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At least 829 records · Page 46

Statistical equilibrium in cometary C2. III - Triplet-singlet, Phillips, Ballik-Ramsay, and Mulliken bands

A new series of vibrational bands is predicted which arises from transitions between the lowest electron states of the triplet and singlet states of homonuclear C2. The predictions are useful for C2 identifications and for disentangling congested low resolution spectra that characterize new observations. Predictions are also made for Mulliken, Phillips, and Ballik-Ramsay band sequences, and all calculations are made with the assumed molecular constants and computational methods of KSO-II.

Swamy, K. S. K.↗

Optical studies of shock generated transient supersonic base flows

A shock tube employing interferometric and schlieren techniques is used to study transient base flow phenomena following shock wave passage over two plane bluff bodies: a hemicircular cylinder and a cylinder with the Galileo Jovian probe profile. An attempt is made to understand the physics of transition from transient to steady state flow, and to provide code verification for a study employing the Illiac IV computer. Transient base flow interactions include a series of shock diffraction, regular, and Mach reflections, coupled with boundary layer development, separation, and recompression. Vorticity generation and transport underlie these features. The quantitative verification of the computer code includes comparisons of transient pressure and density fields, near wake geometries, and bow shock standoff distances.

Liang, P.-Y.↗

Propeller slipstream/wing boundary layer effects at low Reynolds numbers

The effects of propeller slipstream on the wing laminar boundary are being investigated. Hot-wire velocity sensor measurements have been performed in flight and in a wind tunnel. It is shown that the boundary layer cycles between a laminar state and a turbulent state at the propeller blade passage rate. The cyclic length of the turbulent state increases with decreasing laminar stability. Analyses of the time varying velocity profiles show the turbulent state to lie in a transition region between fully laminar and fully turbulent. The observed cyclic boundary layer has characteristics similar to relaminarizing flow and laminar flow with external turbulence.

Miley, S. J.↗

Wing laminar boundary layer in the presence of a propeller slipstream

The effects of a propeller slipstream on the wing laminar boundary layer are being investigated. Hot-wire velocity sensor measurements have been performed in flight and in a wind tunnel. It is shown that the boundary layer cycles between a laminar state and a turbulent state at the propeller blade passage rate. The cyclic length of the turbulent state increases with decreasing laminar stability. Analyses of the time varying velocity profiles show the turbulent state to lie in a transition region between fully laminar and fully turbulent. The observed cyclic boundary layer has characteristics similar to relaminarizing flow and laminar flow with external turbulence.

Miley, S. J.↗

Resonant enhanced multiphoton ionization studies of atomic oxygen

In resonant enhanced multiphoton ionization (REMPI), an atom absorbs several photons making a transition to a resonant intermediate state and subsequently ionizing out of it. With currently available tunable narrow-band lasers, the extreme sensitivity of REMPI to the specific arrangement of levels can be used to selectively probe minute amounts of a single species (atom) in a host of background material. Determination of the number density of atoms from the observed REMPI signal requires a knowledge of the multiphoton ionization cross sections. The REMPI of atomic oxygen was investigated through various excitation schemes that are feasible with available light sources. Using quantum defect theory (QDT) to estimate the various atomic parameters, the REMPI dynamics in atomic oxygen were studied incorporating the effects of saturation and a.c. Stark shifts. Results are presented for REMPI probabilities for excitation through various 2p(3) (4S sup o) np(3)P and 2p(3) (4S sup o) nf(3)F levels.

Dixit, S. N.↗

Flow energizers. Task A

The effects of a propeller slipstream on the wing laminar boundary are being investigated. Hot-wire velocity sensor measurements have been performed in flight and in a wind tunnel. It is shown that the boundary layer cycles between a laminar state and a turbulent state at the propeller blade passage rate. The cyclic length of the turbulent state increases with decreasing laminar stability. Analyses of the time-varying velocity profiles show the turbulent state to lie in a transition region between fully laminar and fully turbulent. The observed cyclic boundary layer has characteristics similar to relaminarizing flow and laminar flow with external turbulence.

Ward, D.↗

A model for the spectral dependence of optically induced absorption in amorphous silicon

A model based on transitions from localized band tail states to states above the mobility edge is used to explain the broad band induced absorptions observed in recent pump-probe experiments. The model gives the observed decrease of absorption with frequency at subband gap photo energies and high carrier densities (of about 10 to the 20th/cu cm). At lower carrier densities, the absorption has a maximun which is sensitive to the spatial extent of the band tail states.

Lawandy, N. M.↗

Comparison of two transition models

Two transition functions, one given by Arnal, Coustols and Juillen and the other by Narasimha, are incorporated into a boundary layer program along with an otherwise conventional Baldwin-Lomax turbulence model. Calculations are performed for incompressible flow past a flat plate and compressible flow past a sharp cone at Mach 6 from the leading edge through transition to the fully turbulent state. Results from these calculations are compared with the available experimental data.

Dinavahi, Surya P. G.↗

A determination of Mg(+)-ligand binding energies

Theoretical calculations employing large basis sets and including correlation are carried out for Mg(+) with methanol, water, and formaldehyde. For Mg(+) with ethanol and acetaldehyde, the trends in the binding energies are studied at the self-consistent-field level. The predictions for the binding energy of Mg(+) to methanol and water of 41 + or - 5 and 36 + or - 5 kcal/mol, respectively, are much less than the experimental upper bounds, of 61 + or - 5 and 60 + or - 5 kcal mol, determined by using photodissociation techniques. The theoretical results are inconsistent with the onset of Mg(+) production observed in the photodissociation experiments, as the smallest absorptions are calculated at about 80 kcal/mol for both Mg(+)-CH3OH and Mg(+)-H2O, and these transitions are to bound excited states. The binding energy for Mg(+) with formaldehyde is predicted to be similar to Mg(+)-H2O. The relative binding energies are in reasonable agreement with experiment. The binding energy of a second water molecule to Mg(+) is predicted to be similar to the first. This suggests that the reduced reaction rate observed for the second ligand is not a consequence of a significantly smaller binding energy, at least for the smaller ligards such as those considered in this work.

Bauschlicher, Charles W., Jr.↗

Feasibility study of a low-energy gamma ray system for measuring quantity and flow rate of slush hydrogen

As part of a study to demonstrate the suitability of an X-ray or gamma ray probe for monitoring the quality and flow rate of slush hydrogen, mass attenuation coefficients for Cd-109 X- and gamma radiation in five chemical compounds were measured. The Ag-109 K rays were used for water and acetic acid, whereas E3 transition from the first excited state at 87.7 keV in Ag-109 provided the probe radiation for bromobenzene, alpha (exp 2) chloroisodurene, and cetyl bromide. Measurements were made for a single phase (gas, liquid, solid) as well as mixed phases (liquid plus solid) in all cases. It was shown that the mass attenuation coefficient for the selected radiations is independent of the phase of the test fluids or phase ratios in the case of mixed phase fluids. Described here are the procedure and the results for the five fluid systems investigated.

Singh, Jag J.↗

Calculation of two-dimensional shear-driven cavity flows at high Reynolds numbers

The time-dependent Navier-Stokes equations are numerically integrated for two-dimensional incompressible viscous flow in a shear-driven square cavity. Using a time-splitting method and finite differences on a staggered mesh, the momentum and pressure equations are directly solved by a tensor product method where one finite difference direction is diagonalized by eigenvalue decomposition. The effects of increasing Reynolds number are studied and the developing boundary layer is captured by using a finely clustered mesh. At Re = 30,000 the flow is in a continuously developing unsteady regime. Power spectrum plots indicate that the unsteady flow oscillates with one fundamental frequency and exhibits some characteristics of transition between laminar and turbulent states.

Huser, A.↗

Measurements of KrF laser-induced O2 fluorescence in high-temperature atmospheric air

Conditions for obtaining laser-induced O2 fluorescence using a tunable KrF laser has been determined theoretically and experimentally. With this laser source, O2 rotational temperature measurement is possible even in the absence of vibrational equilibrium. Temperature measurement using a two-line excitation scheme has been demonstrated in a high-temperature atmospheric-air furnace. A measurement uncertainty of 10.7 percent for the temperature range 1325-1725 K was realized. At atmospheric pressure, O2 LIF measurements are possible for air temperatures above 1250 K. Interference from OH fluorescence in reacting flows can be avoided by the proper selection of O2 transitions. Depletion of the ground state population by the incident laser is negligible for intensities below 7.5 x 10 to the 6th W/sq cm/per cm.

Grinstead, Jay H.↗

Variable temperature pressure broadening of the 4(1,4)-3(2,1) transition of H2O by O2 and N2

The O2 and N2 pressure-broadening parameters of the 4(1,4)-3(2,1) rotational transition in the ground vibrational state of H2O have been measured in the temperature range between 100 and 520 K. Above 250 K the measurements were made in an equilibrium cell. Below 250 K a cell, which uses collisional cooling to circumvent the temperature limits imposed by the vapor pressure of the sample gas, was used. The data were fitted to an exponential temperature-dependence for data above 150 K with resultant n values of 0.81(3) for O2 and 0.70(3) for N2, where the entries in parentheses represent the error in the last significant figure of the parameter. Below 150 K the measured pressure-broadening parameters are smaller than those calculated using these values of n.

Goyette, Thomas M.↗

Aromatic Polyimides Containing Meta-Biphenoxy Moieties

Synthesis of two novel monomers and subsequent incorporation into aromatic polyimides yields polyimides containing meta-biphenoxy moieties exhibiting stability at high temperatures and having glass-transition temperatures lower than state-of-the-art polyimides containing para-biphenoxy moieties. Because of outstanding thermal stability, low density, resistance to radiation, electrical-insulating capability, toughness, and flexibility, linear aromatic polyimides used increasingly for applications in aerospace and electronics industries and possibly in others.

St. Clair, Terry L.↗

A new method for determining the CO to H2 conversion factor for translucent clouds

In this paper we describe a new technique for obtaining the conversion factor between the molecular hydrogen column density and the CO(J = 1-0) integrated antenna temperature. This factor, typically known as X(sub CO) is often to be of order a few times 10(exp 20)/sq cm/K km/s) for the molecular clouds in the Galaxy and is one of the primary means of determining the molecular cloud mass from CO observations. However, for the low-extinction interstellar clouds known as the translucent molecular clouds, estimates of X(sub CO) vary by up to a factor of 60 depending on the object and techniques employed to calibrate X(sub CO). Since the cloud mass is directly proportional to X(sub CO) uncertainties in mass estimates of translucent clouds can be more than an order of magnitude. We calibrate the H2 content in translucent clouds by using the linear relationship between the CH and H2 column densities. The CH column density is readily determined from observations of the CH ground-state hyperfine main-line transition at 3335 MHz. Using CH as a surrogate tracer for H2 and CO(J = 1-0) observations of a sample of translucent and dark molecular clouds, we find a wide variation in values for X(sub CO). For translucent clouds, X(sub CO) ranges from 0.3 to 6.8 x 10(exp 20) and for dark clouds the values range from 0.8 to 8.6. Although the average values for both types of cloud are similar to the canonical value determined for the Galactic molecular cloud ensemble (2-4 x 10(exp 20)), the scatter in individual X(sub CO) values may indicate that X(sub CO) for a given translucent cloud cannot be determined a priori and must be obtained for each cloud so that a reliable mass determination may be made.

Magnani, L.↗

X-Ray Spectral Behavior of the Relativistic Jet Source Cygnus X-3

Cyg X-3 is an unusual X-ray binary which shows remarkable correlative behavior between the hard X-ray, soft X-ray, and the radio. We present an analysis of these long term light curves in the context of spectral changes of the system. This analysis will also incorporate a set of pointed RXTE observations made during a period when Cyg X-3 made a transition from a quiescent radio state to a flaring state (including a major flare) and then returned to a quiescent radio state.

McCollough, M. L.↗

RXTE Observations of Cygnus X-3

In the period between May 1997 and August 1997 a series of pointed RXTE observations were made of Cyg X-3. During this period Cyg X-3 made a transition from a quiescent radio state to a flare state (including a major flare) and then returned to a quiescent radio state. Analyses of the observations are made in the context of concurrent observations in the hard X-ray (CGRO/BATSE), soft X-ray (RXTE/ASM) and the radio (Green Bank Interferometer, Ryle Telescope, and RATAN-600). Preliminary analyses of the observations are presented.

McCollough, M. L.↗

A Wind-Tunnel Investigation of a 4-Foot-Diameter Ducted Fan Mounted on the Tip of a Semispan Wing

Power, wing angle of attack, and the angle of the duct relative to the wing were varied to achieve a specified lift and thrust for a forward velocity range from 0 to 140 knots. In this manner a so-called transition program of steady-state conditions was defined over the velocity range. It was found-that large pitch-up moments resulted when the ducted fan was operated at an angle of attack to the air stream. A deflected vane installed in the high-energy air at the duct exit was helpful in reducing these pitch-up moments. Large downwash angles were induced by the ducted fan at a selected horizontal-tail location. The possibility of using guide vanes in the duct inlet to vary thrust for the purpose of roll control at low forward speeds was examined.The maximum incremental thrust available at zero forward velocity was found to be 11% of the total thrust required at that speed.

Yaggy, Paul F.↗