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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 829 records · Page 46
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

An experimental study of the flow field and pollutant formation in a two dimensional premixed, turbulent flame

Spark shadowgraphs, high-speed schlieren movies, and the tracing of individual eddies were used to study a turbulent reacting shear layer in a premixed propane/air flow. The flow took place in a two-dimensional combustor, and the flame was stabilized behind a rearward facing streamlined step. The data show that in the velocity range 7.5 to 22.5 m/sec the mixing layer is dominated by Brown-Roshko type large coherent structures in both reacting and nonreacting flows. Information on the eddies, the flame, and the distribution of gas concentrations is presented.

Ganji, A. R.↗
NASA NTRS1980

Turbulence, combustion, pollutant, and stability characterization of a premixed, step combustor

A two dimensional combustion tunnel was constructed to study a lean premixed turbulent propane/air flame stablized behind a rearward facing step. Studied were: (1) the existence and importance of large coherent structures in turbulent reacting and nonreacting free shear layers behind the steps; (2) the effect of inlet temperature and reference velocity on combustion efficiency; (3) CO, NO2 and NO sub x production in the flame; and (4) the blowout and upstream propagation of the flame. In the ranges studied, the large coherent structures dominated both the reacting and the nonreacting free shear layers behind the step. The growth of the vortices and the propagation of the flamer were intimately linked. Vortex pairing was observed to be one of the mechanisms for introduction of fresh reactants into the shear layer and growth of the shear layer. Probe composition measurements of the flame showed that, in the recirculation zone, the reaction was above 99 percent complete, CO and unburnt hydrocarbons were above the equilibrium level NO sub x concentration was far below the equilibrium level and NO2 comprised a negligible fraction of NO sub x.

Ganji, A. T.↗
NASA NTRS1979

Rates of the reactions of 1, 1, 1-trichloroethane /methyl chloroform/ and 1, 1, 2-trichloroethane with OH

Highly purified samples of the two chlorocarbons, trichloroethane and methyl chloroform, were reacted with OH over the temperature range of 278 to 460 K in a discharge-flow system with resonance flourescence detection of OH. Attention is given to the data obtained at various temperature levels and to the graph of Arrhenius' diagram. It is determined that the methyl chloroform reaction was slower and its temperature dependence somewhat steeper than the earlier measurements had indicated, probably due to the presence of faster reacting olefinic impurities in prior studies. Implications for stratospheric ozone reductions by C10-sub-x catalysis and for tropospheric OH-budget are briefly discussed.

Jeong, K.-M.↗
NASA NTRS1980

Atmospheric perturbation and control of a shuttle/tethered satellite

A simplified model of the strong atmospheric perturbation of a small satellite attached to the orbiter by a long, rigid tether predicts undesirable uncontrolled libration motions similar to those from sophisticated models. The simplified model is used to compare performance limitations of two simple control systems that rely only on tether tension for three-dimensional control. Because the effects on libration of both the changing kinematic and atmospheric drag torques caused by changing length are largely predictable, the controller that models these changes has substantially better performance. In particular, the altitude variation of the tethered satellite above an oblate earth can be controlled substantially better with a controller that uses a length command adapted to these predictable changes than one that only reacts to tension changes. Also, small amplitude out-of-plane librations, that are coupled only to second-order with changing length, can be damped substantially faster by the controller that periodically commands properly phased length changes than by the controller that only reacts to the second-order changes in tension.

Spencer, T. M.↗
NASA NTRS1980

Studies on chemical evolution using carbon suboxide

It was learned that when carbon suboxide polymers react with hydroxylamine in modified sea water the amino acids glycine and lysine are produced and that they react with urea to produce nucleic acid-like substances. These results lead to the supposition that it is possible that carbon suboxide polymers may have accumulated in the primeval sea some three or more billion years ago and were transformed into the procursors of living molecules.

Yanagawa, H.↗
NASA NTRS1982

Chemical modification of TiO2 surfaces with methylsilanes and characterization by infrared absorption spectroscopy

Infrared absorption spectra of methylsilanes bonded to a TiO2 powder were obtained. The reacting silanes include Me sub (4-n)SiX sub n (n=1-4; X=Cl, OMe) and hexamethyldisilazane (HMDS). Reactions were performed on hydroxylated-but-anhydrous TiO2 surfaces in the gas phase. IR spectra confirm the presence of a bonded silane layer. Terminal surface OH groups are found to react more readily than bridging OH groups. By-products of the modification adsorp tenaciously to the surface. The various silanes show only small differences in their ability to sequester surface OH groups. Following hydrolysis in moist air, Si-OH groups are observed only for the tetrafunctional silanes.

Finklea, H. O.↗
NASA NTRS1982

Surface profile changes of scuffed bearing surfaces

A phase locked interference microscope capable of resolving depth differences to 30 A and planar displacements of 6000 A was constructed for the examination of the profiles of bearing surfaces without physical contact. This instrument was used to determine surface chemical reactivity by applying a drop of dilute alcoholic hydrochloric acid and measuring the profile of the solid surface before and after application of this probe. Scuffed bearing surfaces reacted much faster than unscuffed ones, but bearing surfaces which had been previously exposed to lubricants containing an organic chloride reacted much more slowly. In a separate series of experiments, a number of stainless steel plates were heated in a nitrogen atmosphere to different temperatures and their reactivity examined later at room temperature. The change of surface contour as a result of the probe reaction followed an Arrhenius type relation with respect to heat treatment temperature. This result could have implications on the scuffing mechanism.

Lauer, J. L.↗
NASA NTRS1983

High performance liquid chromatographic hydrocarbon group-type analyses of mid-distillates employing fuel-derived fractions as standards

Two high performance liquid chromatographic (HPLC) methods have been developed for the determination of saturates, olefins and aromatics in petroleum and shale derived mid-distillate fuels. In one method the fuel to be analyzed is reacted with sulfuric acid, to remove a substantial portion of the aromatics, which provides a reacted fuel fraction for use in group type quantitation. The second involves the removal of a substantial portion of the saturates fraction from the HPLC system to permit the determination of olefin concentrations as low as 0.3 volume percent, and to improve the accuracy and precision of olefins determinations. Each method was evaluated using model compound mixtures and real fuel samples.

Seng, G. T.↗
NASA NTRS1983

Monte Carlo Modeling in Elliptic Flows

A Monte Carlo method capable of predicting scalar (e.g., concentration) probability density functions (pdf's) in nonreacting and reacting elliptic flows was developed. A research combustor specifically designed to provide measurements of concentration and temperature pdf's in nonreacting and reacting flows is emphasized.

Radhakrishnan, K.↗
NASA NTRS1982

Microscopic contour changes of tribological surfaces by chemical and mechanical action

An electronic optical laser interferometer capable of resolving depth differences of as low as 30 A and planar displacements of 6000 A was constructed for the examination of surface profiles of bearing surfaces without physical contact. This instrument was used to determine topological chemical reactivity by applying a drop of dilute alcoholic hydrochloric acid and measuring the profile of the solid surface before and after application of this probe. It was found that scuffed bearing surfaces reacted much faster than virgin ones but that bearing surfaces exposed to lubricants containing an organic chloride reacted much more slowly. In a separate series of experiments, a number of stainless steel plates were heated in a nitrogen atmosphere to different temperatures and their reactivity examined later at ambient temperature. The change of surface contour as a result of the probe reaction was found to follow an Arrhenius-type relation with respect to heat treatment temperature. This result could have implications on the scuffing mechanism.

Lauer, J. L.↗
NASA NTRS1984

Surface topographical changes measured by phase-locked interferometry

An electronic optical laser interferometer capable of resolving depth differences of as low as 30 A and planar displacements of 6000 A was constructed to examine surface profiles of bearing surfaces without physical contact. Topological chemical reactivity was determined by applying a drop of dilute alcoholic hydrochloric acid and measuring the profile of the solid surface before and after application of this probe. Scuffed bearing surfaces reacted much faster than virgin ones but that bearing surfaces exposed to lubricants containing an organic chloride reacted much more slowly. The reactivity of stainless steel plates, heated in a nitrogen atmosphere to different temperatures, were examined later at ambient temperature. The change of surface contour as a result of the probe reaction followed Arrhenius-type relation with respect to heat treatment temperature. The contact area of the plate of a ball/plate sliding elastohydrodynamic contact run on trimethylopropane triheptanoate with or without additives was optically profiled periodically. As scuffing was approached, the change of profile within the contact region changed much more rapidly by the acid probe and assumed a constant high value after scuffing. A nonetching metallurgical phase was found in the scuff mark, which was apparently responsible for the high reactivity.

Lauer, J. L.↗
NASA NTRS1984

Process for preparing perfluorotriazine elastomers and precursors thereof

Perfluoroether triazine elastomers having improved properties and utility in seals, gaskets, sealing components and the like are prepared from oligomeric imidoylamidines that have, in turn, been prepared by the process of (1) reacting a perfluorodinitrile with liquid ammonia to yield a perfluorodiamidine, (2) isolating the perfluorodiamidine, (3) reacting the isolated diamidine with a perfluorodinitrile to yield a perfluoror(imidoylamidine) dinitrile, and then repeating step (1), (2), and (3) to sequentially grow an oligomer of desired molecular size. The isolated amidine and nitrile intermediates are also described.

Rosser, R. W.↗
NASA NTRS1985

SSME Fuel Preburner Two-dimensional Analysis

The durability of the SSME turbine is strongly affected by the temperature profile leaving the preburner. A reacting flow computer model to predict the turbine inlet temperature profile was used. Calculations were made by using a reacting flow code, to assess the sensitivity of the turbine inlet temperature profile to variations in the flow entering the SSME preburner.

Thomas J. Vanoverbeke↗
NASA NTRS1984

Polyimide adhesives - Modified with ATBN and silicone elastomers

A series of studies evaluating the effects of added elastomers on the properties of a high-temperature addition polyimide adhesive is reviewed. First, thermoset polyimides containing various butadiene/acrylonitrile and silicone elastomers were synthesized either as physical polybends or by chemically reacting the elastomers directly onto the polymer backbone. The modified adhesive resins were characterized for thermomechanical properties, fracture toughness and adhesive strength. A second series of elastomer-containing polyimides was also prepared in order to study the effects of the elastomer chain length on polymer properties. Aromatic amine-terminated silicone rubbers with repeat units varying from n = 10 to 105 were reacted onto the polyimide backbone, and the resulting polymers were characterized for their adhesive properties.

St. Clair, A. K.↗
NASA NTRS1985

Effect of reactive intermediates on the propagation of turbulent premixed flames

The most simple version of the Bray and Libby model of turbulent flame propagation has been extended to include a two-step reaction mechanism in which reactants decompose into reactive intermediates which then form products. A transport equation for the joint pdf of intermediate and product concentrations was derived, the pdf parameterized, and transport equations for the parameters obtained. The one-dimensional concentration equations were then solved for the parameters of the pdf and the turbulent kinetic energy. Flame speed and angle are recovered as eigenvalues of the problem. The results show the essential features observed in experiments. The product pdf is composed of peaks at zero and unity product concentration, with a continuous structure representing partially reacted gas. The intermediates pdf has a peak at zero concentration and a broad bell-shaped distribution at nonzero concentration, representing partially reacted gas. The results also show the effect of partitioning of energy release on the flame thickness and speed.

Azzazy, M.↗
NASA NTRS1986

Perfluoro (Imidoylamidine) diamidines

Perfluoroether triazine elastomers having improved properties are prepared from oligomeric imidoylamidines that were in turn, prepared by the process of: (1) reacting a perfluorodinitrile with liquid ammonia to yield a perfluorodiamidine, (2) isolating the perfluorodiamidine, (3) reacting the isolated diamidine with a perfluorodinitrile to yield a perfluoro(imidoylamidine) dinitrile, and then repeating the steps to sequentially grow an oligomer of desired molecular size. The isolated amidine and nitrile intermediates are also disclosed. The elastomers can be fashioned into seals, gaskets, and sealing components and the like.

Rosser, R. W.↗
NASA NTRS1986

A shock capturing technique for hypersonic, chemically relaxing flows

A fully coupled, shock capturing technique is presented for chemically reacting flows at high Mach numbers. The technique makes use of a total variation diminishing (TVD) dissipation operator which results in sharp, crisp shocks. The eigenvalues and eigenvectors of the fully coupled system, which includes species conversion equations in addition to the gas dynamics equations, are analytically derived for a general reacting gas. Species production terms for a model dissociating gas are introduced and are included in the algorithm. The convective terms are solved using a first-order TVD scheme while the source terms are solved using a fourth-order Runge-Kutta scheme to enhance stability. Results from one-dimensional numerical experiments are shown for a two species and a three species gas.

Eberhardt, S.↗
NASA NTRS1986

Numerical study of supersonic combustion using a finite rate chemistry model

The governing equations of two-dimensional chemically reacting flows are presented together with a global two-step chemistry model for H2-air combustion. The explicit unsplit MacCormack finite difference algorithm is used to advance the discrete system of the governing equations in time until convergence is attained. The source terms in the species equations are evaluated implicitly to alleviate stiffness associated with fast reactions. With implicit source terms, the species equations give rise to a block-diagonal system which can be solved very efficiently on vector-processing computers. A supersonic reacting flow in an inlet-combustor configuration is calculated for the case where H2 is injected into the flow from the side walls and the strut. Results of the calculation are compared against the results obtained by using a complete reaction model.

Chitsomboon, T.↗