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At least 829 records · Page 46

Suhl instabilities in nanoscopic spheroids

We simulate the magnetization dynamics of a permalloy spheroid of nanoscopic size in zero external field, such that both dipolar and exchange interactions are important. Low excitation power is used to obtain the frequencies and mode patterns of many normal modes. At higher power, non-linear three and four mode couplings between magnons carrying orbital angular momentum are observed to give rise to Suhl instabilities. Suhl’s analysis of the selection rules governing the allowed processes is extended to initial states other than uniform precession. These rules are studied and confirmed by the simulations. Both down- and up-conversion are seen as well as three and four-mode processes. As a result, general trends are inferred for preferred instabilities among those that are allowed, although the thresholds for some instabilities appear to be very high.

3D nanomagnetism↗

Intelligent, grid-friendly, modular extreme fast charging system with solid-state DC protection

The development of electric vehicle (EV) charging infrastructure is crucial for the widespread adoption of electric transportation. However, implementing such infrastructure is a complex task that requires consideration of factors such as space limitations, adherence to industry standards, grid capacity, and other technical and policy issues. This project seeks to create a framework for the efficient design of compact medium voltage (MV) extreme fast charging (XFC) stations for EVs. The station design involves the use of a solid-state transformer (SST) that connects to the MV distribution network, delivering power to a shared DC bus. This innovative approach eliminates the need for a step-down transformer to provide low-voltage service by connecting directly to the MV distribution network. Eliminating the low-frequency transformer not only reduces the system footprint and losses but also eliminates inrush currents during grid black-start. Additionally, placing power electronics directly on the distribution system allows for high-bandwidth filtering and power factor correction. The inclusion of a shared DC bus enables multiple charging dispensers and DC storage/generation units to connect, forming a DC microgrid. This setup facilitates power sharing with minimal conversion stages. The project showcases a DC distribution network protected by intelligent solid-state (SS) DC circuit breakers (DCCB) capable of isolating the smallest section of the faulted circuit much faster than existing mechanical solutions.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Model Formulations: Market clearing models, market design specifications, and dispatch simulation

This document provides various model formulations that will be implemented for the Energy Storage Participation Algorithm pilot competition (ESPA-Comp). This competition will assess the performance of different storage offer algorithms in terms of their ability to maximize the value of storage resources participating under various market designs that vary in the range of complexity of possible storage offers. The model formulations include a general market clearing optimization model and specification to implement it in various market designs. We provide specifications for three market designs to be tested in ESPA-Comp, which we call the two-settlement, multi-settlement, and rolling horizon forward markets. The market designs include different trading frequencies and offer formats. Storage resources participating in the market are provided with primitive values for the resource’s physical capabilities, and they are provided with a storage offer format that their algorithms will be tasked with populating. A detailed physical model is used to assess each storage resource’s ability to maintain its scheduled dispatch according to its state-of-charge, operating temperature, and power conversion efficiency.

25 ENERGY STORAGE↗

A 100 GHz Josephson mixer using resistively-shunted Nb tunnel junctions

The authors describe preliminary mixer results using resistively shunted Nb/AlO(x)/Nb tunnel junctions in a 100-GHz waveguide mixer mount. The mixer utilizes robust, lithographically defined devices which have nonhysteretic I-V curves. A receiver temperature of 390 K (DSB) has been obtained with a conversion loss of -6.5 dB. The receiver's behavior agrees qualitatively with the behavior predicted by the resistively shunted junction model. Substantial improvements in performance are expected with the use of better-optimized shunted junctions, and numerical simulations suggest that, if devices with higher ICRN (critical current-normal state resistance) products can be obtained, Josephson effect mixers could be competitive with SIS mixers at high frequencies.

Schoelkopf, R. J.↗

Tunable CW diode-pumped Tm,Ho:YLiF4 laser operating at or near room temperature

A conversion efficiency of 42% and slope efficiency of 60% relative to absorbed pump power are obtained from a continuous wave diode-pumped Tm,Ho:YLiF4 laser at 2 microns with output power of 84 mW at a crystal temperature of 275 K. The emission spectrum is etalon tunable over a range of7 nm (16.3/cm) centered on 2.067 microns with fine tuning capability of the transition frequency with crystal temperature at a measured rate of -0.03/(cm)K. The effective emission cross-section is measured to be 5 x 10(exp -21) cm squared. These and other aspects of the laser performance are disclosed in the context of calculated atmospheric absorption characteristics in this spectral region and potential use in remote sensing applications. Single frequency output and frequency stabilization are achieved using an intracavity etalon in conjunction with an external reference etalon.

Mcguckin, Brendan T.↗

Sub-Micron Long HTS Ho Electron Mixers

The hot-electron bolometer mixer made from a high-T, superconductor (HTS) was introduced recently as an alternative to a Schottky mixer at THz frequencies. The performance of the mixer depends on the total thermal conductance for heat removal from the phonon sub-system due to either length-dependent phonon diffusion or phonon escape to the substrate. We have measured both the length and temperature dependencies of the IF bandwidth of the mixers fabricated from 25-35 mn thick YBCO films on MgO and sapphire substrates. The films were grown by a laser deposition technique and electron-beam lithography was used to define bridge lengths down to 50 nm. Mixer measurements were done using signal frequencies in the range of 1-100 GHz. For 50 nm and 400 nm long devices on MgO, the 3-dB bandwidth was about 100 MHz. At temperatures below 60 K, the hot-electron plateau was clearly seen starting around 2-3 GHz. At temperatures above 70 K, the flux-flow effects begin to dominate and the IF bandwidth increases to 1-8 GHz, while the conversion efficiency drops by several dB. This temperature dependence of the IF bandwidth can account for previously reported unexpectedly high bandwidth of HTS mixers.

Harnack, 0.↗

Observation of bound valence excited electronic states of deprotonated 2-hydroxytriphenylene using photoelectron, photodetachment, and resonant two-photon detachment spectroscopy of cryogenically cooled anions

Polycyclic aromatic hydrocarbons (PAHs) are common atmospheric pollutants, and they are also ubiquitous in the interstellar medium. Here, we report the study of a complex O-containing PAH anion, the deprotonated 2-hydroxytriphenylene (2-OtPh–), using high-resolution photoelectron imaging and photodetachment spectroscopy of cryogenically cooled anions. Vibrationally resolved photoelectron spectra yield the electron affinity of the 2-OtPh radical as 2.629(1) eV and several vibrational frequencies for its ground electronic state. Photodetachment spectroscopy reveals bound valence excited electronic states for the 2-OtPh– anion, with unprecedentedly rich vibronic features. Evidence is presented for a low-lying triplet state (T1) and two singlet states (S1 and S2) below the detachment threshold. Single-color resonant two-photon photoelectron spectroscopy uncovers rich photophysics for the 2-OtPh– anion, including vibrational relaxation in S1, internal conversion to the ground state of 2-OtPh–, intersystem crossing from S2 to T1, and a long-lived autodetaching shape resonance about 1.3 eV above the detachment threshold. The rich electronic structure and photophysics afforded by the current study suggest that 2-OtPh– would be an interesting system for pump–probe experiments to unravel the dynamics of the excited states of this complex PAH anion.

Chemistry↗

Adaptive Reinforcement Learning (ARL) Control of a Multi-port Resonant Converter in UAV Systems

This study presents an adaptive reinforcement learning (ARL) control framework for a multi-port resonant converter used in hybrid unmanned aerial vehicle (UAV) power systems. The converter integrates high-frequency half-bridge input ports connected to a rectified engine–generator set and a battery energy storage system, along with a semi-bridgeless active rectifier supplying the propulsion load. A deep RL agent is trained to dynamically regulate inter-port phase-shift commands in real time based on flight conditions and load power demand. The ARL controller autonomously identifies phase-shift combinations that maximize conversion efficiency while maintaining stable and coordinated power flow, even under rapidly varying operating scenarios. This data-driven approach eliminates the need for explicit system modeling or extensive manual tuning and enables coordinated control among multiple power ports without inter-port communication. Experimental results validate that the ARL based strategy achieves reliable power sharing and consistently high-efficiency operation across diverse UAV operating conditions.

Asa, Erdem [ORNL] (ORCID:0000000190884812)↗

Development of in situ thickness sensor for vapor diffused Nb3Sn films

Fermilab is one of the leaders in development of vapor diffused Nb3Sn films inside niobium cavities. This material has a higher critical temperature (Tc) than niobium, enabling cavity operation at 4.2 K. This higher operational temperature significantly reduces the infrastructure required for cooling compared to 2 K systems, making superconducting radio-frequency (SRF) technology more accessible. Current deposition methods have relied on iterative testing to determine nominal film thickness, a process that can be time-consuming and imprecise. To address this, we are developing a sensor to measure the thickness of Nb3Sn thin film in situ during vapor diffusion. Our design involves the resistance measurement of a thin film of niobium. During coating, the change in resistance reflects the conversion of the film to Nb3Sn, which allows simple integration with the current furnace infrastructure. This sensor would allow real time measurement of the thickness, allowing for increased precision in future depositions.

Howard, K. [Unlisted] (ORCID:0000000325613308)↗

Tunable CW diode-pumped Tm,Ho:YLiF4 laser operating at or near room temperature

A conversion efficiency of 42 percent and slope efficiency of 60 percent relative to absorbed pump power are obtained from a continuous wave diode-pumped Tm,Ho:YLiF4 laser at 2 microns with output power of 84mW at a crystal temperature of 275K. The emission spectrum is etalon tunable over a range of 7nm (16.3 cm(sup -1) centered on 2.067 microns with fine tuning capability of the transition frequency with crystal temperature at a measured rate of -0.03/(cm)K. The effective emission cross-section is measured to be 5 x 10(sup -21) cm squared. These and other aspects of the laser performance are disclosed in the context of calculated atmospheric absorption characteristics in this spectral region and potential use in remote sensing applications. Single frequency output and frequency stabilization are achieved using an intracavity etalon in conjunction with an external reference etalon.

Mcguckin, Brendan T.↗

A discrete gust model for use in the design of wind energy conversion systems

A discrete gust model has been designed which includes an expression for the number of times per unit time thy wind exceeds a specific value. This expression, based on Rice's (1944, 1945) number-of-crossings model, assumes that the yearly mean wind speed is averaged over a period of 10 minutes to 1 (one) hour. Vertical and lateral coherence functions are the basis for a mathematical filter which isolates atmospheric disturbances of a characteristic size (e. g., those which would completely engulf a rotor). Predictions are calculated usising the given definition of cut-off frequency, then they are compared with actual data, showing that the model is reliable. The expression is provided in a format such that it may be used for engineering design calculations.

Frost, W.↗

Logistics Reduction and Repurposing Technology for Long Duration Space Missions

One of NASA's Advanced Exploration Systems (AES) projects is the Logistics Reduction and Repurposing (LRR) project, which has the goal of reducing logistics resupply items through direct and indirect means. Various technologies under development in the project will reduce the launch mass of consumables and their packaging, enable reuse and repurposing of items, and make logistics tracking more efficient. Repurposing also reduces the trash burden onboard spacecraft and indirectly reduces launch mass by one manifest item having two purposes rather than two manifest items each having only one purpose. This paper provides the status of each of the LRR technologies in their third year of development under AES. Advanced clothing systems (ACSs) are being developed to enable clothing to be worn longer, directly reducing launch mass. ACS has completed a ground exercise clothing study in preparation for an International Space Station technology demonstration in 2014. Development of launch packaging containers and other items that can be repurposed on-orbit as part of habitation outfitting has resulted in a logistics-to-living (L2L) concept. L2L has fabricated and evaluated several multi-purpose cargo transfer bags for potential reuse on-orbit. Autonomous logistics management is using radio frequency identification (RFID) to track items and thus reduce crew time for logistics functions. An RFID dense reader prototype is under construction and plans for integrated testing are being made. A heat melt compactor (HMC) second generation unit for processing trash into compact and stable tiles is nearing completion. The HMC prototype compaction chamber has been completed and system development testing is under way. Research has been conducted on the conversion of trash-to-gas (TtG) for high levels of volume reduction and for use in propulsion systems. A steam reformation system was selected for further system definition of the TtG technology.

Broyan, James Lee, Jr.↗

Logistics Reduction and Repurposing Technology for Long Duration Space Missions

One of NASA's Advanced Exploration Systems (AES) projects is the Logistics Reduction and Repurposing (LRR) project, which has the goal of reducing logistics resupply items through direct and indirect means. Various technologies under development in the project will reduce the launch mass of consumables and their packaging, enable reuse and repurposing of items and make logistics tracking more efficient. Repurposing also reduces the trash burden onboard spacecraft and indirectly reduces launch mass by replacing some items on the manifest. Examples include reuse of trash as radiation shielding or propellant. This paper provides the status of the LRR technologies in their third year of development under AES. Advanced clothing systems (ACS) are being developed to enable clothing to be worn longer, directly reducing launch mass. ACS has completed a ground exercise clothing study in preparation for an International Space Station (ISS) technology demonstration in 2014. Development of launch packaging containers and other items that can be repurposed on-orbit as part of habitation outfitting has resulted in a logistics-to-living (L2L) concept. L2L has fabricated and evaluated several multi-purpose cargo transfer bags (MCTBs) for potential reuse on orbit. Autonomous logistics management (ALM) is using radio frequency identification (RFID) to track items and thus reduce crew requirements for logistics functions. An RFID dense reader prototype is under construction and plans for integrated testing are being made. Development of a heat melt compactor (HMC) second generation unit for processing trash into compact and stable tiles is nearing completion. The HMC prototype compaction chamber has been completed and system development testing is underway. Research has been conducted on the conversion of trash-to-gas (TtG) for high levels of volume reduction and for use in propulsion systems. A steam reformation system was selected for further system definition of the TtG technology. And benefits analysis of all LRR technologies have been updated with the latest test and analysis results.

Broyan, James L.↗

Observation of a dipole-bound excited state in 4-ethynylphenoxide and comparison with the quadrupole-bound excited state in the isoelectronic 4-cyanophenoxide

Negative ions do not possess Rydberg states, but can have Rydberg-like nonvalence excited states near the electron detachment threshold, including dipole-bound states (DBSs) and quadrupole-bound states (QBSs). While DBSs have been studied extensively, quadrupole-bound excited states have been more rarely observed. 4-cyanophenoxide (4CP – ) was the first anion observed to possess a quadrupole-bound exited state 20 cm-1 below its detachment threshold. Here we report the observation of a DBS in the isoelectronic 4-ethynylphenoxide anion (4EP – ), providing a rare opportunity to compare the behaviors of a dipole-bound and a quadrupole-bound excited state in a pair of very similar anions. Photodetachment spectroscopy (PDS) of cryogenically-cooled 4EP – reveals a DBS 76 cm -1 below its detachment threshold. Photoelectron spectroscopy (PES) at 266 nm shows that the electronic structure of 4EP – and 4CP – are nearly identical. The observed vibrational features in both the PDS and PES, as well as autodetachment from the nonvalence excited states, are also found to be similar for both anions. However, resonant two-photon detachment (R2PD) from the bound vibrational ground state is observed to be very different for the DBS in 4EP – and the QBS in 4CP – . The R2PD spectra reveal that decays take place from both the DBS and QBS to the respective anion ground electronic states within the 5 ns detachment laser pulse due to internal conversion followed by intramolecular vibrational redistribution (IVR), but the decay mechanisms appear to be very different. In the R2PD spectrum of 4EP – , we observe strong threshold electron signals, which are due to detachment, by the second photon, of highly rotationally excited anions resulted from the decay of the DBS. On the other hand, in the R2PD spectrum of 4CP – we observe well-resolved vibrational peaks due to the three lowest-frequency vibrational modes of 4CP – , which are populated from the decay of the QBS. Here, the different behaviors of the R2PD spectra suggest unexpected differences between the relaxation mechanisms of the dipole-bound and quadrupole-bound excited states.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Quantum metrology timing limits of the Hong-Ou-Mandel interferometer and of general two-photon measurements

We examine the precision limits of Hong-Ou-Mandel (HOM) timing measurements, as well as precision limits applying to generalized two-photon measurements. As a special case, we consider the use of two-photon measurements using photons with variable bandwidths and frequency correlations. When the photon bandwidths are not equal, maximizing the measurement precision involves a trade-off between high interference visibility and strong frequency anticorrelations, with the optimal precision occurring when the photons share non-maximal frequency anticorrelations. We show that a generalized measurement has precision limits that are qualitatively similar to those of the HOM measurement whenever the generalized measurement is insensitive to the net delay of both photons. Finally, by examining the performance of states with more general frequency distributions, our analysis allows for engineering of the joint spectral amplitude for use in realistic situations, in which both photons may not have ideal spectral properties.

79 ASTRONOMY AND ASTROPHYSICS↗

A tunable dual frequency dye laser - dual frequency oscillator design

The pulsed dye laser offers a tunable oscillator, followed by three amplifiers. It is pumped by a dual frequency Nd:YAG laser. Tuning and spectral width are controlled by a holographic network connected to a high power telescope. The modified two wavelength dye laser allows for absorption lidar techniques for remote sensing of the atmosphere. Line switching is achieved by electrooptical commutation. A feasibility experiment was performed with the original oscillator. A model was then built, and tested with different dyes. After a few modifications were made to improve the conversion efficiency, this oscillator was inserted in the laser to check whether the amplifier stages were correctly adjusted.

Abury, Y.↗

Origin and Variability of Upper Tropospheric Nitrogen Oxides and Ozone at Northern Mid-Latitudes

Measurements of NO(x) and ozone performed during the NOXAR project are compared with results from the coupled chemistry-climate models ECHAM4.L39(DLR)/CHEM and GISS-model. The measurements are based on flights between Europe and the East coast of America and between Europe and the Far East in the latitude range 40 deg N to 65 deg N. The comparison concentrates on tropopause altitudes and reveals strong longitudinal variations of seasonal mean NO,, of 200 pptv. Either model reproduced strong variations 3 km below but not at the tropopause, indicating a strong missing NO(x) or NO(y) sink over remote areas, e.g. NO(x) to HNO3 conversion by OH from additional OH sources or HNO3 wash-out. Vertical profiles show maximum NO(x) values 2-3 km below the tropopause with a strong seasonal cycle. ECHAM4.L39(DLR)/CHEM reproduces a maximum, although located at the tropopause with a less pronounced seasonal cycle, whereas the GISS model reproduces the seasonal cycle but not the profile's shape due to its coarser vertical resolution. A comparison of NO(x) frequency distributions reveals that both models are capable of reproducing the observed variability, except that ECHAM4.L39(DLR)/CHEM shows no very high NO(x) mixing ratios. Ozone mean values, vertical profiles and frequency distributions are much better reproduced in either model, indicating that the NO(x) frequency distribution, namely the most frequent NO(x) mixing ratio, is more important for the tropospheric photochemical ozone production than its mean value. Both models show that among all sources, NO(x) from lightning contributes most to the seasonal cycle of NO(x) at tropopause altitudes. The impact of lightning in the upper troposphere on NO(x) does not vary strongly with altitude, whereas the impact of surface emissions decreases with altitude. However, the models show significant differences in lightning induced NO(x) concentrations, especially in winter, which may be related to the different treatment of the lower stratospheric coupling between dynamics and chemistry.

Grewe, V.↗

Conversion of electrostatic plasma waves into electromagnetic waves - Numerical calculation of the dispersion relation for all wavelengths.

The dispersion curves have been computed for a wide range of wavelengths from electromagnetic waves to electrostatic waves in a magnetoactive warm plasma with a Maxwellian velocity distribution function. The computation was carried out mainly for the perpendicular propagation mode. The upper hybrid resonance is the connection point of the electrostatic waves and the electromagnetic waves. The electrostatic waves not associated with the upper hybrid resonance are subjected to electron cyclotron damping when the wavelength becomes long. Oblique propagation is allowed for the electrostatic waves in a frequency range from the plasma frequency to the upper hybrid resonance frequency in the long-wavelength region where Landau damping can be neglected and where the electrostatic mode smoothly connects to the electromagnetic X-mode. In a slightly inhomogeneous plasma, the Bernstein-mode electrostatic wave can escape by being converted into the O-mode electromagnetic wave; two reflections take place during this escape process.

Oya, H.↗