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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 829 records · Page 46
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

New integration techniques for chemical kinetic rate equations. II - Accuracy comparison

A comparison of the accuracy of several techniques recently developed for solving stiff differential equations is presented. The techniques examined include two general purpose codes EEPISODE and LSODE developed for an arbitrary system of ordinary differential equations, and three specialized codes CHEMEQ, CREKID, and GCKP84 developed specifically to solve chemical kinetic rate equations. The accuracy comparisons are made by applying these solution procedures to two practical combustion kinetics problems. Both problems describe adiabatic, homogeneous, gas phase chemical reactions at constant pressure, and include all three combustion regimes: induction heat release, and equilibration. The comparisons show that LSODE is the most efficient code - in the sense that it requires the least computational work to attain a specified accuracy level. An important finding is that an iterative solution of the algebraic enthalpy conservation equation for the temperature can be more accurate and efficient than computing the temperature by integrating its time derivative.

Radhakrishnan, K.↗
NASA NTRS2002

Noachian Martian Volcanics a Water Source

H2O was supplied to the Noachian atmosphere by eruptions, or in association with large impacts. Most water outgassed into an extremely cold atmosphere, and condensate deposits were inevitable. High heat flow could lead to subglacial melting only if ice thicknesses were greater than 500-1000m, which is extremely unlikely. Subareal melting and flow is contingent upon temperatures periodically exceeding 273 K, and retarding evaporative loss of the flow. In still air, evaporation into a dry atmosphere is in the free convection regime, and a stream with 2 cu m/s discharge, flowing 1 m/s could persist for hundreds of days and cover distances greater than any valley reach. The zero-wind-shear condition is considered implausible however. We investigate the possibility that evaporation rates were suppressed because the atmosphere was regionally charged with H2O as it moved over snow/ice fields. Our initial concern is precipitation from volcanic plumes. A Kilauea-style eruption on the martian surface would cover a 10km circular deposit with 10cm of H2O, if all H2O could be precipitated near the vent. The characteristics of the eruption at the vent, (vent size, temperature, H2O content, etc.) are independent of the environmental conditions. The subsequent behavior of the plume, including precipitation of ash and H2O condensate depends strongly on the environment. Hence, the proximal fate of volcanic H2O is amenable to treatment in a model. A simple bulk thermodynamic model of the rise of an H2O plume through a stably stratified CO2 atmosphere, with only adiabatic cooling, produces runaway plume rise. A more complex treatment includes the effects of latent heat release, wind shear along the plume, divergence of ash and H2O, and will yield more realistic estimates of H2O transport in eruptive plumes. Results of these simulations will be presented.

Zent, A. P.↗
DOE OSTI2022

A New 1-step Arrhenius Decomposition Model for PBX 9501: Calibration with Isochoric-Adiabatic High-Activation-Energy Asymptotics and Uncertainty Quantification

Here we present a new 1-step Arrhenius thermal decomposition model of PBX 9501. As opposed to previous studies, we use high-energy asymptotic theory, and previously published equations of state to parameterize the model to experimental critical-time data. The model parameters were fit to experimental data using a bootstrapping procedure to capture the effects of experimental uncertainty. Subsequent implementation of the model in a chemicalkinetics ODE solver shows good agreement of times to ignition vs initial temperature in isochoric thermal explosion calculations with the results of the high-energy asymptotic theory. We also compare the resultant ZND structures to those of one of our previously calibrated burn models.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗
DOE OSTI2022

Bound on hot-spot mix in high-velocity, high-adiabat direct-drive cryogenic implosions based on comparison of absolute x-ray and neutron yields

In laser-driven implosions for laboratory fusion, the comparison of hot-spot x-ray yield to neutron production can serve to infer hot-spot mix. For high-performance direct-drive implosions, this ratio depends sensitively on the degree of equilibration between the ion and electron fluids. A scaling for x-ray yield as a function of neutron yield and characteristic ion and electron hot-spot temperatures is developed on the basis of simulations with varying degrees of equilibration. We apply this model to hot-spot x-ray measurements of direct-drive cryogenic implosions typical of the direct-drive designs with best ignition metrics. Furthermore, the comparison of the measured x-ray and neutron yields indicates that hot-spot mix, if present, is below a sensitivity estimated as ~ 2% by-atom mix of ablator plastic into the hot spot.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1992

Nonadiabatic heating of the central plasma sheet at substorm onset

Heating events in the plasma sheet boundary layer and central plasma sheet are found to occur at the onset of expansive phase activity. The main effect is a dramatic increase in plasma temperature, coincident with a partial dipolarization of the magnetic field. Fluxes of energetic particles increase without dispersion during these events which occur at all radial distances up to 23 RE, the apogee of the ISEE spacecraft. A major difference between these heating events and those observed at geosynchronous distances lies in the heating mechanism which is nonadiabatic beyond 10 RE but may be adiabatic closer to earth. The energy required to account for the increase in plasma thermal energy is comparable with that required for Joule heating of the ionosphere. The plasma sheet must be considered as a major sink in the energy balance of a substorm. Lobe magnetic pressures during these events are estimated. Change in lobe pressure are generally not correlated with onsets or intensifications of expansive phase activity.

Huang, C. Y.↗
DOE OSTI2024

O 2 -Dependence of reactions of 1,2-dimethoxyethanyl and 1,2-dimethoxyethanylperoxy isomers

Reaction mechanisms of Ṙ and ROȮ radicals derived from low-temperature oxidation of 1,2-dimethoxyethane (CH 3 O(CH 2 ) 2 OCH 3 ) were investigated using speciation from multiplexed photoionization mass spectrometry (MPIMS) measurements via Cl-initiated oxidation, in conjunction with electronic structure calculations. The experiments were conducted at 5 bar, from 450 K – 650 K, and O 2 concentrations from 1 · 10 14 cm –3 – 6 · 10 18 cm –3 to probe the effects on competing reaction channels of 1,2-dimethoxyethanyl (Ṙ) and 1,2-dimethoxyethanylperoxy (ROȮ) isomers. Several species were detected with photoionization spectral fitting – ethene, formaldehyde, methyl vinyl ether, and 2-methoxyacetaldehyde – and, as determined by electronic structure calculations, may form via unimolecular decomposition of 1,2-dimethoxyethanyl or 1,2-dimethoxyethanylperoxy. O 2 -dependent yield ratios show that the formation pathways for all species undergo a competition between O 2 -addition and unimolecular decomposition. Here, adiabatic ionization energies were also calculated and utilized along with exact mass determinations to infer contributions for other species derived exclusively from first- and second-O 2 -addition, including 1,2-dimethoxyethene, cyclic ethers, and dicarbonyls.

1,2-dimethoxyethane↗
NASA NTRS1991

An analytic solution to the steady-state double adiabatic equations

A set of 20 generalized moment-transport equations applicable to low-beta (low random energy density/magnetic energy density) plasmas of thermal origin in rotating planetary magnetospheres. An analytic solution is obtained for a set of simplified equations characterizing the steady-state transport of collisionless plasma; the novel element of this analytic solution is a closed-form solution for the parallel-flow velocity variation along magnetic field lines. It is shown that only T(perpendicular)/B remains constant along the field line, while density, parallel temperature, and parallel Mach number vary.

Gombosi, Tamas I.↗
NASA NTRS1972

Very high temperature laminar flow of a gas through the entrance region of a cooled tube - Numerical calculations and experimental results.

The laminar flow equations in differential form are solved numerically on a digital computer for flow of a very high temperature gas through the entrance region of an externally cooled tube. The solution method is described and calculations are carried out in conjunction with experimental measurements. The agreement with experiment is good, with the result indicating relatively large energy and momentum losses in the highly cooled flows considered where the pressure is nearly uniform along the flow and the core flow becomes non-adiabatic a few diameters downstream of the inlet. The effects of a large range of Reynolds number and Mach number (viscous dissipation) are also investigated.

Back, L. H.↗
NASA NTRS1973

Atmospheric and cloud structures of the Jovian planets

Wet adiabatic atmospheric models are computed for the four Jovian planets. Possible cloud-forming condensates considered are H2O ice, aqueous NH3 solution, NH4SH, and solid NH3, CH4, and Ar. Some techniques for computer calculation of condensation in a multiphase system of variable composition are discussed. Nominal models are computed for all four planets, and the effects of variations in composition and different pressure-temperature regimes are investigated in detail for Jupiter. The meaning of the calculated closed densities and their relation to the actual densities are discussed. The computed atmospheric profiles represent average conditions, subject to considerable local variations.

Weidenschilling, S. J.↗
NASA NTRS1981

Energetics of a sudden stratospheric warming simulated with a three-dimensional, spectral, quasi-geostrophic model

The energetics of a three dimensional, quasi-geostrophic simulation of a sudden stratospheric warming which developed spontaneously during an annual cycle simulation are described. Daily values of the stratospheric temperatures, zonal winds, heating rates, energies, and energy conversions are discussed and compared with those for observed warmings. It is shown that, like observed warmings, the simulated warming was preceded by an increased vertical flux of eddy kinetic energy from the troposphere and the polar heating resulted because of the strong convergence of the horizontal, eddy heat flux which was only partially balanced by adiabatic and diabatic cooling. There is a significant similarity between the energetics of the simulated and observed warmings. In addition, the warming was spontaneous and the model did not develop a major warming in each winter of the simulation. These facts suggest that this model may be useful for studying not only the warming process but also the conditions that favor its development.

Haggard, K. V.↗
NASA NTRS1994

Rotational excitation of H2 in collision with H

Rate coefficients for the reactive processes of ortho-para conversion in which the j = 0 rotational level of molecular hydrogen is excited to the j = 1 and j = 3 level by impacts with hydrogen atoms are calculated for temperatures between 30 K and 1000 K using a fully converged complete close-coupled method. Rate coefficients are also obtained for the excitation from the j = 0 to the j = 2 rotational level and from the j = 1 to the j = 3 rotational level. The interference between the direct and reactive channels is taken into account as is the geometric phase resulting from the adiabatic separation of electronic and nuclear motion that generates the potential energy surface. Convenient analytic representations of the rate coefficients are presented.

Sun, Y.↗
NASA NTRS2022

Climatology of Mesosphere and Lower Thermosphere Residual Circulations and Mesopause Height Derived From SABER Observations

In the mesosphere and lower thermosphere (MLT) region, residual circulations driven by gravity wave breaking and dissipation significantly impact constituent distribution and the height and temperature of the mesopause. The distribution of CO2 can be used as a proxy for the residual circulations. Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) CO2 volume mixing ratio (VMR) and temperature measurements from 2003 to 2020 are used to study the monthly climatology of MLT residual circulations and the mesopause height. Our analyses show that (a) mesopause height strongly correlates with the CO2 VMR vertical gradient during solstices; (b) mesopause height has a discontinuity at midlatitude in the summer hemisphere, with a lower mesopause height at mid-to-high latitudes as a result of adiabatic cooling driven by strong adiabatic upwelling; (c) the residual circulations have strong seasonal variations at mid-to-high latitudes, but they are more uniform at low latitudes; and (d) the interannual variability of the residual circulations and mesopause height is larger in the Southern Hemisphere (SH; 4–5 km) than in the Northern Hemisphere (NH; 0.5–1 km).

SABER↗
NASA NTRS1992

Nonadiabatic processes in the Earth's magnetotail

The challenge of the assumption of an adiabatic equation of state for the plasma sheet made in several studies of quiet time convection and expansive phase activity is addressed. The observed plasma pressures at distances of approximately 10 RE are less than that predicted by adiabatic convection by over an order of magnitude. Studies of the local plasma properties for individual events as well as an ensemble of all quiet time plasma sheet samples during two years of ISEE coverage show that the polytropic index is below 5/3, and on occasion may be less than unity. During substorm activity the main effect of the plasma sheet is an increase in plasma temperature. This is seen both in statistical and case studies of individual substorms. The nature of the heating process is nonadiabatic, as evidenced by the anticorrelation between changes in plasma density and temperature. These recent observations of nonadiabatic behavior emphasize thermodynamic processes in the magnetosphere, an area which has been largely ignored.

Huang, C. Y.↗
DOE OSTI2025

The Atacama Cosmology Telescope: DR6 constraints on extended cosmological models

We use new cosmic microwave background (CMB) primary temperature and polarization anisotropy measurements from the Atacama Cosmology Telescope (ACT) Data Release 6 (DR6) to test foundational assumptions of the standard cosmological model, ΛCDM, and set constraints on extensions to it. We derive constraints from the ACT DR6 power spectra alone, as well as in combination with legacy data from the Planck mission. To break geometric degeneracies, we include ACT and Planck CMB lensing data and baryon acoustic oscillation data from DESI Year-1. To test the dependence of our results on non-ACT data, we also explore combinations replacing Planck with WMAP and DESI with BOSS, and further add supernovae measurements from Pantheon+ for models that affect the late-time expansion history. We verify the near-scale-invariance (running of the spectral index dn s /d ln k = 0.0062 ± 0.0052) and adiabaticity of the primordial perturbations. Neutrino properties are consistent with Standard Model predictions: we find no evidence for new light, relativistic species that are free-streaming (N eff = 2.86 ± 0.13, which combined with astrophysical measurements of primordial helium and deuterium abundances becomes N eff = 2.89 ± 0.11), for non-zero neutrino masses (∑m ν < 0.089 eV at 95% CL), or for neutrino self-interactions. We also find no evidence for self-interacting dark radiation (N idr < 0.134), or for early-universe variation of fundamental constants, including the fine-structure constant (α EM /α EM,0 = 1.0043 ± 0.0017) and the electron mass (m e /m e,0 = 1.0063 ± 0.0056). Our data are consistent with standard big bang nucleosynthesis (we find Y p = 0.2312 ± 0.0092), the COBE/FIRAS-inferred CMB temperature (we find T CMB = 2.698 ± 0.016 K), a dark matter component that is collisionless and with only a small fraction allowed as axion-like particles, a cosmological constant (w = -0.986 ± 0.025), and the late-time growth rate predicted by general relativity (γ = 0.663 ± 0.052). We find no statistically significant preference for a departure from the baseline ΛCDM model. In fits to models invoking early dark energy, primordial magnetic fields, or an arbitrary modified recombination history, we find H 0 = 69.9 +0.8 -1.5 , 69.1 ± 0.5, or 69.6 ± 1.0 km/s/Mpc, respectively; using BOSS instead of DESI BAO data reduces the central values of these constraints by 1–1.5 km/s/Mpc while only slightly increasing the error bars. In general, models introduced to increase the Hubble constant or to decrease the amplitude of density fluctuations inferred from the primary CMB are not favored over ΛCDM by our data.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1951

Meteorological Analysis of Icing Conditions Encountered in Low-Altitude Stratiform Clouds

Liquid-water content, droplet size, and temperature data measured during 22 flights in predominatly stratiform clouds through the 1948-49 and the 1949-50 winters are presented. Several icing encounters were of greater severity than those previously measured over the same geographical area, but were within the limits of similar measurements obtained over different terrain within the United States. An analysis of meteorological conditions existing during the 74 flights conducted for four winters indicated an inverse relation of liquid-water concentration to maximum horizontal extent of icing clouds. Data on the vertical extent of supercooled clouds are also presented. Icing conditions were most likely to occur in the southwest and northwest quadrants of a cyclone area, and least likely to occur in the southeast and northeast quadrants where convergent air flow and lifting over the associated warm frontal surface usually cause precipitation. Additional data indicated that, icing conditions were usually encountered in nonprecipitating clouds existing at subfreezing temperatures and were unlikely over areas where most weather observing stations reported the existence of precipitation. Measurements of liquid-water content obtained during 12 flights near the time and location of radiosonde observations were compared with theoretical values. The average liquid-water content of a cloud layer, as measured by the multicylinder technique, seldom exceeded two-thirds of that which could be released by adiabatic lifting. Local areas near the cloud tops equaled or occasionally exceeded the calculated maximum quantity of liquid water.

Kline, D. B.↗
DOE OSTI2025

Progress toward hydro-equivalent ignition in OMEGA direct-drive DT-layered implosions

Considerable progress has been made in deuterium-tritium-layered implosion experiments on the OMEGA Laser System, bringing the prospects for thermonuclear ignition in direct-drive configurations with megajoule-class lasers closer to reality. Doing so has required navigating the balance between improved 1D performance and multidimensional stability. Using statistical modeling based on over 350 cryogenic implosions to identify various degradation mechanisms, and combined with multidimensional simulations and experimental techniques such as target offsets to combat residual flows, core conditions have repeatably been achieved that extrapolate to the burning-plasma state when scaled to 2.15 MJ of symmetric laser illumination. Using high implosion velocities (⁠> 450 km/s) and moderately high adiabats (⁠~5⁠), these experiments produced record-high scaled Lawson parameters in direct drive equal to 89 ± 2% of that required for ignition with expected yields of up to 1.5 ± 0.2 MJ. To improve these results still further, focused physics studies are performed to improve physics understanding and identify routes to even greater performance. Recent studies include investigations into the impact of mounting features, laser imprint, reduced fuel temperatures, and greater on-target intensities through subscale experiments. This manuscript gives a summary of the cryogenic direct-drive program on the OMEGA laser, including routes taken to achieve the current best performance, the status of recent focused physics investigations, and future designs—such as target solutions to laser imprint and reducing vapor density to increase convergence—that are expected lead to the demonstration of hydro-equivalent ignition on OMEGA.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

On the Breakdown of ENSO's Relationship With Thermocline Depth in the Central-Equatorial Pacific

Recent classification of El Nino-Southern Oscillation (ENSO) into two types, Eastern (EP) and Central (CP) events, has highlighted the importance of the central Pacific. We show here that the local correlation between ENSO subsurface temperatures (T sub ) in the upper 100-m and thermocline depth anomalies breaks down in the central equatorial Pacific, whereas T sub remains well correlated with sea surface height anomalies. This observed difference in the central equatorial Pacific is simulated by almost all climate models. It arises from a vertically slanted Tsub anomaly structure that is unique to the central equatorial Pacific. We show that this feature is an adiabatic response to wind-driving that is even present in a linear dynamic model, as long as the model has enough baroclinic modes to adequately represent the observed vertical complexity. Our findings have implications for better understanding the different importance of thermocline feedback in CP and EP events.

58 GEOSCIENCES↗
DOE OSTI2021

Entropy generation from hydrodynamic mixing in inertial confinement fusion indirect-drive targets

The increase in entropy from the physical mixing of two adjacent materials in inertial confinement fusion (ICF) implosions and gas-filled hohlraums is analytically assessed. An idealized model of entropy generation from the mixing of identical ideal-gas particles across a material interface in the presence of pressure and temperature gradients is applied. Physically, mix-driven entropy generation refers to the work done by the gases in expanding into a larger common volume from atomic mixing under the condition of no internal energy change, or work needed to restore the initial unmixed state. Furthermore, the effect of a mix-generated entropy increase is analytically shown to lead to less compression of the composite ICF fluid under adiabatic conditions. The amount of entropy generation is estimated to be ~10 J for a Rayleigh–Taylor-induced micrometer-scale annular mixing layer between the solid deuterium–tritium fuel and (undoped) high-density carbon pusher of an imploding capsule at the National Ignition Facility (NIF). This level of entropy generation is consistent with lower-than-expected fuel compressions measured on the NIF [Hurricane et al., Phys. Plasmas 26, 052704 (2019)]. The degree of entropy increase from mixing of high-Z hohlraum wall material and low-Z, moderate- to high-density gas fills is estimated to lead to ~100 kJ of heat generation for NIF-scale experiments [Moody et al., Phys. Plasmas 21, 056317 (2014)]. This value represents a significant fraction of the inferred missing x-ray drive energy based on observed delays in capsule implosion times compared with mainline simulations [Jones et al., Phys. Plasmas 19, 056315 (2012)].

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗