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DOE OSTI2021

Incidence, scaling relations and physical conditions of ionized gas outflows in MaNGA

ABSTRACT In this work, we investigate the strength and impact of ionized gas outflows within z ∼ 0.04 MaNGA galaxies. We find evidence for outflows in 322 galaxies ($12{{\ \rm per\ cent}}$ of the analysed line-emitting sample), 185 of which show evidence for hosting an active galactic nucleus (AGN). Most outflows are centrally concentrated with a spatial extent that scales sublinearly with Re. The incidence of outflows is enhanced at higher masses, central surface densities, and deeper gravitational potentials, as well as at higher star formation rate (SFR) and AGN luminosity. We quantify strong correlations between mass outflow rates and the mechanical drivers of the outflow of the form $\dot{M}_{\rm out} \propto \rm SFR^{0.97}$ and $\dot{M}_{\rm out} \propto L_{\rm AGN}^{0.55}$. We derive a master scaling relation describing the mass outflow rate of ionized gas as a function of M⋆, SFR, Re, and LAGN. Most of the observed winds are anticipated to act as galactic fountains, with the fraction of galaxies with escaping winds increasing with decreasing potential well depth. We further investigate the physical properties of the outflowing gas finding evidence for enhanced attenuation in the outflow, possibly due to metal-enriched winds, and higher excitation compared to the gas in the galactic disc. Given that the majority of previous studies have focused on more extreme systems with higher SFRs and/or more luminous AGN, our study provides a unique view of the non-gravitational gaseous motions within ‘typical’ galaxies in the low-redshift Universe, where low-luminosity AGN and star formation contribute jointly to the observed outflow phenomenology.

Avery, Charlotte R.↗

DOE OSTI2022

Decoding the star forming properties of gas-rich galaxy pairs

Here we extend the analysis of Bok et al. (2020) in which the H i content of isolated galaxies from the AMIGA (Analysis of the interstellar Medium in Isolated GAlaxies) sample and selected paired galaxies from ALFALFA (Arecibo Legacy Fast ALFA) were examined as a potential driver of galaxy location on the WISE (Wide-field Infrared Survey Explorer) mid-infrared SFR–M * sequence. By further characterizing the isolated and pair galaxy samples, i.e. in terms of optical galaxy morphology, a more detailed and quantitative description of local galaxy environment by way of the local number density (η) and tidal strength (Q) parameters, star formation efficiency (SFE HI ), and H i integrated profile asymmetries, we present plausible pathways for the broadening of the pair sample H i deficiency distribution towards both high and low deficiencies compared to the narrower isolated galaxy sample distribution (i.e. σ PAIRS = 0.34 versus σ AMIGA = 0.28). We associate the gas-rich tail of the pair deficiency distribution with the highest Q values, large profile asymmetries, and low SFEs. From this, we infer that merger activity is enhancing gas supplies, as well as disrupting the efficiency of star formation, via strong gravitational torques. The gas-poor wing of the deficiency distribution appears to be populated with galaxies in denser environments (with larger η values on average), more akin to groups. Despite our gas-rich selection criterion, there is a small population of early-type galaxies in the pair sample, which primarily fall in the positive deficiency wing of the distribution. These results suggest that a combination of a denser galaxy environment, early-type morphology, and higher stellar mass is contributing to the broadening of the deficiency distribution towards larger deficiencies.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2022

SDSS-IV MaNGA: the chemical co-evolution of gas and stars in spiral galaxies

ABSTRACT We investigate archaeologically how the metallicity in both stellar and gaseous components of spiral galaxies of differing masses evolve with time, using data from the SDSS-IV MaNGA survey. For the stellar component, we can measure this evolution directly by decomposing the galaxy absorption-line spectra into populations of different ages and determining their metallicities. For the gaseous component, we can only measure the present-day metallicity directly from emission lines. However, there is a well-established relationship between gas metallicity, stellar mass, and star formation rate which does not evolve significantly with redshift; since the latter two quantities can be determined directly for any epoch from the decomposition of the absorption-line spectra, we can use this relationship to infer the variation in gas metallicity over cosmic time. Comparison of present-day values derived in this way with those obtained directly from the emission lines confirms the validity of the method. Application of this approach to a sample of 1619 spiral galaxies reveals how the metallicity of these systems has changed over the last 10 billion yr since cosmic noon. For lower-mass galaxies, both stellar and gaseous metallicity increase together, as one might expect in well-mixed fairly isolated systems. In higher-mass systems, the average stellar metallicity has not increased in step with the inferred gas metallicity, and actually decreases with time. Such disjoint behaviour is what one might expect if these more massive systems have accreted significant amounts of largely pristine gas over their lifetimes, and this material has not been well mixed into the galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2022

MASCOT: molecular gas depletion times and metallicity gradients – evidence for feedback in quenching active galaxies

ABSTRACT We present results from the first public data release of the MaNGA-ARO Survey of CO Targets (MASCOT), focusing our study on galaxies whose star formation rates and stellar masses place them below the ridge of the star-forming main sequence. In optically selected type 2 AGN/low-ionization nuclear emission regions (LINERs)/Composites, we find an empirical relation between gas-phase metallicity gradients ∇Z and global molecular gas depletion times $t_{\rm dep} = M_{\rm H_2} /{\rm SFR}$ with ‘more quenched’ systems showing flatter/positive gradients. Our results are based on the O3N2 metallicity diagnostic (applied to star-forming regions within a given galaxy), which was recently suggested to also be robust against emission by diffuse ionized gas (DIG) and LINERs. We conduct a systematic investigation into possible drivers of the observed ∇Z − tdep relation (ouflows, gas accretion, in situ star formation, mergers, and morphology). We find a strong relation between ∇Z or tdep and centralized outflow strength traced by the [O iii] velocity broadening. We also find signatures of suppressed star formation in the outskirts in AGN-like galaxies with long depletion times and an enhancement of metals in the outer regions. We find no evidence of inflows impacting the metallicity gradients, and none of our results are found to be significantly affected by merger activity or morphology. We thus conclude that the observed ∇Z–tdep relation may stem from a combination of metal redistribution via weak feedback, and a connection to in situ star formation via a resolved mass-metallicity–SFR relation.

Astronomy & Astrophysics↗

DOE OSTI2023

The GMRT archive atomic gas survey – II. Mass modelling and dark matter halo properties across late-type spirals

Studying the kinematics and mass modelling of galaxies from H i 21 cm data provides valuable insights into the properties of both the baryonic components and the dark matter halo in nearby galaxies. Despite many observational studies, mass modelling of galaxies remains challenging due to different limitations. For example, most of the previous studies involving mass modelling are based on rotation curves derived from 2D velocity fields from H i or H α spectroscopic observation which are often affected by beam smearing and projection effect. However, kinematic modelling done by fitting the ‘Tilted ring model’ to 3D data cube is not affected by these issues. In this study, we present and compare 3D kinematic modelling of a pilot sample of 11 galaxies from the GMRT archive atomic gas survey (GARCIA) using two different publicly available pipelines. We model the observed H i rotation curve using 3.6-μm infrared data and SDSS r-band data for stellar contribution, H i surface density profile for gas, and Navarro–Frenk–White profile for dark matter halo; and employ the Markov chain Monte Carlo optimization method for parameter estimation. Further, to validate our analysis, we revisit important scaling relations, e.g. the M gas –M star relation, M star –M halo relation, M gas –M halo relation and Baryonic Tully–Fisher relation. Here, the scaling relations from our analysis are broadly consistent with that reported in the literature. A larger sample of galaxies from GARCIA in the near future will allow studying these scaling relations in greater details.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2023

Gas metallicity distributions in SDSS-IV MaNGA galaxies: what drives gradients and local trends?

ABSTRACT The gas metallicity distributions across individual galaxies and across galaxy samples can teach us much about how galaxies evolve. Massive galaxies typically possess negative metallicity gradients, and mass and metallicity are tightly correlated on local scales over a wide range of galaxy masses; however, the precise origins of such trends remain elusive. Here, we employ data from SDSS-IV MaNGA to explore how gas metallicity depends on the local stellar mass density and on galactocentric radius within individual galaxies. We also consider how the strengths of these dependencies vary across the galaxy mass-size plane. We find that radius is more predictive of local metallicity than stellar mass density in extended lower-mass galaxies, while we find density and radius to be almost equally predictive in higher-mass and more compact galaxies. Consistent with previous work, we find a mild connection between metallicity gradients and large-scale environment; however, this is insufficient to explain variations in gas metallicity behaviour across the mass-size plane. We argue our results to be consistent with a scenario in which extended galaxies have experienced smooth gas accretion histories, producing negative metallicity gradients over time. We further argue that more compact and more massive systems have experienced increased merging activity that disrupts this process, leading to flatter metallicity gradients and more dominant density-metallicity correlations within individual galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2025

Seedless nonresonant gas-flow velocimetry with single-shot coherent Rayleigh-Brillouin scattering

We demonstrate neutral gas-flow velocimetry by exploiting the optical dipole forces exerted by precisely tailored high-intensity laser fields on polarizable particles, in the form of single-shot coherent Rayleigh-Brillouin scattering (CRBS). This enables mapping of the velocity distribution function of the particles in a single laser shot of approximately 200 ns duration, allowing us to perform spectroscopic measurements in the time, rather than the frequency, domain. Importantly, CRBS results in a coherent signal beam, which renders the technique ideal for measurements in optically noisy environments. By correlating the time shift of the resulting spectrum to the Doppler shift caused by the bulk motion of particles, we perform neutral gas-flow velocimetry without the need to seed the flow, nondestructively, for a variety of gases, atomic or molecular. We demonstrate gas-flow velocimetry at flow velocities as low as 1 m ⁢s −1 , with similar velocity resolution, while temperature and gas density can also be estimated from the same single-shot spectra. To prove the effectiveness of the measurement technique, we benchmark it against Pitot tube measurements, which show excellent agreement.

Gerakis, Alexandros [Luxembourg Institute of Scien↗

DOE OSTI2025

Missing baryons recovered: A measurement of the gas fraction in galaxies and groups with the kinematic Sunyaev-Zel’dovich effect and CMB lensing

We present new constraints on the halo masses and matter density profiles of DESI galaxy groups by cross-correlating samples of luminous red galaxies (LRGs) and bright galaxy survey (BGS) galaxies with the publicly available CMB lensing convergence map from ACT DR6. This provides an independent, lensing-based calibration of halo masses, complementary to methods relying on clustering or dynamics. We derive constraints on the mean halo mass for three DESI-selected samples, finding log⁡(𝑀 halo /(𝑀 ⊙ /ℎ)) ≈ 13.18, 13.03 and 13.02 for the main LRG, extended LRG, and BGS samples, respectively. Using a halo model approach, we also compare the projected galaxy-matter density profiles with previously reported gas profiles inferred from measurements of the kinematic Sunyaev-Zel’dovich (kSZ) effect. This work addresses one of the key uncertainties in interpreting kSZ signals—the unknown host halo mass distribution—by providing an independent and consistent mass calibration. The agreement between the gas and total mass profiles at large aperture suggests that sufficiently far from the group center (2–3 virial radii), we recover all the baryons, offering a resolution to the missing baryon problem. We further study the cumulative gas fractions for all galaxies as well as for the most massive galaxy groups in the sample [log⁡(𝑀 halo /(𝑀 ⊙ /ℎ)) ≈ 13.5], finding values that are physically sensible and in agreement with previous findings using kSZ and x-ray data: compared to the TNG300 simulation, the observed gas fractions are systematically lower at fixed radius by ≳ 4⁢𝜎, providing compelling, independent evidence for stronger baryonic feedback in the real Universe. These findings highlight the power of combining CMB lensing with galaxy surveys to probe the interplay between baryons and dark matter in group-sized halos.

Hadzhiyska, Boryana [Lawrence Berkeley National La↗

DOE OSTI2024

Impact of mid- Z gas fill on dynamics and performance of shock-driven implosions at the OMEGA laser

Shock-driven implosions with 100% deuterium (D 2 ) gas fill compared to implosions with 50:50 nitrogen-deuterium (N 2 ⁢D 2 ) gas fill have been performed at the OMEGA laser facility to test the impact of the added mid-Ζ fill gas on implosion performance. Ion temperature (Τ ion ) as inferred from the width of measured DD-neutron spectra is seen to be 34%±6% higher for the N 2⁢ D 2 implosions than for the D 2 -only case, while the DD-neutron yield from the D 2 -only implosion is 7.2±0.5 times higher than from the N 2⁢ D 2 gas fill. The T ion enhancement for N 2 ⁢D 2 is observed in spite of the higher Z, which might be expected to lead to higher radiative loss, and higher shock strength for the D 2 -only versus N 2 ⁢D 2 implosions due to lower mass, and is understood in terms of increased shock heating of N compared to D, heat transfer from N to D prior to burn, and limited amount of ion-electron-equilibration-mediated additional radiative loss due to the added higher-Z material. Further, this picture is supported by interspecies equilibration timescales for these implosions, constrained by experimental observables. The one-dimensional (1D) kinetic Vlasov-Fokker-Planck code ifp and the radiation hydrodynamic simulation codes hyades (1D) and xrage [1D, two-dimensional (2D)] are brought to bear to understand the observed yield ratio. Comparing measurements and simulations, the yield loss in the N 2 ⁢D 2 implosions relative to the pure D 2 -fill implosion is determined to result from the reduced amount of D 2 in the fill (fourfold effect on yield) combined with a lower fraction of the D 2 fuel being hot enough to burn in the N 2 ⁢D 2 case. The experimental yield and T ion ratio observations are relatively well matched by the kinetic simulations, which suggest interspecies diffusion is responsible for the lower fraction of hot D 2 in the N 2 ⁢D 2 relative to the D 2 -only case. The simulated absolute yields are higher than measured; a comparison of 1D versus 2D XRAGE simulations suggest that this can be explained by dimensional effects. The hydrodynamic simulations suggest that radiative losses primarily impact the implosion edges, with ion-electron equilibration times being too long in the implosion cores. The observations of increased T ion and limited additional yield loss (on top of the fourfold expected from the difference in D content) for the N 2 ⁢D 2 versus D 2 -only fill suggest it is feasible to develop the platform for studying CNO-cycle-relevant nuclear reactions in a plasma environment.

47 OTHER INSTRUMENTATION↗

DOE OSTI2025

Changing Interactions Between Trace Gas Fluxes, Belowground Chemistry, and Plant Traits Across an Arctic Thermokarst Landscape

Arctic permafrost soils are increasingly subject to thermokarst that is, abrupt ground subsidence caused by thaw. Wetlands can form within these depressions, leading to changes in organic matter decomposition and gas fluxes (CO 2 , CH 4 , N 2 O, NH 3 ). Thermokarst wetlands tend to be dominated by graminoids, while surrounding upland tussock tundra tends to be dominated by mixed communities of shrubs and graminoids. Here, to investigate how thermokarst alters the land-atmosphere exchange of C and N gases in Arctic tundra, we analyzed soil, porewater, above- and belowground biomass, and measured gas fluxes across dominant plant functional types (PFTs) within a lowland thermokarst wetland and adjacent upland tussock tundra. Both locations were overall sinks of CO 2 , sources of CH 4 , and sources of both N 2 O and NH 3 . We found that thermokarst wetlands emitted enough CH 4 to generate a positive radiative forcing in CO 2 equivalents (+1.2 μmol m −2 s −1 CO 2 -eq), counteracting the high CO 2 uptake. In contrast, the upland tussock tundra had a net negative radiative forcing (−1.2 μmol m −2 s −1 CO 2 -eq). Differences in gas flux and soil chemistry between upland and lowland are primarily driven by flooded conditions present in thermokarst wetland. Additionally, root biomass from graminoids across both lowlands and uplands significantly correlated with CH 4 fluxes, supporting previous observations of plant-mediated transport of CH 4 . Graminoid cover was correlated with increases in low molecular weight dissolved organic carbon, possibly associated with root exudates that fuel methanogenesis. Forb cover in the upland tussock tundra was significantly correlated with nine soil chemical variables, indicating that forbs may influence local soil chemistry or conversely, that soil chemistry controls where forbs grow. Overall, our findings indicate the variability in gas fluxes in the upland tussock tundra is partially controlled by PFT cover, while thermokarst wetlands emit enough CH 4 to counteract CO 2 uptake, with implications for carbon budget changes in Arctic systems.

Land-atmosphere feedback↗

DOE OSTI2020

Comparing energy and water use of aqueous and gas-based metalworking fluids

Gas-based metalworking fluids (MWFs) have been proposed as alternative coolants and lubricants in machining operations to mitigate concerns surrounding water use and pollution, industrial hygiene, occupational health, and performance limitations associated with water-based (aqueous) MWFs that are ubiquitously used in the metals manufacturing industry. This study compares the primary energy and water use associated with the consumptive use, delivery, and disposal of aqueous MWFs with three gas-based MWFs in the literature-minimum quantity lubricant-in-compressed air (MQL), liquid/gaseous N-2, and liquid/supercritical CO2. The comparison accounts for reported differences in machining performance in peer-reviewed experimental studies across several machining processes and materials. The analysis shows that despite the reported improvement in tool life with N-2 and CO2-based MWFs, the electricity- and water-intensive separation and purification processes for N-2 and CO2 lead to their higher primary energy and water use per volume of material machined relative to water-based MWFs. Although MQL is found to have lower primary energy use, significant consumptive water use associated with the vegetable oil commonly used with this MWF leads to higher overall water use than aqueous MWF, which is operated in a recirculative system. Gas-based MWFs thus shift the water use upstream of the manufacturing plant. Primary energy and water use of gas-based MWFs could be reduced by focusing on achieving higher material removal rates and throughput compared to aqueous MWF instead of solely targeting improvements in tool life. Additionally, the consumptive use of CO2 and N-2 MWFs could be minimized by optimizing their flow rates and delivery to precisely meet the cooling and lubrication needs of specific machining processes instead of flooding the tool and workpiece with these gases. This article met the requirements for a gold-gold JIE data openness badge described at http://jie.click/badges.

cutting fluids↗

DOE OSTI2021

A Compact Gas Liquid Separator for the Spallation Neutron Source Mercury Process Loop

Upgrades at the spallation neutron source (SNS) accelerator at Oak Ridge National Laboratory are underway to double its proton beam power from 1.4 to 2.8 MW. About 2 MW will go to the current first station while the rest will go to the future Second Target Station. The increase of beam power to the first target station is especially challenging for its mercury target. When the short proton beam hits the target, strong pressure waves are generated, causing cavitation erosion and challenging stresses for the target's weld regions. SNS has successfully operated reliably at 1.4 MW by mitigating the pressure wave with the injection of small Helium bubbles into the mercury. To operate reliably at 2 MW, more gas will be injected into mercury to mitigate the pressure wave further. However, the mercury process loop was not originally designed for gas injection, and the accumulation of gas in the pipes is a concern. Due to space constraints, a custom gas liquid separator (GLS) was designed to fit a 90-deg horizontal elbow space in the SNS mercury loop. Simulations and experiments were performed, and a successful design was developed that has the desired efficiency while keeping the pressure losses acceptable.

42 ENGINEERING↗

DOE OSTI2020

Deciphering atomistic mechanisms of the gas-solid interfacial reaction during alloy oxidation

Gas-solid interfacial reaction is critical to many technological applications from heterogeneous catalysis to stress corrosion cracking. A prominent question that remains unclear is how gas and solid interact beyond chemisorption to form a stable interphase for bridging subsequent gas-solid reactions. Here, we report real-time atomic-scale observations of Ni-Al alloy oxidation reaction from initial surface adsorption to interfacial reaction into the bulk. We found distinct atomistic mechanisms for oxide growth in O 2 and H 2 O vapor, featuring a “step-edge” mechanism with severe interfacial strain in O 2 , and a “subsurface” one in H 2 O. Ab initio density functional theory simulations rationalize the H 2 O dissociation to favor the formation of a disordered oxide, which promotes ion diffusion to the oxide-metal interface and leads to an eased interfacial strain, therefore enhancing inward oxidation. Our findings depict a complete pathway for the Ni-Al surface oxidation reaction and delineate the delicate coupling of chemomechanical effect on gas-solid interactions.

36 MATERIALS SCIENCE↗

DOE OSTI2022

The Conventional Gas Diffusion Electrode May Not Be Resistant to Flooding during CO 2 /CO Reduction

The electrochemical CO 2 or CO reduction to chemicals and fuels using renewable energy is a promising way to reduce anthropogenic carbon emissions. The gas diffusion electrode (GDE) design enables low-carbon manufacturing of target products at a current density (e.g., 500 mA cm –2 ) relevant to industrial requirements. However, the long-term stability of the GDE is restricted by poor water management and flooding, resulting in a significant hydrogen evolution reaction (HER) within almost an hour. The optimization of water management in the GDE demands a thorough understanding of the role of the gas diffusion layer (GDL) and the catalyst layer (CL) distinctively. In this work, the hydrophobicity of the GDL and CL is independently adjusted to investigate their influence on gas transport efficiency and water management. The gas transport efficiency is more enhanced with the increase in hydrophobicity of the GDL than the CL. Direct visualization of water distribution by optical microscope and micro-computed tomography demonstrates that the water flow pattern transfers from the stable displacement to capillary fingering as GDL hydrophobicity increases. Unfortunately, only increasing the hydrophobicity is not sufficient to prevent flooding. A revolutionary change in the design of the GDE structure is essential to maintain the long-term stability of CO 2 /CO reduction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2026

Membrane Degradation in PEM Fuel Cells: Part I. Modeling Gas Crossover and the Pt Band

Understanding chemical degradation of the proton-exchange membrane in fuel cells is crucial for extending their lifetimes. Herein, various degradation reactions reported in literature are organized and analyzed, including direct radical generation and an indirect (Fenton) pathway. To understand the transport of dissolved H 2 and O 2 crossover gases as they relate to membrane degradation, an agglomerate-scale model is introduced, treating gas, ionomer, and catalyst as discrete phases. The model reveals a key phenomenon: at working potentials, dissolved gases are mostly consumed at the interface between the catalyst layer and the membrane, leaving little gas to cross the membrane. Under open-circuit conditions, dissolved gases are not consumed and can then cross the membrane. This explains high H 2 O 2 concentrations and degradation rates seen in experiments but not captured in previous models. Following mixed-potential theory, crossover gases supply the hydrogen-oxidation and oxygen-reduction reactions, which occur simultaneously on individual Pt particles comprising the Pt band in the membrane, forming reactive species (H 2 O 2 , OH·). Results show crossover gas almost entirely reacts on the Pt band, allowing little to reach the opposite electrode. Furthermore, the micro-scale geometry of the catalyst-layer/membrane interface impacts the gas crossover at working potentials, indicating that cell construction affects membrane durability.

Johnson, Evan F. [Lawrence Berkeley National Labor↗

DOE OSTI2021

The research into the propagation law of the shock wave of a gas explosion inside a building

Based on the dissipation rate conservation equations of turbulent kinetic energy in the k‐ ε turbulence model, a complicated three‐dimensional finite element model of a kitchen filled with gas mixture is developed by using the open source field operation and manipulation (OpenFOAM). Two representative kitchens were used to investigate the propagation law of the shock wave of a gas explosion inside a building by considering the key characteristics of the blast shock wave. The influence of some crucial parameters, such as initial conditions and kitchen parameters, on the properties of the blast shock wave is investigated. The basic steps to predict the peak pressure of the blast shock wave are given in consideration of the initial condition and the kitchen whilst the injury effect of the blast shock wave on the humans and animals is evaluated. The research results indicate that the pressure time history and the peak pressure space distribution are greatly influenced by the kitchen design layout. The coupled interaction between the initial temperature and gas volume concentration, especially at the upper and lower explosion limits of the gas, significantly affects the peak pressure. The peak pressure varies significantly with the opening and the buffer; however, it has little relation with the width, length, and height of the kitchen. The proposed method can accurately and effectively predict the peak pressure of the blast shock wave inside buildings. In terms of the peak pressure space distribution of the explosion shock wave, the peak pressure is much higher than the threshold of the killing pressure, which is unsafe for the humans and animals in the building.

Lin, Shu-Chao↗

DOE OSTI2020

Gas Generation Models for Thermal Runaway in Lithium Ion Batteries

A numerical model is implemented to study cell venting, internal pressure, and gas-phase dynamics behavior of Li-ion cells undergoing thermal runaway. A k-ɛ Reynolds-Averaged Navier-Stokes (RANS) model is adopted to describe the turbulent flow out of the cells, while the fluid dynamics inside the cells is described by Darcy-Forchheimer’s equation. Thermal abuse reactions and gas generation kinetics are described by a single-step lumped reaction model. A series of computational fluid dynamics (CFD) simulations are conducted on a single cell at various states-of-charge (100%, 50%, 25%) to demonstrate detailed flow and thermal behavior as a function of quantity of gas generated during cell venting. Venting events are categorized into two stages: i) breaching of the cell container and ii) thermal runaway reactions. It is shown that the cell response is dominated by the second stage since most of the gases are generated during thermal runaway. Also, the propensity for propagation is highly affected by state-of-charge (SOC). Cells at higher SOCs produce more heat and gas during the venting event, owing to higher mass and concentrations of reacting gases, and consequently reach higher internal cell pressures which increase the risk of side-wall breaching.

Kim, Jinyong↗

DOE OSTI2025

Regional Oil and gas Aerial Methane Synthesis model (ROAMS) v2.0

The Regional Oil and gas Aerial Methane Synthesis model is a tool to convert the results of wide-area, source-resolved aerial methane remote sensing surveys of oil and natural gas infrastructure in a given region into methane emissions inventories (estimates of the magnitude and breakdown of methane emissions from the surveyed infrastructure). The tool leverages databases of source-resolved methane emissions detected in aerial surveys, aerial survey coverage information (which areas were measured and when), data summarizing surveyed oil and natural gas infrastructure and production (derived from third-party databases), as well as state-of-the-art mechanistic emissions simulation tools to characterize emissions too small for the aerial system to see. The regional methane emissions estimates produced by this tool are much more granular in both space and asset type than common satellite- or flux tower-based regional estimates. Unlike other tools for converting site-level measurements into regional emissions estimates, our unique geostatistical approach integrates aerially measured emissions with limited need for statistical extrapolation, which can be highly sensitive to modeler assumptions. As a result, ROAMS-based estimates of regional methane emissions from oil and gas activity are widely viewed as highly credible, as evidenced by the success of Dr. Sherwin's recent paper in Nature.

Sherwin, Evan [Lawrence Berkeley National Laborato↗