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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 829 records · Page 46
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Solder hermetic sealing for OLEDs

An OLED device comprising a substrate with a top surface; a first electrode covering the top surface of the substrate; a first insulating structure patterned over a portion of the first electrode where the pattern defines an inside area of the first electrode that is completely surrounded by the insulating structure, and an outside area of the first electrode not covered by the insulating structure; at least one organic layer for light emission within the inside area defined by the insulating structure; a second electrode over the at least one organic layer within the inside area defined by the insulating structure and at least partially over the first insulating structure; a cover slip located at least over the second electrode in the inside area defined by the insulating structure; and an electrically conductive solder seal making a hermetic seal between the insulating structure and the cover slip where the solder seal is in electrical contact with the second electrode. The insulating structure is desirably made of glass frit.

42 ENGINEERING↗
DOE OSTI2015

Electronic structure and thermoelectric properties of pnictogen-substituted ASn{sub 1.5}Te{sub 1.5} (A = Co, Rh, Ir) skutterudites

Substituting group 14 and 16 elements on the pnictogen site in the skutterudite structure yields a class of valence-precise ternary AX{sub 1.5}Y{sub 1.5} compounds (A = Co, Rh, Ir, X = Sn, Ge, and Y = S, Se, Te), in which X and Y form an ordered sub-structure. Compared with unfilled binary skutterudites, pnictogen-substituted phases exhibit extremely low lattice thermal conductivity due to increased structural complexity. Here, we investigate the role of the transition metal species in determining the electronic structure and transport properties of ASn{sub 1.5}Te{sub 1.5} compounds with A = Co, Rh, Ir. Density functional calculations using fully ordered structures reveal semiconducting behavior in all three compounds, with the band gap varying from 0.2 to 0.45 eV. In CoSn{sub 1.5}Te{sub 1.5}, the electronic density of states near the gap is significantly higher than for A = Ir or Rh, leading to higher effective masses and higher Seebeck coefficients. Experimentally, Ir and Rh samples exhibit relatively large p-type carrier concentrations and degenerate semiconducting behavior. In contrast, CoSn{sub 1.5}Te{sub 1.5} shows mixed conduction, with n-type carriers dominating the Seebeck coefficient and light, high mobility holes dominating the Hall coefficient. zT values of up to 0.35 were obtained, and further improvement is expected upon optimization of the carrier concentration or with n-type doping.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2011

Pre-Test Analysis Predictions for the Shell Buckling Knockdown Factor Checkout Tests - TA01 and TA02

This report summarizes the pre-test analysis predictions for the SBKF-P2-CYL-TA01 and SBKF-P2-CYL-TA02 shell buckling tests conducted at the Marshall Space Flight Center (MSFC) in support of the Shell Buckling Knockdown Factor (SBKF) Project, NASA Engineering and Safety Center (NESC) Assessment. The test article (TA) is an 8-foot-diameter aluminum-lithium (Al-Li) orthogrid cylindrical shell with similar design features as that of the proposed Ares-I and Ares-V barrel structures. In support of the testing effort, detailed structural analyses were conducted and the results were used to monitor the behavior of the TA during the testing. A summary of predicted results for each of the five load sequences is presented herein.

Thornburgh, Robert P.↗
DOE OSTI2017

Textile Inspired Lithium-Oxygen Battery Cathode with Decoupled Oxygen and Electrolyte Pathways

The lithium–air (Li–O 2 ) battery has been deemed one of the most promising next–generation energy–storage devices due to its ultrahigh energy density. However, in conventional porous carbon–air cathodes, the oxygen gas and electrolyte often compete for transport pathways, which limit battery performance. Here, a novel textile–based air cathode is developed with a triple–phase structure to improve overall battery performance. The hierarchical structure of the conductive textile network leads to decoupled pathways for oxygen gas and electrolyte: oxygen flows through the woven mesh while the electrolyte diffuses along the textile fibers. Due to noncompetitive transport, the textile–based Li–O 2 cathode exhibits a high discharge capacity of 8.6 mAh cm –2 , a low overpotential of 1.15 V, and stable operation exceeding 50 cycles. The textile–based structure can be applied to a range of applications (fuel cells, water splitting, and redox flow batteries) that involve multiple phase reactions. In conclusion, the reported decoupled transport pathway design also spurs potential toward flexible/wearable Li–O 2 batteries.

25 ENERGY STORAGE↗
NASA NTRS1986

Science applications

Possible scientific applications in the field of the neutral ionized atmosphere and of the solid Earth in terms of the TSS are summarized. Studies of the vertical, zonal, and meridional neutral winds and temperature, whose extensive variations suggest the importance of energy transfer mechanism in modifying the structural properties of the region are reviewed. Layers below the F region of high plasma density that propagate to lower altitudes with drift velocities will be studied for their electron and ion composition and motion. These are to be measured by the TSS in conjunction with ground based radar observations. Basic fluid dynamics problems will be studied onboard tethered satellites. Studies will be conducted on the structure of the equatorial electrojet, in particular its longitudinal and meridional extent. Magnetic measurements will also be used to probe the tether current distribution in the plasma sheath.

Mariani, F.↗
NASA NTRS1974

Measured electric field in the vicinity of a thunderstorm system at an altitude of 37 km

A balloon-borne experiment to measure the atmospheric electric field was flown from the National Scientific Balloon Facility at Palestine, Texas, on July 10, 1973. The electric field and atmospheric conductivity were measured during ascent and for a 4-hour float period at 37-km altitude. Termination of the flight occurred near a thunderstorm line in west Texas. The perturbing influence of the thunderstorms on the electric field was observed at least 100 km from the storm line. The measured electric field is in reasonable agreement with calculations based on simple models of cloud structure and atmospheric conductivity. Large pulses in the measured electric field are interpreted as being the result of intracloud lightning.

Benbrook, J. R.↗
DOE OSTI2017

Investigation of Thermal Conductivities and Expansion Coefficients of (Yb{sub 1 − x}La{sub x}){sub 2}AlTaO{sub 7} Ceramics

The (Yb{sub 1 − x}La{sub x}){sub 2}AlTaO{sub 7} (x = 0, 0.1, 0.3, 0.5) ceramics were prepared by solid-state reaction method. The phase composition, microstructure, thermophysical properties of (Yb{sub 1 − x}La{sub x}){sub 2}AlTaO{sub 7} ceramics were investigated. Results reveal that (Yb{sub 1 − x}La{sub x}){sub 2}AlTaO{sub 7} (x = 0, 0.1, 0.3) ceramics exhibit a single pyrochlore-type structure, and the (Yb{sub 0.5}La{sub 0.5}){sub 2}AlTaO{sub 7} has an orthorhombic weberite structure. The thermal conductivities of (Yb{sub 1 − x}La{sub x}){sub 2}AlTaO{sub 7} (x = 0, 0.1, 0.3) ceramics decrease with increasing Yb{sub 2}O{sub 3} contents. (Yb{sub 0.5}La{sub 0.5}){sub 2}AlTaO{sub 7} has the highest thermal conductivity among all the ceramics studied, within the range of 1.48-1.75 W/m K (20-1200 °C). The thermal expansion coefficients of (Yb{sub 1 − x}La{sub x}){sub 2}AlTaO{sub 7} ceramics decrease gradually with increasing La{sub 2}O{sub 3} fractions, and the thermal expansion coefficients are close to those of YSZ.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Oxygen vacancy-driven evolution of structural and electrical properties in SrFeO 3₋δ thin films and a method of stabilization

Epitaxial SrFeO 3-δ (SFO) thin films have been grown on various substrates by pulsed laser deposition. The structural and electrical properties of SFO thin films are monitored with time in different atmospheres at room temperature, showing time-dependent crystal structure and electrical conductivity. The increased out-of-plane lattice parameter and resistivity over time are associated with the increased oxygen vacancies density in SFO thin films. The epitaxial strain plays an important role in determining the initial resistivity, and the sample environment determines the trend of resistivity change over time. An amorphous Al 2 O 3 passivation layer has been found to be effective in stabilizing the structure and electrical properties of SFO thin films. Lastly, this work explores time dependent structure and properties variation in oxide films and provides a way to stabilize thin film materials that are sensitive to oxygen vacancies.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1991

Experimental results using active control of traveling wave power flow

Active structural control experiments conducted on a 24-ft pinned-free beam derived feedback compensators on the basis of a traveling-wave approach. A compensator is thus obtained which eliminates resonant behavior by absorbing all impinging power. A causal solution is derived for this noncausal compensator which mimics its behavior in a given frequency range, using the Wiener-Hopf. This optimal Wiener-Hopf compensator's structure-damping performance is found to exceed any obtainable by means of rate feedback. Performance limitations encompassed the discovery of frequencies above which the sensor and actuator were no longer dual and an inadvertent coupling of the control hardware to unmodeled structure torsion modes.

Miller, David W.↗
DOE OSTI2017

EFFECT OF INCLINED WAVES ON DEEPLY EMBEDDED NUCLEAR FACILITIES

Several conceptual designs for advanced reactors show that most if not all of the structure is embedded in the soil. Consequently, analysis techniques that have been verified and validated for the analysis of light water reactors on surface foundations may not be directly applicable to deeply embedded reactors. Specifically two effects that may change the in-structure response (ISR) of embedded facilities are: (i) the effect of the kinematic interaction becomes more prominent as the embedment depth increases; (ii) non-vertically propagating waves, which are usually not considered for surface-founded facilities, may be more important for deeply embedded facilities. A preliminary study is presented in this article to understand the response of embedded nuclear facilities to non-vertically propagating seismic waves. The inclined wave field is generated from source-to-site simulations using representative earthquake faults with different dip angles. The embedment depth of the nuclear containment facility is also varied to obtain a better understanding of the effect of embedment. This analysis of the soil-structure ensemble is conducted using the application called Multi-hazard Analysis for STOchastic time-DOmaiN phenomena (MASTODON), developed on top of Idaho National Lab’s open source MOOSE finite element framework. The Domain Reduction Method implemented in MASTODON to incorporate the seismic excitation within the region of interest is verified and then used to reduce the computational effort in analyzing this problem. Preliminary analysis using linear soil and structure material properties and tied contact between the soil and structure indicate that embedding the nuclear facility reduces significantly the response of the structure in all the earthquake scenarios considered.

42 ENGINEERING↗
NASA NTRS1992

Development of a machine vision system for automated structural assembly

Research is being conducted at the LaRC to develop a telerobotic assembly system designed to construct large space truss structures. This research program was initiated within the past several years, and a ground-based test-bed was developed to evaluate and expand the state of the art. Test-bed operations currently use predetermined ('taught') points for truss structural assembly. Total dependence on the use of taught points for joint receptacle capture and strut installation is neither robust nor reliable enough for space operations. Therefore, a machine vision sensor guidance system is being developed to locate and guide the robot to a passive target mounted on the truss joint receptacle. The vision system hardware includes a miniature video camera, passive targets mounted on the joint receptacles, target illumination hardware, and an image processing system. Discrimination of the target from background clutter is accomplished through standard digital processing techniques. Once the target is identified, a pose estimation algorithm is invoked to determine the location, in three-dimensional space, of the target relative to the robots end-effector. Preliminary test results of the vision system in the Automated Structural Assembly Laboratory with a range of lighting and background conditions indicate that it is fully capable of successfully identifying joint receptacle targets throughout the required operational range. Controlled optical bench test results indicate that the system can also provide the pose estimation accuracy to define the target position.

Sydow, P. Daniel↗
NASA NTRS2021

Mapping Boreal Forest Spruce Beetle Health Status at the Individual Crown Scale Using Fused Spectral and Structural Data

The frequency and severity of spruce bark beetle outbreaks are increasing in boreal forests leading to widespread tree mortality and fuel conditions promoting extreme wildfire. Detection of beetle infestation is a forest health monitoring (FHM) priority but is hampered by the challenges of detecting early stage (“green”) attack from the air. There is indication that green stage might be detected from vertical gradients of spectral data or from shortwave infrared information distributed within a single crown. To evaluate the efficacy of discriminating “non-infested”, “green”, and “dead” health statuses at the landscape scale in Alaska, USA, this study conducted spectral and structural fusion of data from: (1) Unoccupied aerial vehicle (UAV) multispectral (6 cm) + structure from motion point clouds (~700 pts per sq. m); and (2) Goddard Lidar Hyperspectral Thermal (G-LiHT) hyperspectral (400 to 1000 nm, 0.5 m) + SWIR-band lidar (~32 pts per sq.m). We achieved 78% accuracy for all three health statuses using spectral + structural fusion from either UAV or G-LiHT and 97% accuracy for non-infested/dead using G-LiHT. We confirm that UAV 3D spectral (e.g., greenness above versus below median height in crown) and lidar apparent reflectance metrics (e.g., mean reflectance at 99th percentile height in crown), are of high value, perhaps capturing the vertical gradient of needle degradation. In most classification exercises, UAV accuracy was lower than G-LiHT indicating that collecting ultra-high spatial resolution data might be less important than high spectral resolution information. While the value of passive optical spectral information was largely confined to the discrimination of non-infested versus dead crowns, G-LiHT hyperspectral band selection (~400, 675, 755, and 940 nm) could inform future FHM mission planning regarding optimal wavelengths for this task. Interestingly, the selected regions mostly did not align with the band designations for our UAV multispectral data but do correspond to, e.g., Sentinel-2 red edge bands, suggesting a path forward for moderate scale bark beetle detection when paired with suitable structural data.

Janice Cessna↗
NASA NTRS2019

Photogrammetry-Based Analysis of the On-Orbit Structural Dynamics of the Roll-Out Solar Array

The Roll-Out Solar Array (ROSA) flight experiment was launched to the International Space Station (ISS) on June 3rd, 2017. ROSA is an innovative, lightweight solar array with a flexible substrate that makes use of the stored strain energy in its composite structural members to provide deployment without the use of motors. This paper will discuss the results of various structural dynamics experiments conducted on the ISS during the weeks following launch. Data gathered from instrumentation on the solar array wing during the experiments was previously compared with pre-flight predictions from two different Finite Element Modeling (FEM) efforts. In this paper, data generated from photogrammetry is compared with accelerometer data and used to extend previous conclusions. Whereas previous analyses were only able to track the accelerations of six discrete points on the structure and photovoltaic (PV) blanket of ROSA, the photogrammetry analysis makes available displacements for dozens of points distributed throughout the array. This larger data set makes it possible to compare higher-order PV blanket modes with FEM predictions, in addition to verifying conclusions reached using accelerometer data. The goal in this effort was to better understand the performance of ROSA and to improve modeling efforts for future designs of similar solar arrays.

Chamberlain, Matthew K.↗
DOE OSTI2024

Tailoring Growth Interfaces of Virtual Substrates for Power Electronics

Power electronics materials are poised to play a critical role in fulfilling next generation energy needs, with up to 90% of future energy demand predicted to flow through power electronics at some point. AlxGa1-xN ranks high among candidate materials, having bipolar dopability, thermal and chemical stability and an ultra-wide bandgap. However, AlGaN growth is limited by a lack of lattice-matched substrates, ultimately stunting material quality at higher thicknesses needed for power electronics applications. Further, high power applications increasingly call for fully vertical device structures, necessitating a conductive substrate. Recently our group identified the (111) plane of TaC as a conductive surface lattice-matched to Al0.55Ga0.45N, taking inspiration from prior work of AlN and GaN binaries on carbide and boride substrates. In this talk we demonstrate the growth of (111)-oriented TaC by RF sputtering. We investigate the interface of TaC with sapphire and SiC substrates and identify means to suppress competing Ta2C nucleation in order to stabilize (111)-oriented TaC. Potential stacking sequences are identified with respect to crystal structure and observed twinning in the TaC films. We next assess structural changes and film recrystallization that results from face-to-face annealing of TaC thin films at high temperatures above 1500 degrees C. Changes to grain structure and domain size are assessed by x-ray diffraction and surface morphology is explored using atomic force microscopy. Figure 1 shows significant improvements to in- and out-of-plane strain following annealing along with the formation of terraced step edges at the film surface. Strain as a function of material composition and thickness is considered, as this may play a major role in future nucleation of AlGaN layers. (1) R. J. in a face-to-face configuration, as illustrated in the schematic at left. Kaplar et al 2017, ECS J. Solid State Sci. Technol. 6 Q3061; (2) D. M. Roberts et al 2022, https://arxiv.org/abs/2208.11769; (3) T. Aizawa et al 2008, J Crys Growth 310, 1 22; (4) R. Liu et al 2002, Appl. Phys. Lett. 81, 3182-3184.

ENGINEERING↗
NASA NTRS1984

Detailed studies of the dynamics and energetics of coronal bullets

Coronal bullets are small ejecta of cool, dense plasma observed to accelerate through the solar atmosphere from 20 to 450 km/s. The NRL Dynamic Flux Tube Model has been used to simulate the evolving physical properties of these dynamic events. The present calculations utilize an adaptive-gridding technique to resolve the fine structure within and around the bullets. In this work, an identification was made of a component of shocked plasma which piles up ahead of the bullet and eventually dominates both the dynamics and heating of the original bullet mass. The observational consequences of this shocked component are discussed in terms of the available HRTS EUV data, and suggestions are made for optimizing future observations of this phenomenon. An investigation has also been conducted of the structure of the bullet material visible in EUV spectral lines and the observable characteristics of the EUV-emitting plasma. Finally, the most likely mechanisms for accelerating the bullets, as well as favorable sites of origin are evaluated.

Karpen, J. T.↗
DOE OSTI2018

Dose rate verification for SNS spent structures - 25433

Residual dose rate measurements were conducted on two Spallation Neutron Source spent structures, target vessel no. 13 and proton beam window no. 5, after extraction from their service locations. These measurements were used to verify calculation methods for radionuclide inventory assessment that are typically performed for nuclear waste characterization and transportation. Neutronics analyses for predicting residual dose rates were carried out using complex and rigorous geometric models of the structures and their surroundings. Calculational results were analyzed and compared to the measured dose rates. (authors)

43 PARTICLE ACCELERATORS↗
NASA NTRS1990

Possibilities for LWIR detectors using MBE-grown Si(/Si(1-x)Ge(x) structures

Traditionally, long wavelength infrared (LWIR) detection in Si-based structures has involved either extrinsic Si or Si/metal Schottky barrier devices. Molecular beam epitaxially (MBE) grown Si and Si/Si(1-x)Ge(x) heterostructures offer new possibilities for LWIR detection, including sensors based on intersubband transitions as well as improved conventional devices. The improvement in doping profile control of MBE in comparison with conventional chemical vapor deposited (CVD) Si films has resulted in the successful growth of extrinsic Si:Ga, blocked impurity-band conduction detectors. These structures exhibit a highly abrupt step change in dopant profile between detecting and blocking layers which is extremely difficult or impossible to achieve through conventional epitaxial growth techniques. Through alloying Si with Ge, Schottky barrier infrared detectors are possible, with barrier height values between those involving pure Si or Ge semiconducting materials alone. For both n-type and p-type structures, strain effects can split the band edges, thereby splitting the Schottky threshold and altering the spectral response. Measurements of photoresponse of n-type Au/Si(1-x)Ge(x) Schottky barriers demonstrate this effect. For intersubband multiquntum well (MQW) LWIR detection, Si(1-x)Ge(x)/Si detectors grown on Si substrates promise comparable absorption coefficients to that of the Ga(Al)As system while in addition offering the fundamental advantage of response to normally incident light as well as the practical advantage of Si-compatibility. Researchers grew Si(1-x)Ge(x)/Si MQW structures aimed at sensitivity to IR in the 8 to 12 micron region and longer, guided by recent theoretical work. Preliminary measurements of n- and p-type Si(1-x)Ge(x)/Si MQW structures are given.

Hauenstein, Robert J.↗
NASA NTRS2017

On-Orbit Structural Dynamics Performance of the Roll-Out Solar Array

The Roll-Out Solar Array (ROSA) flight experiment was launched to the International Space Station (ISS) on June 3rd, 2017. ROSA is an innovative, lightweight solar array with a flexible substrate that makes use of the stored strain energy in its composite structural members to provide deployment without the use of motors. This paper will discuss the results of various structural dynamics experiments conducted on the ISS during the weeks following launch. Data gathered from instrumentation on the solar array wing during the experiments are compared with pre-flight predictions from two different finite element modeling efforts. Two distinct methods were used to reconstruct the modal characteristics of ROSA from the data collected on orbit. Of particular interest in this effort are the first few system modes and mode shapes of the array, the amount of structural damping present, and degree of structural thermal interaction seen during eclipse exit. Discrepancies between the behavior predicted by the models and that observed on orbit are identified and discussed. The goal in this effort was to better understand the performance of ROSA and to improve modeling efforts for future designs of similar solar arrays.

Chamberlain, Matthew K.↗