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Data, scripts, and figures associated with a manuscript studying impact of climate and topography on post-fire vegetation recovery.

This data package is associated with the publication “Impact of Topography and Climate on Post-fire Vegetation Recovery Across Different Burn Severity and Land Cover Types through Machine Learning” submitted to Remote Sensing of Environment (Zahura et al. 2023). In this research, a machine learning algorithm, random forest (RF), was utilized to examine the impact of climate and topography on post-fire vegetation recovery. We used enhanced vegetation index (EVI) to examine varying burn severity and land cover types. The data package includes the input files for RF model training, outputs from model predictions and analysis, and python scripts to run the model, analyze the results to understand model performance and interpretability, and plot manuscript figures. This data package contains three folders (Data, Scripts, and Figures), a file-level metadata (FLMD) csv, and a data dictionary (dd) csv. Please see Postfire_recovery_flmd.csv for a list of all files contained in this data package and descriptions for each. The data dictionary (Postfire_recovery_dd.csv) describes the csv column headers. The “Data” folder provides all the inputs and outputs to train the RF model, evaluate performance, and interpret predictions. The “Scripts” folder contains python scripts and jupyter notebooks for model training and result analysis. The “Figures” folder includes the figures used in the manuscript in “.png” and “.jpg” format.

54 ENVIRONMENTAL SCIENCES↗

Beam Line Design and Beam Physics Study of Energy Recovery Linac Free Electron Laser at Peking University

Energy recovering linac (ERL) offers an attractive alternative for generating intense beams of charged particles by approaching the operational efficiency of a storage ring while maintaining the superior beam quality typical of a linear accelerator. In ERLs, the decelerated beam cancels the beam loading effects of the accelerated beam with high repetition rate. Therefore, ERLs can, in principle, accelerate very high average currents with only modest amounts of RF power. So the efficiency of RF power to beam is much higher. Furthermore, the energy of beam to dump is lower, so it will reduce dump radiation. With the successful experiments in large maximum-to-injection energy ratio up to 51:1 and high power FEL up to 14kW, the use of ERL, especially combining with superconducting RF technology, provides a potentially powerful new paradigm for generation of the charged particle beams used in MW FEL, synchrotron radiation sources, high-energy electron cooling devices and so on. The 3+1/2 DC-SC photo injector and two 9cell TESLA superconducting cavity for IR SASE FEL in PKU provides a good platform to achieve high average FEL with Energy Recovery. The work of this thesis is on Beam line design and Beam dynamics study of Energy Recovery Linac Free Electron Laser for Peking University. It is the upgrade of PKU facility, which is under construction. With ERL, this facility can work in CW mode, so it can operate high average beam current without RF power constraint in main linac and generate high average FEL power. Moreover, it provides a test facility to study the key technology in ERL. System parameters are optimized for PKU ERL-FEL. The oscillation FEL output power is studied with different bunch charge, transverse emittance, bunch length and energy spread. The theory of optimal RF power and Q{sub ext} with ERL and without ERL is analyzed and applied to PKU injector and linac including microphonic effect. pace charge effect in the injector and merger is studied for beam energy at ~5MeV. Simulation shows that in the 3+1/2 DC- C injector, there is a region the beam could be over focused by RF electromagnetic field and the transverse emittance in the transport line up to linac will increase instantly due to over focusing. In order to eliminate this effect on beam emittance, several solutions are investigated to avoid over focusing. This result is very important for beam loading experiment for low bunch charge operation. Meanwhile, different merger structures are compared in terms of error sensitivity and emittance increase with space charge effect. In recirculation beam line, a new symmetric 180{degree} arc structure is designed. It fulfills the achromatic condition and adjustable bunch compression. These two parameters are controlled by different Quads knob. With this novel structure, the recirculation lattice can achieve path length adjustment, bunch compression and decompression in a large range. With beamline error, the beam central orbit will deviate from the designed trajectory. An orbit correction system is optimized, which balances between cost and performance of orbit after correction at design level. Different methods are used to estimate its robustness. The BBU instability, especially multi-pass BBU imposed a potentially severe limitation to the average current that can be accelerated in an ERL. Simulation gives the harmful HOMs and predicts that the threshold average current in this machine is much higher than the possible operation current. This work is based on the existing facility in PKU, so it provides guidelines for the facility operation and upgrade in the future. The theoretical analysis of ERL requirement and FEL requirement on beam transport line and beam property paves the way for future ERL research.

43 PARTICLE ACCELERATORS↗

Industrial Waste Heat Recovery - Potential Applications, Available Technologies and Crosscutting R&D Opportunities

The purpose of this report was to explore key areas and characteristics of industrial waste heat and its generation, barriers to waste heat recovery and use, and potential research and development (R&D) opportunities. The report also provides an overview of technologies and systems currently available for waste heat recovery and discusses the issues or barriers for each. Also included is information on emerging technologies under development or at various stages of demonstrations, and R&D opportunities cross-walked by various temperature ranges, technology areas, and energy-intensive process industries.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Designing a Successful Transportation Project: Lessons Learned from the Clean Cities American Recovery and Reinvestment Act Projects

The largest source of funding for alternative fuel vehicle and infrastructure projects in the U.S. Department of Energy's Clean Cities program's history came from the American Recovery and Reinvestment Act (Recovery Act). In 2009, the 25 cost-share projects totaled nearly $300 million in federal government investment. This effort included the involvement of 50 Clean Cities coalitions and their nearly 700 stakeholder partners who provided an additional $500 million in matching funds to support projects in their local communities. In total, those 25 projects established 1,380 alternative fueling stations and put more than 9,000 alternative fuel and advanced technology vehicles on the road. Together, these projects displaced 154 million gasoline gallon equivalents (GGE) of petroleum and averted 254,000 tons of greenhouse gas (GHG) emissions, while supporting U.S. energy independence and contributing to regional economic development. During post-project interviews, project leaders consistently cited a number of key components - ranging from technical and logistical factors, to administrative capabilities - for accomplishing an effective and impactful project. This report summarizes the high-level project design and administrative considerations for conducting a successful transportation project.

30 DIRECT ENERGY CONVERSION↗

Integrated Flue Gas Purification and Latent Heat Recovery for Pressurized Oxy-Combustion (Final Scientific/Technical Report)

Pressurized oxy-combustion has been identified by DOE as a transformational technology for coal power with carbon capture due to the advantages that are realized when the combustion process is pressurized. The staged pressurized oxy-combustion (SPOC) process is particularly attractive as the efficiency of the process is almost 6 percentage points greater than that of first generation oxy-combustion. A critical component of the SPOC process, and potentially other pressurized combustion processes, is the Direct Contact Cooler (DCC) where the latent heat of the flue gas moisture is recovery to improve plant efficiency while simultaneously removing SO x and NO x from the flue gas, so that the FGD and de-NO x processes can be eliminated, and the cost of electricity minimized. The objective of this R&D effort was to advance the TRL of the DCC technology, which included performance testing at a 100 kW scale to validate the process and obtain key engineering data for scale-up. A collateral objective was to study the gas- and liquid-phase kinetics, and the development of a systematic chemical mechanism validated by experimental data. Experiments in a bench-scale stirred reactor provided an updated understanding of the liquid chemistry and the effects of temperature and pH. This information was used to develop a reduced reaction mechanism, which was subsequently incorporated in an ASPENbased process model, to allow for evaluation of the DCC at full scale. A small-pilot DCC column was designed, constructed and tested using simulated flue gas at the pressurized oxy-combustion test facility at Washington University in St. Louis. In the majority of tests, the SO 2 capture approached 100%, making the NO x capture the primary metric of capture efficiency. An NO x capture efficiency of 90% was achieved when the gas residence time was 95 seconds, demonstrating that high capture rates can be attained with reasonable reactor size. At higher temperatures (up to 200°C inlet gas temperature) the total NO x scrubbing efficiency was reduced by approximately 10% (compared to room temp.) and this was attributed to a reduced NO oxidation rate. A significant amount of SO 2 was present in the gas outlet (10%) only when the temperature was high and the N:S ratio was low (N/S < 1), which highlights the necessity of controlling the NOx concentration in the flue gas for complete sulfur scrubbing. After incorporated our optimized chemical mechanism into an ASPEN process model, various full-scale configurations of the DCC were evaluate, and the results indicate that the proposed DCC can accomplish its intended goals at full scale and at a modest size. Thus, the results of this project indicate that the DCC is a promising technology for recovery of the latent heat of the moisture in the flue gas while simultaneously scrubbing the nitrogen and sulfur oxides, thus enabling pressurized oxy-combustion, in general, and the SPOC process, in particular.

01 COAL, LIGNITE, AND PEAT↗

Department of Energy Water Power Technologies Office Cyber Response & Recovery Flipbook [Slides]

Protecting hydroelectric plants from incidents that adversely impact their cyber-physical systems presents unique challenges due to the plants’ widely dispersed geographic locations and varied configurations as well as the relative nascent nature of the cyberattacks targeting these facilities. To help hydroelectric plants better respond to and mitigate cybersecurity incidents, this Department of Energy Water Power Technologies Office Cyber Response & Recovery Flipbook is to be used at a hydroelectric plant to quickly respond to an anomalous event. In addition to this product, there are three other products meant to be distributed to a hydroelectric plant to assist in their cyber incident response and recovery. The first, a report on the processes of building this flip book based on a large set of existing guidance. The second, a handy guide of hydroelectric and cyber guidance in responding to the cyber and physical systems within a hydroelectric plant. And the third is a correlated alignment of the steps an hydroelectric plant operator would take for both a cyber incident as well as an emergency response process if the event rises to a cyber incident affecting the safe and reliable operations of a hydroelectric plant.

13 HYDRO ENERGY↗

Hydroelectric Cybersecurity Response and Recovery Overview

Protecting hydroelectric plants from incidents that adversely impact their cyber-physical systems presents unique challenges due to the plants’ widely dispersed geographic locations and varied configurations as well as the relative nascent nature of the cyberattacks targeting these facilities. To help hydroelectric plants better respond to and mitigate cybersecurity incidents, this Department of Energy Water Power Technologies Office Cyber Response & Recovery Overview document discusses the process of defining how a hydroelectric plant might respond to and recover from an anomalous event. In addition to this product, there are three other products meant to be distributed to a hydroelectric plant to assist in their cyber incident response and recovery. The first, a handy flip book that guides an operator in the midst of a cyber event through the R&R process of the incident and if the event warrants, through an emergency action plan to recover the plant itself. The second, a handy guide of hydroelectric and cyber guidance in responding to the cyber and physical systems within a hydroelectric plant. And the third is a correlated alignment of the steps an hydroelectric plant operator would take for both a cyber incident as well as an emergency response process if the event rises to a cyber incident affecting the safe and reliable operations of a hydroelectric plant.

13 HYDRO ENERGY↗

End-Use Savings Shapes Measure Documentation: Heat Pump Rooftop Units With Exhaust Air Energy Recovery

This technical report documents the Advanced Rooftop Unit Control End Use Savings Shapes (EUSS) measure, including providing a description of the technology, modeling methods, and the energy savings calculated from applying the measure to applicable across the US commercial building stock using ComStock to quantify its potential. This measure replaces gas furnace and electric resistance rooftop units with high-efficiency variable speed heat pump rooftop units (HP-RTU) that include exhaust air heat or energy recovery. The measure uses the same assumptions and technology as the variable speed HP-RTU measure from EUSS 2023 release 1 but adds energy recovery to precondition outdoor ventilation air to reduce HVAC loads. The HP-RTU compressor lockout temperature is modeled as 0 degrees Fahrenheit; below this temperature, the heat pump is set to shut off. The unit is sized based on the design cooling loads, with backup electric resistance heating addressing any remaining loads including heating hours below the compressor lockout temperature when there is no heat pump heating.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Engineered Water for Improved Oil Recovery from Fractured Reservoirs (Final Scientific/Technical Report)

The goal of this proposal is to field test the novel technology of engineered water (modifying ionic composition and/or adding surfactants or nanoparticles) injection to improve oil recovery from the carbonate matrix in fractured reservoirs. Carbonate reservoirs tend to be oil-wet/mixed-wet due to positively charged carbonate mineral surfaces and negatively charged acidic/asphaltic components in the oil. Many carbonate reservoirs are also highly fractured. Water injection does not work efficiently in fractured oil-wet reservoirs because water does not imbibe into the matrix. The water composition can be engineered with ionic modification, surfactants and nanoparticles which can change the wettability of carbonate rocks towards more water-wet conditions which can imbibe water into the matrix and push the oil into the fractures. The engineered water can also lower interfacial tension and minimize capillary forces so that gravity can push the oil up and out of the matrix. Wettability alteration also increases water relative permeability which can also improve oil recovery in non-fractured carbonate reservoirs. This technology, if successful, can be a game changer for West Texas carbonates.

02 PETROLEUM↗

Chemically Enabled CO 2 -Enhanced Oil Recovery in Multi-Porosity, Hydrothermally Altered Carbonates in the Southern Michigan Basin (Final Technical Report)

This is the Final Technical Report for the project "Chemically Enabled CO 2 -Enhanced Oil Recovery in Multi-Porosity, Hydrothermally Altered Carbonates in the Southern Michigan Basin." Over the course of six years of collaboration between Battelle and project partners, all stated objectives of the program have been completed, including full geological characterization of the TBR trend (See companion report for Task2), laboratory and modeling experiments to determine the optimum composition and design of CO 2 -EOR operations in the TBR trend, execution of a field test of chemically-enhanced CO 2 in a TBR well, and integration of the data and learnings gathered during these efforts into a full-trend development plan. Detailed reporting on these activities, their outcomes, and implications for trend-wide development is provided in the report. This report and encompassed data will provide TBR field operators with detailed information on what worked, what did not work, and how to proceed with production optimization of their TBR assets using chemically-enhanced CO 2 -EOR. CO 2 -EOR is a relatively well understood and broadly implemented strategy for increasing incremental production across the oil and gas industry, but its application has been primarily focused on reservoirs with limited heterogeneity. The intention of this project was show first that the same physical mechanisms that improve recovery factors in homogeneous reservoirs (namely wettability alteration, viscosity alteration, oil swelling, and mobility control) are at play in heterogeneous reservoirs. This was proven by the project’s laboratory studies and dynamic simulations, with the potential exception of mobility control, which needs further study. The second intention was to demonstrate via direct field testing that CO 2 -EOR can work in a strongly heterogeneous reservoir. While the field test strategy implemented during this project did not succeed in producing oil, data gathered during the test sheds light on what may work for field operators who try chemically-enhanced CO 2 -EOR within their own reservoirs, significantly reducing the level of uncertainty carried by first-of-a-kind commercial efforts that could (and should) follow this test. Simultaneously, the project has identified several large-volume ethanol plants and other sources of CO 2 emissions in the region and provided a handrail that CO 2 emitters and field operators can leverage to capture, transport, and inject that CO 2 into their fields. This project has also shown that, in many cases, the economics of CO 2 -EOR in the TBR are attractive. And finally, by completing a project of this scope in the southern Michigan Basin, the project has contributed to the knowledge base and operational experience of field operators, state regulatory agencies, local service companies, and state universities, with CO 2 -EOR projects which should allow follow-on projects to proceed safely and efficiently.

02 PETROLEUM↗

Application of Ionic Liquids for the Recycling and Recovery of Technologically Critical and Valuable Metals

Population growth has led to an increased demand for raw minerals and energy resources; however, their supply cannot easily be provided in the same proportions. Modern technologies contain materials that are becoming more finely intermixed because of the broadening palette of elements used, and this outcome creates certain limitations for recycling. The recovery and separation of individual elements, critical materials and valuable metals from complex systems requires complex energy-consuming solutions with many hazardous chemicals used. Significant pressure is brought to bear on the improvement of separation and recycling approaches by the need to balance sustainability, efficiency, and environmental impacts. Due to the increase in environmental consciousness in chemical research and industry, the challenge for a sustainable environment calls for clean procedures that avoid the use of harmful organic solvents. Ionic liquids, also known as molten salts and future solvents, are endowed with unique features that have already had a promising impact on cutting-edge science and technologies. This review aims to address the current challenges associated with the energy-efficient design, recovery, recycling, and separation of valuable metals employing ionic liquids.

36 MATERIALS SCIENCE↗

Recovery and Enhanced Upgrading of Rare Earth Elements from Coal-Based Resources: Bioleaching and Precipitation

Rare earth elements (REEs) are of great importance to modern society and their reliable supply is a major concern of many industries that utilize them in metal alloys, semiconductors, electrical equipment, and defense equipment. REEs in the coal waste have been revealed to be an alternative resource for REEs production. In this study, the extraction, recovery, and upgrading of the REEs from coal waste has been realized with the bioleaching and precipitation processes. Reliable and sustainable acid and oxidant production from the oxidation of the pyrite with Acidithiobacillus ferrooxidans to generate acid for leaching were realized in this research. The acidified bioleaching solution was used to extract REEs from coal waste, with 13–14% yields for most REE elements (~72 h of leaching). However, recovery for longer duration tests was significant higher (varies from 40–60% for individual REEs). After extraction, precipitation and separation processes were designed with the aid of Visual Minteq calculations and modeling to concentrate the REEs. With the procedures designed in this research, a final REEs precipitate product containing 36.7% REEs was produced.

01 COAL, LIGNITE, AND PEAT↗

Coprocessing Corn Germ Meal for Oil Recovery and Ethanol Production: A Process Model for Lipid-Producing Energy Crops

Efforts to engineer high-productivity crops to accumulate oils in their vegetative tissue present the possibility of expanding biodiesel production. However, processing the new crops for lipid recovery and ethanol production from cell wall saccharides is challenging and expensive. In a previous study using corn germ meal as a model substrate, we reported that liquid hot water (LHW) pretreatment enriched the lipid concentration by 2.2 to 4.2 fold. This study investigated combining oil recovery with ethanol production by extracting oil following LHW and simultaneous saccharification and co-fermentation (SSCF) of the biomass. Corn germ meal was again used to model the oil-bearing energy crops. Pretreated germ meal hydrolysate or solids (160 and 180 °C for 10 min) were fermented, and lipids were extracted from both the spent fermentation whole broth and fermentation solids, which were recovered by centrifugation and convective drying. Lipid contents in spent fermentation solids increased 3.7 to 5.7 fold compared to the beginning germ meal. The highest lipid yield achieved after fermentation was 36.0 mg lipid g−1 raw biomass; the maximum relative amount of triacylglycerol (TAG) was 50.9% of extracted oil. Although the fermentation step increased the lipid concentration of the recovered solids, it did not improve the lipid yields of pretreated biomass and detrimentally affected oil compositions by increasing the relative concentrations of free fatty acids.

09 BIOMASS FUELS↗

Safety in recovery operations.

Manned spacecraft recovery safety noting operational testing of postlanding systems, recovery support and retrieval procedures for Apollo

SPACECRAFT RECOVERY↗

Spin-Tunnel Investigation of a 1/40-Scale Model of the F-111A Airplane with Store Loadings and with Supplementary Spin-Recovery Devices

An investigation has been made in the Langley spin tunnel to determine the spin and spin-recovery characteristics of the F-111A airplane in the symmetric and asymmetric stores loading conditions. Tests were also made with the model in the clean condition to determine whether the spin-recovery characteristics could be improved by the use of supplementary devices.

Spin-recovery parachute↗

Flux Recovery of a Forward Osmosis Membrane After a Fouling Process

Wastewater treatment through Forward Osmosis (FO) membranes is a process that has been evaluated in the past years as an innovative technology for the Next Generation Life Support Systems. FO technologies are cost effective, and require very low energy consumption, but are subject to membrane fouling. Membrane fouling occurs when unwanted materials accumulate on the active side of the membrane during the wastewater treatment process, which leads to a decrease in membrane flow rates. Membrane fouling can be reversed with the use of antifoulant solutions. The aim of this study is to identify the materials that cause flow rate reduction due to membrane fouling, as well as to evaluate the flux recovery after membrane treatment using commercially available antifoulants. 3D Laser Scanning Microscope images were taken to observe the surface of the membrane. Fourier Transform Infrared (FTIR) spectrometry results identified possible compounds that cause membrane fouling and FO testing results demonstrated flow rate recovery after membrane treatment using antifoulants.

Forward osmosis↗

Self-Cleaning Boudouard Reactor for Full Oxygen Recovery from Carbon Dioxide

Oxygen recovery from respiratory carbon dioxide is an important aspect of human spaceflight. Methods exist to sequester the carbon dioxide, but production of oxygen needs further development. The current International Space Station Carbon Dioxide Reduction System (CRS) uses the Sabatier reaction to produce water (and ultimately breathing air). Oxygen recovery is limited to 50% because half of the hydrogen used in the Sabatier reactor is lost as methane, which is vented overboard. The Bosch reaction, which converts carbon dioxide to oxygen and solid carbon is capable of recovering all the oxygen from carbon dioxide, and is the only real alternative to the Sabatier reaction. However, the last reaction in the cycle, the Boudouard reaction, produces solid carbon and the resulting carbon buildup will eventually foul the nickel or iron catalyst, reducing reactor life and increasing consumables. To minimize this fouling and increase efficiency, a number of self-cleaning catalyst designs have been created. This paper will describe recent results evaluating one of the designs.

Oxygen recovery↗