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At least 829 records · Page 46

Passive sensing of a microparticle modified hybrid, fiber-reinforced composite

The widespread commercial adoption of high-performance, fiber-reinforced composites has pushed research interests toward the next generation of composites. These new composites are tasked with integrating additional functionalities into the structures without causing a trade-off in mechanical performance. One such functionality that has received significant interest is sensing. This is especially important for composites using high-performance fibers (e.g., carbon fiber) because their strain-to-failure is relatively low, resulting in brittle fracture. Besides, fiber damage can be hidden within the composite, potentially leading to premature catastrophic failure if not detected. In prior research, we demonstrated continuous feed-through deposition of ceramic nanoparticles on carbon fiber’s surface that simultaneously enhanced both the piezoresistive response and interlaminar shear strength. In this work, a similar continuous feed-through deposition process was used to demonstrate passive sensing and energy harvesting by integrating ferroelectric microparticles on the surface of electrically nonconductive fibers. The sensing and energy harvesting capabilities were characterized by mechanically straining composite beams and measuring the power generated. The improvements in mechanical properties are shown through interlaminar shear strength tests. Therefore, this research aims to demonstrate a high throughput, commercially scalable approach to coat fibers with ferroelectric microparticles that enable passive sensing as well as improved mechanical performance when fabricated into a fiber-reinforced composite.

Bowland, Christopher↗

SU-E-T-287: Robustness Study of Passive-Scattering Proton Therapy in Lung: Is Range and Setup Uncertainty Calculation On the Initial CT Enough to Predict the Plan Robustness?

Purpose: Plan robustness of the passive-scattering proton therapy treatment of lung tumors has been studied previously using combined uncertainties of 3.5% in CT number and 3 mm geometric shifts. In this study, we investigate whether this method is sufficient to predict proton plan robustness by comparing to plans performed on weekly verification CT scans. Methods: Ten lung cancer patients treated with passive-scattering proton therapy were randomly selected. All plans were prescribed 6660cGy in 37 fractions. Each initial plan was calculated using +/− 3.5% range and +/− 0.3cm setup uncertainty in x, y and z directions in Eclipse TPS(Method-A). Throughout the treatment course, patients received weekly verification CT scans to assess the daily treatment variation(Method-B). After contours and imaging registrations are verified by the physician, the initial plan with the same beamline and compensator was mapped into the verification CT. Dose volume histograms (DVH) were evaluated for robustness study. Results: Differences are observed between method A and B in terms of iCTV coverage and lung dose. Method-A shows all the iCTV D95 are within +/− 1% difference, while 20% of cases fall outside +/−1% range in Method-B. In the worst case scenario(WCS), the iCTV D95 is reduced by 2.5%. All lung V5 and V20 are within +/−5% in Method-A while 15% of V5 and 10% of V20 fall outside of +/−5% in Method-B. In the WCS, Lung V5 increased by 15% and V20 increased by 9%. Method A and B show good agreement with regard to cord maximum and Esophagus mean dose. Conclusion: This study suggests that using range and setup uncertainty calculation (+/−3.5% and +/−3mm) may not be sufficient to predict the WCS. In the absence of regular verification scans, expanding the conventional uncertainty parameters(e.g., to +/−3.5% and +/−4mm) may be needed to better reflect plan actual robustness.

60 APPLIED LIFE SCIENCES↗

SU-E-T-591: Measurement and Monte Carlo Simulation of Stray Neutrons in Passive Scattering Proton Therapy: Needs and Challenges

Purpose: Measure stray radiation inside a passive scattering proton therapy facility, compare values to Monte Carlo (MC) simulations and identify the actual needs and challenges. Methods: Measurements and MC simulations were considered to acknowledge neutron exposure associated with 75 MeV ocular or 180 MeV intracranial passively scattered proton treatments. First, using a specifically-designed high sensitivity Bonner Sphere system, neutron spectra were measured at different positions inside the treatment rooms. Next, measurement-based mapping of neutron ambient dose equivalent was fulfilled using several TEPCs and rem-meters. Finally, photon and neutron organ doses were measured using TLDs, RPLs and PADCs set inside anthropomorphic phantoms (Rando, 1 and 5-years-old CIRS). All measurements were also simulated with MCNPX to investigate the efficiency of MC models in predicting stray neutrons considering different nuclear cross sections and models. Results: Knowledge of the neutron fluence and energy distribution inside a proton therapy room is critical for stray radiation dosimetry. However, as spectrometry unfolding is initiated using a MC guess spectrum and suffers from algorithmic limits a 20% spectrometry uncertainty is expected. H*(10) mapping with TEPCs and rem-meters showed a good agreement between the detectors. Differences within measurement uncertainty (10–15%) were observed and are inherent to the energy, fluence and directional response of each detector. For a typical ocular and intracranial treatment respectively, neutron doses outside the clinical target volume of 0.4 and 11 mGy were measured inside the Rando phantom. Photon doses were 2–10 times lower depending on organs position. High uncertainties (40%) are inherent to TLDs and PADCs measurements due to the need for neutron spectra at detector position. Finally, stray neutrons prediction with MC simulations proved to be extremely dependent on proton beam energy and the used nuclear models and cross sections. Conclusion: This work highlights measurement and simulation limits for ion therapy radiation protection applications.

07 ISOTOPE AND RADIATION SOURCES↗

Experimental demonstration of passive acoustic imaging in the human skull cavity using CT-based aberration corrections

Purpose: Experimentally verify a previously described technique for performing passive acoustic imaging through an intact human skull using noninvasive, computed tomography (CT)-based aberration corrections Jones et al. [Phys. Med. Biol. 58, 4981–5005 (2013)]. Methods: A sparse hemispherical receiver array (30 cm diameter) consisting of 128 piezoceramic discs (2.5 mm diameter, 612 kHz center frequency) was used to passively listen through ex vivo human skullcaps (n = 4) to acoustic emissions from a narrow-band fixed source (1 mm diameter, 516 kHz center frequency) and from ultrasound-stimulated (5 cycle bursts, 1 Hz pulse repetition frequency, estimated in situ peak negative pressure 0.11–0.33 MPa, 306 kHz driving frequency) Definity™ microbubbles flowing through a thin-walled tube phantom. Initial in vivo feasibility testing of the method was performed. The performance of the method was assessed through comparisons to images generated without skull corrections, with invasive source-based corrections, and with water-path control images. Results: For source locations at least 25 mm from the inner skull surface, the modified reconstruction algorithm successfully restored a single focus within the skull cavity at a location within 1.25 mm from the true position of the narrow-band source. The results obtained from imaging single bubbles are in good agreement with numerical simulations of point source emitters and the authors’ previous experimental measurements using source-based skull corrections O’Reilly et al. [IEEE Trans. Biomed. Eng. 61, 1285–1294 (2014)]. In a rat model, microbubble activity was mapped through an intact human skull at pressure levels below and above the threshold for focused ultrasound-induced blood–brain barrier opening. During bursts that led to coherent bubble activity, the location of maximum intensity in images generated with CT-based skull corrections was found to deviate by less than 1 mm, on average, from the position obtained using source-based corrections. Conclusions: Taken together, these results demonstrate the feasibility of using the method to guide bubble-mediated ultrasound therapies in the brain. The technique may also have application in ultrasound-based cerebral angiography.

60 APPLIED LIFE SCIENCES↗

SU-E-T-239: Design and Evaluation of a Nozzle Shielding System in Passively Scattered Proton Therapy

Purpose: To design, implement and evaluate a shielding system that will reduce out-of-field dose experienced by the patient and associated electronic systems in passively scattered proton therapy treatment. Methods: A multi-stage neutron shielding system was retrofitted to the Gantry 1 treatment nozzle at Loma Linda University Medical Center. The system uses multiple borated polyethylene plates staged after the primary beam modifying devices to attenuate and absorb neutrons produced by such devices. This arrangement locates increasing levels of shielding between the sources of secondary particles in the nozzle and the patient. Additionally, the design of this shielding structure allows it to be easily retrofitted to an existing proton nozzle system without impacting design or treatment beam characteristics. The effectiveness of the shielding was evaluated both through experimental measurements and Geant4 Monte Carlo simulations. Results: Measurements were completed with Landauer Luxel+ dosimeters that use optically stimulated luminescence and CR-39 to detect fast neutrons, thermal neutrons, protons, photons and beta particles. Measurements of a 250 MeV proton beam indicated that the shielding system reduced out-of-field dose to the patient by almost half with dose equivalent values at 50 and 40 cm from the field edge decreasing from 0.965 and 1.262 mSv/Gy to 0.596 and 0.777 mSv/Gy respectively. The installation of the multi-stage shielding system also reduced dose equivalent experienced by electronic systems installed in the treatment room by up to 80%. Geant4 simulations were also used to evaluate the neutron fluence at various positions in the treatment room as well as provide information on microdosimetry spectra within the patient and treatment room. Conclusion: The shielding system described above proved to be an effective an inexpensive method of reducing out-of-field doses to the patient and electronic systems and can be easily retrofitted to existing passive scattering nozzles.

60 APPLIED LIFE SCIENCES↗

MO-F-CAMPUS-T-03: Verification of Range, SOBP Width, and Output for Passive-Scattering Proton Beams Using a Liquid Scintillator Detector

Purpose: Liquid scintillators have been shown to provide fast and high-resolution measurements of radiation beams. However, their linear energy transfer-dependent response (quenching) limits their use in proton beams. The purpose of this study was to develop a simple and fast method to verify the range, spread-out Bragg peak (SOBP) width, and output of a passive-scattering proton beam with a liquid scintillator detector, without the need for quenching correction. Methods: The light signal from a 20×20×20 cm3 liquid scintillator tank was collected with a CCD camera. Reproducible landmarks on the SOBP depth-light curve were identified which possessed a linear relationship with the beam range and SOBP width. The depth-light profiles for three beam energies (140, 160 and 180 MeV) with six SOBP widths at each energy were measured with the detector. Beam range and SOBP width calibration factors were obtained by comparing the depth-light curve landmarks with the nominal range and SOBP width for each beam setting. The daily output stability of the liquid scintillator detector was also studied by making eight repeated output measurements in a cobalt-60 beam over the course of two weeks. Results: The mean difference between the measured and nominal beam ranges was 0.6 mm (σ=0.2 mm), with a maximum difference of 0.9 mm. The mean difference between the measured and nominal SOBP widths was 0.1 mm (σ=1.8 mm), with a maximum difference of 4.0 mm. Finally an output variation of 0.14% was observed for 8 measurements performed over 2 weeks. Conclusion: A method has been developed to determine the range and SOBP width of a passive-scattering proton beam in a liquid scintillator without the need for quenching correction. In addition to providing rapid and accurate beam range and SOBP measurements, the detector is capable of measuring the output consistency with a high degree of precision. This project was supported in part by award number CA182450 from the National Cancer Institute.

07 ISOTOPE AND RADIATION SOURCES↗

SU-F-T-143: Implementation of a Correction-Based Output Model for a Compact Passively Scattered Proton Therapy System

Purpose: To commission and investigate the accuracy of an output (cGy/MU) prediction model for a compact passively scattered proton therapy system. Methods: A previously published output prediction model (Sahoo et al, Med Phys, 35, 5088–5097, 2008) was commissioned for our Mevion S250 proton therapy system. This model is a correction-based model that multiplies correction factors (d/MUwnc=ROFxSOBPF xRSFxSOBPOCFxOCRxFSFxISF). These factors accounted for changes in output due to options (12 large, 5 deep, and 7 small), modulation width M, range R, off-center, off-axis, field-size, and off-isocenter. In this study, the model was modified to ROFxSOBPFxRSFxOCRxFSFxISF-OCFxGACF by merging SOBPOCF and ISF for simplicity and introducing a gantry angle correction factor (GACF). To commission the model, outputs over 1,000 data points were taken at the time of the system commissioning. The output was predicted by interpolation (1D for SOBPF, FSF, and GACF; 2D for RSF and OCR) with inverse-square calculation (ISF-OCR). The outputs of 273 combinations of R and M covering total 24 options were measured to test the model. To minimize fluence perturbation, scattered dose from range compensator and patient was not considered. The percent differences between the predicted (P) and measured (M) outputs were calculated to test the prediction accuracy ([P-M]/Mx100%). Results: GACF was required because of up to 3.5% output variation dependence on the gantry angle. A 2D interpolation was required for OCR because the dose distribution was not radially symmetric especially for the deep options. The average percent differences were −0.03±0.98% (mean±SD) and the differences of all the measurements fell within ±3%. Conclusion: It is concluded that the model can be clinically used for the compact passively scattered proton therapy system. However, great care should be taken when the field-size is less than 5×5 cm{sup 2} where a direct output measurement is required due to substantial output change by irregular block shape.

60 APPLIED LIFE SCIENCES↗

Hydroxylation of the surface of PbS nanocrystals passivated with oleic acid

Controlling the structure of colloidal nanocrystals (NCs) is key to the generation of their complex functionality. This requires an understanding of the NC surface at the atomic level. The structure of colloidal PbS NCs passivated with oleic acid has been studied theoretically and experimentally. We show the existence of surface OH(-) groups, which play a key role in stabilizing the PbS(111) facets, consistent with x-ray photoelectron spectroscopy as well as other spectroscopic and chemical experiments. The role of water in the synthesis process is also revealed. Our model, along with existing observations of NC surface termination and passivation by ligands, helps to explain and predict the properties of NCs and their assemblies.

Science & Technology - Other Topics↗

Effect of ammonium-sulfide solvent on the surface passivation of GaSb (100)

X-ray photoemission spectroscopy and scanning electron microscopy are used to study the effect of a solvent on the chemical composition of a sulfide passivating layer formed on GaSb (100) surface. Treatment of the GaSb (100) surface with ammonium-sulfide solutions results in the formation of a thick (several tens of nanometers) coating composed of a mixture of various binary and ternary gallium and antimony sulfides. The chemical compositions of the passivating sulfide layers formed in aqueous and alcoholic ammonium-sulfide solutions are different. Annealing of the sulfide layer at 360°C in ultrahigh vacuum leads to the partial desorption of antimony from the surface, the decomposition of ternary sulfides into their binary constituents, and change in the surface band bending of this layer.

36 MATERIALS SCIENCE↗

Imaging and Modeling of Passive Water Management in a Miniature Fuel Cell

A small microwatt fuel cell stack with 8 cells was designed, fabricated, and tested for passive operation with pure H 2 and O 2 to provide continuous power for multiple decades with uncontrolled fluctuating ambient conditions. The stack was designed to operate with dead ended gas flows with water removal via passive membrane diffusion to notches in the bipolar plates. Two stacks with active areas of 0.2 cm 2 , one with 200 nm of membrane and the other with 400 urn, were assembled and tested at varying temperatures and current conditions. Temperatures ranged -55 °C to 70 °C, with focus on the lower temperatures. Factors affecting water production and removal included temperature, gas crossover, and membrane thickness. Currents were applied from 16 uA to 10 mA after the cells were stabilized at temperature, followed by a period of drying to observe water transport to the external peripheries of the cell. Finally, a two-dimensional multiphysics model was developed to further explore the water management system in varying conditions.

25 ENERGY STORAGE↗

A Comprehensive Numerical and Experimental Study for the Passive Thermal Management in Battery Modules and Packs

Cooling plates in battery packs of electric vehicles play critical roles in passive thermal management systems to reduce risks of catastrophic thermal runaway. In this work, a series of numerical simulations and experiments are carried out to unveil the role of cooling plates (both between cells and a bottom plate parallel to the cell stack) on the thermal behavior of battery modules and packs under nail penetrations. First, we investigated the role of side cooling plates on the thermal runaway propagation mitigation in battery modules (1S3P) and packs (3S3P) by varying the key parameters of the side cooling plates, such as plate thicknesses, thermal contact resistances, and materials. Then, three important factors for passive thermal management systems are identified: (i) thermal mass of side cooling plates, (ii) interfacial thermal contact resistances, and (iii) the effective heat transfer coefficients at exterior surfaces. The roles of bottom cooling plates on thermal runaway propagation mitigation in 1S3P and 1S5P battery modules are numerically investigated by comparing the thermal behavior of the modules with only side cooling plates and with both side and bottom cooling plates.

25 ENERGY STORAGE↗

Estimation of Tropical Cyclone Intensity in the North Atlantic and Northeastern Pacific Basins Using TRMM Satellite Passive Microwave Observations

Here, a statistical passive microwave intensity estimation (PMW-IE) algorithm for estimating the intensity of tropical cyclones (TCs) in the North Atlantic and northeastern and central Pacific basins is developed and tested. The algorithm is derived from Tropical Rainfall Measuring Mission (TRMM) Microwave Imager (TMI) 85-GHz brightness temperatures and near-surface rain-rate retrievals to provide objective estimates of current maximum sustained surface winds (Vmax) and 6-h future Vmax of TCs. The full record of TRMM data (1998–2013) including 2326 TMI overpasses of 503 TCs is separated into dependent samples (1998–2010) for model development and independent samples (2011–13) for model verification. The best track intensities are used as dependent variables in a stepwise multiple-regression approach. Separately for each basin, three regression models are derived using selected 1) 85-GHz-only variables, 2) rain-rate-only variables, and 3) combined 85-GHz and rain variables. The algorithms are assessed using independent samples and those with contemporaneous aircraft-reconnaissance measurements. Rain-only and combined models perform better than the 85-GHz-only model. Lower errors are found for estimating the 6-h future Vmax than estimating the current Vmax using all three models. This implies that it is optimal to use passive-microwave-retrieved rain variables observed a few hours earlier to estimate TC intensity. The MAE (RMSE) of 6-h future Vmax is 9 (12) kt (1 kt ≈ 0.51 m s -1 ) when testing the combined models with ATL and EPA independent samples. Aircraft-reconnaissance-based independent samples yields a MAE of 9.6 kt and RMSE of 12.6 kt for estimating 6-h future Vmax.

58 GEOSCIENCES↗

Defect passivation in nanostructured silica for stable birefringence in polarization optics

Nanostructured materials with anisotropic microstructure exhibit direction-dependent refractive index, known as form birefringence. One of the main advantages of these nanostructured materials is that the ease of fabrication significantly reduces the cost of production. However, their birefringence is affected by humidity as well as time. The hypothesis is that defects, particularly silanols, are responsible. Here, in this work, we present the use of hexamethyldisilazane (HMDS) vapor as a passivation strategy. Using spectroscopic ellipsometry and Raman scattering, the data show that HMDS successfully passivates silanol groups and promotes O-Si-O bond formation, resulting in improved stability. The results demonstrate a simple method to enhance the reliability of all-silica polarization optics offering potential advancements for high-power laser components.

Mireles, Marcela [Univ. of Rochester, NY (United S↗

Passive methods for spent fuel characterisation at the Finnish geological repository

Development of the Passive Gamma Emission Tomography (PGET) and Passive Neutron Albedo Reactivity (PNAR) methods in the context of the Finnish geological repository for spent nuclear fuel has shown that they provide, for BWR fuel assemblies, the comprehensive verification needed to meet the nuclear safeguards objectives of the repository. The principles of the PGET and PNAR methods and the design and operation of the respective instruments are presented. A few results from measurements at the spent fuel storage pools at the Finnish nuclear power plants are discussed. The directions of ongoing and future developments are indicated.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Local-Level Prognostics Health Management Systems Framework for Passive AdvSMR Components. Interim Report

This report describes research results to date in support of the integration and demonstration of diagnostics technologies for prototypical AdvSMR passive components (to establish condition indices for monitoring) with model-based prognostics methods. The focus of the PHM methodology and algorithm development in this study is at the localized scale. Multiple localized measurements of material condition (using advanced nondestructive measurement methods), along with available measurements of the stressor environment, enhance the performance of localized diagnostics and prognostics of passive AdvSMR components and systems.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Spent fuel measurements. passive neutron albedo reactivity (PNAR) and photon signatures

The International Atomic Energy Agency’s (IAEA) safeguards technical objective is the timely detection of a diversion of a significant quantity of nuclear material from peaceful activities to the manufacture of nuclear weapons or of other nuclear explosive devices or for purposes unknown, and deterrence of such diversion by the risk of early detection. An important IAEA task towards meeting this objective is the ability to accurately and reliably measure spent nuclear fuel (SNF) to verify reactor operating parameters and verify that the fuel has not been removed from reactors or SNF storage facilities. This dissertation analyzes a method to improve the state-of-the-art of nuclear material safeguards measurements using two combined measurement techniques: passive neutron albedo reactivity (PNAR) and passive spectral photon measurements.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Enhanced Passive Cooling for Waterless-Power Production Technologies

Recent advances in the literature and at SNL indicate the strong potential for passive, specialized surfaces to significantly enhance power production output. Our exploratory computational and experimental research indicates that fractal and swirl surfaces can help enable waterless-power production by increasing the amount of heat transfer and turbulence, when compared with conventional surfaces. Small modular reactors, advanced reactors, and non-nuclear plants (e.g., solar and coal) are ideally suited for sCO2 coolant loops. The sCO2 loop converts the thermal heat into electricity, while the specialized surfaces passively and securely reject the waste process heat in an environmentally benign manner. The resultant, integrated energy systems are highly suitable for small grids, rural areas, and arid regions.

14 SOLAR ENERGY↗

Proof-of-Concept Testing of the Passive Cooling System (T-CLIP™) for Solar Thermal Applications at an Elevated Temperature

The Applied Engineering and Technology-1 group (AET-1) at Los Alamos National Laboratory (LANL) conducted the proof-of-concept tests of SolarSPOT LLC’s solar thermal Temperature- Clipper, or T-CLIP™ under controlled thermal conditions using a thermal conditioning unit (TCU) and a custom made environmental chamber. The passive T-CLIP™ is a plumbing apparatus that attaches to a solar thermal collector to limit working fluid temperature and to prevent overheating, since overheating may lead to various accident scenarios. The goal of the current research was to evaluate the ability of the T-CLIP™ to control the working fluid temperature by using its passive cooling mechanism (i.e. thermosiphon, or natural circulation) in a small-scale solar thermal system. The assembled environmental chamber that is thermally controlled with the TCU allows one to simulate the various possible weather conditions, which the solar system will encounter. The performance of the T-CLIP™ was tested at two different target temperatures: 1) room temperature (70 °F) and 2) an elevated temperature (130 °F). The current test campaign demonstrated that the T-CLIP™ was able to prevent overheating by thermosiphon induced cooling in a small-scale solar thermal system. This is an important safety feature in situations where the pump is turned off due to malfunction or power outages.

14 SOLAR ENERGY↗