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DOE OSTI2024

Plant Cell Wall Loosening by Expansins

Expansins comprise an ancient group of cell wall proteins ubiquitous in land plants and their algal ancestors. During cell growth, they facilitate passive yielding of the wall's cellulose networks to turgor-generated tensile stresses, without evidence of enzymatic activity. Expansins are also implicated in fruit softening and other developmental processes and in adaptive responses to environmental stresses and pathogens. The major expansin families in plants include α-expansins (EXPAs), which act on cellulose-cellulose junctions, and β-expansins, which can act on xylans. EXPAs mediate acid growth, which contributes to wall enlargement by auxin and other growth agents. The genomes of diverse microbes, including many plant pathogens, also encode expansins designated expansin-like X. Expansins are proposed to disrupt noncovalent bonding between laterally aligned polysaccharides (notably cellulose), facilitating wall loosening for a variety of biological roles.

Cell Biology↗

DOE OSTI2016

Directed plant cell-wall accumulation of iron: Embedding co-catalyst for efficient biomass conversion

Plant lignocellulosic biomass is an abundant, renewable feedstock for the production of biobased fuels and chemicals. Previously, we showed that iron can act as a co-catalyst to improve the deconstruction of lignocellulosic biomass. However, directly adding iron catalysts into biomass prior to pretreatment is diffusion limited, and increases the cost of biorefinery operations. Recently, we developed a new strategy for expressing iron-storage protein ferritin intracellularly to accumulate iron as a catalyst for the downstream deconstruction of lignocellulosic biomass. In this study, we extend this approach by fusing the heterologous ferritin gene with a signal peptide for secretion into Arabidopsis cell walls (referred to here as FerEX). The transgenic Arabidopsis plants. FerEX. accumulated iron under both normal and iron-fertilized growth conditions; under the latter (iron-fertilized) condition, FerEX transgenic plants showed an increase in plant height and dry weight by 12 and 18 %, respectively, compared with the empty vector control plants. The SDS- and native-PAGE separation of cell-wall protein extracts followed by Western blot analyses confirmed the extracellular expression of ferritin in FerEX plants. Meanwhile, Perls' Prussian blue staining and X-ray fluorescence microscopy (XFM) maps revealed iron depositions in both the secondary and compound middle lamellae cell-wall layers, as well as in some of the corner compound middle lamella in FerEX. Remarkably, their harvested biomasses showed enhanced pretreatability and digestibility, releasing, respectively, 21 % more glucose and 34 % more xylose than the empty vector control plants. These values are significantly higher than those of our recently obtained ferritin intracellularly expressed plants. This study demonstrated that extracellular expression of ferritin in Arabidopsis can produce plants with increased growth and iron accumulation, and reduced thermal and enzymatic recalcitrance. Here, the results are attributed to the intimate colocation of the iron co-catalyst and the cellulose and hemicellulose within the plant cell-wall region, supporting the genetic modification strategy for incorporating conversion catalysts into energy crops prior to harvesting or processing at the biorefinery.

09 BIOMASS FUELS↗

DOE OSTI2020

Improved analysis of arabinoxylan-bound hydroxycinnamate conjugates in grass cell walls

Background: Arabinoxylan in grass cell walls is acylated to varying extents by ferulate and p-coumarate at the 5-hydroxy position of arabinosyl residues branching off the xylan backbone. Some of these hydroxycinnamate units may then become involved in cell wall radical coupling reactions, resulting in ether and other linkages amongst themselves or to monolignols or oligolignols, thereby crosslinking arabinoxylan chains with each other and/or with lignin polymers. This crosslinking is assumed to increase the strength of the cell wall, and impedes the utilization of grass biomass in natural and industrial processes. A method for quantifying the degree of acylation in various grass tissues is, therefore, essential. We sought to reduce the incidence of hydroxycinnamate ester hydrolysis in our recently introduced method by utilizing more anhydrous conditions. Results: The improved methanolysis method minimizes the undesirable ester-cleavage of arabinose from ferulate and p-coumarate esters, and from diferulate dehydrodimers, and produces more methanolysis vs. hydrolysis of xylan-arabinosides, improving the yields of the desired feruloylated and p-coumaroylated methyl arabinosides and their diferulate analogs. Free ferulate and p-coumarate produced by ester-cleavage were reduced by 78% and 68%, respectively, and 21% and 39% more feruloyl and p-coumaroyl methyl arabinosides were detected in the more anhydrous method. The new protocol resulted in an estimated 56% less combined diferulate isomers in which only one acylated arabinosyl unit remained, and 170% more combined diferulate isomers conjugated to two arabinosyl units. Conclusions: Overall, the new protocol for mild acidolysis of grass cell walls is both recovering more ferulate- and p-coumarate-arabinose conjugates from the arabinoxylan and cleaving less of them down to free ferulic acid, p-coumaric acid, and dehydrodiferulates with just one arabinosyl ester. This cleaner method, especially when coupled with the orthogonal method for measuring monolignol hydroxycinnamate conjugates that have been incorporated into lignin, provides an enhanced tool to measure the extent of crosslinking in grass arabinoxylan chains, assisting in identification of useful grasses for biomass applications.

09 BIOMASS FUELS↗

DOE OSTI2016

Impaired Chloroplast Biogenesis in Immutans, an Arabidopsis Variegation Mutant, Modifies Developmental Programming, Cell Wall Composition and Resistance to Pseudomonas syringae

The immutans (im) variegation mutation of Arabidopsis has green- and white- sectored leaves due to action of a nuclear recessive gene. IM codes for PTOX, a plastoquinol oxidase in plastid membranes. Previous studies have revealed that the green and white sectors develop into sources (green tissues) and sinks (white tissues) early in leaf development. In this report we focus on white sectors, and show that their transformation into effective sinks involves a sharp reduction in plastid number and size. Despite these reductions, cells in the white sectors have near-normal amounts of plastid RNA and protein, and surprisingly, a marked amplification of chloroplast DNA. The maintenance of protein synthesis capacity in the white sectors might poise plastids for their development into other plastid types. The green and white im sectors have different cell wall compositions: whereas cell walls in the green sectors resemble those in wild type, cell walls in the white sectors have reduced lignin and cellulose microfibrils, as well as alterations in galactomannans and the decoration of xyloglucan. These changes promote susceptibility to the pathogen Pseudomonas syringae. Enhanced susceptibility can also be explained by repressed expression of some, but not all, defense genes. We suggest that differences in morphology, physiology and biochemistry between the green and white sectors is caused by a reprogramming of leaf development that is coordinated, in part, by mechanisms of retrograde (plastid-tonucleus) signaling, perhaps mediated by ROS. Lastly, we conclude that variegation mutants offer a novel system to study leaf developmental programming, cell wall metabolism and hostpathogen interactions.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2015

Moisture Durability Assessment of Selected Well-insulated Wall Assemblies

This report presents the results from studying the hygrothermal performance of two well-insulated wall assemblies, both complying with and exceeding international building codes (IECC 2015 2014, IRC 2015). The hygrothermal performance of walls is affected by a large number of influential parameters (e.g., outdoor and indoor climates, workmanship, material properties). This study was based on a probabilistic risk assessment in which a number of these influential parameters were simulated with their natural variability. The purpose of this approach was to generate simulation results based on laboratory chamber measurements that represent a variety of performances and thus better mimic realistic conditions. In total, laboratory measurements and 6,000 simulations were completed for five different US climate zones. A mold growth indicator (MGI) was used to estimate the risk of mold which potentially can cause moisture durability problems in the selected wall assemblies. Analyzing the possible impact on the indoor climate due to mold was not part of this study. The following conclusions can be reached from analyzing the simulation results. In a hot-humid climate, a higher R-value increases the importance of the airtightness because interior wall materials are at lower temperatures. In a cold climate, indoor humidity levels increase with increased airtightness. Air leakage must be considered in a hygrothermal risk assessment, since air efficiently brings moisture into buildings from either the interior or exterior environment. The sensitivity analysis of this study identifies mitigation strategies. Again, it is important to remark that MGI is an indicator of mold, not an indicator of indoor air quality and that mold is the most conservative indicator for moisture durability issues.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2015

Approximate Augmentation of Turbulent Law-of-the-Wall by Periodic Free-Stream Disturbances

We examine the role of periodic sinusoidal free-stream disturbances on the inner law law-of-the-wall (log-law) for turbulent boundary layers. This model serves a surrogate for the interaction of flight vehicles with atmospheric disturbances. The approximate skin friction expression that is derived suggests that free-stream disturbances can cause enhancement of the mean skin friction. Considering the influence of grid generated free stream turbulence in the laminar sublayer/log law region (small scale/high frequency) the model recovers the well-known shear layer enhancement suggesting an overall validity for the approach. The effect on the wall shear associated with the lower frequency due to the passage of the vehicle through large (vehicle scale) atmospheric disturbances is likely small i.e. on the order 1% increase for turbulence intensities on the order of 2%. The increase in wall pressure fluctuation which is directly proportional to the wall shear stress is correspondingly small.

42 ENGINEERING↗

DOE OSTI2017

Dissecting the functional significance of non-catalytic carbohydrate binding modules in the deconstruction of plant cell walls

The project seeks to investigate the mechanism by which CBMs potentiate the activity of glycoside hydrolases against complete plant cell walls. The project is based on the hypothesis that the wide range of CBMs present in bacterial enzymes maximize the potential target substrates by directing the cognate enzymes not only to different regions of a specific plant cell wall, but also increases the range of plant cell walls that can be degraded. In addition to maximizing substrate access, it was also proposed that CBMs can target specific subsets of hydrolases with complementary activities to the same region of the plant cell wall, thereby maximizing the synergistic interactions between these enzymes. This synergy is based on the premise that the hydrolysis of a specific polysaccharide will increase the access of closely associated polymers to enzyme attack. In addition, it is unclear whether the catalytic module and appended CBM of modular enzymes have evolved unique complementary activities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2018

A status review on DNB prediction using CASL baseline boiling model and possible suggestions regarding wall boiling closures

The main goal of FY18 THM’s focus task is to evaluate where the current CASL boiling model stands for DNB predictive performance, to identify which components should be improved or calibrated to enhance DNB performance. Over the past three year’s validation tests, Gen1A boiling model has presented an under-predictive behavior for DNB at the high pressure of interest for PWR application. With this in mind, this year’s task is to focus on 1) best practice guidelines on DNB detection criteria, 2) interfacial momentum transfer closure tests, and 3) wall boiling closure sensitivity on DNB. Best practice guidelines on DNB detection criteria are demonstrated by the following three monitoring variables: 1) max wall temperature, 2) K-value and 3) energy balance. Interfacial momentum transfer closure govern the bubble distribution, especially in lateral direction, as well as bubble mean diameter. A clear correlation between interfacial momentum closure and DNB prediction is not observed in the current tests. However, void distributions are changed with different interfacial momentum closure tests which requires further validation with corresponding experimental measurement. From a variety of wall boiling closure tests, bubble departure diameter seems the most sensitive for DNB performance while fulfilling numerical robustness in DNB simulation. Tolubinski’s bubble departure diameter model was calibrated to see if any improvement is observed in DNB performance. Notable DNB improvement was observed as the bubble departure diameter is reduced. However, reduced bubble departure diameter by calibrated Tolubinski’s model seemed to lead to relatively high wall superheat temperature prediction which requires further validation with associated experimental measurement It should be noted that lack of experimental measurement close to DNB condition hampers this boiling closure sensitivity study significantly. This situation directly reflects some of limitations of the CASL boiling model development. With this in mind, the implementation of improved boiling closure on 5x5 NMVG and MVG tests will be pursued in FY19, the associated DNB best practice guidelines and possible limitations will be addressed for industry DNB application.

42 ENGINEERING↗

DOE OSTI2019

In situ scanning probe microscopy studies of cross-coupled domains and domain walls. Final technical report

The objective of this project is to explore the nanoscale emergent phenomena and to understand the unconventional properties of cross-coupled domains and domain walls in multiferroics, where both ferroelectricity and magnetism coexist. The giant magnetoelectric effect due to coupled ferroic orders in multiferroics is of both fundamental and technological interest and is promising for energy-efficient multifunctional applications. The presence of domains and domain walls is a distinguishing feature of any ferroic order; their responses to external stimuli determine the macroscopic properties and the functionalities of ferroic materials. To address the challenges and to directly visualize the cross-coupled domains and domain walls and their responses to the applied electric and magnetic fields, this project will develop a unique, high-resolution and high-sensitivity in situ scanning force microscopy (SFM). The real space imaging of domains and domain walls by SFM aims to fundamentally understand the nature of magnetoelectric cross-coupling in representative multiferroic and magnetoelectric materials.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2020

3D CFD Model Validation Using Benchmark Data of 1/16th Scaled VHTR Upper Plenum and Development of Wall Heat-Transfer Correlation For Laminar Flow

With support from the U.S. Department of Energy-Office of Nuclear Energy’s (DOE-NE’s) Nuclear Energy Advanced Modeling and Simulation (NEAMS) program, an effort has been pursued to support high-temperature gas-cooled reactor (HTGR) technology development and its modeling and simulation needs. There is a particular need for advanced modeling and simulation tools to predict thermal-fluid behavior in the nuclear reactor primary system, especially in the core and the lower and upper plena, during safety-related transients. In this report, two main such activities are presented relevant to the HTGRs: (1) three-dimensional (3D) computational fluid dynamics (CFD) validation using benchmark data from the upper plenum of Texas A&M University’s 1/16th scaled very-high-temperature gas-cooled reactor (VHTR), and (2) development of wall heat-transfer correlation for laminar flow in a wall-heated pipe. The CFD tool validation exercises can be helpful to choose the models and CFD tools to simulate and design specific components of the HTRGs such as upper plenum where jet mixing is a complex phenomenon. In a loss of forced circulation event, the laminar flow can be observed during the development of natural circulation flow. This work includes the development and validation of heat transfer correlations for laminar flow using the Nek5000 CFD code due to limited available experimental data for laminar flow conditions to guide low-order models (1D). In this report, the flow characteristics of a single isothermal jet discharging into the upper plenum was investigated using the Nek5000 Large-Eddy Simulation (LES) CFD tool. Several numerical simulations were performed for various jet-discharged Reynolds numbers ranging from 3,413 to 12,819. A grid-independent study was performed. The numerical results of mean velocity, root-mean-square fluctuating velocity, and Reynolds stress were compared against the benchmark data. Good agreement was obtained between simulated and measured data for axial mean velocities, except near the upper plenum hemisphere. The maximum predicted errors for axial mean velocities at various normalized coolant channel diameter heights of 1, 5, and 10 are 1.56%, 1.88%, and 3.82%, respectively. In addition, the predicted root-mean-square fluctuating velocity and Reynolds stress are qualitatively in agreement with the experimental data. The Nek5000 code was used to develop wall-heat transfer correlation for laminar flow in a cylindrical tube. Several simulations were performed for various Reynolds flow and wall-heat fluxes. A new heat transfer correlation was developed using data from Nek5000 simulation results and regression functions in Matlab. The developed heat transfer correlation is valid for various Reynolds flows from 200 to 2000. The predicted R² value for model fit was 0.875, which ensures that 87.5% of the model data lies on the Nek5000 data. Moreover, a machine learning (ML) tool was used to train and test the Nek5000 data. A good fit of the ML-based model was observed with the test data.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

DOE OSTI2022

Wall plug efficiency analysis of a compact SRF industrial accelerator [Poster]

Superconducting radiofrequency cavities offer extremely high (>90%) RF-to-beam energy conversion efficiency. Recent breakthroughs in the Nb 3 Sn SRF cavity technology, successful demonstration of the conduction cooling technique, and the availability of high cooling capacity cryocoolers has made possible the use of SRF for industrial particle accelerators. However, the overall wall plug-to-beam efficiency of such an SRF accelerator can be limited by the wall plug-to-RF power efficiency of the RF source powering this accelerator. The present study quantifies the wall plug-to-beam efficiency of a conduction-cooled SRF accelerator considering several different choices of the RF power source. The study concludes that the wall plug efficiency of the accelerator is indeed limited by that of the power source.

43 PARTICLE ACCELERATORS↗

DOE OSTI2022

Wall plug efficiency analysis of a compact SRF industrial accelerator [Poster]

43 PARTICLE ACCELERATORS↗

DOE OSTI2022

High-Temperature Tensile and Creep Test Results on Thin Wall Tube Specimens of ODS Alloys 14YWT and OFRAC

High-temperature tensile and strain rate jump (SRJ) creep tests were conducted on axial specimens fabricated from thin wall tubes of the oxide dispersion strengthened (ODS) alloys 14YWT and OFRAC. The dimensions of the 14YWT thin wall tube was 10.7 mm OD, 0.5 mm WT and 0.92 m and of the OFRAC thin wall tube was 8.5 mm OD + 0.5 mm WT and 1.78 m in length. The axial specimens fabricated from the thin wall tubes were based on a dual-gauge design with gauge dimensions of 4 mm long and 2 mm wide. The tensile tests were conducted in air at 800ºC, 900ºC and 1,000ºC and the SRJ creep tests were conducted in air at 800ºC. Two axial specimens were used in each tensile and SRJ creep tests. The results of the tensile tests showed much lower yield stress (YS) compared to ultimate tensile strength (UTS) indicative of large work hardening properties. The results showed the UTS of OFRAC was higher than that of 14YWT by ~35 MPa at 800ºC. At 900ºC, the UTS of OFRAC and 14YWT was similar at 900ºC and at 1000ºC, the UTS of 14YWT was higher than that of OFRAC by ~10 MPa. The ductility properties of OFRAC were greater than that of 14YWT with higher values of uniform elongation (UE) and total elongation (TE) at all tensile test temperatures. The creep properties of 14YWT and OFRAC were evaluated by the strain rate jump test method at 800ºC. The stress exponent (n) for creep was obtained from the SRJ test data by plotting the values of the log strain rate against the log stress, which is measured from the stress-strain curve generated during the SRJ test. The results showed the highest stress exponents of n = 19.8 and n = 35.0 were measured from the two SRJ tests on 14YWT. The stress exponent measured from one successful SRJ test on OFRAC was n = 13.3, which was lower than that of 14YWT. Nevertheless, these high values of stress exponent are consistent with ODS ferritic alloys such as 14YWT and OFRAC since they indicate dislocation-particle interactions are the dominant creep mechanism for specific ranges of temperature and stress. The results obtained from the tensile and SRJ creep tests conducted on axial specimens in this study indicate that 14YWT and OFRAC retain high strengths at temperatures up to 1,000ºC and good creep performance at 800ºC.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Wall Upgrades for Energy Retrofits: A Techno-Economic Study

Homes built before 1992, when the U.S. Department of Energy’s (DOE) Building Energy Codes Program was established, represent approximately 68% of the residential building stock in the country. Up to 43% of these homes have little to no insulation in the walls and have very high air leakage rates of 10 or more air changes per hour at 50 pascals of pressure (ACH50). These issues can represent a substantial portion of unnecessary money spent on utility bills for homeowners, especially in the colder climates. There is a significant need for cost-effective, reliable retrofit methods for these homes that include air, moisture, and vapor controls which are considered best practices for high-performance new home construction. Well-tested and documented wall retrofit systems can help to achieve substantial energy savings and also improve durability, comfort, health, and resilience. In 2018, DOE’s Building Technologies Office awarded Pacific Northwest National Laboratory, Oak Ridge National Laboratory, and the University of Minnesota funding to complete a 3-year project to compare a range of residential wall retrofit systems that prioritized affordability, durability and energy savings potential. In addition to these core criteria, the ease-of-construction and the wide-scale applicability of the solutions also were considered. In this project, the research team identified, constructed, tested, simulated, and analyzed the feasibility and economics of 16 wall retrofit assemblies (14 test configurations and two baseline configurations).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2022

Updates to Nek5000: RANS wall functions, NRC support, and documentation

As a key part of the U.S. Department of Energy’s Nuclear Energy Advanced Modeling and Simulation program (NEAMS), the next generation of tools for nuclear reactor design are being developed. A primary metric for success of this program is the adoption of those tools by industry stakeholders. To help meet this metric for Nek5000, development efforts this year have focused on the expansion of the available Reynolds-averaged Navier-Stokes (RANS) turbulence models to include wall function models, continued support of the U.S. Nuclear Regulatory Commission in simulating a hydrogen mitigation benchmark experiment, and expansion of the Nek5000 documentation to enhance the code’s usability. The implementation of wall functions is intended to significantly decrease time to-solution for a wide range of problems and it has been identified as an important feature by stakeholders across the nuclear community. The initial implementation of standard and pressure corrected wall functions has been tested in Nek5000 on the classical problems of channel flow and a backward facing step. It has also been tested on a 2D molten salt fast reactor core and a T-junction. The recommended formulation of choosing y + = 30 as a boundary value combined with a Neumann-Neumann formulation of the boundary condition for k and τ produces the most consistent results compared to a wall resolved approach. The collaboration with the NRC is a continuing exercise that has been ongoing for multiple years. This year we have concluded investigations into appropriate inlet conditions, showing that fully developed turbulent conditions are adequate for the full PANDA domain. We have also concluded simulations for an unobstructed jet and are now refocusing to the original obstructed jet case. The expansion of the code documentation has also been an ongoing effort over the past few years to address feedback from the various stakeholders. The documentation now more fully covers many of the available features and closes identified SQA gaps. Finally we report on three training sessions that were offered over the past year in an effort to expand the Nek5000 user base.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

DOE OSTI2023

Performance of Windows in Walls With Continuous Insulation

Window openings in walls are a significant contributor to poor thermal performance because of thermal bridging through the framing members (e.g., studs, joists, plates, bracing) and because windows lack the thermal properties of insulation. This report, Performance of Windows in Walls with Continuous Insulation , explores the common method for installing windows in walls with continuous insulation and presents acceptance criteria for evaluating the performance of windows installed in walls with and without continuous insulation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2023

Assessing Methodologies for Detecting Water Intrusion in Wall Systems: Phase 2

Studies by the University of Florida, the Environmental Protection Agency (EPA) and the U.S. Department of Housing (HUD) have revealed that there is a substantial fraction of commercial and residential buildings that have been exposed to moisture resulting in damage or durability problems. Water intrusion into building envelope components leads to a variety of undesirable conditions such as mold, wood rot, corrosion, and aesthetic damage. Tests methods that are presently used to evaluate the amount of water intrusion into a building envelope component are usually qualitative in nature. For example, ASTM E 331, Standard Test Method for Water Penetration of Exterior Windows, Curtain Walls, and Doors by Uniform Static Air Pressure Difference requires that you “observe and record points of water leakage, if any.” This test was originally developed to assess the performance of fenestration products but is commonly adapted to evaluate other enclosure assemblies. However, when it is typically used for walls, this procedure is limited to recognizing if the moisture is visually observable from the backside side of the sheathing. It does not address moisture that is absorbed in the layers of the building envelope component, which could impact the durability of the assembly. Clearly a quantitative means of determining water penetration would improve the quality of this type of test and assist with better understanding the resultant impact on enclosure assemblies. In 2018-20, Oak Ridge National Laboratory, in conjunction with the Air Barrier Association of America, initiated a research project to address this issue. The purpose of that study was to evaluate nine different methods of detecting moisture intrusion through a wall assembly. air and water barrier. The wall assemblies included metal frame construction faced with gypsum sheathing and both self-adhered and fluid applied air and water barriers (AWB) were evaluated for this exercise. This project did not test the efficacy of the different AWBs, rather, fasteners were purposely installed in various ways to foster water penetration and activate the different methods of detection. Each detection method was evaluated for five features that included simplicity of use, cost of implementation, whether the method was quantitative or subjective, accuracy, and applicability. A scale of green/yellow/red was used to assess each feature where green was acceptable, yellow was borderline, and red was not to be pursued at this time. This report covers additional research that has been undertaken to extend the activities initiated in this earlier project with refinements for specific detection methods and considerations for expansion related to field versus laboratory testing standards.

42 ENGINEERING↗

DOE OSTI2024

Evaluation of flame propagation of retrofit energy efficient wall assemblies

Leveraging safety science experience and industry relationships, UL Solutions and the International Association of Fire Fighters (IAFF) initiated a joint project in 2022 under an agreement with the US Department of Energy to evaluate the flame propagation of retrofit energy efficient wall assemblies. A draft of the protocol from the ASTM work was used to test and comparatively study various retrofit energy efficient designs to gain a better understanding of their fire behavior. The goals of this study were as follows: Develop an understanding of fire propagation across new, cost effective, and energy efficient exterior retrofit wall assemblies. Refine the flame propagation draft test method for exterior wall assemblies based on ASTM E2707. Identify conditions that create fire propagation hazards in exterior wall assemblies and educate the fire service on the findings.

42 ENGINEERING↗