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At least 829 records · Page 46
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

The chemical composition of the pre-solar nebula

The chemical composition of comets may reflect an origin in the molecular cloud which subsequently formed the solar nebula. The chemistry of different types of interstellar clouds is contrasted, including an inventory of molecular species detected in Orion and in TMC 1. The first astronomical detections of the J = (1-0) transition of HCS(+) and the J = (16-15) transition of HC5N and the first detection of SO2 in a cold dust cloud are reported.

Irvine, W. M.↗
NASA NTRS1984

The reactions of cobalt, iron and nickel in SO-2 atmospheres: Similarities and differences

The reactions of cobalt, iron and nickel in SO2 atmospheres are reviewed and compared. A mixed oxide-sulfide product layer is observed in all cases. Cobalt and nickel exhibits similar behavior. The observed rates are near the sulfidation rates, and the reaction rate is strongly influenced by the outward diffusion of metal through an interconnected sulfide network. A continuous interconnected sulfide is not observed in the oxide-sulfide scales formed on iron, and the reaction rates are more difficult to summarize. The differences and similarities among the three metals are explained in terms of the absence of scale-gas equilibrium and the ratio of the metal diffusivity in the corresponding oxide and sulfide.

Jacobson, N. S.↗
NASA NTRS1984

Solar thermochemical process interface study

The design and analyses of a subsystem of a hydrogen production process are described. The process is based on solar driven thermochemical reactions. The subject subsystem receives sulfuric acid of 60% concentration at 100 C, 1 atm pressure. The acid is further concentrated, vaporized, and decomposed (at a rate of 122 g moles/sec H2SO4) into SO2, O2, and water. The produce stream is cooled to 100 C. Three subsystem options, each being driven by direct solar energy, were designed and analyzed. The results are compared with a prior study case in which solar energy was provided indirectly through a helium loop.

Source record↗
NASA NTRS1985

Oxidation and hot corrosion of hot-pressed Si3N4 at 1000 deg C

The oxidation and hot corrosion of a commercial, hot-pressed Si3N4 were investigated at 1000 C under an atmosphere of flowing O2. For the hot corrosion studies, thin films of Na2SO4 were airbrushed on the Si3N4 surface. The hot corrosion attack was monitored by the following techniques: continuous weight measurements, SO2 evolution, film morphology, and chemical analyses. Even though the hot corrosion weight changes after 25 hr were relatively small, the formation of SiO2 from oxidation of Si3N4 was an order of magnitude greater in the presence of molten Na2SO4. The formation of a protective SiO2 phase at the Si3N4 surface is minimized by the fluxing action of the molten Na2SO4 thereby allowing the oxidation of the Si3N4 to proceed more rapidly. A simple process is proposed to account for the hot corrosion process.

Fielder, W. L.↗
NASA NTRS1985

Sulfur Cycle

Among the general categories of tropospheric sulfur sources, anthropogenic sources have been quantified the most accurately. Research on fluxes of sulfur compounds from volcanic sources is now in progress. Natural sources of reduced sulfur compounds are highly variable in both space and time. Variables, such as soil temperature, hydrology (tidal and water table), and organic flux into the soil, all interact to determine microbial production and subsequent emissions of reduced sulfur compounds from anaerobic soils and sediments. Available information on sources of COS, CS2, DMS, and H2S to the troposphere in the following paragraphs are summarized; these are the major biogenic sulfur species with a clearly identified role in tropospheric chemistry. The oxidation of SO2 to H2SO4 can often have a significant impact on the acidity of precipitation. A schematic representation of some important transformations and sinks for selected sulfur species is illustrated.

Hariss, R.↗
NASA NTRS1985

Geologic processes on Venus: An update

Studies of Venera 15 and 16 radar image and altimetry data and reevaluation of Pioneer Venus and earlier Venera data have greatly expanded the perception of the variety and complexity of geologic processes on Venus. PV data have discriminated four highland regions (each different in geomorphic appearance), a large upland rolling plains region, and smaller areas of lowland plains. Two highland volcanic centers were identified that may be presently active, as suggested by their geomorphologic appearance combined with positive gravity anomalies, lightning strike clusters, and a change in SO2 content in the upper atmosphere. Geochemical data obtained by the Venera landers have indicated that one upland area and nearby rolling plains are composed of volcanic rocks, probably basalts or syenites. New Venera radar images of the Ishtar Terra region show folded and/or faulted linear terrain and associated volcanic features that may have been deformed by both compressional and extensional forces. Lowland surfaces resemble the mare basaltic lava flows that fill basins on the Moon, Mars and Earth. Ubiquitous crater like forms may be of either volcanic or impact origin; the origin of similar lunar features was determined by the character of their ejecta deposits.

Masursky, H.↗
NASA NTRS1984

Drift wave instabilities in a high beta multispecies plasma

The dispersion relation for drift-Alfven waves in two-component (cold and hot), high beta inhomogeneous multispecies plasma containing protons, oxygen, and sulfur ions is solved numerically. The magnetic field is assumed to have a gradient in simple slab geometry configuration. The plasma ion composition consists of H, O, S, SO2, and Na ions. The effect of heavy ions and multiple charge states on the growth rates has been numerically estimated for assumed ion compositions. The numerical calculations of growth rates also have been performed by using ion composition and plasma parameters based on Voyager spacecraft in the magnetospheres of Jupiter and Saturn.

Patel, V. L.↗
NASA NTRS1984

Importance of formaldehyde in cloud chemistry

A physical-chemical model which is an extension of that of Hong and Carmichael (1983) is used to investigate the role of formaldehyde in cloud chemistry. This model takes into account the mass transfer of SO2, O3, NH3, HNO3, H2O2, CO2, HCl, HCHO, O2, OH and HO2 into cloud droplets and their subsequent chemical reactions. The model is used to assess the importance of S(IV)-HCHO adduct formation, the reduction of H2O2 by HCHO, HCHO-free radical interactions, and the formation of HCOOH in the presence of HCHO in cloud droplets. Illustrative calculations indicate that the presence of HCHO inhibits sulfate production rate in cloud droplets. The direct inhibition of sulfate production rate in cloudwater due to nucleophilic addition of HSO3(-) to HCHO(aq) to form hydroxymethanesulfonate is generally low for concentrations of HCHO typical of ambient air. However, inhibition of sulfate production due to formaldehyde-free radical interactions in solution can be important. These formaldehyde-free radical reactions can also generate appreciable quantities of formic acid.

Adewuyi, Y. G.↗
NASA NTRS1984

Reaction products on current or potential reversal in Li/SOCl2 cells

The products formed during abnormal operation due to current or potential reversal in Li/SOCl2 cells have been identified by several complementary analytical techniques. In addition to the expected corrosion of cell components, the following compounds were found: Cl2, SO2, SO2Cl2, S2Cl2 and SCl2. The presence of Cl2O and ClO2 reported by Salmon el al. (1982) has not been confirmed.

Carter, B. J.↗
NASA NTRS1985

Mechanistic studies related to the safety of Li/SOCl2 cells

Mechanistic studies of the reactions in Li-SOCl2 cells have been undertaken to improve understanding of the safety problems of these cells. The electrochemical reduction of 1.5M LiAlCl4/SOCl2 has been investigated using gas chromatography, electron spin resonance spectroscopy, and infrared spectroscopy. Cl2 and S2Cl2 have been identified as intermediates in the reduction of SOCl2, along with a radical species (g/xx/ = 2.004, g/yy/ = 2.016, g/zz/ = 2.008) and the proposed triplet ground-state dimer of this radical. SO2 and sulfur have been identified as products. Based upon these findings, a mechanism for the electrochemical reduction of 1.5M LiAlCl4/SOCl2 has been proposed, and its implications for safety of Li-SOCl2 cells during discharge to +0.5V at 25-30 C are discussed.

Carter, B. J.↗
NASA NTRS1985

Mass Transport Phenomena Between Bubbles and Dissolved Gases in Liquids Under Reduced Gravity Conditions

The long term objective of the experiment is to observe the dissolution of isolated, immobile gas bubbles of specified size and composition in a solvent liquid of known concentration in the reduced gravity environment of earth orbit. Preliminary bubble dissolution experiment conducted both in the NASA Lewis 2.2 sec drop tower and in normal gravity using SO2 - Toluene system were not completely successful in their objective. The method of gas injection and lack of bubble interface stabiliy experienced due to the extreme solubility of SO in Toluene has the effects of changing the problem from that of bubble dissolution to one of bubble formation stability and subsequent dissolution in a liquid of unknown initial solute concentration. Current work involves further experimentation in order to refine the bubble injection system and to investigate the concept of having a bubble with a critical radius in a state of unstable equilibrium.

Dewitt, K. J.↗
NASA NTRS1985

Laboratory evaluation and application of microwave absorption properties under simulated conditions for planetary atmospheres

Radio absorptivity data for planetary atmospheres obtained from spacecraft radio occultation experiments and Earth-based radio astronomical observations can be used to infer abundances of microwave absorbing atmospheric constituents in those atmospheres, as long as reliable information regarding the microwave absorbing properties of potential constituents is available. The use of theoretically-derived microwave absorption properties for such atmospheric constituents, or laboratory measurements of such properties under environmental conditions which are significantly different than those of the planetary atmosphere being studied, often lead to significant misinterpretation of available opacity data. Steffes and Eshleman showed that under environmental conditions corresponding to the middle atmosphere of Venus, the microwave absorption due to atmospheric SO2 was 50 percent greater than that calculated from Van Vleck-Weiskopff theory. Similarly, the opacity from gaseous H2SO4 was found to be a factor of 7 greater than theoretically predicted for conditions of the Venus middle atmosphere. The recognition of the need to make such measurements over a range of temperatures and pressures which correspond to the periapsis altitudes of radio occultation experiments, and over a range of frequencies which correspond to both radio occultation experiments and radio astronomical observations, has led to the development of a facility at Georgia Tech which is capable of making such measurements.

Steffes, P. G.↗
NASA NTRS1986

Role of molybdenum in the Na sub 2SO sub 4 induced corrosion of superalloys at high temperatures

Sodium sulfate induced corrosion of a molybdenum containing nickel-base superalloy, Udimet 700, was studied in laboratory furnace tests and in a high velocity (Mach 0.3) burner rig. The effect of SO2 content in the atmosphere on the corrosion behavior in the laboratory furnace tests was determined. Catastrophic corrosion occurs only when the melt contains MoO3 in addition to Na2SO4 and Na2MoO4. The conditions under which catastrophic corrosion occurs are identified and a mechanism is described to explain the catastrophic corrosion.

Misra, A. K.↗
NASA NTRS1986

Chemical analysis of aerosol in the Venusian cloud layer by reaction gas chromatography on board the Vega landers

The experiment on sulfuric acid aerosol determination in the Venusian cloud layer on board the Vega landers is described. An average content of sulfuric acid of approximately 1 mg/cu m was found for the samples taken from the atmosphere at heights from 63 to 48 km and analyzed with the SIGMA-3 chromatograph. Sulfur dioxide (SO2) was revealed in the gaseous sample at the height of 48 km. From the experimental results and blank run measurements, a suggestion is made that the Venusian cloud layer aerosol consists of more complicated particles than the sulfuric acid water solution does.

Gelman, B. G.↗
NASA NTRS1986

Measurements of the composition of aerosol component of Venusian atmosphere with Vega 1 lander, preliminary data

Preliminary investigation of mass spectra of gaseous products of pyrolyzed Venusian cloud particles collected and analyzed by the complex device of mass-spectrometer and collector pyrolyzer on board Vega 1 lander revealed the presence of heavy particles in the upper cloud layer. Based on 64 amu peak (SO2+), an estimate of the lower limit of the sulfuric acid aerosol content at the 62 to 54 km heights of approximately 2.0 mg/cu m is obtained. A chlorine line (35 and 37 amu) is also present in the mass spectrum with a lower limit of the chlorine concentration of approximately 0.3 mg/ cu m.

Surkov, Y. A.↗
NASA NTRS1985

Observational tests for sulfur allotropes on Io

It has been established that, if the Io surface is primarily composed of sulfur allotropes, a change in reflectivity at certain wavelengths should be observable shortly after eclipse reappearance (ER). Four ERs were observed during July and August 1983 with a 61-cm telescope on Mauna Kea, Hawaii, and no posteclipse brightening effects in the filter bands selected for sensitivity to color changes in sulfur were found. The proposed model of the brightness change of elemental sulfur (S8) implies that this material covers less than 50 percent of the Io surface. It is concluded that no significant condensation of optically thick SO2 occurred on the Io surface during the four eclipses.

Hammel, H. B.↗
NASA NTRS1986

Kinetics and mechanism of corrosion of SiC by molten salts

Corrosion of sintered alpha-SiC under thin films of Na2CO3/CO2, Na2SO4/O2, and Na2SO4/SO3 was investigated at 1000 C. Chemical analysis was used to follow silicate and silica evolution as a function of time. This information coupled with morphology observations leads to a detailed corrosion mechanism. In all cases the corrosion reactions occur primarily in the first few hours. In the Na2CO3/CO2 case, rapid oxidation and dissolution lead to a thick layer of silicate melt in about 0.25 h. After this, silica forms a protective layer on the carbide. In the Na2SO4/O2 case, a similar mechanism occurs. In the Na2SO4/SO3 case, a porous nonprotective layer of SiO2 grows directly on the carbide, and a silicate melt forms above this. In addition, SiO2 and regenerated Na2SO4 form at the melt/gas interface due to reaction of silicate with SO3 and SO2 + O2. The reaction slows when the lower silica layer becomes nonporous.

Jacobson, N. S.↗
NASA NTRS1985

The photochemistry of the atmospheres of the outer planets and their satellites

The thermal structure and composition of Uranus, Neptune, Saturn, Jupiter, Titan, and Io are described. Molecular hydrogen is the dominant constituent in the atmosphere of the outer planets. The hydrogen and helium, methane, ammonia and phosphine, and carbon monoxide photochemical reactions of the outer planets are studied. The importance of Jupiter's lightning as a source of organic matter is examined. The aerosol and haze layers of the stratosphere of Jupiter, Saturn, Neptune, and Uranus are observed. The photochemistry of Titan's atmosphere, which includes nitrogen, methane, carbon monoxide, and carbon dioxide reactions, is analyzed. The SO2 atmosphere on Io is discussed.

Strobel, D. F.↗