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At least 829 records · Page 46

Analysis of mid-tropospheric Space Shuttle exhausted aluminum oxide particles

Aluminum oxide particles from the exhaust of the Space Shuttle were collected immediately after the launch of the SEPEX mission and during the descent over the altitude interval of 7.6-4.6 km. The SEM examination revealed that the particles were spherical and ranged in diameter from about 0.1 micron to 10 microns. Results from the energy dispersive analysis (by an X-ray method) and of the particle chemistry (by electron spectroscopy) confirmed that the particles were predominantly composed of aluminum and oxygen. The particle size distribution of the Al2O3 was bimodal, with one observed peak centered near 2.0 microns; the other distribution mode centered at a diameter of less than 0.3 micron, but could not be accurately located. A mass median diameter was slightly less than 2 microns. Evaluation of ice nucleation activity revealed only a small fraction (about 1 ppm) of active ice nuclei among the Al2O3 particulates.

Cofer, Wesley R., III↗

Dynamic Monitoring of Cleanroom Fallout Using an Air Particle Counter

The particle fallout limitations and periodic allocations for the James Webb Space Telescope are very stringent. Standard prediction methods are complicated by non-linearity and monitoring methods that are insufficiently responsive. A method for dynamically predicting the particle fallout in a cleanroom using air particle counter data was determined by numerical correlation. This method provides a simple linear correlation to both time and air quality, which can be monitored in real time. The summation of effects provides the program better understanding of the cleanliness and assists in the planning of future activities. Definition of fallout rates within a cleanroom during assembly and integration of contamination-sensitive hardware, such as the James Webb Space Telescope, is essential for budgeting purposes. Balancing the activity levels for assembly and test with the particle accumulation rate is paramount. The current approach to predicting particle fallout in a cleanroom assumes a constant air quality based on the rated class of a cleanroom, with adjustments for projected work or exposure times. Actual cleanroom class can also depend on the number of personnel present and the type of activities. A linear correlation of air quality and normalized particle fallout was determined numerically. An air particle counter (standard cleanroom equipment) can be used to monitor the air quality on a real-time basis and determine the "class" of the cleanroom (per FED-STD-209 or ISO-14644). The correlation function provides an area coverage coefficient per class-hour of exposure. The prediction of particle accumulations provides scheduling inputs for activity levels and cleanroom class requirements.

Perry, Radford↗

Nanosized Organo-Silica Particles with “Built-In” Surface-Initiated Atom Transfer Radical Polymerization Capability as a Platform for Brush Particle Synthesis

A facile synthetic method was developed to prepare sub-5 nm organo-silica (oSiO 2 ) nanoparticles through the self-condensation of ATRP-initiator-containing silica precursors. The obtained oSiO 2 nanoparticles were characterized by a combination of nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA), transmission electron microscopy (TEM), dynamic light scattering (DLS) and small-angle neutron scattering (SANS). The accessibility of the surface -Br initiating sites was evaluated by the polymerization of poly(methyl methacrylate) (PMMA) ligands from the surface of the oSiO 2 nanoparticles using surface-initiated atom transfer radical polymerization (SI-ATRP). Here, the ultra-small size, tunable composition and ease of surface modification may render these organosilica nanoparticle systems with built-in SI-ATRP capability an interesting alternative to conventional silica nanoparticles for functional material design.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Searching for metastable particles using graph computing

The reconstruction of charged particle trajectories at the Large Hadron Collider and future colliders relies on energy depositions in sensors placed at distances ranging from a centimeter to a meter from the colliding beams. We propose a method of detecting charged particles that decay invisibly after traversing a short distance of about 25 cm inside the experimental apparatus. One of the decay products may constitute the dark matter known to be 84% of all matter at galactic and cosmological distance scales. Our method uses graph computing to cluster spacepoints recorded by two-dimensional silicon pixel sensors into mathematically-defined patterns. The algorithm may be implemented on silicon-based integrated circuits using field-programmable gate array technology to augment or replace traditional computing platforms.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Small Particle Response to Fluid Motion Using Tethered Particles to Simulate Microgravity

This paper reports on ground based work conducted to support the Spaceflight Definition project SHIVA (Spaceflight Holography Investigation in a Virtual Apparatus). SHIVA will advance our understanding of the movement of a particle in a fluid. Gravity usually dominates the equations of motion, but in microgravity as well as on earth other terms can become important. Through an innovative application of fractional differential equations, two members of our team produced the first analytical solution of a fundamental equation of motion, which had only been solved numerically or by approximation before. The general solution predicts that the usually neglected history term becomes important in particle response to a sinusoidal fluid movement when the characteristic viscous time is in the same order as the fluid oscillation period and peaks when the two times are equal. In this case three force terms, the Stokes drag, the added mass, and the history drag must all be included in predicting particle movement. We have developed diagnostic recording methods using holography to save all of the particle field data, allowing the experiment to essentially be transferred from space back to earth in what we call the virtual apparatus for on-earth microgravity experimentation. We can quantify precisely the three-dimensional motion of sets of particles, allowing us to test and apply the new analytical solutions. We are examining the response of particles up to 2 mm radius to fluid oscillation at frequencies up to 80 Hz with amplitudes up to 200 microns. Ground studies to support the flight development program have employed various schemes to simulate microgravity. One of the most reliable and meaningful methods uses spheres tethered to a fine hair suspended in the fluid. We have also investigated particles with nearly neutral buoyancy. Recordings are made at the peak amplitudes of vibration of the cell providing a measure of the ratio of fluid to particle amplitude. The experiment requires precise location of the particle to within microns during recording, and techniques for achieving this are one of the project challenges. Focused microscopic images and diffraction patterns are used. To make the experiment more versatile, the spaceflight system will record holograms both on film and electronically. A cross correlation procedure enables sub pixel accuracies for electronic recordings, partially accommodating the lower spatial resolution of CCDs. The electronic holograms can be down linked providing real time data. Results of the ground experiments, the flight experiment design, and data analysis procedures are reported.

Trolinger, James↗

Theories and Constraints for Massive Higher Spins (Final Technical Report)

The goal of this project was to develop methods for constraining the scattering amplitudes of interacting theories containing massive higher spin particles, and to apply these methods to search for, constrain, and apply theories containing massive high spins. During the 3 year term of the project, 15 papers containing results from the project were published in peer reviewed journals. Highlights of these results include: proofs of the best possible strong coupling scales for theories with massive spin 2 particles, causality constraints on couplings in such theories, the discovery of new effective field theories with extended shift symmetries on curved space, the discovery of a new symmetry of the decoupling limit of massive gravity, a study of the possible shapes of graviton non-gaussianities during inflation, classification results of supersymmetric partially massless fields, and the development of the geometric bootstrap, a novel method to generate new mathematical results about the spectrum of various Laplacian operators on closed Einstein manifolds.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Rock sampling

A method for sampling rock and other brittle materials and for controlling resultant particle sizes is described. The method involves cutting grooves in the rock surface to provide a grouping of parallel ridges and subsequently machining the ridges to provide a powder specimen. The machining step may comprise milling, drilling, lathe cutting or the like; but a planing step is advantageous. Control of the particle size distribution is effected primarily by changing the height and width of these ridges. This control exceeds that obtainable by conventional grinding.

Blum, P.↗

Excited state lifetime modulation in semiconductor nanocrystals for super-resolution imaging

Abstract We report on proof of principle measurements of a concept for a super-resolution imaging method that is based on excitation field density-dependent lifetime modulation of semiconductor nanocrystals. The prerequisite of the technique is access to semiconductor nanocrystals with emission lifetimes that depend on the excitation intensity. Experimentally, the method requires a confocal microscope with fluorescence-lifetime measurement capability that makes it easily accessible to a broad optical imaging community. We demonstrate with single particle imaging that the method allows one to achieve a spatial resolution of the order of several tens of nanometers at moderate fluorescence excitation intensity.

36 MATERIALS SCIENCE↗

Measurement of Beam-Correlated Background Neutrons from the Fermilab Booster Neutrino Beam in ANNIE Phase-I

The Accelerator Neutrino Neutron Interaction Experiment (ANNIE) aims to make a unique measurement of neutron yield from neutrino-nucleus interactions and to perform R&D for the next generation of water-based neutrino detectors. In this paper, we characterize beam-induced neutron backgrounds in the experimental hall at Fermi National Accelerator Laboratory. It is shown that the background levels are sufficiently low to allow the next stage of the experiment to proceed. These measurements are relevant to other Booster Neutrino Beam (BNB) [1] experiments located adjacent to ANNIE Hall, where dirt neutrons and sky-shine could present similar backgrounds.

Particle identification methods↗

Retrieval of aerosol size distribution moments from multiwavelength particulate extinction data

An iterative method for deriving the particle size distribution from multiwavelength satellite remote sensing data is presented and its use illustrated with an application to SAGE II data. The compression size distribution method (CSD) features interpolation and look-up features for relating the coefficients of a least-squares fit as a function of wavelength to parameters of the compression function that have been obtained by Mie calculations. Results are reported of comparisons between particulate radii predicted for the El Chichon volcano aerosol based on SAGE II data and 14 radii measured with NASA flights through the aerosol with aircraft carrying wire impactors.

Livingston, J. M.↗

Planar particle/droplet size measurement technique using digital particle image velocimetry image data

A method for determining a mass flux of an entrained phase in a planar two-phase flow records images of particles in the two-phase flow. Respective sizes of the particles (the entrained phase) are determined as a function of a separation between spots identified on the particle images. Respective velocities of the particles are determined. The mass flux of the entrained phase is determined as a function of the size and velocity of the particles.

Wernet, Mark P.↗

Comparison of CALIPSO-Like, LaRC, and MODIS Retrievals of Ice Cloud Properties over SIRTA in France and Florida during CRYSTAL-FACE

This study compares cirrus particle effective radius retrieved by a CALIPSO-like method with two similar methods using MODIS, MODI Airborne Simulator (MAS), and GOES imagery. The CALIPSO-like method uses lidar measurements coupled with the split-window technique that uses the infrared spectral information contained at the 8.65-micrometer, 11.15-micrometer and 12.05-micrometer bands to infer the microphysical properties of cirrus clouds. The two other methods, sing passive remote sensing at visible and infrared wavelengths, are the operational MODIS cloud products (referred to by its archival product identifier MOD06 for MODIS Terra) and MODIS retrievals performed by the CERES team at LaRC (Langley Research Center) in support of CERES algorithms; the two algorithms will be referred to as MOD06- and LaRC-method, respectively. The three techniques are compared at two different latitudes: (i) the mid-latitude ice clouds study uses 18 days of observations at the Palaiseau ground-based site in France (SIRTA: Site Instrumental de Recherche par Teledetection Atmospherique) including a ground-based 532 nm lidar and the Moderate Resolution Imaging Spectrometer (MODIS) overpasses on the Terra Platform, (ii) the tropical ice clouds study uses 14 different flight legs of observations collected in Florida, during the intensive field experiment CRYSTAL-FACE (Cirrus Regional Study of Tropical Anvils and cirrus Layers-Florida Area Cirrus Experiment), including the airborne Cloud Physics Lidar (CPL) and the MAS. The comparison of the three methods gives consistent results for the particle effective radius and the optical thickness, but discrepancies in cloud detection and altitudes. The study confirms the value of an active remote-sensing method (CALIPSO-like) for the study of sub-visible ice clouds, in both mid-latitudes and tropics. Nevertheless, this method is not reliable in optically very thick tropical ice clouds.

Chiriaco, M.↗

Dynamical tuning of the chemical potential to achieve a target particle number in grand canonical Monte Carlo simulations

We present a method to facilitate Monte Carlo simulations in the grand canonical ensemble given a target mean particle number. The method imposes a fictitious dynamics on the chemical potential, to be run concurrently with the Monte Carlo sampling of the physical system. Corrections to the chemical potential are made according to time-averaged estimates of the mean and variance of the particle number, with the latter being proportional to thermodynamic compressibility. Here, we perform a variety of tests, and in all cases find rapid convergence of the chemical potential—inexactness of the tuning algorithm contributes only a minor part of the total measurement error for realistic simulations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A Large-Particle Monte Carlo Code for Simulating Non-Linear High-Energy Processes Near Compact Objects

High-energy radiation processes in compact cosmic objects are often expected to have a strongly non-linear behavior. Such behavior is shown, for example, by electron-positron pair cascades and the time evolution of relativistic proton distributions in dense radiation fields. Three independent techniques have been developed to simulate these non-linear problems: the kinetic equation approach; the phase-space density (PSD) Monte Carlo method; and the large-particle (LP) Monte Carlo method. In this paper, we present the latest version of the LP method and compare it with the other methods. The efficiency of the method in treating geometrically complex problems is illustrated by showing results of simulations of 1D, 2D and 3D systems. The method is shown to be powerful enough to treat non-spherical geometries, including such effects as bulk motion of the background plasma, reflection of radiation from cold matter, and anisotropic distributions of radiating particles. It can therefore be applied to simulate high-energy processes in such astrophysical systems as accretion discs with coronae, relativistic jets, pulsar magnetospheres and gamma-ray bursts.

Stern, Boris E.↗

Direct Simulation of Extinction in a Slab of Spherical Particles

The exact multiple sphere superposition method is used to calculate the coherent and incoherent contributions to the ensemble-averaged electric field amplitude and Poynting vector in systems of randomly positioned nonabsorbing spherical particles. The target systems consist of cylindrical volumes, with radius several times larger than length, containing spheres with positional configurations generated by a Monte Carlo sampling method. Spatially dependent values for coherent electric field amplitude, coherent energy flux, and diffuse energy flux, are calculated by averaging of exact local field and flux values over multiple configurations and over spatially independent directions for fixed target geometry, sphere properties, and sphere volume fraction. Our results reveal exponential attenuation of the coherent field and the coherent energy flux inside the particulate layer and thereby further corroborate the general methodology of the microphysical radiative transfer theory. An effective medium model based on plane wave transmission and reflection by a plane layer is used to model the dependence of the coherent electric field on particle packing density. The effective attenuation coefficient of the random medium, computed from the direct simulations, is found to agree closely with effective medium theories and with measurements. In addition, the simulation results reveal the presence of a counter-propagating component to the coherent field, which arises due to the internal reflection of the main coherent field component by the target boundary. The characteristics of the diffuse flux are compared to, and found to be consistent with, a model based on the diffusion approximation of the radiative transfer theory.

spheres↗

Use of Transmission Electron Microscopy for Analysis of Aerosol Particles and Strategies for Imaging Fragile Particles

For over 25 years, transmission electron microscopy (TEM) has provided a method for the study of aerosol particles with sizes from below the optical diffraction limit to several microns, resolving the particles as well as smaller features. The wide use of this technique to study aerosol particles has contributed important insights about environmental aerosol particle samples and model atmospheric systems. TEM produces an image that is a 2D projection of aerosol particles that have been impacted onto grids and, through associated techniques and spectroscopies, can contribute additional information such as the determination of elemental composition, crystal structure, and 3D particle structures. Soot, mineral dust, and organic/inorganic particles have all been analyzed using TEM and spectroscopic techniques. TEM, however, has limitations that are important to understand when interpreting data including the ability of the electron beam to damage and thereby change the structure and shape of particles, especially in the case of particles composed of organic compounds and salts. In this paper, we concentrate on the breadth of studies that have used TEM as the primary analysis technique. Another focus is on common issues with TEM and cryogenic-TEM. Insights for new users on best practices for fragile particles, that is, particles that are easily susceptible to damage from the electron beam, with this technique are discussed. Tips for readers on interpreting and evaluating the quality and accuracy of TEM data in the literature are also provided and explained.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗