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This paper describes a set of analytical methods which have been developed to enable quantitative analysis of encapsulation system designs for terrestrial photovoltaic modules. Design factors determined most important include: encapsulant thickness and modules, emissivity of module surface, ribs on substrate modulus, and AR.
PMR polyimide resin was prepared from 4,4'-methylenedianiline, the dimethyl ester of 3,3',4,4'-benzophenonetetracarboxylic acid and the monomethyl ester of 5-norbornene-2,3-dicarboxylic acid (NE). The NE group serves as a chain terminator and crosslinking site. PMR/Celion 6000 composites were fabricated from resins having varying NE concentrations using two molding processes, and the laminates characterized in forced torsion. Glass transition temperatures (T(g)) of 360-390 C were observed in the crosslinked resins, as compared with the literature value of 284 C reported for the uncrosslinked system. T(g) did not decrease with decreasing NE concentrations over the range from 2.0 to 1.25 moles. Stoichiometry, within the range studied, showed little influence on shear properties; however, a 25% variation in matrix shear modulus with processing was observed. The G(12) values determined in forced torsion were in excellent agreement with those reported from tensile tests of + or - 45 deg laminates. A branching and possible secondary crosslink mechanism is proposed based on dynamic mechanical behavior and infrared spectra of the composites.
Progress in the development of processes for production of Celion/LARC-160 graphite-polyimide materials, quality control, and the fabrication of Space Shuttle composite structure components is reported. Liquid chromatographic analyses of three repeatibility batches were performed and are compared to previous Hexcel standard production and to variables study LARC-160 intermediate resins. Development of processes for chopped fiber molding are described and flexural strength, elastic modulus, and other physical and mechanical properties of the molding are presented.
A geometrically nonlinear finite element analysis of cohesive failure in typical joints is presented. Cracked-lap-shear joints were chosen for analysis. Results obtained from linear and nonlinear analysis show that nonlinear effects, due to large rotations, significantly affect the calculated mode 1, crack opening, and mode 2, inplane shear, strain-energy-release rates. The ratio of the mode 1 to mode 2 strain-energy-relase rates (G1/G2) was found to be strongly affected by he adhesive modulus and the adherend thickness. The ratios between 0.2 and 0.8 can be obtained by varying adherend thickness and using either a single or double cracked-lap-shear specimen configuration. Debond growth rate data, together with the analysis, indicate that mode 1 strain-energy-release rate governs debond growth. Results from the present analysis agree well with experimentally measured joint opening displacements.
The incorporation of specific metal ions into polyimides is described. Detailed studies have included various compounds of copper, lithium, and palladium as dopants. Addition of the metal during polymerization or after formation of the polyamic acid precedes the thermal imidization step. With many dianhydride-diamine-dopant combinations high quality variously colored films are produced. Many metal doped films exhibit (1) improved high temperature adhesive properties, (2) increased electrical conductivity, (3) excellent thermal stability, (4) improved acid/base resistance, (5) increased modulus in flexible films and (6) excellent high temperature tensile strength. X-ray photo-electron spectroscopic study of these films suggests that many of the additives undergo chemical modification during thermal imidization. Palladium dopants appear to be partially reduced to the metallic state, while lithium and copper dopants are probably converted to their oxides. Ion etching experiments with Auger electron spectroscopy monitoring are discussed.
The development of an iron-base alloy that combines the normally divergent properties of high toughness and high strength at cryogenic temperatures is discussed. Specifically, alloy properties were sought which at -196 C would exhibit a fracture toughness of 220 MPa-m(1/2) with a corresponding yield strength of 1.4 GPa (200 ksi). Early work showed that high toughness could be achieved in Fe-12Ni alloys containing reactive metal additions such as Al, Nb, Ti, and V. Further research emphasized strengthening of these tough alloys by thermomechanical processing and the addition of Cu. Results showed that high strength and high toughness could be achieved in a single alloy at temperatures as low as -196 C. An alloy with composition Fe-12Ni-9.5Al-2Cu exhibited a yield strength of 1.65 GPa with a corresponding fracture toughness of 220 MPa-m(1/2) at -196 C. Strengthening due to Cu additions to the Fe-12Ni base alloys results primarily from precipitation of Cu-rich epsilon particles approximately 20 nm in diameter. Strengthening mechanisms are discussed in terms of an elastic modulus hardening model and are supported by transimission electron microscopy examinations of selected test specimens.
In the analysis of rolling-sliding concentrated contacts, such as gears, bearings and traction drives, the traction characteristics of the lubricant are of prime importance. The elastic shear modulus and limiting shear stress properties of the lubricant dictate the traction/slip characteristics and power loss associated with an EHD contact undergoing slip and/or spin. These properties can be deducted directly from the initial slope m and maximum traction coefficient micron of an experimental traction curve. In this investigation, correlation equations are presented to predict m and micron for two modern traction fluids based on the regression analysis of 334 separate traction disk machine experiments. The effects of contact pressure, temperature, surface velocity, ellipticity ratio are examined. Problems in deducing lubricant shear moduli from disk machine tests are discussed.
A test program is undertaken to verify that the lifetime of a shuttle launchable dewar can be increased by using passive orbital disconnect struts (PODS). A detailed design is performed on the cold end (PODS-III) portion of the strut. Structural analysis of the thin-wall fiberglass tube allows selection of the optimum winding angle and tube dimensions. Structural tests on the thin-wall fiberglass tube measure both the tension and compression modulus at ambient and LN2 temperatures, the radial deflection versus side load, and the ultimate compression strength of the tube at LN2 temperature. The thermal expansion of the fiberglass tube plus Invar is also measured down to 78 K. The axial gap at the wedge portion of the stem is set based on these data. The PODS-III test article parts are fabricated and assembled using a detailed assembly procedure. The thermal conductants in the orbital configuration was measured for body temperatures between 5 and 40 K. This temperature range covers the predicted ground hold and orbit temperatures for vapor-cooled supports. The test results are then compared with heat leak values predicted before the test began. Side load, axial compression load, and tension load tests conclude the test program.
A simple model to study low velocity transverse impact of thin plates made of fiber-reinforced composite material, in particular T300/5208 graphite-epoxy was discussed. This model predicts the coefficient of restitution, which is a measure of the energy absorbed by the target during an impact event. The model is constructed on the assumption that the plate is inextensible in the fiber direction and that the material is incompressible in the z-direction. Such a plate essentially deforms by shear, hence this model neglects bending deformations of the plate. The coefficient of restitution is predicted to increase with large interlaminar shear strength and low transverse shear modulus of the laminate. Predictions are compared with the test results of impacted circular and rectangular clamped plates. Experimentally measured values of the coefficient of restitution are found to agree with the predicted values within a reasonable error.
Light optical and scanning electron microscope studies were conducted to characterize the erosion resistance of polymethyl methacrylate (PMMA), polycarbonate (PC), polytetrafluoroethylene (PTFE) and ultra-high-molecular-weight-polyethylene (UHMWPE). Erosion was caused by a jet of spherical micro-glass beads at normal impact. During the initial stages of damage, the surfaces of these materials were studied using a profilometer. Material buildup above the original surface was observed on PC and PMMA. As erosion progressed, this buildup disappeared as the pit became deeper. Little or no buildup was observed on PTFE and on UHMWPE. UHMWPE and PTFE are the most resistant materials and PMMA the least. Favorable properties for high erosion resistance seem to be high values of ultimate elongation, and strain energy and a low value of the modulus of elasticity. Erosion-rate-versus-time curves of PC and PTFE exhibit incubation, acceleration and steady state periods. A continuously increasing erosion rate period was observed however for PMMA instead of a steady state period. At early stages of damage and at low impact pressure material removal mechanisms appear to be similar to those for metallic materials.
Design features of the stacking triangular articulated compact beam (Stacbeam) as a candidate truss structure for GEOS spacecraft solar power arrays are explored. Solar arrays of increasing size require folding, noninterfering structures, minimal thermal effects, slow and controlled deployment, and a high aspect ratio. The Stacbeam consists of a triangular batten frame perpendicular to the beam axis, three longerons attached at the corners of the batten frame and mounted parallel to the beam axis, and three diagonals to provide shear and torsional stiffness. Locking hinges are installed at the midpoint and ends of each longeron and at the midpoint and ends of each diagonal. The material is graphite/epoxy composite with a 120 GPa modulus and a 1500 kg/sq m density. Successful vertical deployment on the ground has been effected with a prototype deployer, together with horizontal cantilever in a fully deployed configuration.
A brief description is given of the 1m-EUV-Telescope and its focal plane instrumentation, namely an EUV spectrometer and six EUV/FUV photometers. The telescope is scheduled for launch on an Aries rocket on June 17, 1982. The principal goals are the white dwarf HZ43 and a photometric scan across the sky in an area of the sky where 21 cm line observations reveal a steep density gradient. The optical bench of the telescope is a cylinder made of a graphite epoxy compound. Despite its low specific weight, the bench shows an excellent mechanical performance, with an elasticity modulus of approximately 70,000 N/cu mm. It is pointed out that by carefully combining layers with different winding angles of the carbon fiber, the thermal expansion along the cylinder axis is almost negligible, even under severe thermal loads
The 116-394 K temperature range elastic constants, ultimate strengths and thermal expansion behavior of T300/5208 graphite/epoxy laminates of various different lay-up types have been determined. It is noted that most properties exhibit nearly linear temperature dependencies, although the transverse modulus and axial thermal expansion vary nonlinearly with temperature, and change in value by an order of magnitude over the present temperature range.
The plane elasticity problem for a nonhomogeneous medium containing a crack is considered. It is assumed that the Poisson's ratio of the medium is constant and the Young's modulus E varies exponentially with the coordinate parallel to the crack. First the half plane problem is formulated and the solution is given for arbitrary tractions along the boundary. Then the integral equation for the crack problem is derived. It is shown that the integral equation having the derivative of the crack surface displacement as the density function has a simple Cauchy type kernel. Hence, its solution and the stresses around the crack tips have the conventional square root singularity. The solution is given for various loading conditions. The results show that the effect of the Poisson's ratio and consequently that of the thickness constraint on the stress intensity factors are rather negligible.
Laminate elastic constants and coefficients of thermal expansion calculated for near-zero-expansion graphite/aluminum and graphite/ magnesium composites. Report presents results in graphic form for these properties as function of laminate angle and fiber volume fraction for four high-modulus continuous-pitch fiber.
An angular-contact ball bearing provides an easily obtainable, precise mechanical system for rheological tests on thin films under high pressure. The test conditions are by definition similar to those found in practice. Accessible independent variables include size, pressure, bulk temperature, roughness, adsorbed surfactant, fluid type, fluid quantity, fluid supply rate, film thickness, entrainment velocity, transit time, and combined strain. Easily measured or inferred variables include slip, changes in film thickness with time (transients), strain rate, lubricant elastic modulus (thin film, high pressure), tractive force, lubricant chemical degradation rate, and lubricant degradation product. Methods for setting and obtaining these quantities in a bearing are discussed, together with experimental limitations on them.
The behavior of acoustic attenuation in a solid is related to the electrical transmission line model where the electrical shunt conductance, which is frequency dependent, represents the loss due to the scattering sites in the solid. Results indicate that the absolute value of attenuation at a given frequency depends on both the normalized mean square deviation of the density and bulk modulus of the scattering sites from the ambient medium and the spatial scattering correlation function. Besides establishing the absolute value of attenuation, the spatial correlation function determines the attenuation profile as a function of frequency.
The stability of finite difference models of hyperbolic initial boundary value problems is connected with the propagation and reflection of parasitic waves. Wave propagation ideas are applied to models containing two boundaires or interfaces, where repeated reflection of trapped wave packets is a potential new source of instability. Various known instability phenomena are accounted for in a unified way. Results show: (1) dissipativity does not ensure stability when three or more formulas are concatenated at a boundary or internal interface; (2) algebraic GKS instabilities can be converted by a second boundary to exponential instabilities only when an infinite numerical reflection coefficient is present; and (3) GKS-stability and P-stability can be established in certain problems by showing that all numerical reflection coefficients have modulus less than 1.