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At least 829 records · Page 46
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Rate constant for the reaction of atomic oxygen with phosphine at 298 K

The rate constant for the reaction of atomic oxygen with phosphine has been measured at 298 K using flash photolysis combined with time-resolved detection of O(3P) via resonance fluorescence. Atomic oxygen was produced by flash photolysis of N2O or NO highly diluted in argon. The results were shown to be independent of (PH3), (O), total pressure and the source of O(3P). The mean value of all the experiments is k1 = (3.6 + or -0.8) x 10 to the -11th cu cm/s (1 sigma). Two previous measurements of k1 differed by more than an order of magnitude, and the results support the higher value obtained in a discharge flow-mass spectrometry study. A comparison with rate data for other atomic and free radical reactions with phosphine is presented, and the role of these reactions in the aeronomy or photochemistry of Jupiter and Saturn is briefly considered.

Stief, L. J.↗
NASA NTRS1987

Compilation and development of K-6 aerospace materials for implementation in NASA spacelink electronic information system

Spacelink is an electronic information service to be operated by the Marshall Space Flight Center. It will provide NASA news and educational resources including software programs that can be accessed by anyone with a computer and modem. Spacelink is currently being installed and will soon begin service. It will provide daily updates of NASA programs, information about NASA educational services, manned space flight, unmanned space flight, aeronautics, NASA itself, lesson plans and activities, and space program spinoffs. Lesson plans and activities were extracted from existing NASA publications on aerospace activities for the elementary school. These materials were arranged into 206 documents which have been entered into the Spacelink program for use in grades K-6.

Blake, Jean A.↗
NASA NTRS1987

Thermal response of integral multicomponent composites to a high-energy aerothermodynamic heating environment with surface temperature to 1800 K

Laminated composite insulations developed for potential use on advanced spacecraft operating between GEO and LEO were tested in an aerothermodynamic environment simulating an AOTV aerobraking maneuver (altitude 82.3 km and velocity = 9.0 km/s). Comparisons are discussed between these data and predictions of in-depth temperature response using dynamical thermal conductivity values to 2000 K.

Stewart, David A.↗
NASA NTRS1987

On the inability of magnetically constricted transition regions to account for the 10 to the 5th to 10 to the 6th K plasma in the quiet solar atmosphere

Static models of the plasma in the quiet solar atmosphere incorporating not only conduction and radiation but also the effects of large magnetic constrictions are examined. It is found that the bulk of the solar plasma at temperatures below 7 x 10 to the 5th K cannot be produced by a conductive transition region when it is modeled by flux tubes with constriction compatible with observations. The present findings suggest that the major portion of the UEV plasma may be maintained in an ensemble of small, individual magnetic loops located within the supergranular network and having peak temperatures ranging from chromospheric to coronal values.

Dowdy, James F., Jr.↗
NASA NTRS1988

A k-permutation algorithm for Fixed Satellite Service orbital allotments

A satellite system synthesis problem, the satellite location problem (SLP), is addressed in this paper. In SLP, orbital locations (longitudes) are allotted to geostationary satellites in the Fixed Satellite Service. A linear mixed-integer programming model is presented that views SLP as a combination of two problems: (1) the problem of ordering the satellites and (2) the problem of locating the satellites given some ordering. A special-purpose heuristic procedure, a k-permutation algorithm, that has been developed to find solutions to SLPs formulated in the manner suggested is described. Solutions to small example problems are presented and analyzed.

Reilly, Charles H.↗
NASA NTRS1988

Superconductivity up to 114 K in the Bi-Al-Ca-Sr-Cu-O compound system without rare-earth elements

Stable superconductivity up to 114 K has been reproducibly detected in Bi-Al-Ca-Sr-Cu-O multiphase systems without any rare-earth elements. Pressure has only a slight positive effect on T(c). These observations provide an extra material base for the study of the mechanism of high-temperature superconductivity and also the prospect of reduced material cost for future applications of superconductivity.

Chu, C. W.↗
NASA NTRS1988

The equilibrium constant for N2O5 = NO2 + NO3 - Absolute determination by direct measurement from 243 to 397 K

Direct determinations of the equilibrium constant for the reaction N2O5 = NO2 + NO3 were carried out by measuring NO2, NO3, and N2O5 using long-path visible and infrared absorption spectroscopy as a function of temperature from 243 to 397 K. The first-order decay rate constant of N2O5 was experimentally measured as a function of temperature. These results are in turn used to derive a value for the rate coefficient for the NO-forming channel in the reaction of NO3 with NO2. The implications of the results for atmospheric chemistry, the thermodynamics of NO3, and for laboratory kinetics studies are discussed.

Cantrell, C. A.↗
NASA NTRS1988

Ionization of K-shell electrons by highly relativistic protons

A comparative study of three theoretical formalisms by Anholt et al. (1976), Scofield (1978), and Becker et al. (1985) for K-shell ionization by highly relativistic protons has been carried out. The importance of the spin-flip mechanism is emphasized. It is concluded that in the analysis of such inner-shell ionization processes, an accurate description of the projectile-target interaction is of much more significance than the accuracy of the wave functions of the atomic electrons.

Rustgi, M. L.↗
NASA NTRS1988

The long-period K + Be binary HR 2577 (MWC 827)

New spectroscopic observations near H-alpha and Na I D, along with ultraviolet IUE scans, have been obtained for the K + Be composite system HR 2577. High-precision radial-velocity measures do not support the suggested 58-year orbit of Hendry (1982). The H-alpha emission from the Be component undergoes considerable variations typical of its class. The presence of a Li I 6707 A feature as well as the IUE observations support the idea that little or no interaction between the binary components of HR 2577 is taking place.

Dempsey, Robert C.↗
NASA NTRS1988

Relations between broad-band linear polarization and Ca II H and K emission in late-type dwarf stars

Broadband UBV linear polarization data acquired for a sample of late-type dwarfs are compared with contemporaneous measurements of Ca II H and K line core emission. A weighted average of the largest values of the polarization degree is shown to be the best parameter for chromospheric activity diagnosis. The average maximum polarization in the UV is found to increase from late-F to late-G stars. It is noted that polarization in the U band is considerably more sensitive to activity variations than that in the B or V bands. The results indicate that stellar magnetic fields and the resulting saturation in the Zeeman-sensitive absorption lines are the most probably source of linear polarization in late-type main-sequence stars.

Huovelin, Juhani↗
NASA NTRS1988

The Instrument Test Dewar (ITD): Testing satellite instruments at 1.5 K

The Instrument Test Dewar (ITD) is a cryogenic facility designed and built to test Cosmic Background Explorer (COBE) satellite instruments at 1.5 K. The facility provides a high vacuum and thermal environment with payload thermal, electrical and optical interfaces. There are two concentric vacuum spaces which are not hermitically sealed. The instrument vacuum space is 81.28 cm by 243.84 cm and is cooled by an LHe shroud. The guard vacuum space surrounds an LN2 shroud. There are two separate cryosorption pumping systems and a mechanical LHe pumping system. The data acquisition systems provide payload and housekeeping data. There have been various problems with the facility, and changes and improvements have been made to assure optimum test conditions. COBE instrument testing has been completed on structural, thermal model hardware and the protoflight units.

Milam, Laura J.↗
NASA NTRS1988

Dynamics of exploding magma chambers: Implications for K-T volcanism and mass extinctions

Although it is well known that unconfined chemical explosives may yield pressures to several megabars on detonation in air, the explosive literature has yet to be accessed by some contributors to the volcanological literature who've indicated that pressures in excess of the overburden and/or tensile cannot be obtained. Idealized ballistic assessments of pressures internal to volcanoes yield pressures in the hundreds of kilobar range upon correction by addition of friction, etc. Previous assessments of exploding magma chamber pressure have been made from the characteristics of the Mt. St. Helens explosion. A variety of methods yield pressures of similar value: at least hundreds of kilobars. Such results are consistent with free energy requirements for quench supersaturation explosion, a process occurring in solidifying industrial melts. Several reviews of geochemical literature emphasize the carbon event at the Cretaceous-Tertiary (K-T) boundary as being an indicator of a massive dump of CO2 derived from the mantle and entering the atmosphere by extensive global volcanism. Oxygen isotope data indicates extreme warming at the end of the Cretaceous which is consistent with a greenhouse effect attending the CO2 event. Reaction rate equations for the quench supersaturation explosion mechanism indicated, are consistent with the rise in pressure to 30 kbar on solidification of magmatic melts, these pressures limited by the strength of the experimental apparatus.

Rice, A. R.↗
NASA NTRS1988

Marine and continental K-T boundary clays compared

Detailed geochemical and mineralogical studies (1 to 5) of sediments across the Cretaceous-Tertiary (K-T) boundary at Stevns Klint, Karlstrup, Nye Klov, Dania, and Kjolby Gaard in Denmark, at Limhamn in Sweden, at Caravaca in Spain, at Waipara and Woodside Creek in New Zealand, at Trinidad in Colorado, and at various sites in Montana, have induced conclusions and reflections which are given and briefly discussed.

Schmitz, B.↗
NASA NTRS1989

Measurements of complex permittivity of microwave substrates in the 20 to 300 K temperature range from 26.5 to 40.0 GHz

A knowledge of the dielectric properties of microwave substrates at low temperatures is useful in the design of superconducting microwave circuits. Results are reported for a study of the complex permittivity of sapphire (Al2O3), magnesium oxide (MgO), silicon oxide (SiO2), lanthanum aluminate (LaAlO3), and zirconium oxide (ZrO2), in the 20 to 300 Kelvin temperature range, at frequencies from 26.5 to 40.0 GHz. The values of the real and imaginary parts of the complex permittivity were obtained from the scattering parameters, which were measured using a HP-8510 automatic network analyzer. For these measurements, the samples were mounted on the cold head of a helium gas closed cycle refrigerator, in a specially designed vacuum chamber. An arrangement of wave guides, with mica windows, was used to connect the cooling system to the network analyzer. A decrease in the value of the real part of the complex permittivity of these substrates, with decreasing temperature, was observed. For MgO and Al2O3, the decrease from room temperature to 20 K was of 7 and 15 percent, respectively. For LaAlO3, it decreased by 14 percent, for ZrO2 by 15 percent, and for SiO2 by 2 percent, in the above mentioned temperature range.

Miranda, Felix A.↗
NASA NTRS1989

Chromospherically active stars. VI - HD 136901 = UV CrB: A massive ellipsoidal K giant single-lined spectroscopic binary

The variable star HD 136901 = UV CrB is a chromospherically active K2 III single-lined spectroscopic binary with an orbital period of 18.665 days. It has modest-strength Ca H and K emission and UV features, while H-alpha is a strong absorption feature containing little or no emission. The inclination of the system is 53 + or - 12 deg. The v sin i of the primary is 42 + or - 2 km/s, resulting in a minimum radius of 15.5 + or - 0.8 solar. When compared with the Roche lobe radius, this results in a mass ratio of 2.90 or larger. Additional constraints indicate that the secondary has a mass between 0.85 and 1.25 solar. Thus, the mass of the primary is at least 2.5 solar and probably is in the range 2.5-4 solar.

Fekel, Francis C.↗
NASA NTRS1989

Correlation of molecular valence- and K-shell photoionization resonances with bond lengths

The relationship between the interatomic distance and the positions of valence-shell and K-shell sigma(asterisk) photoionization resonances is investigated theoretically for the molecules C2, F2, N2, O2, CO, NO, C2H2, C2H4, C2H6, HCN, H2CO, N20, CO2, and C2N2. The results of molecular-orbital computations are presented in three-dimensional diagrams, which are shown to be similar to the wave functions of a particle in a cylindrical well, confirming the validity of free-electron molecular-orbital (FEMO) approximations for modeling the potential along the symmetry axis. FEMO orbital energies and resonance positions are found to be in good agreement with previous theoretical and experimental results. Also included is a Feshbach-Fano analysis of the relevance of virtual-valence orbitals to the appearance of single-channel resonances in molecular photoionization cross sections.

Sheehy, J. A.↗
NASA NTRS1990

A comparison of analytical results for 20 K LOX/hydrogen instabilities

Test data from NASA Lewis' Effect of Thrust Per Element on Combustion Stability Characteristics of Hydrogen-Oxygen Rocket Engines test program are used to validate two recently released stability analysis tools. The first tool is a design methodology called ROCCID (ROCket Combustor Interactive Design). ROCCID is an interactive design and analysis methodology that uses existing performance and combustion stability analysis codes. The second tool is HICCIP (High frequency Injection Coupled Combustion Instability Program). HICCIP is a recently developed combustion stability analysis model. Using a matrix of models, results from analytic comparisons with 20 K LOX/H2 experimental data are presented.

Klem, Mark D.↗
NASA NTRS1990

Experiment K-6-08. Biochemical and histochemical observations of vastus medialis

Muscles of the hindlimb in the rat have been used to demonstrate the effects of unloading in weightlessness and in animal models used to mimic weightlessness. The vastus medialis (VM) is discussed here. Samples were obtained from rats exposed to weightlessness for 12 days in Cosmos 1887 (Experiment K-6-08, coordinated by Dr. V.S. Oganov). The principal objective of this study was to ascertain if the vastus medialis responded to 12 days of microgravity exposure. The loss in muscle mass is greatest, -43 percent, when comparing F vs B, and least, -13 percent, when comparing F vs. V. Taken at face value these differences may be misleading. Due to the variability of the muscle weight in the basal group, these muscle mass losses may be exaggerated. In terms of percent water, there were no differences between the flight and the control groups. In spite of the limited sample, researchers conclude that muscle mass changes in the VM are not significant. Although some of the morphological parameters suggest a small degree of atrophy in the vastus medialis, the biochemical analyses (protein, RNA and DNA) suggest that these may be minimal and functionally nonsignificant. The relatively similar CS and LDH activities of VM from F and various control groups, as well as the lack of difference in LPL activity between F and S rats, suggests that there is little or no effect on the oxidative or glycolytic function of this muscle. Since the VM is chiefly a mixed fast twitch muscle, these metabolic indices of energy production are relatively unchanged. The results of VM studies are in agreement with previous observations of another type II fast twitch muscle, the EDL, from SL-3 rats which did not respond markedly to weightlessness and whole body suspension.

Musacchia, X. J.↗