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At least 829 records · Page 46

Bluecrab: Comprehensive Reactor Analysis Bundle

BlueCRAB is a combination of existing codes created in close collaboration with the U.S. NRC useful for various reactor safety analysis simulations. For the purpose of classification it should be noted that BlueCRAB (the bundle) can be split up in several ways. At the heart of the software is "wrapping" and "coupling" code for brining in several non-INL projects from the NRC and Argonne National Laboratory (SAM). These codes facilitate the building and linking of these various codes during compilation and assist with data movement during execution. BlueCRAB can optionally link in several other applications including the following: BISON: fuels performance Griffin: Reactor Physics Pronghorn: CFD IAPS95: EOS for water, helium, nitrogen TRACE: NRC Code for 2 phase flow (system analysis) FAST: NRC Code for fuels performance SAM: ANL Code for single phase system analysis

Permann, Cody↗

Dose Coefficient Calculation for Use in Dosimetry Assessment of a Fission-Based Weapon

In the event of a fission-based weapon or improvised nuclear device (IND) detonation, dose coefficients can be harnessed to provide dose assessments for defense, emergency preparedness, and consequence management, as well as to prospectively inform the assessment of radiation biomarkers and development of medical prophylaxis countermeasures for defense and homeland security stakeholders and decision-makers. Although dose coefficients have previously been calculated for this group, they would apply specifically to the studied population, the 1945 Japanese cohort, after which their anthropomorphic computational phantoms were modeled. For this reason, applications to other populations may be limited, and instead, an assessment of a more standardized population is desired. We employed a series of computational human phantoms representing international reference individuals: UF/NCI voxel phantom series containing newborn, 1-, 5-, 10-, 15-, and 35-year-old males and females. Irradiation of the phantoms was simulated using the Monte Carlo N-Particle transport code to determine organ dose coefficients under four idealized irradiation geometries at three distances from the detonation hypocenter at Hiroshima and Nagasaki using DS02 free-in-air prompt neutron and photon fluence spectra. Through these simulations, age-specific dose coefficients were determined for individual organs. Various articulated PIMAL stylized phantoms were simulated as well to estimate the effect of body posture on dose coefficients and determine the effect of posture on dosimetric estimation and reconstruction. Results additionally demonstrate that 137 Cs and the Watt fission spectra are not ideal general surrogate sources for fission weapons, which may be considered for experimental testing of medical countermeasures. Supplementary data provided tabulates the compilation of organ dose-rate coefficients in this study.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Thermodynamic characterization of synthetic lead-arsenate apatites with different halogen substitutions

Abstract Thermodynamic parameters have been measured for synthetic analogs of the mimetite-group minerals Pb5(AsO4)3X (X = OH, Cl, Br, I) belonging to the apatite supergroup. Phases precipitated from aqueous solutions under ambient conditions with well characterized structures and compositions were studied. For each phase, dissolution enthalpy was experimentally determined by oxide melt drop solution calorimetry in a molten solvent of sodium molybdate (3Na2O·4MoO3) at 976 K. The enthalpy of formation from the elements ΔHf,elo was calculated using thermochemical cycles and was −3030.6 ± 11.5, −3026.6 ± 15.8, −2967.6 ± 25.0, and −2993.1 ± 12.2 kJ/mol for Pb5.00(AsO4)3.00OH0.86(CO3)0.07, Pb5.00(AsO4)3.00Cl0.80(CO3)0.10, Pb5.00(AsO4)3.00Br0.80(CO3)0.10, and Pb5.00(AsO4)3.00I0.45OH0.35(CO3)0.10, respectively. These ΔHf,elo values exhibit typical trends for apatites: they increased (were less negative) with the increasing molar mass and ionic radius of X and decreased with the electronegativity and ionization energy of X. The compilation and comparison of data for Ca-, Pb-, P-, and As-apatites revealed correlations indicating that thermodynamic enthalpic stability is largely influenced by chemical factors (e.g., differences in electronegativities of the elements, ionization energy, or ionic characteristics of the bonds) and to a lesser extent by physical and geometric parameters in the crystal structure related to the mass and size of the X anion. Using the correlations, it was possible to estimate the value of hitherto unknown ΔHf,elo for Pb5(AsO4)3F, −3144.3 ± 66.5 kJ/mol. The observed relationships apply to the entire apatite supergroup and can be used to predict the values of ΔHf,elo for phases that have not been studied experimentally. The new data on environmentally significant phases will contribute to the modeling of mineral-water interactions, particularly for potential use in the remediation of soils and wastes contaminated with Pb and As and in the immobilization of radioactive waste containing I-129.

Geochemistry & Geophysics↗

Optical Vibrational Spectroscopic Investigation of Natural and Synthetic Analogs of Uranyl Oxyhydroxyhydrate Minerals

Uranyl oxy-hydroxy-hydrate minerals are common alteration products of uraninite (UO2+x) which is chemically and structurally analogous to uranium dioxide nuclear fuel. Therefore, structural and spectroscopic investigations of these alteration minerals and their analogous anthropogenic counterparts can provide insight into the environmental behavior of nuclear fuel cycle materials. Previously, we compiled available vibrational spectroscopic data for uranyl minerals in the Compendium of Uranium Raman and Infrared Experimental Spectra (CURIES) and found that only 37% of known uranyl oxy-hydroxy-hydrate minerals had spectra readily available in the literature and existing databases for inclusion therein. Furthermore, no available infrared spectra for this mineral group were included in CURIES. To expand our understanding of the spectroscopic features of uranyl oxy-hydroxy-hydrates and the structural origins thereof, we collected, and now include in CURIES, Raman and infrared spectra for an additional 12 uranyl hydroxide phases. To better understand the impact of structural and compositional variations of these phases on their spectroscopic features, we compare Raman spectra of different anion sheet topological groups and of analogous phases hosting different counter cations. We identify spectroscopic variations related to differences in equatorial bonding and structural changes as a result of cation substitution. We also prepare a uranyl hydroxide phase via hydrolysis of uranyl fluoride (UO2F2) as an analog of hydrolysis reactions that occur in nuclear fuel cycle materials; and we find that the alteration product of UO2F2, despite chemical and structural similarities to uranyl oxy-hydroxy-hydrate minerals, is readily distinguishable from related mineral phases using Raman spectroscopy. In this work, we provide new insights into the structural origins of spectroscopic features in uranyl oxy-hydroxy-hydrate minerals, improve the average Raman spectrum for this group of minerals, and thereby improve capabilities for identifying these mineral species and related anthropogenic phases using Raman spectroscopy.

Barth, Brodie [ORNL] (ORCID:0000000256142601)↗

Assessing the Consistency of Estimated Ground Cover Fractions between the BLM AIM Method and Optical Remote Sensing Method

Since 2012, Argonne National Laboratory (Argonne) has supported the Bureau of Land Management (BLM) in developing remote sensing methodologies for long-term environmental monitoring of Palo Verde Mesa in eastern Riverside County, California, including methods for: detailed mapping of ephemeral streams, estimating fractional cover of desert-land surface components (e.g., trees, shrubs, litters, and bare ground), evaluating erosion risk or land stability, and characterizing vegetation alliances using spatial structure and geostatistical approaches. These studies showed the promise of remote sensing for monitoring changes in desert landscapes by providing information that would be difficult to obtain through field surveys. During this time the BLM has also worked to establish long-term monitoring protocols and compiled field-observation data collected using standardized protocols from the Assessment, Inventory, and Monitoring (AIM) strategy. The AIM data can be compared to data derived from remote sensing methods to evaluate their relative operational utility in monitoring landscape change. If ground cover estimated using remotely sensed imagery is comparable to AIM ground cover estimates, then remote sensing can be used to monitor whether any land cover change in desert landscapes may be related to solar energy development. Therefore, the goal of this study was to determine the consistency in ground cover estimates between AIM data and those derived from publicly- available remotely sensed imagery, such as that available through the U.S. Department of Agriculture, National Agricultural Imagery Program (NAIP), to examine feasibility of a remote sensing method for complementing AIM monitoring. Based on the image analysis in this study, we also provide recommendations for how small unmanned aerial system (sUAS) data may be used to complement BLM’s AIM data and NAIP imagery for future vegetation monitoring. The ground cover types we originally planned to investigate were trees, shrubs, and bare ground. However, the small sample size and a limited range of cover fraction of trees and shrubs in the AIM dataset (e.g., 33 samples with a maximum shrub cover of 18%, 14 samples with a maximum tree cover of 17%) did not allow for performing a meaningful evaluation for the remote sensing approach. Therefore, we conducted the study focusing on bare ground, foliar, and rock cover, all of which are indicators reported in the AIM remote sensing dataset.

47 OTHER INSTRUMENTATION↗

VA EDH Data Curation Documentation FY25-Q1

This data source documentation report provides researchers with valuable insights into the structure, contents, and data sources used to compile the datasets. It specifically covers the Fiscal Year 2024, Fourth Quarter (FY25-Q1) dataset curation documentation for the Environmental Determinants of Health (EDH) project.

97 MATHEMATICS AND COMPUTING↗

A meteorological report for the Mt. Hopkins Observatory: 1968-1971

This document is a compilation of the weather data collected at the Mt. Hopkins Observatory in southern Arizona from 1968 to 1971. It is the second meteorological report aimed at assisting scientists in the scheduling of experiments at the Observatory site.

Pearlman, M. R.↗

Correlations and linkages between the sun and the earth's atmosphere: Needed measurements and observations

A summary of needed measurements and observations is reported to identify the sequence of processes leading from change in solar input to change in tropospheric circulation and weather. Changes in the solar electromagnetic radiation have to be carefully monitored since variations over the solar cycle are small (less than one percent). It is suggested that changes in the ionization at the Pfotzer maximum could influence the formation of thunderstorms by changing the electric potential gradient. This could be checked by measuring the global atmospheric electric field. As an example of spacecraft observations, a worldwide distribution plot of nocturnal thunderstorms compiled from OSO-5 data shown; no obvious correlation with solar data had been found, but the time span of the data is rather limited and more sophisticated observation techniques could be used. Continuous and careful monitoring is recommended of the input of electromagnetic and particle radiation into the earth's atmosphere ozone distributions in the region above 30 km, and wind systems in the mesosphere and lower thermosphere. In addition, special phenomena suspected to be important in the causal chain, such as cirrus cloud formation at high latitudes and thunderstorm activity, should be monitored on a global basis.

Kellogg, W. W.↗

Skylab sleep monitoring experiment (experiment M133)

A summary of the conceptual design of the Skylab sleep monitoring experiment and a comprehensive compilation of the data-analysis results from the three Skylab missions is presented. One astronaut was studied per flight, electroencephalographic, electro-oculographic, and headmotion signals acquired during sleep by use of an elastic recording cap containing sponge electrodes and an attached miniature preamplifier/accelerometer unit are shown. A control-panel assembly, mounted in the sleep compartment, tested electrodes, preserved analog signals, and automatically analyzed data in real time (providing a telemetered indication of sleep stage). Results indicate that men are able to obtain adequate sleep in regularly scheduled eight-hour rest periods during extended space missions.

Frost, J. D., Jr.↗

Aircraft measurement of radio frequency noise at 121.5 MHz, 243 MHz and 406 MHz

An airborne survey measurement of terrestrial radio-frequency noise over U.S. metropolitan areas was carried out at 121.5, 243 and 406 MHz with horizontal-polarization monopole antennas. Flights were at 25,000 feet altitude. Radio-noise measurements, expressed in equivalent antenna-noise temperature, indicate a steady-background noise temperature of 572,000 K, at 121.5 MHz, during daylight over New York City. This data is helpful in compiling radio-noise temperature maps; in turn useful for designing satellite-aided, emergency-distress search and rescue communication systems.

Taylor, R. E.↗

Aircraft measurement of radio frequency noise at 121.5 MHz, 243MHz and 406MHz

An airborne survey measurement of terrestrial radio-frequency noise over U.S. metropolitan areas has been made at 121.5, 243 and 406 MHz with horizontal-polarization monopole antennas. Flights were at 25,000 feet altitude during the period from December 30, 1976 to January 8, 1977. Radio-noise measurements, expressed in equivalent antenna-noise temperature, indicate a steady-background noise temperature of 572,000 K, at 121.5 MHz, during daylight over New York City. This data is helpful in compiling radio-noise temperature maps; in turn useful for designing satellite-aided, emergency-distress search and rescue communication systems.

Taylor, R. E.↗

Study of component technologies for fuel cell on-site integrated energy system. Volume 2: Appendices

This data base catalogue was compiled in order to facilitate the analysis of various on site integrated energy system with fuel cell power plants. The catalogue is divided into two sections. The first characterizes individual components in terms of their performance profiles as a function of design parameters. The second characterizes total heating and cooling systems in terms of energy output as a function of input and control variables. The integrated fuel cell systems diagrams and the computer analysis of systems are included as well as the cash flows series for baseline systems.

Lee, W. D.↗

Chemical kinetics and photochemistry

A compilation of rate constant data for use in stratospheric modeling is presented. The tabulations are divided into two categories: bimolecular and termolecular. Explanations are given for anomalous pressure and temperature dependences.

Source record↗

High-energy processes in solar flares

A detailed study of high-energy processes in solar flares is reported, including the production of neutrons and pions, and incorporating isobaric and scaling models and a recent compilation of pion production data (Dermer, 1986). The broad-band gamma-ray spectrum resulting from the decay of neutral pions, the bremsstrahlung of positrons and electrons from the decay of charged pions, and the annihilation in flight of positrons is evaluated. Also evaluated is the 0.511 MeV gamma-ray line resulting from the annihilation of the positrons which survive annihilation in flight. Calculations were based on an isotropic, thick-target model using the best available nuclear data and models. Results are compared with extensive observation of the June 3, 1982 flare (10-120 MeV gamma rays), 0.511 and 2.2 MeV line emission, nuclear line emission, high-energy neutrons, and interplanetary charged particles.

Murphy, R. J.↗

Hybrid Applications Of Artificial Intelligence

STAR, Simple Tool for Automated Reasoning, is interactive, interpreted programming language for development and operation of artificial-intelligence application systems. Couples symbolic processing with compiled-language functions and data structures. Written in C language and currently available in UNIX version (NPO-16832), and VMS version (NPO-16965).

Borchardt, Gary C.↗

The upper atmosphere research satellite

The NASA Upper Atmosphere Research Satellite (UARS), whose launch is scheduled for 1991, will compile the most extensive data base to date on the coupled chemistry, energetics, and dynamics of the upper atmosphere, thereby directly addressing questions as to the extent of ozone depletion as a result of stratospheric photodissociation of molecules by solar UV radiation. The research efforts undertaken will give attention to the poorly-understood 15-100 km altiture region. Nominal mission lifetime will be 18 months, due to the projected lifetime of the cryogen employed by the Cryogenic Limb-Scanning Atmospheric Emission Spectrometer.

Mcneal, Robert J.↗