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At least 829 records · Page 46

Extinction of Solid Diffusion Flame in Microgravity: Details of Quenching and Blowoff Processes

Long duration microgravity experiments aboard the International Space Station determine diffusion flame extinction limits of PMMA spheres. Upon ignition from an electrically-heated coil, the 4-cm-diameter samples are exposed to forced flows ranging from 0.2 to 80 cm/s and an oxygen ranging from 13 to 28% in one atmosphere total pressure. Extinction is reached as oxygen concentration gradually decreases by natural depletion. Five extinction tests are presented at different flow velocities and oxygen concentrations. Quenching at low velocity is observed with the flame tip shrinking upstream and blowoff is observed when a hole forms in the flame at the forward flow stagnation point. However, these processes are not quasistatic. The quenching motion involves periodic flame tip pulsating toward downstream and shrinking upstream with a continually decreasing flame size at the end of each cycle. In blowoff, the flame base pulsates between the flame hole and the downstream location, although with far fewer cycles compared to quenching. The pulsations appear to be the result of a premixed flame front spreading into a combustible mixture. Two specific cases are discussed. In the first, at very low flow velocity (~ 0.4 cm/s) and elevated oxygen, self-sustained flame tip cyclic pulsations are observed for a lengthy period (~15 minutes). In the second case with a higher flow velocity (50 cm/s), the diffusion flame is stabilized at the shoulder of the spherical sample after local stagnation point blowoff. With steady decrease in ambient oxygen due to depletion, spinning flamelets are formed. The long-duration microgravity environment makes it possible to observe. these interesting and detailed extinction processes.

Flame quenching↗

Retroreflection Focusing Schlieren System

A retroreflective type focusing schlieren system which permits the light source to be positioned on the optic side of the system is introduced. The system includes an extended light source, as opposed to a point source, located adjacent to a beam splitter which projects light through the flow field onto a reflecting grating in the form of a grid which generates sheets of light that are directed back through the flow field and the beam splitter onto a primary lens behind which is located a cut-off grid having a grid pattern which corresponds to the grid pattern of the reflecting grating. The cut-off grid is adjustably positioned behind the primary lens and an image plane for imaging the turbulence is adjustably located behind the cut-off grid.

Heineck, James T.↗

Deceleration of a supersonic flow behind a curved shock wave with isentropic precompression

Three-dimensional supersonic flows of an ideal fluid in the neighborhood of bodies formed by being cut out along the streamlines of an axisymmetric flow are investigated. The flow consists of a region of isoentropic compression and a region of vortex flow. An exact solution with variable entropy is used to describe the flow in the vortex region. In the continuous flow region an approximate solution is constructed by expanding the solution in a series in a small parameter. The effect of the shape of the excision and the vorticity of the flow on compression of the jet and and the total pressure loss coefficient is studied.

Dulov, V. G.↗

Lensless Particle Image Velocimetry

The application of lensless imaging to particle image velocimetry (PIV) is demonstrated. Lensless PIV eliminates the need for imaging lenses to measure flow fields near a surface. Only the camera sensor, a thin mask, and computations are required to image particles in a flow field and to compute the velocity field. The small form factor could enable embedded sensors for near-wall measurements. Flow field measurements are obtained simultaneously for a lensless system and lens-based 2D PIV system, and several different reconstruction techniques are demonstrated. The reconstructed particle images and computed velocity fields compare well for both a uniform and shear flow. The potential for stereo and 3D volumetric PIV with a single camera sensor is demonstrated through different image reconstruction approaches.

Lensless imaging↗

Effects of Particle Mixing and Gravitational Settling on Charge Transport in Carbon Flow-Electrode Cells

Flowable carbon slurries are actively studied and under development for charge transport in various electrochemical systems including flow capacitors, capacitive deionization cells, semi-solid flow batteries, and lithium extraction. However, much less is known about in operando slurry flow dynamics and their corresponding effect on charge transport. We performed an experimental study of mixing and settling dynamics of slurry electrodes within an electrochemical flow cell during continuous operations. The electrochemical cell consisted of two horizontal co-flowing channels, separated by a cation-exchange membrane (CEM). Here we used high-speed optical imaging of planes parallel to gravity and simultaneous electrochemical measurements. At low flow rates, dense yet dynamic particle beds formed on the bottom electrode in each channel, which unexpectedly yielded the highest currents. This approach enables the operation of the flow cell at low system-average particle concentrations while leveraging gravity-driven particle settling to locally enhance carbon concentrations precisely at the current collector sites. Conversely, high flow rates were characterized by thin particle beds and well-mixed particle flows. In the latter case, the electrodes in closest proximity (located on either side of the CEM) achieved a current higher than the other electrode pairs. The observations have implications for slurry control and electrode designs in electrochemical systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Model for the Vortex Pair Associated with a Jet in a Cross Flow

A model is presented for the contrarotating vortex pair that is formed by a round, turbulent, subsonic jet directed normally into a uniform, subsonic cross flow. The model consists of a set of algebraic equations that describe the properties of the vortex pair as a function of their location in the jet plume. The parameters of the model are physical characteristics of the vortices such as the vortex strength, spacing, and core size. These parameters are determined by velocity measurements at selective points in the jet plume.

Sellers, William L.↗

Infrared vibration-rotation spectra of the ClO radical using tunable diode laser spectroscopy

Tunable diode laser spectroscopy is used to measure the infrared vibration-rotation spectra of the ClO radical. The radical is generated in a flow system where a Cl2-He mixture passes through a microwave discharge to dissociate the Cl2. An O3-O2 mixture from an ozone generator is injected into the system downstream of the microwave discharge where O3 combines with Cl to form ClO. By adjusting the gas flow rates to yield an excess of Cl atoms, all the ozone is combined. ClO concentration is measured with UV absorption at 2577 and 2772 A and a deuterium lamp as a continuous source. Total cell pressure is 5.5 torr. The diode laser spectrometer is calibrated with ammonia lines as a reference where possible. The frequency of vibration-rotation lines is expressed as a function of rotational quantum number, fundamental vibrational frequency, and the rotational constants of the upper and lower vibrational states.

Rogowski, R. S.↗

On-Line Measurement of Heat of Combustion of Gaseous Hydrocarbon Fuel Mixtures

A method for the on-line measurement of the heat of combustion of gaseous hydrocarbon fuel mixtures has been developed and tested. The method involves combustion of a test gas with a measured quantity of air to achieve a preset concentration of oxygen in the combustion products. This method involves using a controller which maintains the fuel (gas) volumetric flow rate at a level consistent with the desired oxygen concentration in the combustion products. The heat of combustion is determined form a known correlation with the fuel flow rate. An on-line computer accesses the fuel flow data and displays the heat of combustion measurement at desired time intervals. This technique appears to be especially applicable for measuring heats of combustion of hydrocarbon mixtures of unknown composition such as natural gas.

Sprinkle, Danny R.↗

Drying model of a high salt content cementitious waste form: Effect of capillary forces and salt solution

Highlights: • Drying model for a high salt content cementitious waste form is developed. • Water vapor diffusion and capillary liquid flow are distinguished. • Capillary and salt solution effects are considered in vapor-liquid equilibrium. A water transport model coupling capillary liquid flow with vapor diffusion is developed to describe the drying process for a cementitious waste form with high salinity porewater. Vapor-liquid equilibrium is formulated as the driving force for vapor diffusion and the model accounts for pore capillary and high salinity effects on water thermodynamic activity. Pore filling and porewater surface tension as a function of pore size distribution and water saturation have been quantified for the material. Geochemical speciation modeling is used to simulate porewater activity as a function of composition over the range of saturation. The theoretical relationship between relative humidity and water saturation generally agrees with experimental measurement, and the developed model is capable of predicting drying rates under various external relative humidity conditions. The model was developed to be incorporated into reactive transport models considering the effects of drying such as salt redistribution and efflorescence.

36 MATERIALS SCIENCE↗

Euler solutions for blunt bodies using triangular meshes - Artificial viscosity forms and numerical boundary conditions

A finite volume method is used to calculate compressible inviscid flows over blunt bodies using, in general, unstructured grids. Artificial viscosity forms are derived based on a simplified least squares procedure. The extra second order terms are consistent with the governing equations, hence a systematic treatment of the numerical boundary conditions can be easily implemented. A special treatment of blunt bodies may be required. The discrete equations are linearized and the resulting system is solved by a relaxation method. Preliminary results indicate that the effect of the numerical dissipation is minimal. For subsonic flows over smooth bodies, the solution is practically vorticity-free and the total pressure loss is of the same order as the truncation error. Finally, some extensions of the present method are briefly discussed.

Winterstein, R.↗

Developing flow in S-shaped ducts. 1: Square cross-section duct

Laser-Doppler velocimetry was used to measure the laminar and turbulent flow in an S-duct formed with two 22.5 deg sectors of a bend with ratio of mean radius of curvature to hydraulic diameter of 7.0. The boundary layers at the inlet to the bend were about 25% and 15% of the hydraulic diameter for the laminar and turbulent flows, respectively. Pressure-driven secondary flows develop in the first half of the S-duct and persist into the second half but are largely reversed by the exit plane as a consequence of the change in the sense of curvature. There is, however, a region near the outer wall of the second bend where the redistribution of the streamwise isotachs results in a reinforcement of the secondary flow which was established in the first half of the S-duct. The net redistribution of the streamwise isotachs is comparable to that occurring in unidirectional bends of stronger curvature. The wall pressure distribution was also measured for the turbulent flow and quantifies the expected large variations in the longitudinal pressure gradient distributions which occur at different radial locations.

Taylor, A. M. K. P.↗

Modeling Interface Motion Of Combustion (MINOC). A computer code for two-dimensional, unsteady turbulent combustion

A computer code for calculating the flow field and flame propagation in a turbulent combustion tunnel is described. The model used in the analysis is the random vortex model, which allows the turbulent field to evolve as a fundamental solution to the Navier-Stokes equations without averaging or closure modeling. The program was used to study the flow field in a model combustor, formed by a rearward-facing step in a channel, in terms of the vorticity field, the turbulent shear stresses, the flame contours, and the concentration field. Results for the vorticity field reveal the formation of large-scale eddy structures in the turbulent flow downstream from the step. The concentration field contours indicate that most burning occurred around the outer edges of the large eddies of the shear layer.

Ghoneim, A. F.↗

An Igneous Origin for Features of a Candidate Crater-Lake System in Western Memnonia, Mars

The association of channels, inner terraces, and delta-like features with Martian impact craters has previously been interpreted as evidence in favor of the past existence of crater lakes on Mars. However, examination of a candidate crater-lake system in western Memnonia suggests instead that its features may have formed through igneous processes involving the flow and ponding of lava. Accumulations of material in craters and other topographic lows throughout much of the study region have characteristics consistent with those of volcanic deposits, and terraces found along the inner flanks of some of these craters are interpreted as having formed through drainage or subsidence of volcanic materials. Channels previously identified as inlets and outlets of the crater-lake system are interpreted instead as volcanic rilles. These results challenge previous interpretations of terrace and channel features in the study region and suggest that candidate crater lakes located elsewhere should be reexamined.

Leverington, D. W.↗

Defining a Metric to Assess Leachability of Contaminants from Cementitious Waste Forms in Lab Testing Related to Hanford - 20478

This paper reports on the determination of performance metrics for the release of four contaminants (technetium, iodine, nitrate, and chromium) from a theoretical supplemental low-activity waste (LAW) inventory of grout in the Hanford Integrated Disposal Facility (IDF). The performance metric was defined as a retardation factor, R, that can be used to quantify a waste form's ability to retain one contaminant compared with an un-retarded species (e.g., sodium). By setting the target R value at the magnitude required to maintain concentrations of the contaminants below the drinking water standard at the point of compliance for the IDF, a bar for grout leach performance can be established for screening laboratory leach test data. The R can be converted to a corresponding laboratory-observed diffusivity value against which to assess leach test data. The individual performance metrics were determined through an iterative set of simulations using a variable saturation and transport flow model of a grout waste form inventory in the IDF to calculate the resulting concentration-based requirements at the point of compliance. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Elliptical flux vortices in YBa2Cu3O7

The most energetically favorable vortex in YBa2Cu3O7 forms perpendicular to an anisotropic plane. This vortex is elliptical in shape and is distinguished by an effective interchange of London penetration depths from one axis of the ellipse to another. By generalizing qualitatively from the isotropic to the anisotropic case, we suggest that the flux flow resistivity for the vortex that forms perpendicular to an anistropic plane should have a preferred direction. Similar reasoning indicates that the Kosterlitz-Thouless transition temperature for a vortex mediated transition should be lower if the vortex is elliptical in shape.

Hickman, H.↗

Investigation on the Surface Vortex Formation During Mechanical Stirring with an Axial-Flow Impeller Used in an Aluminum Process

The present study investigated the mechanism of surface vortex formation in an aluminum melt vessel stirred by an axial-flow impeller mechanically. The oxide film is formed at the aluminum melt/air interface, and the movement of the interface entrains the oxide film and inclusions. Hence, the transient movement of melt–air interface is significant. The present study conducted a water model experiment and numerical simulation focusing on the movement of gas–liquid interface. The present study found that the oxide film can be entrained by two phenomena: (1) local surface vortex and (2) sloshing near the vessel wall. The local surface vortex is formed due to the pressure distribution around the impeller, and the sloshing is caused by macroinstabilities, which is generated by the discharged flow of axial-flow impeller. Besides, the shape of gas–liquid interface is dependent on the impeller shape. The axial-flow impeller gives rise to steeply curved shape of gas–liquid interface near the impeller shaft.

36 MATERIALS SCIENCE↗

Exact solutions of burst pressure for thick-walled cylinders in power-law strain hardening steels

Exact solutions of burst pressure for defect-free, thick-walled cylindrical pressure vessels with capped ends are developed using the flow theory of plasticity in terms of the Tresca, von Mises, and Zhu-Leis yield criteria. The material is assumed to obey a power-law strain hardening rule, and the finite strain theory is adopted to describe large plastic deformation. On this basis, internal pressure is obtained as a complex polynomial function of effective strains on the inside and outside surfaces of the pressure vessel with the use of the Bernoulli numbers. At burst failure, the effective strains and stresses on the inside and outside surfaces are first determined, and then three flow solutions of burst pressure are obtained as a power series function of the diameter ratio (D o /D i ), strain hardening exponent (n), and ultimate tensile strength (UTS). The power series solution is confirmed to agree well with the exact flow solution of burst pressure in a closed-form for each yield criterion, and the results show that the von Mises flow solution is an upper bound prediction, the Tresca flow solution is a lower bound prediction, and the Zhu-Leis flow solution is an intermediate prediction of burst pressure. In conclusion, two sets of full-scale burst test data are then utilized to evaluate and validate the proposed flow solutions of burst pressure for both thin-walled pipes and thick-walled cylindrical pressure vessels.

36 MATERIALS SCIENCE↗

Hypersonic merged-layer flow on a sphere

With the objective to achieve the desired reduction in velocity by aerodynamic forces, an aeroassisted orbital transfer vehicle (AOTV) is expected to fly in the higher region of the atmosphere for a sustained period of time. This aeroassist maneuver will occur in the transitional regime, if the vehicle is designed for a low ballistic coefficient. In this case, a merged-layer (ML) is formed around the space vehicle. The flow characteristics of the vehicle can be studied by making use of the full Navier-Stokes (NS) equations, taking into account slip and temperature jump conditions. The present investigation has the objective to obtain a two-term series solution of the full Navier-Stokes equations with surface slip and temperature jump conditions for the ML flow on a sphere. Attention is given to the mathematical formulation of the problem, the numerical method of integration, and the results.

Jain, A. C.↗