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At least 829 records · Page 46

Characterization and Recovery of Rare Earths from Coal and By-Products [Poster]

Roughly 87% of REEs came from China in 2014. There is a potential national security and supply risk for critical rare earths for defense and clean energy: Y, Nd, Eu, Dy, Tb. They are not typically found in concentrated ores and are difficult to extract and separate. Because REs are not distributed evenly, there is an excess supply for some REs and shortages for other REs. Much of the recent research on coal utilization in the United States has focused upon the capture of pollutants such as acid gases, particulates, and mercury, and the greenhouse gas carbon dioxide. The possible recovery of rare earth elements from abundant coal and byproducts is an exciting new research area, representing a dramatic paradigm shift for coal. Additional data is needed on the rare earth contents of coals and byproducts in order to determine the most promising potential feed materials for extraction processes. Future work will likely focus on the characterization of coals and byproducts, as well as separation methods for rare earth recovery.

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Supercritical Carbon Dioxide Primary Power Large-Scale Pilot Plant

The United States electrical power generation fleet encompasses a wide range of technologies, ranging from traditional combustion-based power generation, to nuclear power, to renewable energy. While the distribution of these assets continues to shift due to economic and regulatory influences, coal combustion continues to be a key part of the US energy portfolio. Despite the relative maturity of coal combustion technology, improvements in overall fuel-to-power efficiency and generation flexibility are still possible and will improve both the economic and environmental factors of coal combustion. Echogen Power Systems proposes to lead a world-class team including the University of Missouri, Electric Power Research Institute and Louis Perry Associates in the design, construction and operation of a 10MWe coal-fired supercritical carbon dioxide (sCO 2 ) large-scale pilot. This transformational technology uses sCO 2 as a working fluid instead of water to achieve high thermodynamic efficiencies that can significantly exceed advanced steam-Rankine cycles. Further, the compact nature of sCO 2 turbomachinery offers capital cost and footprint advantages, and the low maintenance of a water-free power cycle can significantly reduce operation and maintenance (O&M) costs over conventional steam-Rankine systems. Recent integration studies of sCO 2 with coal combustion power plants highlight the significant improvements in plant efficiency that sCO 2 can offer relative to even advanced steam Rankine cycles. At commercial scales, coal-sCO 2 plant net efficiency is predicted to be 39-44.0% (HHV), or 10-20% higher output than conventional steam-Rankine systems, which will significantly improve the competitiveness of coal-fired generation. This proposal builds upon projects previously funded by the Department of Energy, including DE-FE0025959 (High-Efficiency Thermal Integration of Closed Supercritical CO 2 Brayton Power Cycles with Oxy-Fired Heaters) and DE-NE0008470 (Conceptual Design for sCO 2 Power Cycle Test Facility). An appropriately-scaled and properly designed and operated pilot project is essential to overcome the natural risk-aversion of the power generation industry and project financing community. The 10 MWe coal-fired sCO 2 pilot power plant proposed herein will reduce the technical and economic risk of this transformational technology, enabling commercial deployment at the conclusion of the project. For the second phase of this project, Echogen lead a team that completed and refined the pilot system conceptual system and key component designs resulting in the completion of a front-end-engineering-design (FEED) study, completed the NEPA review process, completed the permitting process for construction and operation, refined the techno-economic analysis of the proposed system at commercial scale and received commitments for Phase III cost share. The end result of the program will be to demonstrate the technical and economic superiority of the sCO 2 power cycle for coal-fired operation. Major risk elements will have been retired with sufficient operation at high power to enable the power generation industry to move forward with the first commercial deployment of this transformational system.

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APS Science 2020 (Vol. 2)

The U.S. Department of Energy's Advanced Photn Source (APS) is one of the world’s most productive x-ray light source facilities. Each year, the APS provides high-brightness x-ray beams to a diverse community of more than 5,000 researchers in materials science, chemistry, condensed matter physics, the life and environmental sciences, and applied research. Researchers using the APS produce over 2,000 publications each year detailing impactful discoveries, and solve more vital biological protein structures than users of any other x-ray light source research facility. APS x-rays are ideally suited for explorations of materials and biological structures; elemental distribution; chemical, magnetic, electronic states; and a wide range of technologically important engineering systems from batteries to fuel injector sprays, all of which are the foundations of our nation’s economic, technological, and physical well-being. The APS occupies an 80-acre site on the Argonne campus, about 25 miles from downtown Chicago, Illinois. It shares a site with the Center for Nanoscale Materials and the Advanced Protein Characterization Facility.

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Completed Drilling Permit (SECARB Phase III Work Product 3.2.6.a)

The Southeast Regional Carbon Sequestration Partnership’s (SECARB’s) Anthropogenic Test is a demonstration of the deployment of CO 2 capture, transport, geologic storage, and monitoring technologies. The capture component of the test takes place at the James M. Barry Electric Generating Plant in Bucks, Alabama. The capture facility utilizes post-combustion amine capture technology licensed from Mitsubishi Heavy Industries America to process flue gas from a coal-fired power unit at Plant Barry. The amount of CO 2 captured using this process is equivalent to the emissions produced when generating 25 megawatts (MW) of electricity. CO 2 captured at the plant is transported by pipeline for underground storage in a saline geologic formation within the Citronelle Dome. This project is one of the first and the largest fully-integrated commercial prototype coal-fired carbon capture and storage projects in the USA.

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Manufacture of Carbon Foam in Continuous Process at Atmospheric Pressure

CFOAM LLC has been manufacturing CFOAM® vitreous carbon foam from coal in panel form for several years. The process is currently set up in batch mode as two steps, where the first step is conducted at very high pressure. In order to reduce cost and increase capacity, a new process for making carbon foam is being developed that can be performed at atmospheric pressure. This advance in turn would enable the development of a continuous manufacturing process, which is also being pursued. Both carbon foam panels and light weight aggregates are being investigate. Progress on the evolution of the pilot scale manufacturing plant and initial results of processing, microstructure, properties and performance of carbon foam products made using this new process will be discussed. This project is being supported by a cooperative agreement with the Department of Energy – National Energy Technology Laboratory (DE-FOA-0002185, Area of Interest 4: Coal-Derived Carbon Foam Produced via a Continuous Process, award number DE-FE-0031992).

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Final Report on Reservoir Modeling (SECARB Phase III Work Product 4.2.4.c)

The SECARB Partnership Anthropogenic Test, located in the Southeast Unit of the Citronelle oilfield will inject CO 2 into the saline waters of the Cretaceous Paluxy sandstone formation for three years. In order to accurately model the injection, migration, and long-term fate of CO 2 in the subsurface, GEM, a Computer Modeling Group software program for transport and geochemical modeling, was selected for the simulation. GEM is a very robust compositional reservoir simulator, with all the necessary options available for modeling CO 2 trapping mechanisms (including solubility, residual gas and mineralization). This simulation tool is widely known and used in the petroleum and sequestration industries. A reservoir model was built, based on a previously developed comprehensive picture of the subsurface geology at the site (Work Product 4.2.1.d - Report on Subsurface Characterization for the Anthropogenic Test Project Site). This report describes in details the different inputs that were used to create the model as well as the results of the injection scenario in terms of achievable injection rates, plume extent and pressure response.

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Drill and Complete CO 2 Observation Wells (SECARB Work Product 5.2.2.b)

The following report contains details on the drilling and completion of the new wells D-9-8#2 and D-9-9#2, as well as the recompletion work for the previously temporarily abandoned D-4-13 and D-4-14 wells. Each of the four wells will be used for observation activities for the SECARB Phase III Anthropogenic Test. A drilling and completion narrative and an as built description of the well including drawings and material specifications for the D-9- 8#2 and D-9-9#2 are outlined in this report. An outline of the recompletion procedure for the D-4-13 and D-4-14 wells is also included.

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Decision Point on Anthropogenic Test (SECARB Work Product 6.2.1.a)

The Southeast Regional Carbon Sequestration Partnership’s (SECARB’s) Anthropogenic Test is a demonstration of the deployment of CO 2 capture, transport, geologic storage and monitoring technologies. The capture component of the test takes place at the James M. Barry Electric Generating Plant in Bucks, Alabama. The capture facility utilizes post-combustion amine capture technology licensed from Mitsubishi Heavy Industries America to process flue gas from a coal-fired power unit at Plant Barry. The amount of CO 2 captured using this process is equivalent to the emissions produced when generating 25 megawatts (MW) of electricity. CO 2 captured at the plant is transported by pipeline for underground storage in a saline geologic formation within the Citronelle Dome. This project is one of the first and the largest fully-integrated commercial prototype coal-fired carbon capture and storage projects in the USA.

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Site Design and Layout In Preparation for the Anthropogenic Test (SECARB Work Product 6.2.1.b)

Commercial-scale carbon capture and storage (CCS) technology deployment for the electrical utility industry will require a robust international R&D program with governmental support both in cost-share and in risk management. In an effort to comply with environmental legislation or regulation related to CO 2 , the electrical utility industry hopes to be in a position to make financial decisions on utility boiler sourced CCS technology and associated risk management by 2020.

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Staged OMB for Modular Gasifier/Burner

The goal of this final project report is to comprehensively summarize the work conducted on project DE-FE0031506. In accordance with the Statement of Project Objectives (SOPO), the University of Kentucky Center for Applied Energy Research (UK CAER) (Recipient) has developed a staged opposed multi-burner (OMB) gasifier, scaled down from a commercial gasification technology to utilize coal slurry as feed for the high-temperature gasification. The project involved the design, fabrication, commissioning, parametric testing, and performance validation of the entrained gasifier with multiple burners to narrow the major near-term technical gaps that impede the application of small-size gasification by modularizing the system. Project results verified the UK CAER approach to address the major technical challenges on the gasification modularization for a distributed application at a small scale of 1-5 MWe, while maintaining advantages in cost and flexibility, which include: 1) a cost-effective burner configuration to provide high flexibility in both load and fuel feed; 2) the modularized staged-OMB to provide better gasification performance such as a desired temperature profile, better fuel conversion, better gasification efficiency, and long lifetimes of the refractory wall and burners; and 3) load control simply through changing the number of burners firing. UK CAER’s staged gasifier configuration, fuel blend performance, and economic evaluation shows promise, as summarized in this report, as an effective means for improved gasification efficiency with reduced operation cost and process complexity.

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Transportation Design and Products Specification (SECARB Phase III Work Product 6.2.2.a)

The SECARB Anthropogenic Test at the Citronelle oil field in Mobile County, Alabama is the largest fully integrated coal-fired carbon capture, transportation and storage project in the United States. Constructed and funded by Southern Company and Mitsubishi Heavy Industries, the CO 2 capture facility at Alabama Power’s 2,657-megawatt Plant Barry captures up to 500 metric tons of CO 2 per day, the equivalent emissions from 25 MW of the plant’s power generation. Captured CO 2 is transported to the mature Citronelle oil field atop a 16,380 acre (66.3 km2 of surface area), geologic salt dome. Citronelle oil field is operated by Denbury Onshore, LLC. The CO 2 is injected through ten perforated intervals in the injection well casing at depths ranging from 9,436 ft to 9,800 ft into the porous and permeable sandstones of the Paluxy Formation. This report describes the transportation design and product specifications for captured CO 2 transported from the capture facility to the underground storage reservoir. CO 2 is transported through approximately 12 miles of pipeline from Plant Barry’s capture facility and is injected into the saline aquifer sandstones of the Paluxy formation at Citronelle oil field. The following outlines the details and characteristics of each point of transportation and the quality of CO 2 being transported.

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CO 2 Procurement Plan and Agreement (SECARB Phase III Work Product 7.2.1.a)

The Southeast Regional Carbon Sequestration Partnership’s (SECARB) Anthropogenic Test is a demonstration of the deployment of CO 2 capture, transport, geologic storage and monitoring technologies. The capture component of the test takes place at the James M. Barry Electric Generating Plant in Bucks, Alabama. The capture facility utilizes post-combustion amine capture technology licensed from Mitsubishi Heavy Industries America to process flue gas from a coal-fired power unit at Plant Barry. The amount of CO 2 captured using this process is equivalent to the emissions produced when generating 25 megawatts (MW) of electricity. CO 2 captured at the plant is transported by pipeline for underground storage in a saline geologic formation within the Citronelle Dome. This project is one of the first and the largest fully-integrated commercial prototype coal-fired carbon capture and storage projects in the US. This report will highlight the essential pieces necessary to bring CO 2 from the capture facility at Plant Barry to the Anthropogenic Test Site. They are: 1) the capture facility, 2) the pipeline and 3) the well site injection equipment.

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Inject and Store from 33,000 up to 182,500 metric tons of CO 2 (SECARB Phase III Work Product 8.2.2.a)

The Southeast Regional Carbon Sequestration Partnership’s (SECARB’s) Anthropogenic Test is a demonstration of the deployment of CO 2 capture, transport, geologic storage, and monitoring technologies. The capture component of the test takes place at the James M. Barry Electric Generating Plant in Bucks, Alabama. The capture facility utilizes post-combustion amine capture technology licensed from Mitsubishi Heavy Industries America to process flue gas from a coal-fired power unit at Plant Barry. The amount of CO 2 captured using this process is equivalent to the emissions produced when generating 25 megawatts (MW) of electricity. CO 2 captured at the plant is transported by pipeline for underground storage in a saline geologic formation within the Citronelle Dome. This project is one of the first and the largest fully-integrated commercial prototype coal-fired carbon capture and storage projects in the USA.

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Inject and Store from 33,000 up to 182,500 metric tons of CO 2 (2013) (SECARB Phase III Work Product 8.2.2.b)

The Southeast Regional Carbon Sequestration Partnership’s (SECARB’s) Anthropogenic Test is a demonstration of the deployment of CO 2 capture, transport, geologic storage, and monitoring technologies. The capture component of the test takes place at the James M. Barry Electric Generating Plant in Bucks, Alabama. The capture facility utilizes post-combustion amine capture technology licensed from Mitsubishi Heavy Industries America to process flue gas from a coal-fired power unit at Plant Barry. The amount of CO 2 captured using this process is equivalent to the emissions produced when generating 25 megawatts (MW) of electricity. CO 2 captured at the plant is transported by pipeline for underground storage in a saline geologic formation within the Citronelle Dome. This project is one of the first and the largest fully-integrated commercial prototype coal-fired carbon capture and storage projects in the USA. The material in this Report is intended for general information only.

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Inject and Store from 33,000 up to 182,500 metric tons of CO 2 (2014) (SECARB Phase III Work Product 8.2.2.c)

The Southeast Regional Carbon Sequestration Partnership’s (SECARB’s) Anthropogenic Test is a demonstration of the deployment of CO 2 capture, transport, geologic storage, and monitoring technologies. The capture component of the test takes place at the James M. Barry Electric Generating Plant in Bucks, Alabama. The capture facility utilizes post-combustion amine capture technology licensed from Mitsubishi Heavy Industries America to process flue gas from a coal-fired power unit at Plant Barry. The amount of CO 2 captured using this process is equivalent to the emissions produced when generating 25 megawatts (MW) of electricity. CO 2 captured at the plant is transported by pipeline for underground storage in a saline geologic formation within the Citronelle Dome. This project is one of the first and the largest fully-integrated commercial prototype coal-fired carbon capture and storage projects in the USA. The material in this report is intended for general information only.

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