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At least 811 records · Page 45

All sources NASA NTRS DOE OSTI

DOE OSTI2024

Energy performance evaluation of the ASHRAE Guideline 36 control and reinforcement learning–based control using field measurements

This study evaluates the energy performance of ASHRAE Guideline 36–compliant control (ASHRAE 36 control) and reinforcement learning (RL)–based control through experimental field tests and a simulation study. Three field tests were conducted at Oak Ridge National Laboratory’s commercial building test facility in Oak Ridge, Tennessee: a baseline with a baseline conventional control, a test with ASHRAE 36 control, and a test with RL-based control. The selected ASHRAE 36 controls were trim and respond control, as well as variable air volume (VAV) box control. We compared the measured supply air temperature of the rooftop unit, VAV box supply air temperature, and VAV box supply airflow rate across the three test cases. The field data indicated that ASHRAE 36 controls operated as specified by ASHRAE Guideline 36. Based on these data, ASHRAE 36 control achieved a 45 % reduction in hourly averaged HVAC energy consumption compared with the baseline, and RL-based control achieved a 66 % reduction. These potential annual energy savings were confirmed using a calibrated whole-building energy model. Compared with the baseline, ASHRAE 36 control reduced HVAC energy consumption by 42 %, and RL-based control achieved a 54 % reduction. Furthermore, RL-based control reduced total HVAC energy consumption by 21 % more than ASHRAE 36 control.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2024

Relating Molecular Properties to the Persistence of Marine Dissolved Organic Matter with Liquid Chromatography–Ultrahigh-Resolution Mass Spectrometry

Marine dissolved organic matter (DOM) contains a complex mixture of small molecules that eludes rapid biological degradation. Spatial and temporal variations in the abundance of DOM reflect the existence of fractions that are removed from the ocean over different time scales, ranging from seconds to millennia. However, it remains unknown whether the intrinsic chemical properties of these organic components relate to their persistence. Here, we elucidate and compare the molecular compositions of distinct DOM fractions with different lability along a water column in the North Atlantic Gyre. Our analysis utilized ultrahigh-resolution Fourier transform ion cyclotron resonance mass spectrometry at 21 T coupled to liquid chromatography and a novel data pipeline developed in CoreMS that generates molecular formula assignments and metrics of isomeric complexity. Clustering analysis binned 14 857 distinct molecular components into groups that correspond to the depth distribution of semilabile, semirefractory, and refractory fractions of DOM. The more labile fractions were concentrated near the ocean surface and contained more aliphatic, hydrophobic, and reduced molecules than the refractory fraction, which occurred uniformly throughout the water column. These findings suggest that processes that selectively remove hydrophobic compounds, such as aggregation and particle sorption, contribute to variable removal rates of marine DOM.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2022

Time-Evolving Chirality Loss in Molecular Photodissociation Monitored by X-ray Circular Dichroism Spectroscopy

In this work, the ultrafast photoinduced chirality loss of 2-iodobutane is studied theoretically by time- and frequency-resolved X-ray circular dichroism (TRXCD) spectroscopy. Following an optical excitation, the iodine atom dissociates from the chiral center, which we capture by quantum non-adiabatic molecular dynamics simulations. At variable time delays after the pump, the resonant X-ray pulse selectively probes the iodine and carbon atom involved in the chiral dissociation through a selected core-to-valence transition. The TRXCD signal at the iodine L 1 edge accurately captures the timing of C–I photodissociation and thereby chirality loss, c.a 70 fs. The strong electric dipole–electric quadrupole (ED–EQ) response makes this signal particularly sensitive to vibronic coherence at the high X-ray regime. At the carbon K-edges, the signals monitor the molecular chirality of the 2-butyl radical photoproduct and the spin state of the iodine atom. The ED–EQ response is masked under the strong electric dipole-magnetic dipole response, making this signal intuitive for the electronic population. The evolution of the core electronic states and its chiral sensitivity is discussed. Overall, the element-specific TRXCD signal provides a detailed picture of molecular dynamics and offers a unique sensitive window into the time-dependent chirality of molecules.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

Conductivity space isotherm behavior in quantum anomalous Hall devices

The quantum Hall effect (QHE) has enhanced accessibility to measure and disseminate electrical units, owed in part to the recently redefined International System of Units in 2019. Graphene remains one of the preferred options to realize the ohm despite the limitations of high magnetic fields to produce a robust QHE. Topological insulators, on the other hand, show promise in providing quantized resistance via the quantum anomalous Hall effect, a phenomenon that removes the need for magnetic fields during operation. To optimize future devices for metrological applications, it is important to gain a better understanding of magnetically doped topological insulators like Cr-doped bismuth antimony telluride. The application of differential conductivity space analyses offers a more sensitive way to analyze the data and distinguish between 2D and 3D transport behaviors. This is particularly important in thin films, where the transition between 2D and 3D behavior can be subtle. The ability to confidently determine the dimensionality of the transport is crucial for selecting appropriate theoretical models for future device optimization. Furthermore, this work identifies variable range hopping as the dominant transport mechanism in the 2D regime using a rigorous statistical analysis (via the Bayes factor). These elements assist in the understanding of microscopic processes that govern charge transport in these materials.

Tran, N. T. M. [National Inst. of Standards and Te↗

DOE OSTI2021

A Novel Variable Extensometer Method for Measuring Ductility Scaling Parameters From Single Specimens

Abstract Macro-scale ductility is not an intrinsic material property but is dependent on the overall geometry of the specimen. To account for variety in specimen geometries, multiple ductility scaling laws have been developed, which scale ductility between different specimen sizes. Traditionally, these ductility laws rely on testing multiple different specimens of varying sizes to obtain material parameters, often done by varying gauge lengths. With the use of digital image correlation (DIC), this study presents a technique where multiple different gauge lengths are extracted from a single specimen to obtain ductility scaling parameters from a single experiment. This technique provides orders of magnitude more data from each specimen than previous techniques. This variable extensometer method is then validated by testing multiple different geometries, and select scaling laws are then compared.

Mechanics↗

DOE OSTI2023

Electrochemical Characteristics of Intermetallic Phases in Al–Cu–Li Alloys

This study provides a comprehensive overview of the electrochemical characteristics of intermetallic compounds (IMCs) commonly encountered in the 3rd generation Al–Cu–Li alloys. The electrochemical measurements were carried out on a AA2070-T8 alloy and surrogate alloys that have the compositions of select IMCs, typically found in AA2070-T8. The effects of environmental variables such as [Cl − ] and pH on the corrosion potential, pitting potential, repassivation potential, corrosion rate, and galvanic current of these IMCs were thoroughly evaluated utilizing the electrochemical microcell method. An electrochemical database was documented that covers eight groups of common IMCs in various Al alloys. The findings improve the understanding of interactions between matrix and IMCs in Al alloys, with implications for corrosion mitigation and new materials design.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Single Photon Emitters Coupled to Photonic Wire bonds

This project will test the coupling of light emitted from silicon vacancy and nitrogen vacancy defects in diamond into additively manufactured photonic wire bonds toward integration into an "on-chip quantum photonics platform". These defects offer a room-temperature solid state solution for quantum information technologies but suffer from issues such as low activation rate and variable local environments. Photonic wire bonding will allow entanglement of pre-selected solid-state defects alleviating some of these issues and enable simplified integration with other photonic devices. These developments could prove to be key technologies to realize quantum secured networks for national security applications.

42 ENGINEERING↗

DOE OSTI2024

Innovating the next generation of commercial smart building software

Nearly 30% of commercial building energy use is wasted due to equipment faults and HVAC controls problems. The result is increased emissions, compromised comfort and productivity, and less reliable coordination of building power needs with a clean grid. The energy impact alone represents $17 billion in potential savings. Today’s smart building software provides a robust solution to address these operational deficiencies. Energy management and information systems (EMIS) are saving up to 9% on average, with two-year paybacks. They are being incorporated into energy management processes, commissioning services, and utility programs. As effective as they are, two barriers prevent even deeper benefits; limited personnel to fix problems once they are identified, and the expense and time to manually implement changes in control systems. In partnership with the research community, the EMIS industry is developing new capabilities to overcome these barriers. Moving beyond siloed products for either fault detection and diagnostics, or optimal control, these new capabilities empower users to not only automatically identify faults, but also to push corrective action, and control improvements to their buildings. In this paper, several areas for enhancements are documented: ‘one-time’ correction of faults such as setpoints, schedules, and economizer lockouts; short-term active testing for automated proportional integral derivative (PID) loop tuning and functional testing; and continuous supervisory control for demand flexibility and year-round efficiency. Results are presented from a pair of partner implementations out of a dozen providers integrating these enhancements into their products, including field tests from across the country, and insights into operator acceptance and integration into operations and maintenance practices.

Casillas, Armando↗

NASA NTRS1974

A study of the diffusional behavior of a two-phase metal matrix composite exposed to a high temperature environment

The progress of diffusion-controlled filament-matrix interaction in a metal matrix composite where the filaments and matrix comprise a two-phase binary alloy system was studied by mathematically modeling compositional changes resulting from prolonged elevated temperature exposure. The analysis treats a finite, diffusion-controlled, two-phase moving-interface problem by means of a variable-grid finite-difference technique. The Ni-W system was selected as an example system. Modeling was carried out for the 1000 to 1200 C temperature range for unidirectional composites containing from 6 to 40 volume percent tungsten filaments in a Ni matrix. The results are displayed to show both the change in filament diameter and matrix composition as a function of exposure time. Compositional profiles produced between first and second nearest neighbor filaments were calculated by superposition of finite-difference solutions of the diffusion equations.

Tenney, D. R.↗

NASA NTRS1976

Computational alternatives to obtain time optimal jet engine control

Two computational methods to determine an open loop time optimal control sequence for a simple single spool turbojet engine are described by a set of nonlinear differential equations. Both methods are modifications of widely accepted algorithms which can solve fixed time unconstrained optimal control problems with a free right end. Constrained problems to be considered have fixed right ends and free time. Dynamic programming is defined on a standard problem and it yields a successive approximation solution to the time optimal problem of interest. A feedback control law is obtained and it is then used to determine the corresponding open loop control sequence. The Fletcher-Reeves conjugate gradient method has been selected for adaptation to solve a nonlinear optimal control problem with state variable and control constraints.

Basso, R. J.↗

NASA NTRS1979

Accuracy and performance of LACIE crop development models

Of the three principal phenological crop calendar models evaluated for LACIE, Robertson's triquadratic model which predicts the rate of progression of wheat through its biological development, was selected. Daily maximum and minimum temperatures and day length are the input variables, and the principal output is a daily increment of development through six physiological growth stages. Because wheat corresponds differently to the environment during each growth stage, five different equations are required. The estimated and observed crop development data were compared in order to establish a measure of confidence in the model and to identify consistent discrepancies that would adversely affect LACIE operation. Although the model provided reliable estimates for various wheat growing regions of the world, it was found that there are still areas in need of further model improvement or development.

Woolley, S. K.↗

NASA NTRS1985

Stability robustness improvement using constrained optimization techniques

In a multiloop feedback control system, stability margin improvement by singular value shaping can be achieved by a noise adjustment procedure. A direct method for shaping singular value spectrum using constrained optimization technique is described. The design algorithm minimizes a standard LQG performance index while trying to satisfy minimum singular value constraints at the plant input, or output, or at both. Selected parameters of a stabilizing control law are used as the design variables. The capabilities of this method are demonstrated using a two input two output system representing a drone aircraft and its lateral attitude control system.

Mukhopadhyay, V.↗

NASA NTRS1987

Electronically Controlled Resistor Bank

Resistance quickly varied in small steps over wide range. Device with no moving parts provides variable electrical resistance. Used with analog or digital circuity to provide electronic selection of large number of resistance values for testing, simulation, control, or other purposes. Nearest electromechanical equivalent of all-electronic device is potentiometer driven by servomotor.

Ross, Walter L.↗

NASA NTRS1987

An experimental evaluation of apparent strain from foil strain gauges attached to carbon composite substrates

An experimental evaluation of apparent thermal strains is conducted using various combinations of substrate/gauge/attachment structure and redundant high temperature extensometry. It is found that the extensometry could either confirm independent measurements of the substrate's thermal expansion, or quantify nonzero mechanical strains resulting from uncertain material behavior and boundary conditions. Apparent strain and thermal expansion behavior data can then be used to modify the raw strain measurements in order to determine either stress producing or total strains. Limitation of the correction procedure for the three selected strain gauges is noted which is due to relatively large gauge/attachment variability.

Scott, B. R.↗

NASA NTRS1990

Identification of Cirrus over Wausau during the 1986 FIRE IFO from ground-based radiometer data

The potential of using irradiation data to indicate episodes of cirrus cloudiness during the daylight hours is explored. Thresholds separating cirrus from other clouds and clear skies are determined using four days of irradiation data, hourly weather observations, sky photographs, sky video, and occasional lidar observations. Data were gathered during the First International Satellite Cloud Climatology Program (ISCCP) Regional Experiment (FIRE) Intensive Field Observations (IFO) cirrus project. Thresholds are tested using data from the remaining 17 days of the IFO. Cirrus episodes are defined as intervals when the sky cover is primarily cirrus. Measurements of incoming shortwave and near infrared full hemispheric and diffuse irradiation, and atmospheric infrared irradiation were made at Wausau, Wisconsin Municipal Airport. Data were collected between October 13 and November 2, 1986 and are one minute averages of ten second samples. Data from October 23 and from October 27 to 29 were used for threshold determination. Using weather observations, lidar output, photographs and video, sky conditions were grouped into three categories: noncirrus cloudy, cirrus, and clear. Irradiation data from all periods falling under each of the sky categories were then examined and thresholds denoting a change from one sky category to another were determined. Variables with only a small amount of overlap between sky categories were selected as key indicators.

Robinson, David A.↗

NASA NTRS1993

Experimental effects of wing location on wing-body pressures at supersonic speeds

An experimental study was performed at supersonic speeds to measure wing and body spanwise pressure distributions on an axisymmetric-body delta wing model on which the wing vertical location on the body was systematically varied from low- to high-mounted positions. In addition, for two of these positions both horizontal and radial wing angular orientations relative to the body were tested, and roll angle effects were investigated for one of the positions. Seven different wing-body configurations and a body-alone configuration were studied. The test was conducted at Mach numbers from 1.70 to 2.86 at angles of attack from about -4 deg to 24 deg. Pressure orifices were located at three longitudinal stations on each wing-body model, and at each station the orifices were located completely around the body, along the lower surface of the right wing (looking upstream), and along the upper surface of the left wing. All pressure coefficient data are tabulated and selected samples are shown graphically to illustrate the effects of the test variables. The effects of angle of attack, roll angle, Mach number, longitudinal station, wing vertical location, wing angular orientation, and wing-body juncture are analyzed. The vertical location of the wing on the body had a very strong effect on the body pressures. For a given angle of attack at a roll angle of 0 deg, the pressures were virtually constant in the spanwise direction across the windward surfaces of the wing-body combination. Pressure-relieving, channeling, and vortex effects were noted in the data.

Allen, Jerry M.↗

NASA NTRS1994

Solventless, curable fluid oligomeric systems for high performance microwave, acoustical and mechanical applications

While establishing the basis for a 'Technology 2000' product plan several years ago we plugged in the usual factors contributing toward product success: price/performance justifiable; profitable, warranting high quality maintenance, enhancement, and specific property improvement; narrow inventory requirements; and raw material integrable backwards with easily variable properties (molecular weight, functionality, and isomer control). We resolved this by selecting radical functional, low molecular weight polybutadiene liquid polymers. Encouraged by the need for solid rocket binders, several companies embarked on various perceptions of binder performance requirements over four decades ago. Initially dominated by progress of liquid polysulfides, soon a few settled primarily upon polybutadiene based binders. Such an approach in a few instances was exploited quite viably with a series of functional group terminated liquid polybutadienes: hydroxyl, mercaptan, carboxyl, vinyl, and amine. Good results are obtained for oligomers, liquid polymers, and their hybrids. The only significant limits on compounded products has been solvent resistance and oxidative sensitivity, unless sufficient proportion of sulfide or nitrile moiety is incorporated. For convenience, they have been grouped under the trademarks Nylane, Seamax, Oligomax, and Castomax.

Lefave, G. M.↗

NASA NTRS1995

The CCD/Transit Instrument (CTI) data-analysis system

The automated software system for archiving, analyzing, and interrogating data from the CCD/Transit Instrument (CTI) is described. The CTI collects up to 450 Mbytes of image-data each clear night in the form of a narrow strip of sky observed in two colors. The large data-volumes and the scientific aims of the project make it imperative that the data are analyzed within the 24-hour period following the observations. To this end a fully automatic and self evaluating software system has been developed. The data are collected from the telescope in real-time and then transported to Tucson for analysis. Verification is performed by visual inspection of random subsets of the data and obvious cosmic rays are detected and removed before permanent archival is made to the optical disc. The analysis phase is performed by a pair of linked algorithms, one operating on the absolute pixel-values and the other on the spatial derivative of the data. In this way both isolated and merged images are reliably detected in a single pass. In order to isolate the latter algorithm from the effects of noise spikes a 3x3 Hanning filter is applied to the raw data before the analysis is run. The algorithms reduce the input pixel-data to a database of measured parameters for each image which has been found. A contrast filter is applied in order to assign a detection-probability to each image and then x-y calibration and intensity calibration are performed using known reference stars in the strip. These are added to as necessary by secondary standards boot-strapped from the CTI data itself. The final stages involve merging the new data into the CTI Master-list and History-list and the automatic comparison of each new detection with a set of pre-defined templates in parameter-space to find interesting objects such as supernovae, quasars and variable stars. Each stage of the processing from verification to interesting image selection is performed under a data-logging system which both controls the pipe-lining of data through the system and records key performance monitor parameters which are built into the software. Furthermore, the data from each stage are stored in databases to facilitate evaluation, and all stages offer the facility to enter keyword-indexed free-format text into the data-logging system. In this way a large measure of certification is built into the system to provide the necessary confidence in the end results.

Cawson, M. G. M.↗