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At least 829 records · Page 46

Effects of sea salts on the physical characteristics of reusable surface insulation

Test results show that sea salt contamination and thermal cycles cause significant changes in the morphology of surface insulation coatings with increased melting. Sea salt contamination and thermal cycles do not have a significant effect on emittance of mullite and silica composite coatings at high temperatures (1300 K). At the lower temperatures there is apparently some effect on emittance but the evidence is inconclusive because of the absence of multiple tests.

Ransone, P. O.↗

Planned Environmental Microbiology Aspects of Future Lunar and Mars Missions

With the establishment of the Constellation Program, NASA has initiated efforts designed similar to the Apollo Program to return to the moon and subsequently travel to Mars. Early lunar sorties will take 4 crewmembers to the moon for 4 to 7 days. Later missions will increase in duration up to 6 months as a lunar habitat is constructed. These missions and vehicle designs are the forerunners of further missions destined for human exploration of Mars. Throughout the planning and design process, lessons learned from the International Space Station (ISS) and past programs will be implemented toward future exploration goals. The standards and requirements for these missions will vary depending on life support systems, mission duration, crew activities, and payloads. From a microbiological perspective, preventative measures will remain the primary techniques to mitigate microbial risk. Thus, most of the effort will focus on stringent preflight monitoring requirements and engineering controls designed into the vehicle, such as HEPA air filters. Due to volume constraints in the CEV, in-flight monitoring will be limited for short-duration missions to the measurement of biocide concentration for water potability. Once long-duration habitation begins on the lunar surface, a more extensive environmental monitoring plan will be initiated. However, limited in-flight volume constraints and the inability to return samples to Earth will increase the need for crew capabilities in determining the nature of contamination problems and method of remediation. In addition, limited shelf life of current monitoring hardware consumables and limited capabilities to dispose of biohazardous trash will drive flight hardware toward non-culture based methodologies, such as hardware that rapidly distinguishes biotic versus abiotic surface contamination. As missions progress to Mars, environmental systems will depend heavily on regeneration of air and water and biological waste remediation and regeneration systems, increasing the need for environmental monitoring. Almost complete crew autonomy will be needed for assessment and remediation of contamination problems. Cabin capacity will be limited; thus, current methods of microbial monitoring will be inadequate. Future methodology must limit consumables, and these consumables must have a shelf life of over three years. In summary, missions to the moon and Mars will require a practical design that prudently uses available resources to mitigate microbial risk to the crew.

Ott, C. Mark↗

Atomic Oxygen Interactions With Silicone Contamination on Spacecraft in Low Earth Orbit Studied

Silicones have been widely used on spacecraft as potting compounds, adhesives, seals, gaskets, hydrophobic surfaces, and atomic oxygen protective coatings. Contamination of optical and thermal control surfaces on spacecraft in low Earth orbit (LEO) has been an ever-present problem as a result of the interaction of atomic oxygen with volatile species from silicones and hydrocarbons onboard spacecraft. These interactions can deposit a contaminant that is a risk to spacecraft performance because it can form an optically absorbing film on the surfaces of Sun sensors, star trackers, or optical components or can increase the solar absorptance of thermal control surfaces. The transmittance, absorptance, and reflectance of such contaminant films seem to vary widely from very transparent SiOx films to much more absorbing SiOx-based films that contain hydrocarbons. At the NASA Glenn Research Center, silicone contamination that was oxidized by atomic oxygen has been examined from LEO spacecraft (including the Long Duration Exposure Facility and the Mir space station solar arrays) and from ground laboratory LEO simulations. The findings resulted in the development of predictive models that may help explain the underlying issues and effects. Atomic oxygen interactions with silicone volatiles and mixtures of silicone and hydrocarbon volatiles produce glassy SiOx-based contaminant coatings. The addition of hydrocarbon volatiles in the presence of silicone volatiles appears to cause much more absorbing (and consequently less transmitting) contaminant films than when no hydrocarbon volatiles are present. On the basis of the LDEF and Mir results, conditions of high atomic oxygen flux relative to low contaminant flux appear to result in more transparent contaminant films than do conditions of low atomic oxygen flux with high contaminant flux. Modeling predictions indicate that the deposition of contaminant films early in a LEO flight should depend much more on atomic oxygen flux than it does later in a mission.

Banks, Bruce A.↗

Surface tension propellant control for Viking 75 Orbiter

The paper describes the selection, development and qualification of the surface tension system and includes results of low-g drop tower tests of scale models, 1-g simulation tests of low-g large ullage settling and liquid withdrawal, structural qualification tests, and propellant surface tension/contact angle studies. Subscale testing and analyses were used to evaluate the ability of the system to maintain or recover the desired propellant orientation following possible disturbances during the Viking mission. This effort included drop tower tests to demonstrate that valid wick paths exist for moving any displaced propellant back over the tank outlet. Variations in surface tension resulting from aging, temperature, and lubricant contamination were studied and the effects of surface finish, referee fluid exposure, aging, and lubricant contamination on contact angle were assessed. Results of movies of typical subscale drop tower tests and full scale slosh tests are discussed.

Dowdy, M. W.↗

Contamination effects study

The in-situ optical surface measurement system is a facility designed to study the deleterious effects of particulate materials on the surface reflectivities of optical materials in the vacuum ultraviolet (VUV). This arrangement is designed to simulate the on-orbit effects of contamination and degradation of optical surfaces. This simulation is accomplished through the use of non-coherent VUV sources illuminating optical surfaces located in a high vacuum chamber. Several sources of contamination are employed. The reflectivity is measured both at the specular reflection as well as at two scattered positions, forward and reverse. The system components are described and an operating procedure is given.

Source record↗

Surface tensions of propellants

An apparatus is described for determining the surface tension of propellants by measuring the maximum bubble pressure using two capillaries of different bores. The innovation is the use of a pressure transducer coupled to a bridge supply and a strip chart recorder for registering the development of the pressure difference as the bubble is formed and released. This enables the measurements to be made under controlled atmospheres and to be remotely operated. Preliminary experiments were done on propellant-grade hydrazine and monomethylhydrazine, and on purified hydrazine, at temperatures between 275.4 and 353.2 K. Straight-line expressions and logarithmic expressions reproduce equally well the variation of surface tension with temperature. Contaminated hydrazine, pre-exposed to coupons of 6Al-4V titanium alloy for long periods, gives slightly higher values of surface tension.

Razouk, R.↗

The right wing of the LEFT airplane

The NASA Leading-Edge Flight Test (LEFT) program addressed the environmental issues which were potential problems in the application of Laminar Flow Control (LFC) to transport aircraft. These included contamination of the LFC surface due to dirt, rain, insect remains, snow, and ice, in the critical leading-edge region. Douglas Aircraft Company designed and built a test article which was mounted on the right wing of the C-140 JetStar aircraft. The test article featured a retractable leading-edge high-lift shield for contamination protection and suction through perforations on the upper surface for LFC. Following a period of developmental flight testing, the aircraft entered simulated airline service, which included exposure to airborne insects, heavy rain, snow, and icing conditions both in the air and on the ground. During the roughly 3 years of flight testing, the test article has consistently demonstrated laminar flow in cruising flight. The experience with the LEFT experiment was summarized with emphasis on significant test findings. The following items were discussed: test article design and features; suction distribution; instrumentation and transition point reckoning; problems and fixes; system performance and maintenance requirements.

Powell, Arthur G.↗

Acquisition of a Gas Chromatograph/Mass Spectrometer System for Laboratory Study of Prebiotic Organic Geochemical Processes on the Early Earth, Mars, and Meteorites

This was a major equipment grant that provided funds ($72K) for purchase of a benchtop gas chromatograph-mass spectrometer (GC-MS) for use in experimental studies of prebiotic organic compounds. An Agilent model 689015973 GC-MS was purchased and installed in the PI's lab in August of 2003. The instrument is now being used for a variety of research projects. The primary use of the instrument is to analyze and quantify organic products of laboratory experiments conducted by the PI. One example is shown, which shows organic products (predominantly n-alkanes) formed during Fischer-Tropsch-type abiotic synthesis under hydrothermal conditions. The analytical capabilities of the GC- MS allowed identification of the numerous organic products of this as well as other laboratory experiments. A key use of the instrument in this research is that the mass spectrometer capabilities allow use of isotopically labeled reactants to trace the progress of reactions and evaluate background contaminants. collaborative projects with other scientists involved in exobiology & astrobiology research (e.g., Mitch Schulte, NASA Ames; Katrina Edwards, Woods Hole Oceanographic Institution). For instance, an analysis of membrane lipids of an lithoautotrophic iron-oxidizing bacteria being grown on basalt as a source of metabolic energy, a project where the instrument is being used to evaluate possible biomarker compounds from these organisms is shown. These iron oxidizers are thought to be similar to those living within the ocean crust, and are being investigated as possible analog organisms to those on the early Earth or crust of Mars. The instrument has also been used by an outside investigator (graduate student Brandon Canfeld, Arizona State University) for identification and isotopic characterization of experimental products of abiotic organic synthesis experiments he is conducting with Dr. John Holloway. analysis of quality control samples for other NASA-funded projects. For instance, an analysis of residual hydrocarbon contaminants on the internal surface of the shell of an atmospheric sounding rocket is shown. This analysis was used to help determine the source of the contaminating compounds. In the future, the instrument will continue to be used for quality control analysis in clean rooms and instrument construction facilities within the Laboratory for Atmospheric and Space Physics, where the GC-MS is housed.

McCollom, Thomas↗

An Assembly Contamination Model

Mathematical model of spacecraft contamination for treating contamination amount and its surface distribution on structures as random variables

SPACECRAFT CONTAMINATION↗

Effects of RAM Exposure on a Low Earth Orbit BroadBand Radiometer (BBR): CERES Experience and Implications for EarthCARE

In order to best detect real changes in the Earth's climate system it is estimated that space based instrumentation measuring the global Earth Radiation Budget (ERB) must remain calibrated with a stability of 0.3% per decade. This level of stability is beyond the specified accuracy of existing ERB programs such as the Clouds and the Earth's Radiant Energy System (CERES, using three broadband radiometric scanning channels: the shortwave (SW 0.3 - 5?m), total (0.3 - >100 micron), and window (8 - 12 micron)). When in low earth orbit, it has been shown that optical response to blue-UV radiance can be reduced significantly (> 3%) due to UV hardened contaminants deposited on the surface of the optics. Evidence suggests that exposure of telescope optics to the forward looking ram direction is the primary cause of this contamination build up. With typical onboard calibration lamps emitting very low energy in the blue-UV region, this darkening is not directly measurable using standard internal calibration techniques. This paper describes a study using a model of ram exposure induced contaminant deposition and darkening, in conjunction standard established in-flight vicarious and internal calibration techniques to derive the spectral shape of the darkening to which a broadband instrument is subjected. The results of the model when applied to the CERES instruments are shown. These findings are of great importance to the EarthCARE project, whose BBR uses one broadband telescope permanently looking forward at 45 degrees, with continual exposure to the ram direction. Specific attention may therefore be needed in the design of BBR optics and on-board calibration in order to prevent or compensate for the spectral darkening seen in the CERES project.

Matthews, Grant↗

Post Viking planetary protection requirements study

Past planetary quarantine requirements were reviewed in the light of present Viking data to determine the steps necessary to prevent contamination of the Martian surface on future missions. The currently used term planetary protection reflects a broader scope of understanding of the problems involved. Various methods of preventing contamination are discussed in relation to proposed projects, specifically the 1984 Rover Mission.

Wolfson, R. P.↗

A spectroscopic survey of B supergiants in the Large Magellanic Cloud

The results of a low-dispersion digital optical spectral survey of about 100 B-type supergiants in the Large Magellanic Cloud are presented. The MK spectral classification framework for B supergiants has been transferred to the metal-weak LMC stars, and recommended classification standards have been designated. Variations among the metal line strengths are examined. The most extreme variations are found for the nitrogen lines, for which a range of a factor of 3 or more may be seen in the equivalent widths within some spectral subclasses. It is suggested that these variations indicate a range of nitrogen surface abundances among the B supergiants, resulting from contamination of some of the stellar surfaces by processed material from the original H-burning core.

Fitzpatrick, Edward L.↗

Computer Simulation of the Forces Acting on a Submerged Polystyrene Probe as it Approaches the Succinonitrile Melt-Solid Interface

A Modeling approach to simulate both mesoscale and microscopic forces acting in a typical AFM experiment is presented. A mesoscale level interaction between the cantilever tip and the sample surface is primarily described by the balance of attractive Van der Waals and repulsive forces. Ultimately, the goal is to measure the forces between a particle and the crystal-melt interface. Two modes of AFM operation are considered in this paper - a stationary and a "tapping" one. The continuous mechanics approach to model tip-surface interaction is presented. At microscopic levels, tip contamination and details of tip-surface interaction are modeled using a molecular dynamics approach for the case of polystyrene - succinonitrile contact. Integration of the mesoscale model with a molecular dynamic model is discussed.

Bune, Andris V.↗

PRP: The Proven Solution for Cleaning Up Oil Spills

The basic technology behind PRP is thousands of microcapsules, tiny balls of beeswax with hollow centers. Water cannot penetrate the microcapsule s cell, but oil is absorbed right into the beeswax spheres as they float on the water s surface. This way, the contaminants, chemical compounds that originally come from crude oil such as fuels, motor oils, or petroleum hydrocarbons, are caught before they settle. PRP works well as a loose powder for cleaning up contaminants in lakes and other ecologically fragile areas. The powder can be spread over a contaminated body of water or soil, and it will absorb contaminants, contain them in isolation, and dispose of them safely. In water, it is important that PRP floats and keeps the oil on the surface, because, even if oil exposure is not immediately lethal, it can cause long-term harm if allowed to settle. Bottom-dwelling fish exposed to compounds released after oil spills may develop liver disease, in addition to reproductive and growth problems. This use of PRP is especially effective for environmental cleanup in sensitive areas like coral reefs and mangroves.

Source record↗

Multimodal Mass Spectrometry Imaging (MSI) of Archean and Jurassic Geologic Samples

Current geochemical analytical techniques such as gas chromatography-mass spectrometry (GC-MS and $G\acute{C}GC-MS$) can effectively determine the composition and structure of the organic biosignatures within a sample but cannot resolve the spatial distribution of organic biosignatures within rocks or sediments. The spatial distribution can be used to determine the character of the organic biosignatures [1], which can be indigenous (deposited with host rocks), non-indigenous (incorporated after deposition via fluid migration), or contaminant. Determining the character of organic biosignatures is critical for ancient samples [2] and will be critical if organics are observed in samples returned from Mars [3].Fs-LDPI-MS has the ability to map organic compounds across the surface of samples at 2 - 10 μm lateral resolution. Furthermore, fs-LDPI-MS can be used to carry out multiple analyses in the same location for micron-scale analysis of previously buried material [4]. We used fs-LDPI-MS to examine a ~164 million year old organic-rich mudstone from SW England (14.2 wt. % total organic carbon) [5] and determined the spatial distribution of likely indigenous components buried below potentially contaminated surface layers.We then used ToF-SIMS to re-analyze the mudstone to directly compare ToF-SIMS to fs-LDPI-MS datasets, and to analyze a series of ~2.7 billion year old geologic samples from Timmins, ON, CA [6]. Ref. [6] previously analyzed the Archean samples and observed a series of archaeal biomarkers, as well as hopanes and steranes. Using ToF-SIMS analysis, we were able to detect hopanes and steranes in the mudstone samples, but not in the Archean samples indicating that the hopanes and steranes are most likely contaminants in the Archean samples. We also did not observe the archaeal biomarkers; however, this may be from the lack of molecular ion preservation during ToF-SIMS.

Pasterski, Michael↗

Inversion layer solar cell fabrication and evaluation

Silicon solar cells with induced junctions were created by forming an inversion layer near the surface of the silicon by supplying a sheet of positive charge above the surface. This charged layer was supplied through three mechanisms: (1) supplying a positive potential to a transparent electrode separated from the silicon surface by a dielectric, (2) contaminating the oxide layer with positive ions, and (3) forming donor surface states that leave a positive charge on the surface. A movable semi-infinite shadow delineated the extent of sensitivity of the cell due to the inversion region. Measurements of the inversion layer cell response to light of different wavelengths indicated it to be more sensitive to the shorter wavelengths of the sun's spectrum than conventional cells. Theory of the conductance of the inversion layer vs. strength of the inversion layer was compared with experiment and found to match. Theoretical determinations of junction depth and inversion layer strength were made as a function of the surface potential for the transparent electrode cell.

Call, R. L.↗

Inversion layer solar cell fabrication and evaluation

Silicon solar cells operating with induced junctions rather than diffused junctions have been fabricated and tested. Induced junctions were created by forming an inversion layer near the surface of the silicon by supplying a sheet of positive charge above the surface. This charged layer was supplied through three mechanisms: (1) applying a positive potential to a transparent electrode separated from the silicon surface by a dielectric, (2) contaminating the oxide layer with positive ions, and (3) forming donor surface states that leave a positive charge on the surface. A movable semi-infinite shadow delineated the extent of sensitivity of the cell due to the inversion region. Measurements of the response of the inversion layer cell to light of different wavelengths indicated it to be more sensitive to the shorter wavelengths of the sun's spectrum than conventional cells. The greater sensitivity occurs because of the shallow junction and the strong electric field at the surface.

Call, R. L.↗