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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 829 records · Page 46
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

One-man electrochemical air revitalization system evaluation

A program to evaluate the performance of a one man capacity, self contained electrochemical air revitalization system was successfully completed. The technology readiness of this concept was demonstrated by characterizing the performance of this one man system over wide ranges in cabin atmospheric conditions. The electrochemical air revitalization system consists of a water vapor electrolysis module to generate oxygen from water vapor in the cabin air, and an electrochemical depolarized carbon dioxide concentrator module to remove carbon dioxide from the cabin air. A control/monitor instrumentation package that uses the electrochemical depolarized concentrator module power generated to partially offset the water vapor electrolysis module power requirements and various structural fluid routing components are also part of the system. The system was designed to meet the one man metabolic oxygen generation and carbon dioxide removal requirements, thereby controlling cabin partial pressure of oxygen at 22 kN/sq m and cabin pressure of carbon dioxide at 400 N/sq m over a wide range in cabin air relative humidity conditions.

Schbert, F. H.↗
NASA NTRS1977

Study of palladium plating components

Palladium deposits were prepared by electrolysis for evaluation as catalytic materials. Electrolysis was carried out in acidic solutions consisting of either 1.0 M in NaCl and 0.01 M PdCl2 or 1.0 M NaCl and 0.04 M PdCl2. It was during the preparation of the palladium deposits that unexpected observations were made that led to the request for analytical services. The analyses did not, nor were they intended to, answer all of the questions. They did, however, shed light on the nature and magnitude of some of the contaminants in the solutions and in the palladium electrodes, as well as characterize the forms of the palladium deposits. Results of analyses are grouped into solution, deposit, and electrode categories for comparison purposes.

Source record↗
NASA NTRS1976

Oxygen electrocatalysts for life support systems

The irreversibility of the oxygen electrode increases by 30 to 60 percent the energy required for water electrolysis over the thermodynamic value in life support systems involving conventional water electrolysis cells. To minimize this voltage loss, high area electrocatalysts, such as platinum metal, are often used for the O2 anode, but even so, the losses are still very substantial. In an attempt to find more effective electrocatalysts for this application, a number of defect metal oxides have been examined.

Ogrady, W. E.↗
NASA NTRS1977

Efficiency and cost advantages of an advanced-technology nuclear electrolytic hydrogen-energy production facility

The concept of an advanced-technology (viz., 1985 technology) nuclear-electrolytic water electrolysis facility was assessed for hydrogen production cost and efficiency expectations. The facility integrates (1) a high-temperature gas-cooled nuclear reactor (HTGR) operating a binary work cycle, (2) direct-current (d-c) electricity generation via acyclic generators, and (3) high-current-density, high-pressure electrolyzers using a solid polymer electrolyte (SPE). All subsystems are close-coupled and optimally interfaced for hydrogen production alone (i.e., without separate production of electrical power). Pipeline-pressure hydrogen and oxygen are produced at 6900 kPa (1000 psi). We found that this advanced facility would produce hydrogen at costs that were approximately half those associated with contemporary-technology nuclear electrolysis: $5.36 versus $10.86/million Btu, respectively. The nuclear-heat-to-hydrogen-energy conversion efficiency for the advanced system was estimated as 43%, versus 25% for the contemporary system.

Donakowski, T. D.↗
NASA NTRS1977

Development of a non-cryogenic nitrogen/oxygen supply system

Modular components were refined or replaced to improve the performance of the electrolysis module in a system which generates both oxygen and hydrogen from hydrazine hydrate. Significant mechanical and electrical performance improvements were achieved in the cathode. Improvements were also made in the phase separation area but at considerable cost in time and money and to the detriment of other investigative areas. Only the pump/bubble separator failed in a manner necessitating redesign. Its failure was, however, due to its being operated above the temperature range for which it was designed. The basic electrolysis cell design was not changed.

Source record↗
NASA NTRS1977

Electrolytic pretreatment of urine

Electrolysis has been under evaluation for several years as a process to pretreat urine for ultimate recovery of potable water in manned spacecraft applications. The conclusions that were drawn from this investigation are the following: (1) A platinum alloy containing 10 percent rhodium has been shown to be an effective, corrosion-resistant anode material for the electrolytic pretreatment of urine. Black platinum has been found to be suitable as a cathode material. (2) The mechanism of the reactions occurring during the electrolysis of urine is two-stage: (a) a total Kjeldahl nitrogen and total organic carbon (TOC) removal in the first stage is the result of electrochemical oxidation of urea to CO2, H2O, and ammonia followed by chloride interaction to produce N2 from ammonia, (b) after the urea has been essentially removed and the chloride ions have no more ammonia to interact with, the chloride ions start to oxidize to higher valence states, thus producing perchlorates. (3) Formation of perchlorates can be suppressed by high/low current operation, elevated temperature, and pH adjustment. (4) UV-radiation showed promise in assisting electrolytic TOC removal in beaker tests, but was not substantiated in limited single cell testing. This may have been due to non-optimum configurations of the single cell test rig and the light source.

Source record↗
NASA NTRS1980

Detecting oxygen in hydrogen or hydrogen in oxygen

Catalytic sensor operates in high-pressure, moisture-laden gases. It was developed for life support system in which water is decomposed by electrolysis to produce oxygen and hydrogen. Sensor has potential applications in gas-detection and measurement instruments, particularly for gases generated by electrolysis, because such gases may contain large amounts of moisture.

Erickson, A. C.↗
NASA NTRS1980

Simulation of isoelectro focusing processes

This paper presents the computer implementation of a model for the stationary electrolysis of two or more charged species. This has specific application to the technique of isoelectric focussing, in which the stationary electrolysis of ampholytes is used to generate a pH gradient useful for the separation of proteins, peptides and other biomolecules. The fundamental equations describing the process are given. These equations are transformed to a form suitable for digital computer implementation. Some results of computer simulation are described and compared to data obtained in the laboratory.

Palusinski, O. A.↗
NASA NTRS1982

Preprototype independent air revitalization subsystem

The performance and maturity of a preprototype, three-person capacity, automatically controlled and monitored, self-contained independent air revitalization subsystem were evaluated. The subsystem maintains the cabin partial pressure of oxygen at 22 kPa (3.2 psia) and that of carbon dioxide at 400 Pa (3 mm Hg) over a wide range of cabin air relative humidity conditions. Consumption of water vapor by the water vapor electrolysis module also provides partial humidity control of the cabin environment. During operation, the average carbon dioxide removal efficiency at baseline conditions remained constant throughout the test at 84%. The average electrochemical depolarized concentrator cell voltage at the end of the parametric/endurance test was 0.41 V, representing a very slowly decreasing average cell voltage. The average water vapor electrolysis cell voltage increased only at a rate of 20 mu/h from the initial level of 1.67 V to the final level of 1.69 V at conclusion of the testing.

Schubert, F. H.↗
NASA NTRS1981

Alkaline regenerative fuel cell systems for energy storage

A description is presented of the results of a preliminary design study of a regenerative fuel cell energy storage system for application to future low-earth orbit space missions. The high energy density storage system is based on state-of-the-art alkaline electrolyte cell technology and incorporates dedicated fuel cell and electrolysis cell modules. In addition to providing energy storage, the system can provide hydrogen and oxygen for attitude control of the satellite and for life support. During the daylight portion of the orbit the electrolysis module uses power provided by the solar array to generate H2 and O2 from the product water produced by the fuel cell module. The fuel cell module supplies electrical power during the dark period of the orbit.

Schubert, F. H.↗
NASA NTRS1985

Space shuttle revitalization system

The Space Shuttle air revitalization system is discussed. The sequential steps in loop closure are examined and a schematic outline of the regenerative air revitalization system is presented. Carbon dioxide reduction subsystem concepts are compared. Schemes are drawn for: static feedwater electrolysis cell, solid polymer electrolyte water electrolysis cell, air revitalization system, nitrogen generation reactions, nitrogen subsystem staging, vapor compression distillation subsystem, thermoelectric integrated membrane evaporation subsystem, catalytic distillation water reclamation subsystem, and space shuttle solid waste management system.

Quattrone, P. D.↗
NASA NTRS1987

Space station onboard propulsion system: Technology study

The objective was to prepare for the design of the space station propulsion system. Propulsion system concepts were defined and schematics were developed for the most viable concepts. A dual model bipropellant system was found to deliver the largest amount of payload. However, when resupply is considered, an electrolysis system with 10 percent accumulators requires less resupply propellant, though it is penalized by the amount of time required to fill the accumulators and the power requirements for the electrolyzer. A computer simulation was prepared, which was originally intended to simulate the water electrolysis propulsion system but which was expanded to model other types of systems such as cold gas, monopropellant and bipropellant storable systems.

Mcallister, J. G.↗
NASA NTRS1988

Space Station propulsion system test bed

The test bed to study H2/O2 propulsion technology for the Space Station is discussed. The test bed consists of propellant accumulators, valving, instrumentation, and controls configured in a 9-ft cube. A water electrolysis module was added to simulate the baseline propulsion system configuration. The activation of the test bed is described, and results are presented from tests of the system, including verification of the control system, thruster tests, electrolysis system testing, and acceptance test, oxidizer system, and fuel system blowdowns.

Norman, A. M.↗
NASA NTRS1988

Hybrid regenerative fuel cell systems for space applications

This paper describes a hybrid regenerative fuel cell (RFC) system for space application, which is made up of an alkaline fuel cell (Space Shuttle fuel cell) and an acid electrolysis unit (solid polymer electrolyte). In the RFC, gas produced from the acid electrolysis unit and water produced by the alkaline fuel cell are repeatedly reacted in the other unit. The results of RFC's tests indicate that the system is feasible in terms of fluid/unit compatibility. In addition, the fuel cell thermal-control system proved capable of controlling fuel cell temperatures throughout long open-circuit periods. Diagrams of the RFC and its subsystems are included.

Saucier, David R.↗
NASA NTRS1989

Space Station Technology Summary

The completion of the Space Station Propulsion Advanced Technology Programs established an in-depth data base for the baseline gaseous oxygen/gaseous hydrogen thruster, the waste gas resistojet, and the associated system operations. These efforts included testing of a full end-to-end system at National Aeronautics and Space Administration (NASA)-Marshall Space Flight Center (MSFC) in which oxygen and hydrogen were generated from water by electrolysis at 6.89 MPa (1,000 psia), stored and fired through the prototype thruster. Recent end-to-end system tests which generate the oxygen/hydrogen propellants by electrolysis of water at 20.67 MPa (3,000 psia) were completed on the Integrated Propulsion Test Article (IPTA) at NASA-Johnson Space Center (JSC). Resistojet testing has included 10,000 hours of life testing, plume characterization, and electromagnetic interference (EMI) testing. Extensive 25-lbf thruster testing was performed defining operating performance characteristics across the required mixture ratio and thrust level ranges. Life testing has accumulated 27 hours of operation on the prototype thruster. A total of seven injectors and five thrust chambers were fabricated to the same basic design. Five injectors and three thrust chambers designed to incorporate improved life, performance, and producibility characteristics are ready for testing. Five resistojets were fabricated and tested, with modifications made to improve producibility. The lessons learned in the area of producibility for both the O2/H2 thrusters and for the resistojet have resolved critical fabrication issues. The test results indicate that all major technology issues for long life and reliability for space station application were resolved.

Iacabucci, R.↗
NASA NTRS1990

Electrochemical incineration of wastes

The novel technology of waste removal in space vehicles by electrochemical methods is presented to convert wastes into chemicals that can be eventually recycled. The important consideration for waste oxidation is to select a right kind of electrode (anode) material that should be stable under anodic conditions and also a poor electrocatalyst for oxygen and chlorine evolution. On the basis of long term electrolysis experiments on seven different electrodes and on the basis of total organic carbon reduced, two best electrodes were identified. The effect of redox ions on the electrolyte was studied. Though most of the experiments were done in mixtures of urine and waste, the experiments with redox couples involved 2.5 M sulfuric acid in order to avoid the precipitation of redox ions by urea. Two methods for long term electrolysis of waste were investigated: (1) the oxidation on Pt and lead dioxide electrodes using the galvanostatic methods; and (2) potentiostatic method on other electrodes. The advantage of the first method is the faster rate of oxidation. The chlorine evolution in the second method is ten times less then in the first. The accomplished research has shown that urine/feces mixtures can be oxidized to carbon dioxide and water, but current densities are low and must be improved. The perovskite and Ti4O7 coated with RuO2 are the best electrode materials found. Recent experiment with the redox agent improves the current density, however, sulphuric acid is required to keep the redox agent in solution to enhance oxidation effectively. It is desirable to reduce the use of acid and/or find substitutes.

Bhardwaj, R. C.↗
NASA NTRS1989

Oxygen and iron production by electrolytic smelting of lunar soil

Previous work has shown that Fe(sup 0) and O2 can be derived by electrolysis from silicate smelt of a composition typical of lunar soils (Lindstrom and Haskin 1979). In the present study, the goal is to refine further the conditions necessary to optimize production and to determine efficiencies of production (how much product is derived for a given current) and purity of products. These depend on several factors, including potential imposed between electrodes, configuration and surface area of the electrodes, composition of the electrolyzed silicate melt, and oxygen fugacity. Experiments were designed to measure the dependence on these variables of three parameters that must be known before production by electrolysis can be optimized. These parameters are: Limiting Current; Actual Current; and Efficiencies of Production.

Haskin, Larry A.↗
NASA NTRS1991

Oxygen production processes on the Moon: An overview

The production of oxygen on the Moon utilizing indigenous material is paramount to a successful lunar colonization. Several processes were put forth to accomplish this. The lunar liquid oxygen (LLOX) generation schemes which have received the most study to date are those involving: (1) the reduction of ilmenite (FeTiO3) by H2, C, CO, CH4, CO-Cl2 plasma; (2) magma electrolysis, both unadulterated and fluoride-fluxed, and (3) several others, including carbo-chlorination, HF acid leaching, fluorine extraction, magma oxidation, and vapor pyrolysis. The H2 reduction of ilmenite and magma electrolysis processes have received the most study to date. At this stage of development, they both appear feasible schemes with various pros and cons. However, all processes should be addressed at least at the onset of the considerations. It is ultimatley the energy requirements of the entire process, including the acquisition of feedstock, which will determine the mode of oxygen productions. There is an obvious need for considerably more experimentation and study. Some of these requisite studies are in progress, and several of the most studied and feasible processes for winning oxygen from lunar materials are reviewed.

Taylor, Lawrence A.↗