for dynamic crystallization control, that is, for the controlled separation of nucleation and growth stages. Individual lysozyme and horse serum albumin crystals were grown in 15-20 mu(l) solution volumes contained in x-ray capillaries. The morphology and kinetics of the growth and dissolution of lysozyme in aqueous solutions with 2.5 percent NaCl and at pH = 4.5 was studied in situ with a depth resolution of 300 A (4 unit cells) by high resolution optical microscopy and digital image processing. The bulk super- or under saturation, sigma, of the solution inside a closed growth cell was controlled by temperature. The growth habit was bound by (110) and (101) faces that grew through layer spreading, although with different growth rate dependencies on supersaturation/temperature. At sigma less than 10 (obtained at higher temperatures) growth was purely kinetic ally controlled, with impurity effects (macrostep formation and kinetic hindrance) becoming significant for sigma less than 2. At sigma greater than 10 (lower temperatures), anisotropies in the interfacial kinetics were more pronounced, with interfacial kinetics and bulk transport becoming equally important to the growth morphology. Growth rates were growth history dependent. The formation of striations (layers of irregularly incorporated solution) was unambiguously correlated with growth temperature variations. Etching exposed dislocations and various high-index faces whose growth morphologies were studied during return to the steady state growth form. Growth steps were observed to originate from two-dimensional nuclei or from outcrops of growth striations, and from dislocations that preferentially formed in growth sector boundaries.

Rosenberger, Franz↗

Manufacturing of Smart Structures Using Fiber Placement Manufacturing Processes

Smart structures research and development, with the ultimate aim of rapid commercial and military production of these structures, are at the forefront of the Synthesis and Processing of Intelligent Cost-Effective Structures (SPICES) program. As part of this ARPA-sponsored program, MDA-E is using fiber placement processes to manufacture integrated smart structure systems. These systems comprise advanced composite structures with embedded fiber optic sensors, shape memory alloys, piezoelectric actuators, and miniature accelerometers. Cost-effective approaches and solutions to smart material synthesis in the fiber-placement process, based upon integrated product development, are discussed herein.

Thomas, Matthew M.↗

Solutions of one-dimensional steady nozzle flow revisited

A formulation is presented by which any iteration process for obtaining the entropy increase in the flow of a one-dimensional steady nozzle is eliminated, and the simple solution of a quadratic equation is obtained. The proper parameters are then explicitly seen in the equation, and their effects on the solution are easily determined. Since only one root of the equation is physically admissible, entropy production, and therefore the shock wave, are uniquely determined by this set of parameters.

Liou, Meng-Sing↗

X-57 Flight Systems Integration Path

The foundation for a safe and successful flight test of the National Aeronautics and Space Administration (NASA) X-57 Maxwell all-electric experimental airplane, or any X-Plane, is comprehensive system testing on the ground. This test campaign includes verification and validation (V&V) that the integrated system operates as designed and expected, as well as understanding how the system reacts and responds to failures that can occur during flight by performing failure modes and effects testing (FMET). The aircraft should be in the final flight configuration for these test activities because any modifications, even those that appear insignificant, could affect test outcomes. Although the plan was to perform V&V and FMET testing once the airplane was in the flight configuration, due to multiple component redesigns, concurrent software development, and other problems with on-aircraft testing, the X-57 Maxwell never made it into a full-flight configuration. As a result, a build-up approach was followed to test software and hardware as they became ready in order to continue making progress wherever possible. Using this approach revealed problems with the hardware and software faster than waiting for a full-flight configuration, allowing solutions to be found more quickly and in parallel with other project tasks. Other than unloaded motor testing in a lab setting, the only other test setup was on the airplane itself. On-aircraft testing was preferrable in order to test things as close to a flight configuration as possible but was time consuming due to the requirements for testing on the airplane. To overcome some of the on-aircraft barriers, off-aircraft test configurations, such as the Systems Integration Laboratory (SIL) and hardware-in-the-loop (HIL) setups, were used, but each of these setups had limitations to be considered. As a result, solutions found in the SIL or HIL configurations did not always work as expected on the airplane, resulting in an iterative process between on- and off-aircraft testing to find the final solution. Having a dedicated test platform such as an iron bird that closely represents the aircraft - without flight hardware - would have been the most effective off-aircraft test setup, which could have allowed the project to save time and money and potentially reach flight. This paper will highlight the V&V and FMET considerations and testing prerequisites, the build-up approaches to both software and system testing, the benefits and drawbacks to different test configurations, as well as battery testing and operations.

Kassidy M. Mclaughlin↗

X-57 Flight Systems Integration Path

The foundation for a safe and successful flight test of the National Aeronautics and Space Administration (NASA) X-57 Maxwell all-electric experimental airplane, or any X-Plane, is comprehensive system testing on the ground. This test campaign includes verification and validation (V&V) that the integrated system operates as designed and expected, as well as understanding how the system reacts and responds to failures that can occur during flight by performing failure modes and effects testing (FMET). The aircraft should be in the final flight configuration for these test activities because any modifications, even those that appear insignificant, could affect test outcomes. Although the plan was to perform V&V and FMET testing once the airplane was in the flight configuration, due to multiple component redesigns, concurrent software development, and other problems with on-aircraft testing, the X-57 Maxwell never made it into a full-flight configuration. As a result, a build-up approach was followed to test software and hardware as they became ready in order to continue making progress wherever possible. Using this approach revealed problems with the hardware and software faster than waiting for a full-flight configuration, allowing solutions to be found more quickly and in parallel with other project tasks. Other than unloaded motor testing in a lab setting, the only other test setup was on the airplane itself. On-aircraft testing was preferrable in order to test things as close to a flight configuration as possible but was time consuming due to the requirements for testing on the airplane. To overcome some of the on-aircraft barriers, off-aircraft test configurations, such as the Systems Integration Laboratory (SIL) and hardware-in-the-loop (HIL) setups, were used, but each of these setups had limitations to be considered. As a result, solutions found in the SIL or HIL configurations did not always work as expected on the airplane, resulting in an iterative process between on- and off-aircraft testing to find the final solution. Having a dedicated test platform such as an iron bird that closely represents the aircraft - without flight hardware - would have been the most effective off-aircraft test setup, which could have allowed the project to save time and money and potentially reach flight. This paper will highlight the V&V and FMET considerations and testing prerequisites, the build-up approaches to both software and system testing, the benefits and drawbacks to different test configurations, as well as battery testing and operations.

Kassidy McLaughlin↗

Similarity solutions for phase-change problems

A modification of Ivantsov's (1947) similarity solutions is proposed which can describe phase-change processes which are limited by diffusion. The method has application to systems that have n-components and possess cross-diffusion and Soret and Dufour effects, along with convection driven by density discontinuities at the two-phase interface. Local thermal equilibrium is assumed at the interface. It is shown that analytic solutions are possible when the material properties are constant.

Canright, D.↗