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At least 829 records · Page 46

Dependence of Convective Heat Flux Calculations on Roughness Lengths

The zero plane displacement height (d) and aerodynamic roughness length (z0) can be determined separately for momentum, heat, and humidity by using a procedure based on the Levenberg-Marquardt method for solving non-linear equations. This procedure is used to analyze profile data previously collected by Lo (1977) in a forested area in Canada and by Morgan et al (1971) on a field at the University of California at Davis (UCD) in the United States. The UCD data base is used to show the effects of allowing for different roughness lengths (zom,z0h,z0q) in calculating sensible and latent heat flux densities from bulk transfer coefficients.

Convective Heat↗

Synthetic and Biomass Alternate Fueling in Aviation

While transportation fueling can accommodate a broad range of alternate fuels, aviation fueling needs are specific, such as the fuel not freezing at altitude or become too viscous to flow properly or of low bulk energy density that shortens range. The fuel must also be compatible with legacy aircraft, some of which are more than 50 years old. Worldwide, the aviation industry alone uses some 85-95 billion gallons of hydrocarbon-based fossil fuel each year, which is about 10% of the transportation industry. US civil aviation alone consumes nearly 14 billion gallons. The enormity of the problem becomes overwhelming, and the aviation industry is taking alternate fueling issues very seriously. Biofuels (algae, cyanobacteria, halophytes, weeds that use wastelands, wastewater and seatwater), when properly sourced, have the capacity to be drop-in fuel replacements for petroleum fuels. As such, biojet from such sources solves the aviation CO2 emissions issue without the downsides of 'conventional' biofuels, such as competing with food and fresh water resources. Of the many current fundamental problems, the major biofuel problem is cost. Both research and development and creative engineering are required to reduce these biofuels costs. Research is also ongoing in several 'improvement' areas including refining/processing and biologics with greater disease resistance, greater bio-oil productivity, reduced water/nutrient requirements, etc. The authors' current research is aimed at aiding industry efforts in several areas. They are considering different modeling approaches, growth media and refining approaches, different biologic feedstocks, methods of sequestering carbon in the processes, fuel certification for aviation use and, overall, ensuring that biofuels are feasible from all aspects - operability, capacity, carbon cycle and financial. The authors are also providing common discussion grounds/opportunities for the various parties, disciplines and concerned organization to share both issues and potential ways for moving forward, and overall, trying to educate those concerned about the innate limitations of 'conventional' biofuels and the solutions provided by non-traditional feedstocks that used waste lands/water or saline/salt water have an immense capacity potential.

Hendricks, R. C.↗

A Functional Comparison of Lunar Regoliths and Their Simulants

Lunar regolith simulants are essential to the development of technology for human exploration of the Moon. Any equipment that will interact with the surface environment must be tested with simulant to mitigate risk. To reduce the greatest amount of risk, the simulant must replicate the lunar surface as well as possible. To quantify the similarities and differences between simulants, the Figures of Merit were developed. The Figures of Merit software compares the simulants and regolith by particle size, particle shape, density, and bulk chemistry and mineralogy; these four properties dictate the majority of the remaining characteristics of a geologic material. There are limitations to both the current Figures of Merit approach and simulants in general. The effect of particle textures is lacking in the Figures of Merit software, and research into this topic has only recently begun with applications to simulants. In addition, not all of the properties for lunar regolith are defined sufficiently for simulant reproduction or comparison; for example, the size distribution of particles greater than 1 centimeter and the makeup of particles less than 10 micrometers is not well known. For simulants, contamination by terrestrial weathering products or undesired trace phases in feedstock material is a major issue. Vapor deposited rims have not yet been created for simulants. Fortunately, previous limitations such as the lack of agglutinates in simulants have been addressed and commercial companies are now making agglutinate material for simulants. Despite some limitations, the Figures of Merit sufficiently quantify the comparison between simulants and regolith for useful application in lunar surface technology. Over time, the compilation and analysis of simulant user data will add an advantageous predictive capability to the Figures of Merit, accurately relating Figures of Merit characteristics to simulant user parameters.

Rickman, D.↗

RUSHMAPS: Real-Time Uploadable Spherical Harmonic Moment Analysis for Particle Spectrometers

RUSHMAPS is a new onboard data reduction scheme that gives real-time access to key science parameters (e.g. moments) of a class of heliophysics science and/or solar system exploration investigation that includes plasma particle spectrometers (PPS), but requires moments reporting (density, bulk-velocity, temperature, pressure, etc.) of higher-level quality, and tolerates a lowpass (variable quality) spectral representation of the corresponding particle velocity distributions, such that telemetry use is minimized. The proposed methodology trades access to the full-resolution velocity distribution data, saving on telemetry, for real-time access to both the moments and an adjustable-quality (increasing quality increases volume) spectral representation of distribution functions. Traditional onboard data storage and downlink bandwidth constraints severely limit PPS system functionality and drive cost, which, as a consequence, drives a limited data collection and lower angular energy and time resolution. This prototypical system exploit, using high-performance processing technology at GSFC (Goddard Space Flight Center), uses a SpaceCube and/or Maestro-type platform for processing. These processing platforms are currently being used on the International Space Station as a technology demonstration, and work is currently ongoing in a new onboard computation system for the Earth Science missions, but they have never been implemented in heliospheric science or solar system exploration missions. Preliminary analysis confirms that the targeted processor platforms possess the processing resources required for realtime application of these algorithms to the spectrometer data. SpaceCube platforms demonstrate that the target architecture possesses the sort of compact, low-mass/power, radiation-tolerant characteristics needed for flight. These high-performing hybrid systems embed unprecedented amounts of onboard processing power in the CPU (central processing unit), FPGAs (field programmable gate arrays), and DSP (digital signal processing) elements. The fundamental computational algorithm de constructs 3D velocity distributions in terms of spherical harmonic spectral coefficients (which are analogous to a Fourier sine-cosine decomposition), but uses instead spherical harmonics Legendre polynomial orthogonal functions as a basis for the expansion, portraying each 2D angular distribution at every energy or, geometrically, spherical speed-shell swept by the particle spectrometer. Optionally, these spherical harmonic spectral coefficients may be telemetered to the ground. These will provide a smoothed description of the velocity distribution function whose quality will depend on the number of coefficients determined. Successfully implemented on the GSFC-developed processor, the capability to integrate the proposed methodology with both heritage and anticipated future plasma particle spectrometer designs is demonstrated (with sufficiently detailed design analysis to advance TRL) to show specific science relevancy with future HSD (Heliophysics Science Division) solar-interplanetary, planetary missions, sounding rockets and/or CubeSat missions.

Figueroa-Vinas, Adolfo↗

Small-Scale Magnetic Flux Ropes in Stream Interaction Regions From Parker Solar Probe and Wind Spacecraft Observations

Using in situ measurements from the Parker Solar Probe and Wind spacecraft, we investigate the small-scale magnetic flux ropes (SFRs) and their properties inside stream interaction regions (SIRs). Within SIRs from ∼0.15 to 1 au, SFRs are found to exist in a wide range of solar wind speeds with more frequent occurrences after the stream interface, and the Alfvénicity of these structures decreases significantly with increasing heliocentric distances. Furthermore, we examine the variation of five corresponding SIRs from the same solar sources. The enhancements of suprathermal electrons within these SIRs persist at 1 au and are observed multiple times. An SFR appears to occur repeatedly with the recurring SIRs and is traversed by the Wind spacecraft at least twice. This set of SFRs has similarities in variations of the magnetic field components, plasma bulk properties, density ratio of solar wind alpha and proton particles, and unidirectional suprathermal electrons. We also show, through the detailed time-series plots and Grad–Shafranov reconstruction results, that they possess the same chirality and carry comparable amounts of magnetic flux. Lastly, we discuss the possibility for these recurring SFRs to be formed via interchange reconnection, maintain the connection with the Sun, and survive up to 1 au.

Solar wind↗

Understanding the limitations and potential of micro tensile testing of tungsten and needs for crystal plasticity modelling

Tungsten is the leading plasma facing material candidate due to its exceptional properties. Understanding the response to neutron irradiation is crucial for the lifetime evaluation of tungsten. The limited space in nuclear reactors and the high levels of radioactivity of the specimens after irradiation are significant barriers to accurately measuring the mechanical properties after neutron irradiation. Testing of micro tensile specimens is one approach to reduce the total amount of irradiated material needed for a set of mechanical testing experiments. However, micro samples are not necessarily measuring the bulk material properties, as size effects produce higher measured mechanical properties than is observed in engineering size counterparts. Determining the minimal sample size for reliable bulk property measurement, combined with modeling efforts, is essential. We conducted room temperature tensile tests on tungsten micro tensile specimens fabricated with focused ion beam, plasma focused ion beam and femto-second laser ablation system to dimension of 2×2×7?µm³, 7×7×18?µm³, and 80×100×233?µm³ (width×thickness×gauge-length), respectively. Elevated tensile testing was performed up to 475°C on 5×5×18?µm³ specimens fabricated with focused ion beam. The smallest specimens exhibited a high degree of ductility and strength, whereas the largest specimens demonstrated behavior akin to bulk tungsten. To investigate the effects introduced by the micro specimen fabrication processes and to obtain the necessary bulk dislocation density for the crystal plasticity model, we employed X-ray diffraction depth profiling. This measurement was performed using different X-ray sources with varying penetration depths. Finally, the potential and limitations of micro mechanical tests for tungsten will be discussed.

36 - MATERIALS SCIENCE↗

Coupling Microstructural Evolution Simulations to Material Property Degradation Predictions for Plasma-Facing Materials

Reliable material performance is required for plasma-facing material (PFM) candidates. Previous research has shown that plasma and neutron radiation exposure induces microstructural changes in PFMs; changes in thermal and electrical conductivities and in material hardening and embrittlement were also observed after neutron irradiation. These material property changes will negatively impact the performance of the PFMs in a fusion reactor. Despite the well-known connection between material microstructure, properties, and performance, there is a need for validated modeling capabilities connecting PFM property degradation with microstructural evolution under fusion-relevant conditions. We are developing a simulation capability to couple plasma-induced microstructural evolution to material property degradation. Our approach relies on deliberate mapping between individual simulation models and experimental characterization for validation. The open-source Multiphysics Object-Oriented Simulation Environment (MOOSE) software was used for this simulation capability development. A MOOSE phase-field model was coupled with the cluster dynamics code, Xolotl, to predict microstructural evolution. Microstructure characterization techniques, including scanning electron microscopy (SEM), transmission electron microscopy (TEM), and laser scanning confocal microscopy (LSCM) are used to validate these microstructural evolution simulations. Calculation of thermal and electrical conductivities with first principles simulations was performed for bulk material and for grain boundaries; these results are used within MOOSE models to calculate effective thermal and electrical conductivities as a function of grain characteristics. Thermoreflectance and four-probe techniques were employed to measure the thermal and electrical conductivities, respectively. A MOOSE crystal plasticity model was adapted to predict microstructure-sensitive deformation behavior, and X-ray diffraction (XRD) was used to collect bulk dislocation density data for validation. After individual simulation validation, these models are coupled to predict material property changes resulting from plasma exposure. We focused here on an experimental design to emphasize the separate effects of moderate thermal loads and plasma exposure using tungsten. Annealing of tungsten was performed under a protective environment for temperatures ranging from 500 C to 1500 C. The plasma exposure was completed in the Tritium Plasma Experiment at Idaho National Laboratory under a deuterium flux of 1e22 D/m^2-s. This incremental approach is employed to build confidence in the modeling capability: separate-effects tests ensure that the models capture key mechanisms from single environmental conditions before predicting PFM property degradation under combined loads. We will show our early results from coupling these simulation models to predict PFM property changes from microstructural evolution. Comparisons of the simulation results with preliminary validation data will be discussed.

36 - MATERIALS SCIENCE↗

Connect microstructure evolution to property degradation with validated simulation

Reliable material performance is required for plasma-facing material (PFM) candidates. Previous research has shown that plasma and neutron radiation exposure induces microstructural changes in PFMs; changes in thermal and electrical conductivities and in material hardening and embrittlement were also observed after neutron irradiation. These material property changes will negatively impact the performance of the PFMs in a fusion reactor. Despite the well-known connection between material microstructure, properties, and performance, there is a need for validated modeling capabilities connecting PFM property degradation with microstructural evolution under fusion-relevant conditions. We are developing a simulation capability to couple plasma-induced microstructural evolution to material property degradation. Our approach relies on deliberate mapping between individual simulation models and experimental characterization for validation. The open-source Multiphysics Object-Oriented Simulation Environment (MOOSE) software was used for this simulation capability development. A MOOSE phase-field model was coupled with the cluster dynamics code, Xolotl, to predict microstructural evolution. Microstructure characterization techniques, including scanning electron microscopy (SEM), transmission electron microscopy (TEM), and laser scanning confocal microscopy (LSCM) are used to validate these microstructural evolution simulations. Calculation of thermal and electrical conductivities with first principles simulations was performed for bulk material and for grain boundaries; these results are used within MOOSE models to calculate effective thermal and electrical conductivities as a function of grain characteristics. Thermoreflectance and four-probe techniques were employed to measure the thermal and electrical conductivities, respectively. A MOOSE crystal plasticity model was adapted to predict microstructure-sensitive deformation behavior, and X-ray diffraction (XRD) was used to collect bulk dislocation density data for validation. After individual simulation validation, these models are coupled to predict material property changes resulting from plasma exposure. We focused here on an experimental design to emphasize the separate effects of moderate thermal loads and plasma exposure using tungsten. Annealing of tungsten was performed under a protective environment for temperatures ranging from 500$^o$C to 1500$^o$C. The plasma exposure was completed in the Tritium Plasma Experiment at Idaho National Laboratory under a deuterium flux of 1e22 $\frac{D}{m^2s}$. This incremental approach is employed to build confidence in the modeling capability: separate-effects tests ensure that the models capture key mechanisms from single environmental conditions before predicting PFM property degradation under combined loads. We will show our early results from coupling these simulation models to predict PFM property changes from microstructural evolution. Comparisons of the simulation results with preliminary validation data will be discussed.

36 - MATERIALS SCIENCE↗

High temperature magnetic properties of SmCo{sub 5}/{alpha}-Fe(Co) bulk nanocomposite magnets

To find alternative high temperature magnets containing no heavy rare earths for power applications, SmCo{sub 5}/Fe bulk nanocomposite magnets with enhanced energy density and high thermal stability have been produced by using a ball-milling plus warm-compaction route. Up to 30% of the Fe soft magnetic phase has been added to the composites with grain size <20 nm distributed homogenously in the matrix of the SmCo{sub 5} hard magnetic phase. It was observed that the microstructure does not change with temperature up to 500 Degree-Sign C. It is also observed that the thermal stability of bulk nanocomposite samples is closely related to bulk density. Energy products above 11 MGOe have been obtained at 300 Degree-Sign C in fully dense bulk SmCo{sub 5}/Fe nanocomposite magnets, which is 65% higher than that of a single-phase counterpart at the same temperature.

36 MATERIALS SCIENCE↗

High moisture corn stover pelleting in a flat die pellet mill fitted with a 6 mm die: physical properties and specific energy consumption

The quality and specific energy consumption (SEC) of the biomass pellets produced depend upon pelleting process conditions. The present study includes understanding the effect of feedstock moisture in the range of 28–38% (wet basis [w.b.]) and preheating in the range of 30–110°C at two die speeds of 40 and 60 Hz on the physical properties and SEC. A flat die pellet mill fitted with a 6 mm die was used in the present study. The physical properties of pellets such as moisture content, unit, bulk and tapped density, durability, and expansion ratio and SEC of the pelleting process are measured. The results indicate that the pellets produced have durability values in the range of 87–98%, and unit bulk and tapped density in the range of 670–1100, 375–575, and 420–620 kg/m³. Increasing the feedstock moisture content from 33% to 38% (w.b) decreased the unit, bulk and tapped density by about 30–40%. Increasing feedstock moisture content increased the expansion ratio and decreased the density values. A higher feedstock moisture content of 38% (w.b.) and higher preheating temperature of 110°C resulted in lower density and a higher expansion ratio, which can be attributed to flash off of moisture as the material extrudes out of the die. The SEC was in the range of 75–275 kWh/ton. Higher feedstock moisture content of 38% (w.b.) and a lower die speed of 40 Hz increased the SEC, whereas lower to medium preheating temperature (30–70°C), medium feedstock moisture content of 33% (w.b.), and a higher die speed of 60 Hz minimized the SEC to <100 kWh/ton.

09 BIOMASS FUELS↗

Superfluid density in overdoped cuprates: Thin films versus bulk samples

Recent study of overdoped La 2–x Sr x CuO 4 cuprate superconductor thin films by Božovic et al. has revealed several unexpected findings, most notably the violation of the BCS description which was believed to adequately describe overdoped cuprates. In particular, it was found that the superfluid density in La 2–x Sr x CuO 4 films decreases on the overdoped side as a linear function of critical temperature T c , which was taken as evidence for the violation of Homes' law. Here we show explicitly that the law is indeed violated, and as the main reason for violation we find that the superfluid density in Božovic's films is suppressed more strongly than in bulk samples. Based on the existing literature data, we show that the superfluid density in bulk cuprate samples does not decrease with doping, but instead tends to saturate on the overdoped side. The result is also supported by our recent measurement of a heavily overdoped bulk La 2–x Sr x CuO 4 sample. Moreover, this saturation of superfluid density might not be limited to cuprates, as we find evidence for similar behavior in two pnictide superconductor families. We argue that quantum phase fluctuations play an important role in suppressing the superfluid density in thin films.

2-dimensional systems↗

Nanoscale temperature mapping in operating microelectronic devices

We report that modern microelectronic devices have nanoscale features that dissipate power nonuniformly, but fundamental physical limits frustrate efforts to detect the resulting temperature gradients. Contact thermometers disturb the temperature of a small system, while radiation thermometers struggle to beat the diffraction limit. Exploiting the same physics as Fahrenheit’s glass-bulb thermometer, we mapped the thermal expansion of Joule-heated, 80-nanometer-thick aluminum wires by precisely measuring changes in density. With a scanning transmission electron microscope (STEM) and electron energy loss spectroscopy (EELS), we quantified the local density via the energy of aluminum’s bulk plasmon. Rescaling density to temperature yields maps with a statistical precision of 3 kelvin/hertz ₋1/2 , an accuracy of 10%, and nanometer-scale resolution. Lastly, many common metals and semiconductors have sufficiently sharp plasmon resonances to serve as their own thermometers.

47 OTHER INSTRUMENTATION↗

Surface area and particle size distribution of plutonium oxides derived from the direct oxidation of Pu metal (LA-UR-18-22581)

The intent of this paper is to interrogate the physical characteristics of PuO 2 powders and aggregates produced by direct metal oxidation to examine possible relationships between process parameters and the physical characteristics of the product. The majority of the PuO 2 samples considered were generated during the pre-production and production phases of the Advanced Recovery and Integrated Extraction System (ARIES) program at Los Alamos National Laboratory (LANL). Oxide formed passively on Pu metal surfaces at ambient atmospheric conditions is also characterized. Plutonium oxide powders from the ARIES Direct Metal Oxidation (DMO) furnace and muffle furnace process lines are very consistent in terms of their bulk and tapped density, specific surface area (SSA) and particle size distribution (PSD). The SSAs of calcined PuO 2 generated in the ARIES DMO-2 and muffle furnaces are between 0.1 and 0.5 m2/g. Oxides from both the DMO-2 and muffle furnaces also had similar tri-modal PSDs with maxima at 0.73–3.16 μm, 10.9–18.5 μm, and 41.3–63.0 μm. The PSDs of the oxide formed passively on Pu metal surfaces at ambient conditions were unimodal, with near-Gaussian distributions and D50 close to 1 μm. In conclusion, the oxide formed passively at ambient conditions also had significantly higher SSAs (6–8 m 2 /g).

36 MATERIALS SCIENCE↗

Processing and characterization of multi-cellular monolithic bioceramics for bone regenerative scaffolds

Multicellular monolithic ceramic body is a ceramic material which has many gas or liquid passages partitioned by thin walls throughout the bulk material. There are many currently known advanced industrial applications of multicellular ceramics structures i.e. as supports for various catalysts, electrode support structure for solid oxide fuel cells, refractories, electric/electronic materials, aerospace vehicle re-entry heat shields and biomaterials for dental as well as orthopaedic implants by naming only a few. Multicellular ceramic bodies are usually made of ceramic phases such as mullite, cordierite, aluminum titanate or pure oxides such as silica, zirconia and alumina. What make alumina ceramics is excellent for the above functions are the intrinsic properties of alumina which are hard, wear resistant, excellent dielectric properties, resists strong acid and alkali attacks at elevated temperatures, good thermal conductivities, high strength and stiffness as well as biocompatible. In this work the processing technology leading to truly multicellular monolithic alumina ceramic bodies and their characterization are reported. Ceramic slip with 66 wt.% solid loading was found to be optimum as impregnant to the polyurethane foam template. Mullitic ceramic composite of alumina-sodium alumino disilicate-Leucite-like phases with bulk and true densities of 0.852 and 1.241 g cm{sup −3} respectively, pore linear density of ±35 cm{sup −1}, linear and bulk volume shrinkages of 7-16% and 32 vol.% were obtained. The compressive strength and elastic modulus of the bioceramics are ≈0.5-1.0 and ≈20 MPa respectively.

36 MATERIALS SCIENCE↗

Compressibility and hardness of Co-based bulk metallic glass: A combined experimental and density functional theory study

An incompressible Co{sub 54}Ta{sub 11}B{sub 35} bulk metallic glass (BMG) was investigated using in situ high-pressure synchrotron diffraction and nanoindendation. The elastic constants were deduced from the experiments based on the isotropic model. The Vickers hardness was measured to be 17.1 GPa. The elastic moduli and hardness are the highest values known in BMGs. The theoretically calculated elastic properties by density-functional study were well consistent with experimental measurements. The analysis of charge density and bonding character indicates the covalent character of Co-B and B-B bonds, underlying the unusually high elastic modulus and hardness in this material.

36 MATERIALS SCIENCE↗

Study of NbC thin films for soft X-ray multilayer applications

Compound materials are being used in soft x-ray and Extreme ultraviolet (EUV) optics applications. Structural properties of compound materials changes drastically when ultrathin films are formed from bulk material. Structural properties need to be investigated to determine the suitability of compound materials in soft x-ray multilayer applications. In the present study Niobium carbide (NbC) thin films were deposited using ion beam sputtering of an NbC target on Si (100) substrate. Thickness roughness and film mass density was determined from the X-ray reflectivity (XRR) data. XRR data revealed that the film mass density was increasing with increase in film thickness. For 500Ǻ thick film, mass density of 6.85 g/cm{sup 3}, close to bulk density was found. Rms roughness for all the films was less than 10Å. Local structure of NbC thin films was determined from EXAFS measurements. The EXAFS data showed an increase in Nb-C and Nb-(C)-Nb peak ratio approaches towards bulk NbC with increasing thickness of NbC. From the present study, NbC thin films were found suitable for actual use in soft x-ray multilayer applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The Effects of Material-Filled Voids on Detonation Wave Shape in Rubberized RDX Explosives

The sensitivity of explosives is affected by inhomogeneities within the material. This is evident in the increased shock sensitivity of explosives with slightly lower densities resulting from an increased number of hotspots. The influence of hotspots on explosive initiation has been well studied; however, few studies have been conducted on the effect of intermediate-sized voids (0.1–10 mm) on a propagating detonation wave. Cylindrical voids filled with air have been studied for diameters ranging from 0.3 mm to 0.8 mm for both 1,3,5,7-tetranitro-1,3,5,7-tetrazocane (HMX) and 1,3,5-trinitro-1,3,5-triazinane (RDX)-based rubberized explosives. Continuing the investigation into single cylindrical voids, this study examined the effects of 0.5 mm diameter voids filled with different inert cylindrical metals on the detonation wave shape for an RDX-based rubberized explosive. The metals selected for experiments were 1066 aluminum, brass, copper, and tungsten. The propagation of the detonation wave was captured using a digital streak camera. Experimental results showed that the extent of detonation wave shaping was closely tied to the density differential between the bulk explosive and metal insert. Forty-four different filler materials, including non-metals, were simulated using a hydrodynamic code to further analyze material inclusion effects. The main factors hypothesized to be of interest were bulk sound speed, shock impedance, and filler material density. We found that the local detonation delay could be correlated fairly well to a ratio of bulk sound speed and density. Understanding the influence of material inclusions on detonation performance and wave shape allows for tailoring of detonations.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Improvement in precision, accuracy, and efficiency in sstandardizing the characterization of granular materials

Useful prediction of the kinematics, dynamics, and chemistry of a system relies on precision and accuracy in the quantification of component properties, operating mechanisms, and collected data. In an attempt to emphasize, rather than gloss over, the benefit of proper characterization to fundamental investigations of multiphase systems incorporating solid particles, a set of procedures were developed and implemented for the purpose of providing a revised methodology having the desirable attributes of reduced uncertainty, expanded relevance and detail, and higher throughput. Better, faster, cheaper characterization of multiphase systems result. Methodologies are presented to characterize particle size, shape, size distribution, density (particle, skeletal and bulk), minimum fluidization velocity, void fraction, particle porosity, and assignment within the Geldart Classification. A novel form of the Ergun equation was used to determine the bulk void fractions and particle density. Accuracy of properties-characterization methodology was validated on materials of known properties prior to testing materials of unknown properties. Several of the standard present-day techniques were scrutinized and improved upon where appropriate. Validity, accuracy, and repeatability were assessed for the procedures presented and deemed higher than present-day techniques. A database of over seventy materials has been developed to assist in model validation efforts and future desig

42 ENGINEERING↗