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All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

Traveling Weather Disturbances in Mars Southern Extratropics: Sway of the Great Impact Basins

As on Earth, between late autumn and early spring on Mars middle and high latitudes within its atmosphere support strong mean thermal contrasts between the equator and poles (i.e. "baroclinicity"). Data collected during the Viking era and observations from both the Mars Global Surveyor (MGS) and Mars Reconnaissance Orbiter (MRO) indicate that this strong baroclinicity supports vigorous, large-scale eastward traveling weather systems (i.e. transient synoptic-period waves). Within a rapidly rotating, differentially heated, shallow atmosphere such as on Earth and Mars, such large-scale, extratropical weather disturbances are critical components of the global circulation. These wave-like disturbances act as agents in the transport of heat and momentum, and moreover generalized tracer quantities (e.g., atmospheric dust, water vapor and water-ice clouds) between low and high latitudes of the planet. The character of large-scale, traveling extratropical synoptic-period disturbances in Mars' southern hemisphere during late winter through early spring is investigated using a high-resolution Mars global climate model (Mars GCM). This global circulation model imposes interactively lifted (and radiatively active) dust based on a threshold value of the instantaneous surface stress. Compared to observations, the model exhibits a reasonable "dust cycle" (i.e. globally averaged, a more dusty atmosphere during southern spring and summer occurs). In contrast to their northern-hemisphere counterparts, southern synoptic-period weather disturbances and accompanying frontal waves have smaller meridional and zonal scales, and are far less intense synoptically. Influences of the zonally asymmetric (i.e. east-west varying) topography on southern large-scale weather disturbances are examined. Simulations that adapt Mars' full topography compared to simulations that utilize synthetic topographies emulating essential large-scale features of the southern middle latitudes indicate that Mars' transient barotropic/baroclinic eddies are significantly influenced by the great impact basins of this hemisphere (e.g., Argyre and Hellas). In addition, the occurrence of a southern storm zone in late winter and early spring is keyed particularly to the western hemisphere via orographic influences arising from the Tharsis highlands, and the Argyre and Hellas impact basins. Geographically localized transient-wave activity diagnostics are constructed that illuminate fundamental differences amongst such simulations and these are described.

Weather disturbances↗
NASA NTRS2019

Satellite Mapping of PM2.5 Episodes in the Wintertime San Joaquin Valley: A "Static" Model Using Column Water Vapor

The use of satellite Aerosol Optical Thickness (AOT) from imaging spectrometers has been successful in quantifying and mapping high PM2.5 (particulate matter mass <2.5µm diameter) episodes for pollution abatement and health studies. However, some regions have high PM2.5 but poor estimation success. The challenges in using Aerosol Optical Thickness (AOT) from imaging spectrometers to characterize PM2.5 worldwide was especially evident in the wintertime San Joaquin Valley (SJV). The SJV's attendant difficulties of high-albedo surfaces and very shallow, variable vertical mixing also occur in other significantly polluted regions around the world. We report on more accurate PM2.5 maps for the whole-winter period in the SJV, Nov 14, 2012?Dec 11, 2013. Intensive measurements by including NASA aircraft were made for several weeks in that winter, the DISCOVER-AQ California mission.We found success with a relatively simple method based on calibration and checking with surface monitors and a characterization of vertical mixing, and incorporating specific understandings of the region's climatology. We estimate PM2.5 to within ~7µgm?3 RMSE and with R values of ~0.9, based on remotely sensed MAIAC (Multi-Angle Implementation of Atmospheric Correction) observations, and that certain further work will improve that accuracy. Mapping is at 1km resolution. This allows a time sequence of mapped aerosols at 1km for cloud-free days. We describe our technique as a "static estimation". Estimation procedures like this one, not dependent on well-mapped source strengths or on transport error, should help full source-driven simulations by deconstructing processes. They also provide a rapid method to create a long-term climatology.Essential features of the technique are (a) daily calibration of the AOT to PM2.5 using available surface monitors, and (b) characterization of mixed-layer dilution using column water vapor (CWV, otherwise "precipitable water"). We noted that on multi-day timescales both water vapor and particles share near-surface sources and both fall to very low values with altitude; indeed, both are largely removed by precipitation. The existence of layers of H2O or aerosol not within the mixed layer adds complexity, but mixed-effects statistical regression captures essential proportionality of PM2.5 and the ratio variable (AOT/CWV). Accuracy is much higher than previous statistical models, and can be extended to the whole Aqua-satellite data record. The maps and time-series we show suggest a repeated pattern for large valleys like the SJV ? progressive stabilization of the mixing height after frontal passages: PM2.5 is somewhat more determined by day-by-day changes in mixing than it is by the progressive accumulation of pollutants (revealed as increasing AOT).

Chatfield, Robert B.↗
NASA NTRS2022

Limitations in Representation of Physical Processes Prevents Successful Simulation of PM2.5 During KORUS-AQ

High levels of fine particulate matter (PM2.5) pollution in East Asia often exceed local air quality standards. Observations from the Korea United States-Air Quality (KORUS-AQ) field campaign in May and June 2016 showed that development of extreme pollution (haze) occurred through a combination of long-range transport and favorable meteorological conditions that enhanced local production of PM2.5. Atmospheric models often have difficulty simulating PM2.5 chemical composition during haze, which is of concern for the development of successful control measures. We use observations from KORUS-AQ to examine the ability of the GEOS-Chem chemical transport model to simulate PM2.5 composition throughout the campaign and identify the mechanisms driving the pollution event. At the surface, the model underestimates sulfate by -64% but overestimates nitrate by +36%. The largest underestimate in sulfate occurs during the pollution event, where models typically struggle to generate elevated sulfate concentrations due to missing heterogeneous chemistry in aerosol liquid water in the polluted boundary layer. Hourly surface observations show that the model nitrate bias is driven by an overestimation of the nighttime peak. In the model, nitrate formation is limited by the supply of nitric acid, which is biased by +100% against aircraft observations. We hypothesize that this is due to a large missing sink, which we implement here as a factor of five increase in dry deposition. We show that the resulting increased deposition velocity is consistent with observations of total nitrate as a function of photochemical age. The model does not account for factors such as the urban heat island effect or the heterogeneity of the built-up urban landscape resulting in insufficient model turbulence and surface area over the study area that likely results in insufficient dry deposition. Other species such as NH3 could be similarly affected but were not measured during the campaign. Nighttime production of nitrate is driven by NO2 hydrolysis in the model, while observations show that unexpectedly elevated nighttime ozone (not present in the model) should result in N2O5 hydrolysis as the primary pathway. The model is unable to represent nighttime ozone due to an overly rapid collapse of the afternoon mixed layer and excessive titration by NO. We attribute this to missing nighttime heating driving deeper nocturnal mixing that would be expected to occur in a city like Seoul. This urban heating is not considered in air quality models run at large enough scales to treat both local chemistry and long-range transport. Key model failures in simulating nitrate, mainly overestimated daytime nitric acid, incorrect representation of nighttime chemistry, and an overly shallow and insufficiently turbulent nighttime mixed layer, exacerbate the model’s inability to simulate the buildup of PM2.5 during haze pollution. To address the underestimate in sulfate most evident during the haze event, heterogeneous aerosol uptake of SO2 is added to the model which previously only considered aqueous production of sulfate from SO2 in cloud water. Implementing a simple parameterization of this chemistry improves the model abundance of sulfate but degrades the SO2 simulation implying that emissions are underestimated. We find that improving model simulations of sulfate has direct relevance to determining local vs. transboundary contributions to PM2.5. During the haze pollution event, the inclusion of heterogeneous aerosol uptake of SO2 decreases the fraction of PM2.5 attributable to long-range transport from 66% to 54%. Locally-produced sulfate increased from 1% to 25% of locally-produced PM2.5, implying that local emissions controls would have a larger effect than previously thought. However, this additional uptake of SO2 is coupled to the model nitrate prediction which affects the aerosol liquid water abundance and chemistry driving sulfate-nitrate-ammonium partitioning. An additional simulation of the haze pollution with heterogeneous uptake of SO2 to aerosol and simple improvements to the model nitrate simulation results in 30% less sulfate due to 40% less nitrate and aerosol water, and results in an underestimate of sulfate during the haze event. Future studies need to better consider the impact of model physical processes such as dry deposition and nighttime boundary layer mixing on the simulation of nitrate and the effect of improved nitrate simulations on the overall simulation of secondary inorganic aerosol (sulfate+nitrate+ammonium) in East Asia. Foreign emissions are rapidly changing, increasing the need to understand the impact of local emissions on PM2.5 in South Korea to ensure continued air quality improvements.

Katherine R. Travis↗
DOE OSTI2026

Influence of plateau, slope, and valley on soil hydrology during the dry season in a Central Amazon old‐growth forest

Soil moisture regulates plant water supply and drought sensitivity in tropical forests, yet its vertical and topographic variation remains poorly characterized. We combined high-frequency time-domain reflectometry measurements from 5 to 100 cm across plateau, slope, and valley landforms at the Zona Florestal 2 research site north of Manaus, Central Amazonia, to quantify how soil moisture memory, timing of responses to rainfall, dry-down rates (τ), and soil–water depletion vary across these contrasting landforms. Landform-specific soil moisture calibration curves ensured accurate volumetric water content estimates in these highly weathered soils. During the 2023 dry-to-wet transition (August–November), soil moisture memory showed strong topographic contrasts, with valley profiles increasing from ∼47 h at 5 cm to ∼154 h at 100 cm, while plateaus exhibited higher near-surface persistence (∼124 h at 5 cm) but weaker memory at depth. Dry-down behavior reinforced these differences as valley soils exhibited τ values exceeding ∼200 h, more than double the characteristic τ of plateau soils (∼90 h). Rainfall–soil moisture correlations indicated immediate responses at shallow depths in valleys and progressively longer lags with depth on plateaus and slopes. These hydrologic patterns were mirrored in depletion profiles, which declined sharply below 30 cm on plateaus but remained high and sustained throughout the upper meter in slopes and valleys. Together, these findings provide the first depth-resolved field measurements of soil moisture memory, rainfall coupling, dry-down constants, and depletion dynamics across major upland landforms in Central Amazonia and offer clear observational benchmarks for improving land-surface and ecosystem model representations of soil–water processes.

Hillslope↗
NASA NTRS2016

Tsunami Generation from Asteroid Airburst and Ocean Impact and Van Dorn Effect

Airburst - In the simulations explored energy from the airburst couples very weakly with the water making tsunami dangerous over a shorter distance than the blast for asteroid sizes up to the maximum expected size that will still airburst (approx.250MT). Future areas of investigation: - Low entry angle airbursts create more cylindrical blasts and might couple more efficiently - Bursts very close to the ground will increase coupling - Inclusion of thermosphere (>80km altitude) may show some plume collapse effects over a large area although with much less pressure center dot Ocean Impact - Asteroid creates large cavity in ocean. Cavity backfills creating central jet. Oscillation between the cavity and jet sends out tsunami wave packet. - For deep ocean impact waves are deep water waves (Phase speed = 2x Group speed) - If the tsunami propagation and inundation calculations are correct for the small (<250MT) asteroids in these simulations where they impact deep ocean basins, the resulting tsunami is not a significant hazard unless particularly close to vulnerable communities. Future work: - Shallow ocean impact. - Effect of continental shelf and beach profiles - Tsunami vs. blast damage radii for impacts close to populated areas - Larger asteroids below presumed threshold of global effects (Ø200 - 800m).

Tsunami↗
DOE OSTI2024

Using phenology to unravel differential soil water use and productivity in a semiarid savanna

Savannas are water-limited ecosystems characterized by two dominant plant types: trees and an understory primarily made up grass. Different phenology and root structures of these plant types complicate how savanna primary productivity responds to changes in water availability. We tested the hypothesis that productivity in savannas is controlled by the temporal and vertical distribution of soil water content (SWC) and differences in growing season length of understory and tree plant functional types. To quantify the relationship between tree, understory, and savanna-wide phenology and productivity, we used PhenoCam and satellite observations surrounding an eddy covariance tower at a semiarid savanna site in Arizona, USA. We distinguished between SWC across two different depth intervals (shallow, <0–30 cm and deep, >30–100 cm). We found that tree greenness increased with SWC at both depths, while understory greenness was only sensitive to the shallower SWC measurements. Onset of ecosystem dormancy, estimated from satellite observations close to the eddy covariance tower, explained more variability in annual gross primary productivity (GPP) than in other phenometrics. Higher SWC led to an extended growing season, caused by delayed dormancy in trees, but the understory showed no evidence of delayed dormancy in wetter periods. We infer that the timing of ecosystem scale dormancy, driven by trees, is important in understanding changes in a savanna's GPP. These findings highlight the important effects of rainfall during the winter. These findings suggest that savanna GPP is conditional on different responses to moisture availability in each of the dominant vegetation components.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1993

An intercomparison of three satellite infrared rainfall techniques over Japan and surrounding waters

Three satellite infrared techniques of increasing complexity for the estimation of rainfall are compared: (1) the GOES precipitation index (Arkin, 1979, 1983), (2) the Negri-Adler-Wetzel (Negri et al., 1984) technique, and (3) the convective-stratiform technique (CST), described by Adler and Negri (1988). It is shown that all three techniques performed poorly in estimating the rain maxima over southeastern Japan associated with shallow orographic warm rain systems. However, when the data set was limited to the ocean-only points, the CST method performed best, with the lowest bias, the lowest rms, and the highest correlation. Daily rainfall estimates had rms errors of almost 200 percent of the mean, and negative biases of about 50 percent of the mean.

Negri, Andrew J.↗
NASA NTRS1977

Borehole hydraulic coal mining system analysis

The borehole hydraulic coal mining system accesses the coal seam through a hole drilled in the overburden. The mining device is lowered through the hole into the coal seam where it fragments the coal with high pressure water jets which pump it to the surface as a slurry by a jet pump located in the center of the mining device. The coal slurry is then injected into a pipeline for transport to the preparation plant. The system was analyzed for performance in the thick, shallow coal seams of Wyoming, and the steeply pitching seams of western Colorado. Considered were all the aspects of the mining operation for a 20-year mine life, producing 2,640,000 tons/yr. Effects on the environment and the cost of restoration, as well as concern for health and safety, were studied. Assumptions for design of the mine, the analytical method, and results of the analysis are detailed.

Floyd, E. L.↗
DOE OSTI2020

Origin of tungsten and geochemical controls on its occurrence and mobilization in shallow sediments from Fallon, Nevada, USA

In this study, tungsten (W) occurrence and speciation was investigated in sediments collected from Fallon, Nevada where previous studies have linked elevated W levels in human body fluids to an unusual cluster of childhood leukemia cases. The speciation of sedimentary W was determined by μ-XRF mapping and μ-XANES. The W content of the analyzed surface sediments ranged between 81 and 25,908 mg/kg, which is significantly higher than the W content in deeper sediments which ranged from 37 to 373 mg/kg at 30 cm depth. The μ-XANES findings reveal that approximately 20–50% of the total W in the shallow sediment occurs in the metallic form (W 0 ); the rest occurs in the oxide form (W VI O 3 ). Because W 0 does not occur naturally, its elevated concentrations in surface sediments point toward a possible local anthropogenic origin. The oxidation of metallic W 0 with meteoric waters likely leads to the formation of W VI O 3 . The chief water-soluble W species was identified as WO 4 2– by chromatographic separation and speciation modeling. These results led us to postulate that W 0 particles from a currently unknown but local source(s) is (are) deposited onto the soils and/or surface sediments. The W 0 in interaction with meteoric water is oxidized to W VI O 3 , and as these sediment-water interactions progress, WO 4 2– is formed in the water at pH ~7. Under pH < 7, and sufficient W concentrations, tungstate tends to polymerize, and polymerized species are less likely to adsorb onto sediments. Polymerized species have lower affinity than monomers, which leads to enhanced mobility of W.

58 GEOSCIENCES↗
DOE OSTI2022

Peak Rain Rate Sensitivity to Observed Cloud Condensation Nuclei and Turbulence in Continental Warm Shallow Clouds During CACTI

Abstract Warm clouds strongly affect Earth's energy budget but remain imperfectly represented in climate models, partly due to the complexity and covariability of relevant processes influencing warm rain. This work presents a detailed analysis of different factors affecting rain rate peak intensity (RR) in continental warm clouds. Clouds were identified with vertically pointing radar and lidar observations and categorized via a temperature‐based cloud type classification algorithm from which warm clouds were isolated. Observations and retrievals of liquid water path (LWP), cloud condensation nuclei concentration (N CCN ), cloud depth, and cloud duration of more than 3,000 separate warm clouds sampled during the Cloud, Aerosol, and Complex Terrain Interactions (CACTI) field campaign are analyzed in this work. Multiple linear regression (MLR) and random forest (RF) models are applied to assess the relative impact of these variables on RR. Overall, RR tends to increase as cloud depth, LWP, and cloud duration increase, or N CCN decreases. Cloud depth affects RR the most while N CCN impacts it the least. When considering over 170 warm clouds observed at least 1 hr in which in‐cloud turbulence is retrieved, the effect of N CCN on RR remains most likely suppressive, but it is not significant at a 75% level for MLR and is highly uncertain for RF. The impact of in‐cloud turbulence depends on the moment and location it is sampled. Cloud base turbulence around the time of RR suppresses RR, while cloud top turbulence effects are inconclusive. Possible difficulties in isolating robust CCN and turbulence effects on RR are discussed.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Formulation of autoconversion and drop spectra shape in shallow cumulus clouds

Two-moment autoconversion parameterizations as compared to accretion parameterizations exhibit significant errors suggesting that additional moments are needed to increase their accuracy. We develop a three-moment autoconversion parameterization using output from an LES model with size-resolved microphysics. Adding the third moment decreases the errors of parameterization and improves precipitation prediction. However, the errors are still significantly larger than errors of accretion rate. An analysis of the cloud drop size distributions (DSDs) in the simulated tropical convective cloud system reveals that most of DSDs have a significant fraction of cloud liquid water content (qc) in the mid-size droplet range (radii from 20 to 40 microns). Our data indicates that more than 30% of DSDs have over half of qc contained in the mid-size range and about 60% of spectra have, at least, one third of qc in this range. Even when the rain/drizzle mode is small (radar reflectivity Z < -10 dBZ), there is a significant number of spectra in which fraction of qc in the mid-size range is as large as 60%. These DSDs are more complex than the frequently used single-mode Gamma or Log-normal distributions, which usually do not have a considerable tail extending to the mid-size range and can be defined by three microphysical moments. The need to define DSDs by more than three moments explains the large errors in the three-moment autoconversion parameterization. The limitation of three-parameter Gamma or Log-normal distributions should be kept in mind when applying them in precipitating shallow Cu clouds.

Kogan, Yefim↗
DOE OSTI2023

An ensemble of 48 physically perturbed model estimates of the 1/8° terrestrial water budget over the conterminous United States, 1980–2015

Terrestrial water budget (TWB) data over large domains are of high interest for various hydrological applications. Spatiotemporally continuous and physically consistent estimations of TWB rely on land surface models (LSMs). As an augmentation of the operational North American Land Data Assimilation System Phase 2 (NLDAS-2) four-LSM ensemble, this paper describes a dataset simulated from an ensemble of 48 physics configurations of the Noah LSM with multi-physics options (Noah-MP). The 48 Noah-MP physics configurations are selected to give a representative cross-section of commonly used LSMs for parameterizing runoff, atmospheric surface layer turbulence, soil moisture limitation on photosynthesis, and stomatal conductance. The dataset spans from 1980 to 2015 over the conterminous United States (CONUS) at a monthly temporal resolution and a 1/8° spatial resolution. The dataset variables include total evapotranspiration and its constituents (canopy evaporation, soil evaporation, and transpiration), runoff (the surface and subsurface components), as well as terrestrial water storage (snow water equivalent, four-layer soil water content from the surface down to 2 m, and the groundwater storage anomaly). The dataset is available at https://doi.org/10.5281/zenodo.7109816. Evaluations carried out in this study and previous investigations show that the ensemble per forms well in reproducing the observed terrestrial water storage, snow water equivalent, soil moisture, and runoff. Noah-MP complements the NLDAS models well, and adding Noah-MP consistently improves the NLDAS es timations of the above variables in most areas of CONUS. Besides, the perturbed-physics ensemble facilitates the identification of model deficiencies. The parameterizations of shallow snow, spatially varying groundwater dynamics, and near-surface atmospheric turbulence should be improved in future model versions.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1992

Does the sedimentology of the Chelmsford formation provide evidence for a meteorite impact origin of the Sudbury structure?

The post-'event' fill of the Paleoproterozoic Sudbury Basin consists of at least 600 m of deep-water mudrocks of the Onwatin Formation, overlain by 850 m of lithic-arkosic muddy sandstones in the Chelmsford Formation. While mudstones of the Onwatin reflect deposition in a deep-water, anoxic setting, there is no clear evidence of local breccias, conglomerates, or sand bodies to support the concept that the basin was protected by the steep walls of an impact crater. Carbonates in the basal, Vermillion Member are of sedimentary exhalitive origin and were not derived from a shallow marine shelf. Turbidites in the Chelmsford Formation show no evidence of centripetal fill as might be expected from a restricted, circular basin. They appear to have been emplaced by predominantly southwesterly flowing turbidity currents, which showed little to no deflection along the depositional axis of an elongate foreland basin that developed in front of the rising Penokean mountain chain. While the presence of minor sandstone-filled fractures in parts of the Chelmsford Formation suggests the presence of north- or south-directed paleoslopes, no evidence is seen to support the existence of subbasins or a central uplift within the Sudbury Basin. While tilt-corrected paleocurrent orientations are ambiguous, due to postdepositional shortening of strata during cleavage development, strain correction of the observations makes little difference to the net, south-southwest-directed paleoflow.

Long, D. G. F.↗
NASA NTRS1992

Geological evidence for a 2.6-Ga strewn field of impact spherules in the Hamersley Basin of Western Australia

Sand-sized spherules up to 1.7 mm across with spherulitic, vesicular, and other crystalline textures that consist mainly of K-feldspar help define a unique horizon in the well-preserved 2.6-Ga Wittenoom Formation in the Hamersley Basin of Western Australia. This layer is informally known as the spherule marker bed. In the northeastern part of the Hamersley Basin, similar spherules again occur at only one horizon, but here they are a minor constituent of a dolomitic debris-flow deposit known as the dolomixtite layer. The dolomixtite layer occurs in the Carawine Dolomite, which is stratigraphically equivalent to the Wittenoom Formation. Moreover, paleocurrent data from closely associated carbonate and volcaniclastic turbidites indicate the spherule marker bed was deposited in deeper-water paleoenvironments than the dolomixtite layer. Therefore, the dolomixtite layer is believed to be a proximal equivalent of the spherule marker bed. The layers that host the spherules are interpreted to be the deposits of a major sediment gravity flow that exhumed and redeposited most of the spherules after shallow burial, although the flow is not believed to have been a direct result of the proposed impact. The most likely site for the proposed impact would have been in the early Precambrian ocean close to the northeastern edge of the Pilbara Craton. Another thin horizon in the overlying Brockman Iron Formation contains spherules that again consist largely of K-feldspar and have internal textures strikingly similar to those of the Wittenoom Formation and Carawine Dolomite. The close resemblance of these spherules to those of the Wittenoom Formation and Carawine Dolomite suggests they also originated as impact melt droplets, even though they are admixed with volcaniclastic detritus. The stratigraphic separation between the two suggests that a second major impact occurred near the Hamersley Basin after a time interval of about 75 m.y. elapsed. This suggests the record of impacts in early Precambrian strata is richer than is generally appreciated.

Simonson, Bruce M.↗
NASA NTRS2021

The GF Convection Parameterization: Recent Developments, Extensions, and Applications

Recent developments and options in the GF (Grell and Freitas, 2014, Freitas et al.,2018) convection parameterization are presented. The parameterization has been expanded to atrimodal spectral size to simulate three convection modes: shallow, congestus and deep. Incontrast to usual entrainment/detrainment assumptions, we assume that Beta Functions (BFs),commonly applied to represent Probability Density Functions (PDF’s), can be used tocharacterize the vertical mass flux profiles for the three modes, and use the BFs to deriveentrainment and detrainment rates. We also added a new closure for non-equilibrium convectionthat improved the simulation of the diurnal cycle of convection, with a better representation ofthe transition from shallow to deep convection regimes over land. The transport of chemicalconstituents (including wet deposition) can be treated inside the GF scheme. The tracer transportis handled in flux form and is mass conserving. Finally, the cloud microphysics has beenextended to include the ice phase to simulate the conversion from liquid water to ice in updraftswith resulting additional heat release and the melting from snow to rain.

Saulo R De Freitas↗
DOE OSTI2020

Liquid-phase mega-electron-volt ultrafast electron diffraction

The conversion of light into usable chemical and mechanical energy is pivotal to several biological and chemical processes, many of which occur in solution. To understand the structure–function relationships mediating these processes, a technique with high spatial and temporal resolutions is required. Here, we report on the design and commissioning of a liquid-phase mega-electron-volt (MeV) ultrafast electron diffraction instrument for the study of structural dynamics in solution. Limitations posed by the shallow penetration depth of electrons and the resulting information loss due to multiple scattering and the technical challenge of delivering liquids to vacuum were overcome through the use of MeV electrons and a gas-accelerated thin liquid sheet jet. To demonstrate the capabilities of this instrument, the structure of water and its network were resolved up to the 3rd hydration shell with a spatial resolution of 0.6 Å; preliminary time-resolved experiments demonstrated a temporal resolution of 200 fs.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2023

A TOPAS model for lens-based proton radiography

Abstract Objective. Proton Radiography can be used in conjunction with proton therapy for patient positioning, real-time estimates of stopping power, and adaptive therapy in regions with motion. The modeling capability shown here can be used to evaluate lens-based radiography as an instantaneous proton-based radiographic technique. The utilization of user-friendly Monte Carlo program TOPAS enables collaborators and other users to easily conduct medical- and therapy- based simulations of the Los Alamos Neutron Science Center (LANSCE). The resulting transport model is an open-source Monte Carlo package for simulations of proton and heavy ion therapy treatments and concurrent particle imaging. Approach. The four-quadrupole, magnetic lens system of the 800-MeV proton beamline at LANSCE is modeled in TOPAS. Several imaging and contrast objects were modelled to assess transmission at energies from 230–930 MeV and different levels of particle collimation. At different proton energies, the strength of the magnetic field was scaled according to βγ, the inverse product of particle relativistic velocity and particle momentum. Main results. Materials with high atomic number, Z, (gold, gallium, bone-equivalent) generated more contrast than materials with low-Z (water, lung-equivalent, adipose-equivalent). A 5-mrad collimator was beneficial for tissue-to-contrast agent contrast, while a 10-mrad collimator was best to distinguish between different high-Z materials. Assessment with a step-wedge phantom showed water-equivalent path length did not scale directly according to predicted values but could be mapped more accurately with calibration. Poor image quality was observed at low energies (230 MeV), but improved as proton energy increased, with sub-mm resolution at 630 MeV. Significance. Proton radiography becomes viable for shallow bone structures at 330 MeV, and for deeper structures at 630 MeV. Visibility improves with use of high-Z contrast agents. This modality may be particularly viable at carbon therapy centers with accelerators capable of delivering high energy protons and could be performed with carbon therapy.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2021

Low diffusive methane emissions from the main channel of a large Amazonian run-of-the-river reservoir attributed to high methane oxidation

The global development of hydropower dams has rapidly expanded over the last several decades and has spread to historically non-impounded systems such as the Amazon River's main low land tributaries in Brazil. Despite the recognized significance of reservoirs to the global methane (CH4) emission, the processes controlling this emission remain poorly understood, especially in Tropical reservoirs. Here we evaluate CH4 dynamics in the main channel and downstream of the Santo Antônio hydroelectric reservoir, a large tropical run-of-the-river (ROR) reservoir in Amazonia. This study is intended to give a snapshot of the CH4 dynamics during the falling water season at the initial stage after the start of operations. Our results show substantial and higher CH4 production in reservoirs' littoral sediment than in the naturally flooded areas downstream of the dam. Despite the large production in the reservoir or naturally flooded areas, high CH4 oxidation in the main channel keep the concentration and fluxes of CH4 in the main channel low. Similar CH4 concentrations in the reservoir and downstream close to the dam suggest negligible degassing at the dam, but stable isotopic evidence indicates the presence of a less oxidized pool of CH4 after the dam. ROR reservoirs are designed to disturb the natural river flow dynamics less than traditional reservoirs. If enough mixing and oxygenation remain throughout the reservoir's water column, naturally high CH4 oxidation rates can also remain and limit the diffusive CH4 emissions from the main channel. Nevertheless, it is important to highlight that our results focused on emissions in the deep and oxygenated main channel. High emissions, mainly through ebullition, may occur in the vast and shallow areas represented by bays and tributaries. However, detailed assessments are still required to understand the impacts of this reservoir on the annual emissions of CH4.

Amazon, aquatic, biogeochemistry, carbon cycling, ↗