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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Pore-scale observations of natural hydrate-bearing sediments via pressure core sub-coring and micro-CT scanning

Abstract Both intra-pore hydrate morphology and inter-pore hydrate distribution influence the physical properties of hydrate-bearing sediments, yet there has been no pore-scale observations of hydrate habit under pressure in preserved pressure core samples so far. We present for the first time a pore-scale micro-CT study of natural hydrate-bearing cores that were acquired from Green Canyon Block 955 in UT-GOM2-1 Expedition and preserved within hydrate pressure–temperature stability conditions throughout sub-sampling and imaging processes. Measured hydrate saturation in the sub-samples, taken from units expected to have in-situ saturation of 80% or more, ranges from 3 ± 1% to 56 ± 11% as interpreted from micro-CT images. Pore-scale observations of gas hydrate in the sub-samples suggest that hydrate in silty sediments at the Gulf of Mexico is pore-invasive rather than particle displacive, and hydrate particles in these natural water-saturated samples are pore-filling with no evidence of grain-coating. Hydrate can form a connected 3D network and provide mechanical support for the sediments even without cementation. The technical breakthrough to directly visualize particle-level hydrate pore habits in natural sediments reported here sheds light on future investigations of pressure- and temperature-sensitive processes including hydrate-bearing sediments, dissolved gases, and other biochemical processes in the deep-sea environment.

58 GEOSCIENCES↗
DOE OSTI2024

Reactive transport modeling of organic carbon degradation in marine methane hydrate systems

Abstract Natural methane hydrate has often been observed in sand layers that contain no particulate organic carbon (POC), but are surrounded by organic-rich, fine-grained marine muds. In this paper, we develop a reactive transport model (RTM) of a microbially-mediated set of POC degradation reactions, including hydrolysis of POC driven by extracellular enzymes, fermentation of the resulting high-molecular weight dissolved organic carbon (HMW-DOC), and methanogenesis that consumes low-molecular weight dissolved organic carbon (LMW-DOC). These processes are mediated by two groups of microbes, fermenters and methanogens that are heterogeneously distributed in different lithologies, with the largest numbers of microbes in the large pores of coarse-grained layers. We find that the RTM can reproduce methane hydrate occurrences observed in two different geological environments, at Walker Ridge Site 313-H (Gulf of Mexico) and IODP Site U1325 (Cascadia Margin). We also find that microbes can degrade POC even if they are physically separated, as extracellular enzymes and DOC can diffuse away from where they are produced by microbes. Microbial activity is highest at relatively early times after burial at shallow depths and near lithological boundaries, where concentration gradients transport solutes to intervals that contain the most microbes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Global peak water limit of future groundwater withdrawals

Over the past 50 years, humans have extracted the Earth’s groundwater stocks at a steep rate, largely to fuel global agro-economic development. Given society’s growing reliance on groundwater, we explore ‘peak water limits’ to investigate whether, when and where humanity might reach peak groundwater extraction. Using an integrated global model of the coupled human–Earth system, we simulate groundwater withdrawals across 235 water basins under 900 future scenarios of global change over the twenty-first century. Here we find that global non-renewable groundwater withdrawals exhibit a distinct peak-and-decline signature, comparable to historical observations of other depletable resources (for example, minerals), in nearly all (98%) scenarios, peaking on average at 625 km 3 yr -1 around mid-century, followed by a decline through 2100. The peak and decline occur in about one-third (82) of basins, including 21 that may have already peaked, exposing about half (44%) of the global population to groundwater stress. Most of these basins are in countries with the highest current extraction rates, including the United States, Mexico, Pakistan, India, China, Saudi Arabia and Iran. Furthermore, these groundwater-dependent basins will probably face increasing costs of groundwater and food production, suggesting important implications for global agricultural trade and a diminished role for groundwater in meeting global water demands during the twenty-first century.

58 GEOSCIENCES↗
DOE OSTI2021

Estimation of the orientation of stress in the Earth’s crust without earthquake or borehole data

Abstract Mechanical stress acting in the Earth’s crust is a fundamental property that is important for a wide range of scientific and engineering applications. The orientation of maximum horizontal compressive stress can be estimated by inverting earthquake source mechanisms and measured directly from borehole-based measurements, but large regions of the continents have few or no observations. Here we present an approach to determine the orientation of maximum horizontal compressive stress by measuring stress-induced anisotropy of nonlinear susceptibility, which is the derivative of elastic modulus with respect to strain. Laboratory and Earth experiments show that nonlinear susceptibility is azimuthally dependent in an anisotropic stress field and is maximum in the orientation of maximum horizontal compressive stress. We observe this behavior in the Earth—in Oklahoma and New Mexico, U.S.A, where maximum nonlinear susceptibility coincides with the orientation of maximum horizontal compressive stress measured using traditional methods. Our measurements use empirical Green’s functions and solid-earth tides and can be applied at different temporal and spatial scales.

58 GEOSCIENCES↗
DOE OSTI2022

Experimental evidence for the impact of soil viruses on carbon cycling during surface plant litter decomposition

To date, the potential impact of viral communities on biogeochemical cycles in soil has largely been inferred from correlational evidence, such as virus-driven changes in microbial abundances, viral auxiliary metabolic genes, and links with soil physiochemical properties. To more directly test the impact of soil viruses on carbon cycling during plant litter decomposition, we added concentrated viral community suspensions to complex litter decomposer communities in 40-day microcosm experiments. Microbial communities from two New Mexico alpine soils, Pajarito (PJ) and Santa Fe (SF), were inoculated onto grass litter on sand, and three treatments were applied in triplicate to each set of microcosms: addition of buffer (no added virus), live virus (+virus), or killed-virus (+killed-virus) fractions extracted from the same soil. Significant differences in respiration were observed between the +virus and +killed-virus treatments in the PJ, but not the SF microcosms. Bacterial and fungal community composition differed significantly by treatment in both PJ and SF microcosms. Combining data across both soils, viral addition altered links between bacterial and fungal diversity, dissolved organic carbon and total nitrogen. Overall, we demonstrate that increasing viral pressure in complex microbial communities can impact terrestrial biogeochemical cycling but is context-dependent.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Assessing reservoir performance for geologic carbon sequestration in offshore saline reservoirs

Carbon capture and storage (CCS) is a technological strategy to reduce CO 2 emissions from hydrocarbon-based energy production and non-energy industrial emitters, like fertilizer and cement production. To expand the geographic opportunities for CCS, offshore geologic settings are increasingly considered for saline CO 2 storage, particularly where legacy oil and gas infrastructure may be repurposed for CO 2 transport and injection. In this context, the Gulf of Mexico (GoM), United States (U.S.), may offer tremendous opportunity for CCS because the surrounding states are among the largest CO 2 producers in the U.S. and there has been extensive oil and gas development over the last half century. Nevertheless, there remains significant uncertainty in how GoM reservoir/seal systems will respond to industrial-scale CO 2 injections, particularly in the context of meso-scale (1–10s of meters) permeability variations that are difficult to identify prior to injection. Such permeability variations can have significant impacts on CO 2 migration and fluid pressure propagation, both of which govern the overall effectiveness of the CCS project. This research uses ensemble simulation methods to quantify the influence of spatially variable and a priori unknown permeability fields on CO 2 plume development and fluid pressure propagation when CO 2 is injected at 1 MMt per year for ten years. Results show a number of characteristic patterns that reveal the substantial influence of both near- and far-field permeability on reservoir performance. By focusing on basin characteristics that are common among offshore basins worldwide, results from this study suggest that offshore CCS may be a feasible carbon management strategy in regions where offshore basins are proximal to industrial CO 2 sources.

42 ENGINEERING↗
DOE OSTI2021

Simulations of the shock-driven Kelvin–Helmholtz instability in inclined gas curtains

In this paper, we present simulation results for the two-dimensional, shock-driven Kelvin–Helmholtz instability. Simulations are performed with a Mach 2.0 shock propagating through a finite-thickness curtain of gas inclined at an angle α0=30° with respect to the shock plane. After the passage of the shock, the gas curtain is accelerated along its axis. A perturbation develops due to shock reflection near the lower wall, and a Kelvin–Helmholtz instability forms near the vertical center of the curtain. This is the first known numerical reproduction of these phenomena that have previously been observed in experiments with an inclined cylindrical gas column. The effects of varying Mach number and column width were explored in detail to complement experimental data. Additionally, the dependence of the Kelvin–Helmholtz wavelength on Mach number closely matches the relationship observed in experiments. This supports the notion that the observed instability is effectively two-dimensional and inviscid (like classical Kelvin–Helmholtz). The growth rate of the perturbations in the gas curtain was also found to be similar for different Mach numbers. The perturbation at the curtain foot, previously unreported in experiments, was found to have a similar relationship to Mach number as the Kelvin–Helmholtz instability. Both perturbation wavelengths are found to be proportional to layer width. Simulations were performed with the fast interfaces and transport in the atmosphere, an exascale ready, graphics processing unit-accelerated compressible flow solver developed at the University of New Mexico.

42 ENGINEERING↗
DOE OSTI2021

Preface to the Proceedings of the 23rd Topical Conference on High-Temperature Plasma Diagnostics

Measurements of phenomena advance our understanding of the physical universe. As our understanding grows, more precise measurements are required, as are measurements of new quantities. Diagnosis of a plasma requires developing new instruments, also called diagnostics, as well as new ways to analyze, interpret, synthesize, and correlate their measurements. Further, as computing power increases and multi-physics codes improve their accuracy, more precise measurements are needed to guide future code developments and to validate predictions of these simulation codes. The Topical Conference on High-Temperature Plasma Diagnostics is focused on presenting and documenting the most recent advances in these instrumentation areas for plasmas. The 23rd occurrence of this biennial conference took place on December 14–17, 2020, and was hosted by Los Alamos National Laboratory. Originally scheduled for June 2020 in Santa Fe, New Mexico, the conference was postponed and then held virtually due to the global COVID-19 pandemic. Conference times were adjusted and presentations were scheduled to meet the needs of attendees in Europe, the USA, and Asia.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

A fiber-coupled dispersion interferometer for density measurements of pulsed power transmission line electron sheaths on Sandia’s Z machine

A fiber-coupled Dispersion Interferometer (DI) is being developed to measure the electron density of plasmas formed in power flow regions, such as magnetically insulated transmission lines, on Sandia National Laboratories (SNL’s) Z machine [D. B. Sinars et al., Phys. Plasmas 27, 070501 (2020)]. The diagnostic operates using a fiber-coupled 1550 nm CW laser with frequency-doubling to 775 nm. The DI is expected to be capable of line-average density measurements between ∼1013 and 1019 cm−2. Initial testing has been performed on a well-characterized RF lab plasma [A. G. Lynn et al., Rev. Sci. Instrum. 80, 103501 (2009)] at the University of New Mexico to quantify the density resolution lower limits of the DI. Initial testing of the DI has demonstrated line-average electron density measurements within 9% of results acquired via a 94 GHz mm wave interferometer for line densities of ∼1 × 1014 cm−2, despite significant differences in probe beam geometries. The instrument will next be utilized for measurements on a ∼1 MA-scale pulsed power driver {MYKONOS [N. Bennett et al., Phys. Rev. Accel. Beams 22, 120401 (2019)] at SNL} before finally being deployed on SNL’s Z machine. The close electrode spacing (mm scale) on Z requires probe beam sizes of ∼1 mm, which can only be obtained with visible or near infrared optical systems, as opposed to longer wavelength mm wave systems that would normally be chosen for this range of density.

Hines, N. R. (ORCID:0000000315316465)↗
DOE OSTI2020

Murray Gell-Mann

Murray Gell-Mann, the preeminent architect of theoretical elementary-particle physics, died on 24 May 2019 in Santa Fe, New Mexico. He received the 1969 Nobel Prize “for his contributions and discoveries concerning the classification of elementary particles and their interactions.” His contributions to physics include many foundational ideas, such as the renormalization group, which is fundamental to quantum field theory and statistical mechanics.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Gradual domestication of root traits in the earliest maize from Tehuacán

Despite their importance in supplying nutrients, root traits related to maize domestication are scarce. We used laser ablation tomography to characterize the root architecture and anatomy of 5,300-y-old maize specimens recovered from San Marcos (Tehuacán, Mexico), revealing exquisite preservation of their cellular organization. Outer cortical cells contained thick and lignified walls typical of extant maize adapted to hard soils. By contrast, the absence of seminal roots is only found in the maize ancestor, teosinte. Two genes important for seminal root development had mutations that could relate to their absence. Our results indicate that some traits related to drought adaptation were not fully present in the earliest maize from Tehuacán, providing clues to conditions prevailing during early maize cultivation.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2022

Ten years of Gulf Coast ecosystem restoration projects since the Deepwater Horizon oil spill

A decade since coastal restoration began across U.S. Gulf of Mexico states after the Deepwater Horizon oil spill, it is timely to examine its collective effects relative to intended outcomes. Through 2021, allocated funds for 570 projects by state, federal, non-profit, and other entities approached half the unprecedented recovery settlements. The need for synthesis of restoration results to inform further expenditures is urgent. Yet, unlike the western and eastern U.S. coasts, this region lacks an entity charged with conducting environmental synthesis. Synthesis of the cumulative effects of large-scale restoration will encompass three challenging components: (1) understanding and accounting for synergistic and antagonistic effects; (2) incorporating long-term environmental trends and acute events; and (3) addressing the relative scale of restoration effects.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Weapons Radiochemistry: Trinity and Beyond

On July 16, 1945, the Trinity nuclear test exploded in the desert near Alamogordo, New Mexico. A variety of new diagnostic experiments were fielded in an effort to understand the detailed performance of the nuclear device. This paper describes a series of radiochemical experiments that were designed to measure the efficiency and neutron fluence of the test. These experiments, and the scientists who led them, laid the foundation of weapons radiochemistry for decades to come.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2021

A New Era of Nuclear Criticality Experiments: The First 10 Years of Comet Operations at NCERC

Comet is a general-purpose, heavy-duty, vertical-lift assembly designed for flexibility in conducting a variety of critical experiments. It is currently located at the National Criticality Experiments Research Center (NCERC) in Nevada. In the past, Comet resided at Technical Area-18 in Los Alamos, New Mexico, as part of the Los Alamos Critical Experiments Facility (LACEF). The Comet assembly was relocated to NCERC in 2008 and became fully operational in June of 2011. The first critical experiment performed on Comet at NCERC was a verification of one of the previous configurations of the Zeus experiment series. Over the next 10 years, many additional experiments followed including other Zeus configurations as well as completely new designs. This paper discusses the Comet vertical-lift assembly, the transition from LACEF to NCERC, and a selection of experiments that have been performed on Comet during its first 10 years of operation at NCERC.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

A New Era of Nuclear Criticality Experiments: The First 10 Years of Planet Operations at NCERC

Planet is a vertical-lift assembly machine currently located at the National Criticality Experiments Research Center (NCERC) at the Nevada National Security Site. In the past, Planet resided at Technical Area-18 in Los Alamos, New Mexico, as part of the Los Alamos Critical Experiments Facility (LACEF). Following the de-inventorying of LACEF, the Planet assembly was relocated to NCERC in 2008 and became fully operational in June of 2011. The Class Foils experiment, which involves stacking highly enriched uranium foils to obtain a critical configuration, was the first critical experiment performed on Planet. As a major component of the Nuclear Criticality Safety Class taught for the U.S. Department of Energy (DOE) Nuclear Criticality Safety Program, the Class Foils experiment allows personnel from all over the DOE complex to handle nuclear material and to complete the approach to critical safely and successfully. This paper describes the Planet vertical assembly and recent engineering upgrade and a selection of the experiments that have been performed on Planet since its transition to NCERC 10 years ago.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2022

Development of Conceptual Lead Cartridge Design to Perform Irradiation Experiments in VTR

This paper seeks to introduce the latest design of the Extended Length Test Assembly–Cartridge Lead (ELTA-CL) with associated thermal-hydraulic (TH) assessment and related experiment activities to support the critical component development performed by the ELTA-CL team (Los Alamos National Laboratory, Westinghouse Electric Company, and the University of New Mexico). The goal of the ELTA-CL program is to develop and validate an experimental capability to perform irradiation experiments in the Versatile Test Reactor (VTR) addressing Lead Fast Reactor (LFR) technology gaps, in support of the commercial development of advanced lead-cooled fast reactor concepts. Through a design maturation process and parametric study, a conceptual design is proposed to meet the requirements for material and corrosion testing. Thermal-hydraulic characteristics for the conceptual design at desired operating conditions are assessed with systems-level (one-dimensional) and computational fluid dynamics (three-dimensional) simulations. Along with the conceptual design work, experimental activities for the development of critical components such as the pump and flowmeter are undertaken. From both the modeling study and the experimental results, the design requirements of the Phase 1 ELTA-CL (e.g., 500°C and 2 m/s) are achievable with the current conceptual design. Additional design improvements and safety assessments at both steady-state and transient conditions for the final ELTA-CL design will be pursued.

42 ENGINEERING↗
DOE OSTI2023

Source Characterization of Volatile Organic Compounds at Carlsbad Caverns National Park

Carlsbad Caverns National Park (CAVE), located in southeastern New Mexico, experiences elevated ground-level ozone (O 3 ) exceeding the National Ambient Air Quality Standard (NAAQS) of 70 ppbv. It is situated adjacent to the Permian Basin, one of the largest oil and gas (O&G) producing regions in the US. In 2019, the Carlsbad Caverns Air Quality Study (CarCavAQS) was conducted to examine impacts of different sources on ozone precursors, including nitrogen oxides (NO x ) and volatile organic compounds (VOCs). Here, we use positive matrix factorization (PMF) analysis of speciated VOCs to characterize VOC sources at CAVE during the study. Seven factors were identified. Three factors composed largely of alkanes and aromatics with different lifetimes were attributed to O&G development and production activities. VOCs in these factors were typical of those emitted by O&G operations. Associated residence time analyses (RTA) indicated their contributions increased in the park during periods of transport from the Permian Basin. These O&G factors were the largest contributor to VOC reactivity with hydroxyl radicals (62%). Two PMF factors were rich in photochemically generated secondary VOCs; one factor contained species with shorter atmospheric lifetimes and one with species with longer lifetimes. RTA of the secondary factors suggested impacts of O&G emissions from regions farther upwind, such as Eagle Ford Shale and Barnett Shale formations. The last two factors were attributed to alkenes likely emitted from vehicles or other combustion sources in the Permian Basin and regional background VOCs, respectively.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

A very high energy hadron collider on the Moon

Abstract The long-term prospect of building a hadron collider around the circumference of a great circle of the Moon is sketched. A circular collider on the Moon (CCM) of ∼11 000 km in circumference could reach a proton–proton center-of-mass collision energy of 14 PeV—a thousand times higher than the Large Hadron Collider at CERN—optimistically assuming a dipole magnetic field of 20 T. Several aspects of such a project are presented, including siting, construction, availability of necessary materials on the Moon, and powering, as well as a discussion of future studies and further information needed to determine the more concrete feasibility of each. Machine parameters and vacuum requirements are explored, and an injection scheme is delineated. Other unknowns are set down. Due to the strong interest from multiple organizations in establishing a permanent Moon presence, a CCM could be the (next-to-) next-to-next-generation discovery machine for high-energy particle physics and a natural successor to next-generation machines, such as the proposed future circular collider at CERN or a super proton–proton collider in China, and other future machines, such as a collider in the Sea, in the Gulf of Mexico. A CCM would serve as an important stepping stone toward a Planck-scale collider sited in our Solar System.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗