Environmental impact, life cycle analysis and battery performance of upcycled carbon anodes
For rechargeable lithium ion batteries, natural and synthetic graphite anodes come with great economic and environmental costs.
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For rechargeable lithium ion batteries, natural and synthetic graphite anodes come with great economic and environmental costs.
Axial running clearance effect on efficiency and mass flow rate of Brayton cycle radial inflow turbines
Thermal stress cycling was performed on gallium arsenide solar cells to investigate their electrical, mechanical, and structural integrity. Cells were cycled under low Earth orbit (LEO) simulated temperature conditions in vacuum. Cell evaluations consisted of power output values, spectral response, optical microscopy and ion microprobe mass analysis, and depth profiles on both front surface inter-grid areas and metallization contact grid lines. Cells were examined for degradation after 500, 5,000, 10,000 and 15,245 thermal cycles. No indication of performance degradation was found for any vendor's cell lot.
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Lithium-ion cells, of DD and D size, are being developed under a contract with the USAF for NASA's Mars Rover Missions. The cells contain spirally wound electrodes of LiNi02 positive electrode material and graphite anode in cylindrical stainless steel hardware.
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Graphical abstract: Self-supported NiO nanowall array is fabricated by a facile hydrothermal synthesis method and exhibits noticeable Li ion battery performance with good cycle life and high capacity. Highlights: ► NiO nanowall array is prepared by a hydrothermal synthesis method. ► NiO nanowall array with high capacity as anode material for Li ion battery. ► Nanowall array structure is favorable for fast ion/electron transfer. - Abstract: Free-standing quasi-single-crystalline NiO nanowall array is successfully fabricated via a simple hydrothermal synthesis method. The as-prepared NiO film exhibits a highly porous nanowall structure composed of many interconnected nanoflakes with thicknesses of ∼20 nm. The NiO nanowalls arrange vertically to the substrate resulting in the formation of extended porous net-like structure with pores of 30–300 nm. As anode material for lithium ion batteries, the quasi-single-crystalline NiO nanowall array exhibits pretty good electrochemical performances with high capacity, weaker polarization, higher coulombic efficiency and better cycling performance as compared to the dense polycrystalline NiO film. The quasi-single-crystalline NiO nanowall array presents an initial coulombic efficiency of 76% and good cycling life with a capacity of 564 mAh g{sup −1} at 0.5 A g{sup −1} after 50 cycles, higher than that of the dense polycrystalline NiO film (358 mAh g{sup −1}). The enhanced performance is due to the unique nanowall array structure providing faster ion/electron transport and better morphological stability.
The energy optimization modeling work described here was performed to determine efficiency improvements that could be achieved for existing coal-fired power plants to retrofit a partial CO 2 capture from the post-combustion flue gas for carbon sequestration through thermal integration. The work presented includes optimization of the mono-ethanol amine (MEA)-based post-combustion CO 2 capture to reduce energy requirements that could be achieved at existing power plants by thermal integration of the steam turbine cycle, boiler, CO 2 compression train and post-combustion CO 2 capture process to offset efficiency and capacity losses that would be incurred by retrofit or implementation of post-combustion CO 2 capture. Furthermore, partial CO 2 capture, involving treatment of less than 100% of the flue gas leaving the plant and modular design of the CO 2 scrubbing system, was also investigated. Thermal integration of the steam turbine cycle with boiler and CO 2 compression train improved cycle and plant performance and offset, in part, the negative effects of post-combustion CO 2 capture. The best-analyzed integration options improved gross power output by 5% and net unit efficiency by 1.57%, relative to the conventional MEA process. Operating with 40% CO 2 capture increased gross power output by 11.6–14% (depending on the MEA thermal integration option), relative to the conventional MEA integration and 90% CO 2 capture. The improvement in net unit performance is larger compared to the improvement in turbine cycle performance because of the CO 2 compression work, which is also reduced by partial CO 2 capture.
A Lithium-Ion Cell Low-Earth-Orbit Verification Test Program is being conducted by NASA Glenn Research Center to assess the performance of lithium-ion (Li-ion) cells over a wide range of low-Earth-orbit (LEO) conditions. The data generated will be used to build an empirical model for Li-ion batteries. The goal of the modeling will be to develop a tool to predict the performance and cycle life of Li-ion batteries operating at a specified set of mission conditions. Using this tool, mission planners will be able to design operation points of the battery system while factoring in mission requirements and the expected life and performance of the batteries. Test conditions for the program were selected via a statistical design of experiments to span a range of feasible operational conditions for LEO aerospace applications. The variables under evaluation are temperature, depth-of-discharge (DOD), and end-of-charge voltage (EOCV). The baseline matrix was formed by generating combinations from a set of three values for each variable. Temperature values are 10 C, 20 C and 30 C. Depth-of-discharge values are 20%, 30% and 40%. EOCV values are 3.85 V, 3.95 V, and 4.05 V. Test conditions for individual cells may vary slightly from the baseline test matrix depending upon the cell manufacturer s recommended operating conditions. Cells from each vendor are being evaluated at each of ten sets of test conditions. Cells from four cell manufacturers are undergoing life cycle tests. Life cycling on the first sets of cells began in September 2004. These cells consist of Saft 40 ampere-hour (Ah) cells and Lith ion 30 Ah cells. These cells have achieved over 10,000 cycles each, equivalent to about 20 months in LEO. In the past year, the test program has expanded to include the evaluation of Mine Safety Appliances (MSA) 50 Ah cells and ABSL battery modules. The MSA cells will begin life cycling in October 2006. The ABSL battery modules consist of commercial Sony hard carbon 18650 lithium-ion cells configured in series and parallel combinations to create nominal 14.4 volt, 3 Ah packs (4s-2p). These modules have accumulated approximately 3000 cycles. Results on the performance of the cells and modules will be presented in this paper. The life prediction and performance model for Li-ion cells in LEO will be built by analyzing the data statistically and performing regression analysis. Cells are being cycled to failure so that differences in performance trends that occur at different stages in the life of the cell can be observed and accurately modeled. Cell testing is being performed at the Naval Surface Warfare Center in Crane, IN.
Fortran 7094 computer program for calculation of design point performance of turbojet and turbofan engine cycles, and thermodynamic equations
Packed-bed thermal stores are integral components in numerous bulk electricity storage systems and may also be integrated into renewable generation and process heat systems. In such applications, the store may undergo charging and discharging periods of irregular durations. Previous work has typically concentrated on the initial charging cycles, or on steady-state cyclic operation. Understanding the impact of unpredictable charging periods on the storage behavior is necessary to improve design and operation. Here in this paper, the influence of the cycle duration (or 'partial-charge' cycles) on the performance of such thermal stores is investigated. The response to perturbations is explained and provides a framework for understanding the response to realistic load cycles.
Tests were conducted in a 20 inch diameter single stage air cooled turbine designed to evaluate the effects of film cooling air on turbine aerodynamic performance. A comparison was made of the experimental results and an analytical method of evaluating film injection effects on turbine performance. The results are used to determine the effects of film cooling on overall engine performance for selected cycle conditions. The engine performance studies are used to show the cycle benefits of increased gas temperature at various coolant flow rates.
Highlights: • Cost-effective swine waste treatment that recovers energy/nutrients was evaluated. • Ion exchange and struvite precipitation were considered for nutrient recovery. • Generally, more than 90% of N, P, and K{sup +} nutrients were recovered. • Life Cycle Cost Analysis was performed, showing significant advantages. - Abstract: Wastes from concentrated animal feeding operations (CAFOs) are challenging to treat because they are high in organic matter and nutrients. Conventional swine waste treatment options in the U.S., such as uncovered anaerobic lagoons, result in poor effluent quality and greenhouse gas emissions, and implementation of advanced treatment introduces high costs. Therefore, the purpose of this paper is to evaluate the performance and life cycle costs of an alternative system for treating swine CAFO waste, which recovers valuable energy (as biogas) and nutrients (N, P, K{sup +}) as saleable fertilizers. The system uses in-vessel anaerobic digestion (AD) for methane production and solids stabilization, followed by struvite precipitation and ion exchange (IX) onto natural zeolites (chabazite or clinoptilolite) for nutrient recovery. An alternative approach that integrated struvite recovery and IX into a single reactor, termed STRIEX, was also investigated. Pilot- and bench-scale reactor experiments were used to evaluate the performance of each stage in the treatment train. Data from these studies were integrated into a life cycle cost analysis (LCCA) to assess the cost-effectiveness of various process alternatives. Significant improvement in water quality, high methane production, and high nutrient recovery (generally over 90%) were observed with both the AD-struvite-IX process and the AD-STRIEX process. The LCCA showed that the STRIEX system can provide considerable financial savings compared to conventional systems. AD, however, incurs high capital costs compared to conventional anaerobic lagoons and may require larger scales to become financially attractive.
High Flux Isotope Reactor (HFIR) highly enriched uranium (HEU) to low-enriched uranium (LEU) conversion activities are ongoing as part of the Department of Energy (DOE) National Nuclear Security Administration (NNSA)’s nuclear nonproliferation mission. Design activities studying the conversion of HFIR from HEU to LEU fuel explored different fuel design features and shapes with a low density uranium-silicide dispersion (U 3 Si 2 -Al) fuel, which has a uranium density of 4.8 gU/cm 3 . The goal of these studies is to generate several HFIR LEU fuel designs of varying fuel fabrication complexity that meet the current HEU performance metrics and safety requirements. The documented designs will serve as references for fuel fabrication and qualification activities. Recent advancements in modeling and simulation tools enable quick prototyping of fuel designs. Shift, a Monte Carlo neutron transport and depletion tool optimized for high-performance computing (HPC) architectures, is used for efficient fuel cycle and performance metrics calculations. The HFIR Steady State Heat Transfer Code (HSSHTC) is used to vet the thermal safety margin. Also, a new automation tool that connects all fuel design analysis steps, named Python HFIR Analysis and Measurement Engine (PHAME), has been developed to expedite the design study in an efficient and reproducible manner. Leveraging these tools, several candidate fuel designs were selected for varying fabrication complexity. This report provides design feature details for four selected HFIR LEU low density U 3 Si 2 -Al fuel designs and their corresponding performance and safety metrics. Nominal, best-estimate design parameters and irradiation conditions, including fission rate densities, power densities, heat fluxes, and cumulative fission densities are provided for candidate fuel designs relevant to framing irradiation experiments to support fuel qualification efforts. Simulations show that the low density U 3 Si 2 -Al, with design features to enhance safety, can meet HEU core performance metrics and safety requirements if the reactor power is increased from 85 MW (HEU) to 95 MW (LEU) and if the active fuel length is increased from 50.80 cm (HEU) to 55.88 cm (LEU).
Cold performance characteristics of small radial inflow turbine designed for Brayton cycle power system
Performance expectations of closed-Brayton-cycle heat exchangers to be used in 100-kWe nuclear space power systems were forecast. Proposed cycle state points for a system supporting a mission to three of Jupiter s moons required effectiveness values for the heat-source exchanger, recuperator and rejection exchanger (gas cooler) of 0.98,0.95 and 0.97, respectively. Performance parameters such as number of thermal units (Nm), equivalent thermal conductance (UA), and entropy generation numbers (Ns) varied from 11 to 19,23 to 39 kWK, and 0.019 to 0.023 for some standard heat exchanger configurations. Pressure-loss contributions to entropy generation were significant; the largest frictional contribution was 114% of the heat-transfer irreversibility. Using conventional recuperator designs, the 0.95 effectiveness proved difficult to achieve without exceeding other performance targets; a metallic, plate-fin counterflow solution called for 15% more mass and 33% higher pressure-loss than the target values. Two types of gas-coolers showed promise. Single-pass counterflow and multipass cross-counterflow arrangements both met the 0.97 effectiveness requirement. Potential reliability-related advantages of the cross-countefflow design were noted. Cycle modifications, enhanced heat transfer techniques and incorporation of advanced materials were suggested options to reduce system development risk. Carbon-carbon sheeting or foam proved an attractive option to improve overall performance.
Performance expectations of closed-Brayton-cycle heat exchangers to be used in 100-k We nuclear space power systems were forecast. Proposed cycle state points for a system supporting a mission to three of Jupiter's moons required effectiveness values for the heat-source exchanger, recuperator and rejection exchanger (gas cooler) of 0.98, 0.95, and 0.97, respectively. Performance parameters such as number of thermal units (Ntu), equivalent thermal conductance (UA), and entropy generation numbers (Ns) varied from 11 to 19, 23 to 39 kW/K, and 0.019 to 0.023 for some standard heat exchanger configurations. Pressure-loss contributions to entropy generation were significant; the largest frictional contribution was 114% of the heat transfer irreversibility. Using conventional recuperator designs, the 0.95 effectiveness proved difficult to achieve without exceeding other performance targets; a metallic, plate-fin counterflow solution called for 15% more mass and 33% higher pressure-loss than the target values. Two types of gas-coolers showed promise. Single-pass counterflow and multipass cross-counterflow arrangements both met the 0.97 effectiveness requirement. Potential reliability-related advantages of the cross-counterflow design were noted. Cycle modifications, enhanced heat transfer techniques and incorporation of advanced materials were suggested options to reduce system development risk. Carbon-carbon sheeting or foam proved an attractive option to improve overall performance.