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At least 829 records · Page 46

Sinterless Fabrication Of Contact Pads On InP Devices

Research has shown that with proper choice of material, low-resistance contact pads deposited on solar cells and other devices by improved technique that does not involve sintering. Research directed at understanding mechanisms involved in contact-sintering process has resulted in identification of special group of materials that includes phosphides of gold, silver, and nickel; specifically, Au(2)P(3), AgP(2), and Ni(3)P. Incorporation of phosphide interlayer substantially reduces resistivity between gold current-carrying layer and indium phosphide substrate. Further research indicated only very thin interlayer of any of these compounds needed to obtain low contact resistance, without subjecting contact to destructive sintering process.

Weizer, Victor G.↗

The updated DESGW processing pipeline for the third LIGO/VIRGO observing run

The DESGW group seeks to identify electromagnetic counterpartsof gravitational wave events seen by the LIGO-VIRGO network, such as thoseexpected from binary neutron star mergers or neutron star- black hole mergers.DESGW was active throughout the first two LIGO observing seasons, followingup several binary black hole mergers and the first binary neutron star merger,GW170817. We describe the modifications to the observing strategy generationand image processing pipeline between the second (ending in August 2017)and third (beginning in April 2019) LIGO observing seasons. The modifica-tions include a more robust observing strategy generator, further parallelizationof the image reduction software and dierence imaging processing pipeline,data transfer streamlining, and a web page listing identified counterpart candi-dates that updates in real time. Taken together, the additional parallelizationsteps enable us to identify potential electromagnetic counterparts within fullycalibrated search images in less than one hour, compared to the 3-5 hours itwould typically take during the first two seasons. These performance improve-ments are critical to the entire EM followup community, as rapid identification(or rejection) of candidates enables detailed spectroscopic followup by multipleinstruments as soon as possible, leading to more information about the environ-ment immediately following such gravitational wave events.

Herner, Kenneth R.↗

Prioritization of Stockpile Maintenance with Layered Pareto Fronts

Difficult choices are required for a decision-making process where resources and budgets are increasingly constrained. This study demonstrates a structured decision-making approach using layered Pareto fronts to identify priorities about how to allocate funds between munitions stockpiles based on their estimated reliability, the urgency of needing available units, and the consequences if adequate numbers of units are not available. This case study, while specific to the characteristics of a group of munitions stockpiles, illustrates the general process of structured decision-making based on first identifying appropriate metrics that summarize the important dimensions of the decision, and then objectively eliminating non-contenders from further consideration. Finally, the final subjective stage incorporates user priorities to select the four stockpiles to receive additional maintenance and surveillance funds based on understanding the trade-offs and robustness to various user priorities.

42 ENGINEERING↗

Describing functional requirements for knowledge sharing communities

Human collaboration in distributed knowledge sharing groups depends on the functionality of information and communication technologies (ICT) to support performance. Since many of these dynamic environments are constrained by time limits, knowledge must be shared efficiently by adapting the level of information detail to the specific situation. This paper focuses on the process of knowledge and context sharing with and without mediation by ICT, as well as issues to be resolved when determining appropriate ICT channels. Both technology-rich and non-technology examples are discussed.

NASA Discipline Space Human Factors↗

Practical Implementation of Failure Mode and Effects Analysis for Safety and Efficiency in Stereotactic Radiosurgery

Purpose: To improve the safety and efficiency of a new stereotactic radiosurgery program with the application of failure mode and effects analysis (FMEA) performed by a multidisciplinary team of health care professionals. Methods and Materials: Representatives included physicists, therapists, dosimetrists, oncologists, and administrators. A detailed process tree was created from an initial high-level process tree to facilitate the identification of possible failure modes. Group members were asked to determine failure modes that they considered to be the highest risk before scoring failure modes. Risk priority numbers (RPNs) were determined by each group member individually and then averaged. Results: A total of 99 failure modes were identified. The 5 failure modes with an RPN above 150 were further analyzed to attempt to reduce these RPNs. Only 1 of the initial items that the group presumed to be high-risk (magnetic resonance imaging laterality reversed) was ranked in these top 5 items. New process controls were put in place to reduce the severity, occurrence, and detectability scores for all of the top 5 failure modes. Conclusions: FMEA is a valuable team activity that can assist in the creation or restructuring of a quality assurance program with the aim of improved safety, quality, and efficiency. Performing the FMEA helped group members to see how they fit into the bigger picture of the program, and it served to reduce biases and preconceived notions about which elements of the program were the riskiest.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

The Updated DESGW Processing Pipeline for the Third LIGO/VIRGO Observing Run

The DESGW group seeks to identify electromagnetic counterparts of gravitational wave events seen by the LIGO-VIRGO network, such as those expected from binary neutron star mergers or neutron star- black hole mergers. DESGW was active throughout the first two LIGO observing seasons, following up several binary black hole mergers and the first binary neutron star merger, GW170817. We describe the modifications to the observing strategy generation and image processing pipeline between the second (ending in August 2017) and third (beginning in April 2019) LIGO observing seasons. The modifications include a more robust observing strategy generator, further parallelization of the image reduction software and difference imaging processing pipeline, data transfer streamlining, and a public webpage listing identified counterpart candidates that updates in real time. Taken together, the additional parallelization steps enable us to identify potential electromagnetic counterpa rts within fully calibrated search images in less than one hour, compared to the 3-5 hours it would typically take during the first two seasons. These performance improvements are critical to the entire EM followup community, as rapid identification (or rejection) of candidates enables detailed spectroscopic followup by multiple instruments as soon as possible, leading to more information about the environment immediately following such gravitational wave events.

79 ASTRONOMY AND ASTROPHYSICS↗

Structural Effects on Solubility and Crystallinity in Polyamide Ionomers

Although polyamides have been an industrial staple for decades, their solubility and processability remain limited due to the strong hydrogen bonding between amide groups. Here, we report a family of polyamides in which aryl rings, alkyl spacers, sulfonate groups, and amide linkages are regularly spaced along the polymer backbone, allowing us to probe the structural elements that affect processability. We accessed these polymers through a synthetic route based on an expanded diamine monomer and characterized them through a range of physical and spectroscopic techniques. Our results show that the combination of sulfonate groups with increased amide content results in highly soluble polymers, which can dissolve in polar solvents such as water, methanol, and N,N-dimethylformamide. Infrared spectroscopy on the solid polymers shows that the aliphatic amides engage in hydrogen bonding with the sulfonate groups, thus inhibiting ion aggregation, crystallization, and microphase separation. These findings expand the avenue to sulfonate-containing polyamide chemistry and provide design rules for the synthesis of more processable ionic polyamides.

amides↗

Elemental characteristics of aerosols emitted from a coal-fired heating plant

Size differentiated aerosols were collected downstream from a heating plant fueled with eastern coal and analyzed using particle induced X-ray emission technique. Based on aerosol masses collected in various size ranges, the aerosol size distribution is determined to be trimodal, with the three peaks centered at 0.54 microns, 4.0 microns, and 11.0 microns, respectively. Of the various trace elements present in the aerosols, sulphur is the only element that shows very strong concentration in the smallest size group. Iron is strongly concentrated in the 4.0 micron group. Potassium, calcium, and titanium also exhibit stronger concentration in the 4.0 micron group than any other group. Other trace elements - vanadium, chromium, manganese, nickel, copper, and barium - are equally divided between the 0.54 microns and the 4.0 microns groups. Apparently, all of the trace elements - except S - enter aerosols during the initial formation and subsequent condensation phases in the combustion process. Excess concentration of sulphur in the 0.54 microns group can only be accounted for by recondensation of sulphur vapors on the combustion aerosols and gas-to-particle phase conversion of sulfate vapors at the stack top.

Singh, J. J.↗

A Photographic Atlas of Rock Breakdown Features in Geomorphic Environments

A primary goal of geomorphological enquiry is to make genetic associations between process and form. In rock breakdown studies, the links between process, inheritance and lithology are not well constrained. In particular, there is a need to establish an understanding of feature persistence. That is, to determine the extent to which in situ rock breakdown (e.g., aeolian abrasion or salt weathering) masks signatures of earlier geomorphic transport processes (e.g., fluvial transport or crater ejecta). Equally important is the extent to which breakdown during geomorphic transport masks the imprint of past weathering. The use of rock features in this way raises the important question: Can features on the surface of a rock reliably indicate its geomorphic history? This has not been determined for rock surfaces on Earth or other planets. A first step towards constraining the links between process, inheritance, and morphology is to identify pristine features produced by different process regimes. The purpose of this atlas is to provide a comprehensive image collection of breakdown features commonly observed on boulders in different geomorphic environments. The atlas is intended as a tool for planetary geoscientists and their students to assist in identifying features found on rocks on planetary surfaces. In compiling this atlas, we have attempted to include features that have formed 'recently' and where the potential for modification by another geomorphic process is low. However, we acknowledge that this is, in fact, difficult to achieve when selecting rocks in their natural environment. We group breakdown features according to their formative environment and process. In selecting images for inclusion in the atlas we were mindful to cover a wide range of climatic zones. For example, in the weathering chapter, clast features are shown from locations such as the hyper-arid polar desert of Antarctica and the semi-arid canyons of central Australia. This is important as some features (e.g., alveoli) occur across climate regimes. We have drawn on the published geomorphological literature and our own field experience. We use, where possible, images of extrusive igneous rocks as the data returned from Mars, Venus and the Moon indicates that this is the predominant rock type. One of the purposes of this atlas is to expand the range of surface features that are known to indicate a particular geomorphic environment or process history. The surface features on boulders in some environments such as aeolian and weathering are well understood. In contrast, those in fluvial or ejecta environments are not. Therefore we have presented a comprehensive assemblage of features that are likely to be produced in each of the geomorphic environments. We hope that this atlas will trigger more research on diagnostic features, particularly their morphometry and detailed morphology, their persistence and rates of formation. In this first edition of the atlas we detail the features found on clasts in three geomorphic environments: aeolian, fluvial and weathering. Future editions of the atlas will include chapters on ejecta, micro-impacts, coastal, colluvial, glacial and structural features.

Bourke, Mary C.↗

GALAXIES IN X-RAY GROUPS. III. SATELLITE COLOR AND MORPHOLOGY TRANSFORMATIONS

While the star formation rates and morphologies of galaxies have long been known to correlate with their local environment, the process by which these correlations are generated is not well understood. Galaxy groups are thought to play an important role in shaping the physical properties of galaxies before entering massive clusters at low redshift, and transformations of satellite galaxies likely dominate the buildup of local environmental correlations. To illuminate the physical processes that shape galaxy evolution in dense environments, we study a sample of 116 X-ray selected galaxy groups at z = 0.2-1 with halo masses of 10{sup 13}-10{sup 14} M{sub Sun} and centroids determined with weak lensing. We analyze morphologies based on Hubble Space Telescope imaging and colors determined from 31 photometric bands for a stellar mass-limited population of 923 satellite galaxies and a comparison sample of 16,644 field galaxies. Controlling for variations in stellar mass across environments, we find significant trends in the colors and morphologies of satellite galaxies with group-centric distance and across cosmic time. Specifically at low stellar mass (log (M{sub *}/M{sub Sun }) = 9.8-10.3), the fraction of disk-dominated star-forming galaxies declines from >50% among field galaxies to <20% among satellites near the centers of groups. This decline is accompanied by a rise in quenched galaxies with intermediate bulge+disk morphologies, and only a weak increase in red bulge-dominated systems. These results show that both color and morphology are influenced by a galaxy's location within a group halo. We suggest that strangulation and disk fading alone are insufficient to explain the observed morphological dependence on environment, and that galaxy mergers or close tidal encounters must play a role in building up the population of quenched galaxies with bulges seen in dense environments at low redshift.

79 ASTRONOMY AND ASTROPHYSICS↗

Chapter 22: Compressed Air Evaluation Protocol. The Uniform Methods Project: Methods for Determining Energy Efficiency Savings for Specific Measures

Compressed-air systems are used widely throughout industry for many operations, including pneumatic tools, packaging and automation equipment, conveyors, and other industrial process operations. Compressed-air systems are defined as a group of subsystems composed of air compressors, air treatment equipment, controls, piping, pneumatic tools, pneumatically powered machinery, and process applications using compressed air. A compressed-air system has three primary functional subsystems: supply, distribution, and demand. Air compressors are the primary energy consumers in a compressed-air system and are the primary focus of this protocol. The two compressed-air energy efficiency measures specifically addressed in this protocol are: High-efficiency/variable speed drive (VSD) compressor replacing modulating, load/unload, or constant-speed compressor; and Compressed-air leak survey and repairs. This protocol provides direction on how to reliably verify savings from these two measures using a consistent approach for each.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Chapter 22: Compressed Air Evaluation Protocol. The Uniform Methods Project: Methods for Determining Energy Efficiency Savings for Specific Measures (September 2011 - August 2020)

Compressed-air systems are used widely throughout industry for many operations, including pneumatic tools, packaging and automation equipment, conveyors, and other industrial process operations. Compressed-air systems are defined as a group of subsystems composed of air compressors, air treatment equipment, controls, piping, pneumatic tools, pneumatically powered machinery, and process applications using compressed air. A compressed-air system has three primary functional subsystems: supply, distribution, and demand. Air compressors are the primary energy consumers in a compressed-air system and are the primary focus of this protocol. The two compressed-air energy efficiency measures specifically addressed in this protocol are: high-efficiency/variable speed drive (VSD) compressor replacing modulating, load/unload, or constant-speed compressor; compressed-air leak survey and repairs. This protocol provides direction on how to reliably verify savings from these two measures using a consistent approach for each.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Exposure to Microgravity for 30 Days Onboard Bion M1 Caused Muscle Atrophy and Decreased Regeneration in the Mouse Femoral Quadriceps

Mechanical unloading of muscle during spaceflight in microgravity is known to cause muscular atrophy, changes in muscle fiber type composition, gene expression, and reductions in regenerative muscle growth. Although limited data exists for long-term effects of microgravity in human muscle, these processes have mostly been studied in rodents for short periods of time. Here we report on how 30-day, long-term, mechanical unloading in microgravity affects mouse muscle of the femoral Quadriceps group. To conduct these studies we used muscle tissue from 6 mice from the NASA Biospecimen Sharing Program conducted in collaboration with the Institute for Biomedical Problems of the Russian Academy of Sciences, during the Russian Bion M1 biosatellite mission in 2013. Muscle morphology observed in histological sections shows signs of extensive atrophy and regenerative hypoplasia. Specifically, we observed a two-fold decrease in the number of myonuclei, their central location, low density of myofibers and myofibrils, in fragmentation and swelling of myofibers. Despite obvious atrophy, muscle regeneration nevertheless appears to have continued after 30 days in microgravity as evidenced by thin and short newly formed myofibers. Many of them however showed evidence of apoptotic, TUNEL positive cells and myofibrils degradation, suggesting long-term unloading in microgravity affects late stages of myofiber differentiation. Ground asynchronous and vivarium control animals showed normal, well-developed tissue structure with sufficient blood and nerve supply and evidence of regenerative formation of new myofibers free of apoptotic nuclei. Myonuclei stress response in spaceflight animals was detected by positive nuclear immunolocalization of c-jun and c-myc proteins. Regenerative activity of satellite cells in muscles is detected in mice of all animal groups, by pax7, MyoD, and myogenin immunostaining and myogenin PCR analysis. In summary, long-term spaceflight in microgravity causes significant atrophy and degeneration of the femoral Quadriceps muscle group, and it may interfere with muscle regenerative processes by inducing apoptosis in newly-formed myofibrils during their differentiation phase.

Grigoryan, E. N.↗

An Overview of NASA's Program of Future M&S VV&A Outreach and Training Activities

NASA's Exploration Systems Mission Directorate (ESMD) is implementing a management approach for modeling and simulation (M&S) that will provide decision-makers information on the model s fidelity, credibility, and quality. The Integrated Modeling & Simulation Verification, Validation and Accreditation (IM&S W&A) process will allow the decision-maker to understand the risks involved in using a model s results for mission-critical decisions. The W&A Technical Working Group (W&A TWG) has been identified to communicate this process throughout the agency. As the W&A experts, the W&A NVG will be the central resource for support of W&A policy, procedures, training and templates for documentation. This presentation will discuss the W&A Technical Working Group s outreach approach aimed at educating M&S program managers, developers, users and proponents on the W&A process, beginning at MSFC with the CLV program.

Caine, Lisa↗

CMIP7 Data Request: atmosphere priorities and opportunities

This paper presents a comprehensive overview of the Coupled Model Intercomparison Project Phase 7 (CMIP7) request for data unlocking key research avenues in atmospheric science and provides justification for the resources needed to produce this data. Topics within the CMIP7 Atmosphere Theme centre around processes and feedbacks in atmospheric science such as clouds, aerosols and atmospheric chemistry, atmospheric circulation, temperature variability and extremes, radiative forcings, and Earth system model evaluation. These topics are summarised in this paper as scientific “opportunities” which will be realised through CMIP7 experiments and Earth system model outputs. These opportunities were submitted by a thematic group of atmospheric science community representatives combined with an extended consultation process. The production of these variables will close key gaps and uncertainties identified during previous rounds of CMIP, and will be broadly used by scientific, policy, governmental, industry, and other communities that rely on climate model projections for research and decision making, including supporting the 7th Intergovernmental Panel on Climate Change Assessment Report (AR7). As an author group, we also reflect on the process used to collate this data request and make recommendations to future CMIP governance on implementing a consultation on this scale in the future.

58 GEOSCIENCES↗

Reaction Pathways and Intermediates in Selective Ring Opening of Biomass-Derived Heterocyclic Compounds by Iridium

While the catalytic hydrogenolysis of biomass-derived aromatic cyclic compounds to functionalized long chain alcohols and polyols has been known for decades, the factors that control the selectivity remain either unknown or controversial. Previous reports have hypothesized full ring saturation of the aromatic ring is necessary prior to hydrogenolysis. Contradictorily, recent studies have shown hydrogenolysis occurs prior to the saturation of the conjugated bonds. Furthermore, it has been assumed the functional groups present are fully reduced prior to hydrogenolysis; however, this has not been shown a priori. In order to resolve these controversies, we combine density functional theory and high-resolution electron energy loss spectroscopy (HREELS) to probe the catalytic hydrogenolysis of saturated and unsaturated heterocyclic molecules (furan, furfural, furfuryl alcohol, and tetrahydrofurfuryl alcohol) on iridium. Our results reveal that full saturation of the aromatic ring is not only unnecessary but leads to slower kinetics and differing selectivities. In contrast to previous studies, we show selective partial ring saturation can enhance the kinetics of the hydrogenolysis process. We report reduction/oxidation of the functional group leads to a change in the electronegativity, resulting in a change in selectivity. These results provide important mechanistic insights allowing for further improvement of catalysts for the effective transformations of biomass-derived oxygenates to value-added products.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Limitations of spectral measures and observations of the group structure of surface waves

Wave-group structure, which plays a significant role in flux processes and the mechanics of the transfer of wave energy and momentum to the mean current field, is studied. The origin of wave groups, in particular sideband instabilities, the effects of amplitude variations on wave frequency and of wave damping on isolated groups, and flow separation over waves, is discussed. The mechanisms that cause the group formation are compared to the dynamics that result in wave propagation. The bifurcation and shift in wave modulations, and the possible existence of a unique asymptotic statistical state for the wave-modulation field are examined.

Mollo-Christensen, Erik↗