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At least 829 records · Page 46

Effects of Rolling Reduction on Critical Current Density and Microstructure of Bi-2212 Wires

Bi-2212 Rutherford cables have been fabricated into flat racetrack coils and canted-cosine-theta dipole magnets. The performance gap between the magnets made with Rutherford cables and the “short-sample-limit” is about 30%. To better understand the influence of Rutherford cable processing on the strand performance, we studied three Bi-2212 wires with filament architectures of 37 × 18 and 55 × 18 and diameters of 0.8 and 1.0 mm. To simulate the deformation caused by cabling process, the three wires were rolled with thickness reductions ranging from 10% to 30%. The aspect ratios of rolled strands are between 1.29 and 2.05. The low aspect-ratio wire is also an interesting form for fabricating solenoid coils with higher packing density. The round and rolled strands were heat-treated under 50 bar and with maximum heat treatment temperatures of 885.5 °C and 890.5 °C. The rolling deformation reduced filament size uniformity, resulting in filament merging in fully heat-treated wires. It was found that rolling reduction reduced wire critical current density (JE) by 16 to 18%, but the JE decrease saturated at 15 to 20% of the thickness reduction. It is believed that the reduced JE results from the filament merging caused by rolling and non-uniform shrinking during overpressure heat treatment.

Bi-2212 wire↗

Shifts in bacterial traits under chronic nitrogen deposition align with soil processes in arbuscular, but not ectomycorrhizal-associated trees

Nitrogen (N) deposition increases soil carbon (C) storage by reducing microbial activity. These effects vary in soil beneath trees that associate with arbuscular (AM) and ectomycorrhizal (ECM) fungi. Variation in carbon C and N uptake traits among microbes may explain differences in soil nutrient cycling between mycorrhizal associations in response to high N loads, a mechanism not previously examined due to methodological limitations. Here, we used quantitative Stable Isotope Probing (qSIP) to measure bacterial C and N assimilation rates from an added organic compound, which we conceptualize as functional traits. As such, we applied a trait-based approach to explore whether variation in assimilation rates of bacterial taxa can inform shifts in soil function under chronic N deposition. We show taxon-specific and community-wide declines of bacterial C and N uptake under chronic N deposition in both AM and ECM soils. N deposition-induced reductions in microbial activity were mirrored by declines in soil organic matter mineralization rates in AM but not ECM soils. Our findings suggest C and N uptake traits of bacterial communities can predict C cycling feedbacks to N deposition in AM soils, but additional data, for instance on the traits of fungi, may be needed to connect microbial traits with soil C and N cycling in ECM systems. In conclusion, our study also highlights the potential of employing qSIP in conjunction with trait-based analytical approaches to inform how ecological processes of microbial communities influence soil functioning.

59 BASIC BIOLOGICAL SCIENCES↗

Machinable, high‐conductivity NaSICON through mitigation of humidity effects during solid‐state synthesis

The Na + super ion conductor (NaSICON, Na 1+x Zr 2 Si x P 3-x O 12 ) is a solid electrolyte well-known for fast, selective Na + transport at low temperatures, uniquely enabling sodium-based batteries. Producing high-quality NaSICON from solid-state methods, especially when cost-effective, potentially hygroscopic precursors are used, is not trivial. To understand and eliminate the influence of humidity during processing, a scheme was developed to reproducibly yield a high Na + conductivity (3.75 mS/cm at 25°C, 81.7 mS/cm at 150°C), high density (97%), and machinable NaSICON without the use of binders, sintering aids, or dopants. Controlled humidity studies over 20%–50% RH coupled with thermal, structural, and electrical analysis reveal that calcination temperatures < 1000°C leave NaSICON processing susceptible to water absorption at > 20% RH due to the presence of hygroscopic Na 3 PO 4 and Na 2 CO 3 during shaping, pressing, and sintering. Water absorption results in NaSICON with lower densities, machinability, and Na+ conductivity, due to impaired intergranular Na+ transport. At the other extreme, fully converting precursor to the NaSICON phase at 1230°C before pressing and sintering leads to poor conductivity and density. By calcining at 1000°C, excellent quality NaSICON may be produced under a range of laboratory environments, enabling low-cost production of high-conductivity, machinable NaSICON necessary the ever-growing energy storage market.

NaSICON↗

Doping Metallic Grain Boundaries to Control Atomic Structure and Damage Tolerance (Final Report)

The interfaces between crystals, known as grain boundaries, often act as sites for crack and void nucleation during plastic deformation of metallic materials. While it is known that interfacial character and structural state can greatly influence this damage nucleation process, the current level of control over such details is extremely limited. The objective of this project was to obtain a fundamental understanding of how metallic grain boundary structure can be controlled through intelligent doping, with the idea of inducing planned grain boundary phases or complexions. The effect of complexion structure on dislocation accommodation mechanisms was studied, to improve the field’s understanding of damage nucleation at interfaces. While mechanical damage was the primary focus, the project showed that amorphous complexions can also improve a material’s resistance to radiation damage, providing a single materials design concept that can address multiple important technological areas. This research used a combination of computational, experimental, and characterization techniques to isolate and understand the importance of nanoscale grain boundary structure and interfacial chemistry. The fundamental insights provided by this project enable the creation of advanced engineering metals with improved damage tolerance.

36 MATERIALS SCIENCE↗

CRADA Number NFE1706843 with SkyNano LLC (CRADA Final Report)

Cooperative Research and Development Agreement (CRADA) NFE-17-06843 between Oak Ridge National Laboratory (ORNL) and SkyNano LLC focused on studying and developing a better fundamental understanding of SkyNano’s technology to capture and convert CO 2 into solid carbon nanostructures, including carbon nanotubes (CNTs), using electrochemistry at elevated temperatures in molten salts. The project focused on developing a fundamental scientific understanding of how electrochemistry influences the dynamic catalytic processes that drive the formation of CNTs on electrodes, while developing synthesis and processing technology relevant to implementation of the technology – including chemical engineering to aid in recapturing the lithium carbonate electrolyte essential to the process, and the modeling and testing of systems with the required thermal management at practical scales.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effect of laser power on roughness and porosity in laser powder bed fusion of stainless steel 316L alloys measured by X-ray tomography

The quality of metal objects fabricated via laser powder bed fusion are highly affected by process parameters, and their influence on final products is yet to be fully explored. In this work, pyrometry signals of the melt pool were collected from a set of stainless-steel samples during manufacturing and the effect of laser power on porosity and roughness of final printed parts was analyzed. Results show that the melt pool pyrometry signal of contours increases with higher laser power, whereas it is lower and decreases for the infilled part. Post-built X-ray computed tomography imaging reveals that porosity decreases while sample roughness increases upon increasing laser power. The decrease in porosity with increasing laser power is attributed to the larger size of the contour welds that were printed first, leading to an increase in dimension of the final products.

36 MATERIALS SCIENCE↗

Functional requirements for onboard management of space shuttle consumables, volume 2.

A study was conducted to develop the functional requirements for onboard management of space shuttle consumables. A specific consumables management concept for the space shuttle vehicle was developed and the functional requirements for the onboard portion of the concept were generated. Consumables management is the process of controlling or influencing the usage of expendable materials involved in vehicle subsystem operation. The subsystems considered in the study are: (1) propulsion, (2) power generation, and (3) environmental and life support.

Graf, P. J.↗

Effectiveness of solid lubricant coatings for friction in hard vacuum (10-9 tor)

A study was made of the efficiency of solid lubricating coatings, based on MoS2 with various binders, during friction and under highvacuum conditions. Mass spectrometry was used for an analysis of the composition of the gas evolved from the coatings in the friction process. It is shown that the vacuum level, loading, and sliding velocity influence coating effectiveness. In the friction process the solid lubricant coatings yield characteristic decay products associated with the chemical nature of the binders. The mechanism of coating breakdown during friction is associated with the binder breakdown mechanism.

Verkin, B. I.↗

Impulsive solar X-ray bursts

A set of 22 simple, impulsive solar flares, identified in the OSO-5 hard X-ray data, were analyzed together with coincident microwave and meterwave radio observations. The rise times and fall times of the X-ray bursts are found to be highly correlated and effectively equal, strongly suggesting a flare energizing mechanism that is reversible. The good time resolution available for these observations reveals that the microwave emission is influenced by an additional process, evident in the tendency of the microwave emission to peak later and decay more slowly than the symmetric X-ray bursts. Meterwave emission is observed in coincidence with the 5 events which show the strongest time correlation between the X-ray and microwave burst structure. This meterwave emission is characterized by U-burst radiation, indicating confinement of the flare source.

Crannell, C. J.↗

Rotor burst protection program: Experimentation to provide guidelines for the design of turbine rotor burst fragment containment rings

Empirical guidelines for the design of minimum weight turbine rotor disk fragment containment rings made from a monolithic metal were generated by experimentally establishing the relationship between a variable that provides a measure of containment ring capability and several other variables that both characterized the configurational aspects of the rotor fragments and containment ring, and had been found from exploratory testing to have had significant influence on the containment process. Test methodology and data analysis techniques are described. Results are presented in graphs and tables.

Mangano, G. J.↗

Impulsive solar X-ray bursts

A set of 22 simple impulsive solar flares, identified in the OSO 5 hard X-ray data, has been analyzed together with coincident microwave and meter-wave radio observations. The rise times and fall times of the X-ray bursts are found to be highly correlated and effectively equal, strongly suggesting a flare-energizing mechanism that is reversible. The good time resolution available for these observations reveals that the microwave emission is influenced by an additional process, evident in the tendency of the microwave emission to peak later and decay more slowly than the symmetric X-ray bursts. Meter-wave emission is observed in coincidence with five events which also show strong time correlation between the X-ray and microwave burst structure. This meter-wave emission is characterized by U-burst radiation, indicating confinement of the flare source. The relationship found between the X-ray burst duration and the calculated flare diameter, together with the thermal character of the X-ray spectra, gives additional support to the hypothesis that the impulsive component is driven by adiabatic compression and expansion of a magnetically confined plasma which is the common primary source of both X-ray and microwave emission.

Crannell, C. J.↗

Satellite Power System (SPS)

Potential organizational options for a solar power satellite system (SPS) were investigated. Selection and evaluation criteria were determined to include timeliness, reliability, and adequacy to contribute meaningfully to the U.S. supply; political feasibility (both national and international); and cost effectiveness (including environmental and other external costs). Based on these criteria, four organizational alternatives appeared to offer reasonable promise as potential options for SPS. A large number of key issues emerged as being factors which would influence the final selection process. Among these issues were a variety having to do with international law, international institutions, environmental controls, economics, operational flexibility, congressional policies, commercial-vs-governmental ownership, national dedication, and national and operational stategic issues.

Edler, H. G.↗

Optimization of a point-focusing, distributed receiver solar thermal electric system

This paper presents an approach to optimization of a solar concept which employs solar-to-electric power conversion at the focus of parabolic dish concentrators. The optimization procedure is presented through a series of trade studies, which include the results of optical/thermal analyses and individual subsystem trades. Alternate closed-cycle and open-cycle Brayton engines and organic Rankine engines are considered to show the influence of the optimization process, and various storage techniques are evaluated, including batteries, flywheels, and hybrid-engine operation.

Pons, R. L.↗

Smoke and dust particles of meteoric origin in the mesosphere and stratosphere

A height profile of ablated mass from meteors is calculated, assuming an incoming mass of 10 to the -16th g/sq cm/s (44 metric tons per day) and the velocity distribution of Southworth and Sekanina, which has a mean of 14.5 km/s. The profile peaks at 84 km. The fluxes of micrometeorites and residual meteoroids are also calculated. The coagulation of the evaporated silicates into 'smoke' particles is then followed by means of a model adapted from a previous study of the stratospheric sulfate layer. Numerous sensitivity tests are made. Features of the results are a sharp cutoff of the particle distribution above 90 km, and a surface area close to 10 to the -9th sq cm/cu cm all the way from 30 to 85 km. Some confirmation is obtained from balloon studies of condensation nuclei, although the various measurements differ greatly. The optical scattering and extinction are shown to be undetectable. Several potential applications are suggested: nucleation of sulfate particles and noctilucent clouds, scavenging of metallic ions and atoms, and perhaps other aeronomical effects. The latter are limited to processes that can be influenced by a collision time of the order of a day.

Hunten, D. M.↗

Development of a solvent processed insensitive propellant

Two types of low vulnerability propellants are studied which are distinguished by whether the binder is a rubber, such as polyurethane or CTBN, or a plasticizable polymer such as ethyl cellulose or cellulose acetate. The former propellants are made by a partial cure extrusion process while the latter are made by the conventional solvent process. Emphasis is given to a cellulose binder (plasticizer) RDX composition. The type of binder used, the particle size of the RDX and the presence of small quantities of nitrocellulose in the solvent processed compositions have important influences on the mechanical and combustion characteristics of the propellant. The low temperature combustion is of particular concern because of potential breakup of the grains that can lead to instability.

Trask, R.↗

Solar wind control of auroral zone geomagnetic activity

Solar wind magnetosphere energy coupling functions are analyzed using linear prediction filtering with 2.5 minute data. The relationship of auroral zone geomagnetic activity to solar wind power input functions are examined, and a least squares prediction filter, or impulse response function is designed from the data. Computed impulse response functions are observed to have characteristics of a low pass filter with time delay. The AL index is found well related to solar wind energy functions, although the AU index shows a poor relationship. High frequency variations of auroral indices and substorm expansions are not predictable with solar wind information alone, suggesting influence by internal magnetospheric processes. Finally, the epsilon parameter shows a poorer relationship with auroral geomagnetic activity than a power parameter, having a VBs solar wind dependency.

Clauer, C. R.↗

Electronic levels and charge distribution near the interface of nickel

The energy levels in clusters of nickel atoms were investigated by means of a series of cluster calculations using both the multiple scattering and computational techniques (designated SSO) which avoids the muffin-tin approximation. The point group symmetry of the cluster has significant effect on the energy of levels nominally not occupied. This influences the electron transfer process during chemisorption. The SSO technique permits the approaching atom or molecule plus a small number of nickel atoms to be treated as a cluster. Specifically, molecular levels become more negative in the O atom, as well as in a CO molecule, as the metal atoms are approached. Thus, electron transfer from the nickel and bond formation is facilitated. This result is of importance in understanding chemisorption and catalytic processes.

Waber, J. T.↗

Warm fog dispersal

The charged particle generator was further tested after some design modification. The generator performance was measured with additional instrumentation and found to confirm previous measurements. Plans for a field testing were than developed. The overall status of the program and the field test plans were presented to a group of atmospheric scientists and electrostatic experts at the NASA/MSFC sponsored USRA Workshop on Electrostatic Fog Dispersal at NCAR, Boulder, Colorado discussed in previous sections. The recommendations from this workshop are being evaluated as to whether NASA should proceed with the field test or whether further theoretical research on the phenomenon of electrostatic fog dispersal and additional development of the charged particle generator should be carried out. Information obtained from the USRA Workshop clearly identified three physical mechanisms that could possibly influence the fog dispersal process, which heretofore have not been considered, and which may provide additional insight to the direction of further fog dispersal work. These mechanisms are: the effect of corona discharge on the electric field strength at the surface, the influx of fog into the cleared volume by turbulent diffusion, and the increase in supersaturation as liquid water is removed, activating haze particles, and thus generating more fog. Plans are being formulated to investigate these mechanisms.

Frost, W.↗