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This document includes steps that building owners and operators can implement to achieve smart, healthy, and low-carbon outpatient healthcare buildings within their existing building portfolios. Outpatient healthcare includes diagnostic and treatment facilities for outpatient care, and these buildings often use packaged rooftop units for heating, cooling, and ventilation.
This work presents and applies a workflow for performing design optimization on gas-cooled pebble-bed reactors. Based on previous research, a representative equilibrium core of a pebble-bed reactor and a depressurized loss-of-forced-cooling model are created. These applications are built using the Multiphysics Object-Oriented Simulation Environment (MOOSE), specifically utilizing Griffin, Pronghorn, and Bison. After defining design-related parameters and quantities of interest regarding reactor safety and efficiency, this multiphysics model is sampled using the MOOSE stochastic tools module. The result is a comprehensive dataset of configurations, enabling sensitivity analysis and the generation of reduced-order models. Subsequently, the dataset and reduced-order models are employed in an optimization study aimed at maximizing fuel utilization while adhering to safety and operational constraints. The optimization process leads to an improvement of fuel utilization by approximately 10\%, compared to engineering-judgment-based nominal conditions.
We show that two-phase internal flow is ubiquitous to many systems due to its ability to transfer large amounts of heat effectively. Recent advances motivated by sustainability have pushed towards augmenting the heat transfer between the tube and the two-phase working fluid. Augmenting heat transfer in two-phase flows enables process intensification, and compactness leading to reduced cost and material consumption. This review investigates the effect of heat transfer enhancement techniques on different fluids including R134a, R407C, R22, etc … The techniques are categorized into passive and active and focus on durable enhancement methods which do not include surface structuring or coating. Passive techniques utilize geometrical and surface modifications to induce better mixing. Several passive techniques are analyzed including fins, inserts, and more. In analyzing these techniques, the effect of changing geometric parameters is studied, and the limitations are highlighted. Further, active techniques that enable heat transfer enhancement through applying power are also investigated. Electrohydrodynamic approaches are analyzed and compared to passive techniques. Additionally, the implications of heat exchange enhancement in the context of global energy are discussed. An energy analysis discretized by the use sector is conducted, with an emphasis on predicting the future potential for renewable and sustainable development. Moreover, although active approaches provide the highest heat transfer enhancement, due to implementation difficulties, passive techniques are more frequently adopted. The review ends with discussion of next-generation heat exchangers which will rely more on additive manufacturing due to its flexibility and reduced cost per part as the technology matures.
W7-X completed its plasma operation in hydrogen with island divertor and inertially cooled test divertor unit (TDU) made of graphite. A substantial set of plasma-facing components (PFCs), including in particular marker target elements, were extracted from the W7-X vessel and analysed post-mortem. The analysis provided key information about underlying plasma–surface interactions (PSI) processes, namely erosion, transport, and deposition as well as fuel retention in the graphite components. The net carbon (C) erosion and deposition distribution on the horizontal target (HT) and vertical target (VT) plates were quantified and related to the plasma time in standard divertor configuration with edge transform ι = 5/5, the dominant magnetic configuration of the two operational phases (OP) with TDU. The operation resulted in integrated high net C erosion rate of 2.8 mg s -1 in OP1.2B over 4809 plasma seconds. Boronisations reduced the net erosion on the HT by about a factor 5.4 with respect to OP1.2A owing to the suppression of oxygen (O). In the case of the VT, high peak net C erosion of 11μm at the strike line was measured during OP1.2B which converts to 2.5 nm s -1 or 1.4 mg s -1 when related to the exposed area of the target plate and the operational time in standard divertor configuration. PSI modelling with ERO2.0 and WallDYN-3D is applied in an interpretative manner and reproduces the net C erosion and deposition pattern at the target plates determined by different post-mortem analysis techniques. This includes also the 13 C tracer deposition from the last experiment of OP1.2B with local 13 CH 4 injection through a magnetic island in one half module. The experimental findings are used to predict the C erosion, transport, and deposition in the next campaigns aiming in long-pulse operation up to 1800 s and utilising the actively cooled carbon-fibre composite (CFC) divertor currently being installed. The CFC divertor has the same geometrical design as the TDU and extrapolation depends mainly on the applied plasma boundary. Extrapolation from campaign averaged information obtained in OP1.2B reveals a net erosion of 7.6 g per 1800 s for a typical W7-X attached divertor plasma in hydrogen.
ABSTRACT Shocks form the basis of our understanding for the density and velocity statistics of supersonic turbulent flows, such as those found in the cool interstellar medium (ISM). The variance of the density field, $\sigma ^2_{\rho /\rho _0}$, is of particular interest for molecular clouds (MCs), the birthplaces of stars in the Universe. The density variance may be used to infer underlying physical processes in an MC, and parametrizes the star formation (SF) rate of a cloud. However, models for $\sigma ^2_{\rho /\rho _0}$ all share a common feature – the variance is assumed to be isotropic. This assumption does not hold when a trans-/sub-Alfvénic mean magnetic field, ${B}_0$, is present in the cloud, which observations suggest is relevant for some MCs. We develop an anisotropic model for $\sigma _{\rho /\rho _0}^2$, using contributions from hydrodynamical and fast magnetosonic shocks that propagate orthogonal to each other. Our model predicts an upper bound for $\sigma _{\rho /\rho _0}^2$ in the high Mach number $(\mathcal {M})$ limit as small-scale density fluctuations become suppressed by the strong ${B}_0$. The model reduces to the isotropic $\sigma _{\rho /\rho _0}^2\!-\!\mathcal {M}$ relation in the hydrodynamical limit. To validate our model, we calculate $\sigma _{\rho /\rho _0}^2$ from 12 high-resolution, three-dimensional, supersonic, sub-Alfvénic magnetohydrodynamical (MHD) turbulence simulations and find good agreement with our theory. We discuss how the two MHD shocks may be the bimodally oriented overdensities observed in some MCs and the implications for SF theory in the presence of a sub-Alfvénic ${B}_0$. By creating an anisotropic, supersonic density fluctuation model, this study paves the way for SF theory in the highly anisotropic regime of interstellar turbulence.
A method of forming a water resistant boundary on a fissile material for use in a water cooled nuclear reactor is described. The method comprises coating the fissile material, such as a pellet of U3Si2 and/or the grain boundaries, to a desired thickness with a suitable coating material, such as atomic layer deposition or a thermal spray process. The coating material may be any non-reactive material with a solubility at least as low as that of UO2. Exemplary coating materials include ZrSiO4, FeCrAl, Cr, Zr, Al—Cr, CrAl, ZrO2, CeO2, TiO2, SiO2, UO2, ZrB2, Na2O—B2O3—SiO2—Al2O3 glass, Al2O3, Cr2O3, carbon, and SiC, and combinations thereof. The water resistant layer may be overlayed with a burnable absorber layer, such as ZrB2 or B2O3—SiO2 glass.
Optical Stochastic Cooling (OSC) is an advanced beam-cooling technique that will advance the traditional stochastic cooling. This method leverages optical radiation and high-precision feedback to cool the particles more efficiently than traditional stochastic methods by more than three orders of magnitude. As such, it is an enabler for the development of next generation discovery science machines at the frontiers of energy and intensity. This paper focuses on the development of the second phase of OSC and improving extreme beam cooling techniques in accelerators. The goal was to build and characterize a Mach-Zehnder Interferometer (MZI) in the FAST laser lab using known glass plates thickness which will allow future measurements of unknown phase change due to nonlinear amplification processes.
Previously, samples of coarse grained (CG, grain diameter > 1 µm), ultra-fine grained (UFG, 1 µm> grain diameter> 100 nm), and nanocrystalline (NC, 100 nm> grain diameter) grade 91 steel were neutron irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL). Grade 91 is a ferritic/martensitic steel alloy with a nominal composition of Fe-9%Cr-1%Mo by weight, and it is being studied for applications in advanced nuclear reactor designs including as a fuel cladding material in gas cooled reactors. To assess the viability of this alloy for nuclear applications, the role of grain boundary size has not been sufficiently explored as a mechanism for developing radiation-tolerant materials. To achieve an UFG microstructure the material was processed using equal channel angular pressing (ECAP), and the NC microstructure was achieved through high pressure torsion (HPT). Such samples of various geometries for different types of characterization were irradiated to a dose of 6 displacements per atom (DPA) at separate temperature conditions of 300 °C and 500 °C. Thus, there were a total of 6 experimental conditions, three grain sizes (CG, UFG, and NC), each irradiated at two different temperature conditions (300 °C and 500 °C).
Abstract The efficiency of air separation is tested using three different small‐scale cryogenic distillation columns. The performance of a random packed column is compared to the performance of two microchannel distillation (MCD) columns that use thin wicking structures and gas flow channels to achieve process intensification. The MCD columns tested include a plate‐type layered column and an additively manufactured porous honeycomb (AMPH) column. For columns with 25.4 cm of active height and run under similar conditions, the packed, plate‐type layering, and AMPH columns achieved approximate height equivalent of a theoretical plate (HETP) values of 5.5, 3.7, and 3.2 cm for nitrogen, and 5.9, 4.9, and 3.3 cm for argon. The AMPH column can produce up to 0.4 SLM of more than 90% purity oxygen with 12 W of cooling lift. These results demonstrate the feasibility of using additive manufacturing to construct MCD devices and pave a way for constructing novel MCD designs.
This document includes steps that building owners and operators can implement to achieve smart, healthy, and low-carbon large office buildings within their existing building portfolios. Large offices are typically over 50,000 square feet and often include complex heating and cooling systems.
In conventional processing, metals go through multiple manufacturing steps including casting, plastic deformation, and heat treatment to achieve the desired property. In additive manufacturing (AM) the same target must be reached in one fabrication process, involving solidification and cyclic remelting. The thermodynamic and kinetic differences between the solid and liquid phases lead to constitutional undercooling, local variations in the solidification interval, and unexpected precipitation of secondary phases. These features may cause many undesired defects, one of which is the so-called hot cracking. The response of the thermodynamic and kinetic nature of these phenomena to high cooling rates provides access to the knowledge-based and tailored design of alloys for AM. Here, we illustrate such an approach by solving the hot cracking problem, using the commercially important IN738LC superalloy as a model material. The same approach could also be applied to adapt other hot-cracking susceptible alloy systems for AM.
The Parker Solar Probe mission has observed near-continuous power in parallel ion cyclotron waves (PICWs) in the young, fast solar wind. These waves are unlikely to be directly produced by the turbulent cascade and are likely born of a local instability; yet, they are observed to both cool – and heat – the plasma. We propose that these observations can be self-consistently explained as the natural consequence of PICWs propagating in the inhomogeneous solar wind after they have been driven unstable. In this work, we argue that strong proton heating by a turbulent cascade of oblique ICWs will result in PICWs being driven unstable in a process known as quasi-linear focusing. Because the power in the turbulent cascade is concentrated at scales above the turbulent transition region, PICWs will be driven unstable within a range of wavenumbers parallel to the background magnetic field, 𝑘 ∥ , that is bounded from above by 𝑘$^{∗}_{∥P}$, corresponding to the start of the transition region. As unstable PICWs propagate away from the Sun to regions of lower proton density, their 𝑘 ∥ , multiplied by the proton inertial length 𝑑 p , increases. Eventually, 𝑘$^{∗}_{∥P}$ of the PICWs becomes larger than 𝑘$^{∗}_{∥P}$𝑑 p and the waves damp, heating the solar wind. We call this effect ‘cyclotron breaking’, in analogy with ocean waves breaking on the shore. We then discuss the testable predictions of the theory, including a distinct heating signature in which PICWs cool fast protons and heat slow protons at any given heliocentric distance 𝑟. Finally, we conjecture that cyclotron breaking can lead to net heating by PICWs if the power emitted as PICWs decreases sufficiently rapidly with 𝑟 that local emission of PICWs is overwhelmed by the local damping of PICWs generated closer to the Sun.
The ability to synthesize compositionally complex nanostructures rapidly is a key to high-throughput functional materials discovery. In addition to being time-consuming, a majority of conventional materials synthesis processes closely follow thermodynamics equilibria, which limit the discovery of new classes of metastable phases such as high entropy oxides (HEO). Herein, a photonic flash synthesis of HEO nanoparticles at timescales of milliseconds is demonstrated. By leveraging the abrupt heating and cooling cycles induced by a high-power-density xenon pulsed light, mixed transition metal salt precursors undergo rapid chemical transformations. Hence, nanoparticles form within milliseconds with a strong affinity to bind to the carbon substrate. Oxygen evolution reaction (OER) activity measurements of the synthesized nanoparticles demonstrate two orders of magnitude prolonged stability at high current densities, without noticeable decay in performance, compared to commercial IrO 2 catalyst. This superior catalytic activity originates from the synergistic effect of different alloying elements mixed at a high entropic state. It is found that Cr addition influences surface activity the most by promoting higher oxidation states, favoring optimal interaction with OER intermediates. The proposed high-throughput method opens new pathways toward developing next-generation functional materials for various electronics, sensing, and environmental applications, in addition to renewable energy conversion.
This study investigates the potential role of isobaric mixing in the formation of marine boundary layer clouds. Cloud formation theory emphasizes uplift and adiabatic cooling, but recent observations support the existence of small clouds forming at various altitudes, even below the lifting condensation level. Isobaric mixing of air with different thermodynamic properties can generate localized supersaturation. A Gaussian mixing model is employed to simulate this process, considering the correlation between temperature and water vapor. Cloud droplet size distributions from aircraft measurements show a persistent and prominent mode of small droplets at 9 m, and the size of this mode compares favorably with predictions from the model. The results suggests that isobaric mixing plausibly contributes to the formation of clouds, particularly those observed at multiple altitudes with narrow droplet size distributions. This finding highlights the importance of considering isobaric mixing processes in understanding and modeling cloud formation.
Spin Hamiltonians in condensed matter and quantum sensing typically utilize pairwise or two-body interactions between constituents in the material or ensemble. However, there is growing interest in exploring more general n-body interactions for n > 2. In this study, we realized an effective n = 3-body Hamiltonian interaction using an ensemble of laser-cooled atoms in a high-finesse optical cavity with the pseudospin 1/2 encoded by two atomic momentum states. We applied two dressing tones that induce the atoms to exchange photons via the cavity to realize a virtual six-photon process; lower-order interactions destructively interfered. We also observed signatures of a n = 4-body interaction mediated by a virtual eight-photon process. Our approach may be extensible to three-body interactions in multilevel systems or to even higher-order interactions.
In any new accelerator proposal, sustainability issues will be heavily scrutinized, be that in electricity and water use, the overall efficiency of the facility, including reusing the heat for other purposes (space heating, biogas production, etc.) or energy recycling. These aspects are important for all new facilities, but ERLs bring a new dimension. Directly returning the energy of an unused beam into RF that can be used for acceleration with practically no losses is a unique feature of ERLs. While not all of the energy can be recovered, the overall efficiency of the process is extremely high. This advantage starts with a reduction in the RF power needed for acceleration, which translates into smaller RF sources and their associated power transformers (reducing the resources needed for their production), and less electric power and water cooling required (reduced operating costs as well as a reduced carbon footprint). Given the inherent advantages of ERLs, it is to be expected that their sustainability profile will eclipse other colliders with similar physics potential.
Previous laboratory-scale crucible testing with batch chemicals confirmed that the sulfate (SO 4 2- ) limit for Sludge Batch 10 (SB10) was 0.65 weight percent (wt.%) in glass. This limit signifies that 0.65 wt.% SO 4 2- can be retained in the glass without the formation of a sulfate phase. The Defense Waste Processing Facility imposes this constraint in the Material Tracking Program. Based on preliminary calculations to support the Material Tracking Program, it was anticipated that transfer volumes of the monosodium titanate/sludge solids (MST/SS) stream from the Salt Waste Processing Facility (SWPF) may need to be reduced to maintain projected sulfate concentrations below 0.65 wt.% in glass. Savannah River Mission Completion requested that the Savannah River National Laboratory perform additional sulfate testing to determine whether a sulfate solubility limit greater than 0.65 wt.% is feasible for SB10, which could allow for higher transfer volumes of the MST/SS stream. This report documents the results of the testing at higher sulfate concentrations for the glass composition region defined by the most recent SB10 projection (November 2022) and Frits 473 and 625. Frit 473 was recommended for SB10 and Frit 625 was used during SB9 processing and the SB9 to SB10 transition. A total of twenty-one glass compositions were developed based on the expected compositional variables, which include sludge-only (SO) and coupled processing with the SWPF, waste loading (WL), and frit composition. The target sulfate concentrations were varied from 0.65-0.85 wt.% at 32 and 40% WL. Each glass was prepared from reagent grade chemicals and melted at 1150 °C. Visual observations were used to confirm the presence of a sulfate salt phase on the cooled glass surfaces. Representative samples of each glass were submitted for chemical composition analysis by inductively coupled plasma-optical emission spectroscopy and Cs analysis by inductively coupled plasma-mass spectrometry. Overall the majority of mean measured values are consistent with the target values for each major oxide of interest with less than 5% error. The percent errors for the measured SO 4 2- concentrations are generally less than 10%, which is comparable with previous sulfate solubility study measurements and acceptable. Only the SO glasses based on Frit 625 formed a sulfate phase at a 0.80 wt.% SO 4 2- target concentration at both 32 and 40% WL. The remainder of the glasses did not form a sulfate layer. Due to the formation of the sulfate phase, the limit is conservatively set at 0.70 wt.% based on the measured sulfate concentrations of 0.71 wt.% and 0.75 wt.% for these two glasses. None of the SO or coupled operation glasses based on Frit 473 formed a sulfate salt phase, which supports a sulfate limit of 0.80 wt.%. The following SO 4 2- concentration limits are recommended during SO and coupled SB10 processing: (1) 0.70 wt.% during processing with Frit 625, and (2) 0.80 wt.% during processing with Frit 473.
Here, the treatment and disposal of hypersaline produced water remains a challenge, particularly for oil and gas producers in the Permian basin where production wells generate significant amounts of wastewater, and the traditional method of injecting wastewater into disposal wells is coming under increasing scrutiny. Here we investigate the viability of using solar energy to power a multi-stage, surface heated, vacuum membrane distillation (SHVMD) with energy recovery to treat hypersaline produced wastewater from Midland, Texas. Membrane distillation is a process that can desalinate waters with high total dissolved solids concentration, and when incorporated into a system with surface heating and energy recovery can achieve high water recovery rates. Model results show that a 6-stage SHVMD system with a 54.4 % water recovery rate and a gained output ratio (GOR) of 3.28 has the potential to be economically viable when used to treat hypersaline produced water in the Permian basin. Assuming energy costs of $\$0.03$/kWh thermal and $\$0.12$kWh electric , we estimate a project net present value (NPV) of $\$225,525$ and an internal rate of return (IRR) of 13.5 % when an air cooled condensor is used to cool the distillate and a NPV of $\$570,791$ and IRR of 24.52 % when a liquid coooling source is available.