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At least 811 records · Page 45

Development of techniques and associated instrumentation for high temperature emissivity measurements

Studies were made to develop a test apparatus for the measurement of total emittance of materials under repeated exposure to simulated earth entry conditions. As no existing test facility met the emittance measurement and entry simulation goals, a new apparatus was designed, fabricated and checked out. This apparatus has the capability of performing total and spectral emittance measurements during cyclic temperature and pressure exposure under sonic and supersonic flow conditions. Emittance measurements were performed on a series of oxidized superalloys, silicide coated columbium alloys and ceramic coatings.

Cunnington, G. R.↗

Aminonitriles - Possible role in chemical evolution

The formation of HCN, ammonium cyanide, alkylnitriles, aminoacetonitrile and its C- and N-methyl homologs was demonstrated earlier in a simulated Jovian atmosphere. The polymeric material resulting in these experiments was shown to give glycine, alanine, sarcosine, aspartic acid and some imino dibasic acids on acid hydrolysis, suggesting thereby the participation of the monomeric nitriles in the formation of the polymeric product(s). Further examination of products resulting from semicorona and arc discharge through a mixture of methane and ammonia has provided evidence for the formation of alkylaminopropionitriles as a complex mixture and also some pyridyl and pyrimidyl type heterocyclic compounds. A gas chromatograph/mass spectrometer examination of the heterocyclics showed resemblance with those found in some carbonaceous chondrites. The significance of these findings in relation to chemical evolution is discussed.

Chadha, M. S.↗

Current technology for development of low solar absorptance/high emittance coatings

A comprehensive program to develop low solar absorptance/high emittance coatings, to be successful, must coordinate basic materials preparation, coatings technology, environmental simulation, production, and flight-test evaluation. The prime criteria for 'white' thermal-control coatings are low solar absorptance and, most importantly, solar-absorptance stability. Many variables affect the solar absorptance and its stability. These effects must be discerned and evaluated. The factors involved, however, are not entirely independent; accordingly, the present paper emphasizes the major variables, the relationships among them, and how important they are in improving the properties and performance of the coatings.

Gilligan, J. E.↗

Study of changes in properties of solar sail materials from radiation exposure

Techniques for monitoring changes in preparation of solar sail materials resulting from space radiation simulation, stressing (e.g., thermal, mechanical) and exposure to terrestrial environments are developed. The properties of interest are: metallic coating deterioration, polymeric film deterioration, interfacial debonding and possible metallic coating diffusion into the polymeric film. Four accelerated tests were devised to simulate the possible degradation processes mentioned above. These four tests are: a thermal shock test to simulate the wide variation of temperature expected in space (260 C to -100 C), a cyclic temperature test to stimulate the 6 minute temperature cycle anticipated in space, a mechanical vibration test to simulate mechanical bonding, folding and handling, and a humidity test to simulate terrestrial environment effects. The techniques for monitoring property changes are: visual and microscopic examination, ellipsometry, surface potential difference (SPD), photoelectron emission (PEE), and water contact angles.

Smith, T.↗

TNT equivalency of M10 propellant

Peak, side-on blast overpressure and scaled, positive impulse have been measured for M10 single-perforated propellant, web size 0.018 inches, using configurations that simulate the handling of bulk material during processing and shipment. Quantities of 11.34, 22.7, 45.4, and 65.8 kg were tested in orthorhombic shipping containers and fiberboard boxes. High explosive equivalency values for each test series were obtained as a function of scaled distance by comparison to known pressure, arrival time and impulse characteristics for hemispherical TNT surface bursts. The equivalencies were found to depend significantly on scaled distance, with higher values of 150-100 percent (pressure) and 350-125 percent (positive impulse) for the extremes within the range from 1.19 to 3.57 m/cube root of kg. Equivalencies as low as 60-140 percent (pressure) and 30-75 percent (positive impulse) were obtained in the range of 7.14 to 15.8 m/cube root of kg. Within experimental error, both peak pressure and positive impulse scaled as a function of charge weight for all quantities tested in the orthorhombic configuration.

Mcintyre, F. L.↗

High current lightning test of space shuttle external tank lightning protection system

During lift-off, the shuttle launch vehicle (external tank, solid rocket booster and orbiter) may be subjected to a lightning strike. Tests of a proposed lightning protection method for the external tank and development materials which were subjected to simulated lightning strikes are described. Results show that certain of the high resistant paint strips performed remarkably well in diverting the 50 kA lightning strikes.

Mumme, E.↗

Evaluation and prediction of long-term environmental effects on nonmetallic materials

Changes in functional properties of a broad spectrum of nonmetallic materials as a function of environment and exposure time were evaluated. Models for predicting long-term material performance are discussed. A literature search on specific materials in the space and simulated space environment was carried out and evaluated.

Source record↗

Evaluation and prediction of long-term environmental effects of nonmetallic materials

The properties of a number of nonmetallic materials were evaluated experimentally in simulated space environments in order to develop models for accelerated test methods useful for predicting such behavioral changes. Graphite-epoxy composites were exposed to thermal cycling. Adhesive foam tapes were subjected to a vacuum environment. Metal-matrix composites were tested for baseline data. Predictive modeling designed to include strength and aging effects on composites, polymeric films, and metals under such space conditions (including the atomic oxygen environment) is discussed. The Korel 8031-00 high strength adhesive foam tape was shown to be superior to the other two tested.

Papazian, H.↗

Spacecraft environmental interactions: A joint Air Force and NASA research and technology program

A joint Air Force/NASA comprehensive research and technology program on spacecraft environmental interactions to develop technology to control interactions between large spacecraft systems and the charged-particle environment of space is described. This technology will support NASA/Department of Defense operations of the shuttle/IUS, shuttle/Centaur, and the force application and surveillance and detection missions, planning for transatmospheric vehicles and the NASA space station, and the AFSC military space system technology model. The program consists of combined contractual and in-house efforts aimed at understanding spacecraft environmental interaction phenomena and relating results of ground-based tests to space conditions. A concerted effort is being made to identify project-related environmental interactions of concern. The basic properties of materials are being investigated to develop or modify the materials as needed. A group simulation investigation is evaluating basic plasma interaction phenomena to provide inputs to the analytical modeling investigation. Systems performance is being evaluated by both groundbased tests and analysis.

Pike, C. P.↗

Elevated temperature crack growth

Critical gas turbine engine hot section components such as blades, vanes, and combustor liners tend to develop minute cracks during early stages of operations. The ability of currently available path-independent (P-I) integrals to correlate fatigue crack propagation under conditions that simulate the turbojet engine combustor liner environment was determined. To date, an appropriate specimen design and a crack displacement measurement method were determined. Alloy 718 was selected as the analog material based on its ability to simulate high temperature behavior at lower temperatures in order to facilitate experimental measurements. Available P-I integrals were reviewed and the best approaches are being programmed into a finite element post processor for eventual comparison with experimental data. The experimental data will include cyclic crack growth tests under thermomechanical conditions, and, additionally, thermal gradients.

Kim, K. S.↗

A mathematical model for predicting cyclic voltammograms of electronically conductive polypyrrole

Polypyrrole is an attractive polymer for use as a high-energy-density secondary battery because of its potential as an inexpensive, lightweight, and noncorrosive electrode material. A mathematical model to simulate cyclic voltammograms for polypyrrole is presented. The model is for a conductive porous electrode film on a rotating disk electrode (RDE) and is used to predict the spatial and time dependence of concentration, overpotential, and stored charge profiles within a polypyrrole film. The model includes both faradic and capacitance charge components in the total current density expression.

Yeu, Taewhan↗

Positive position feedback control for large space structures

A new technique for vibration suppression in large space structures is investigated in laboratory experiments on a thin cantilever beam. This technique, called Positive Position Feedback, makes use of generalized displacement measurements to accomplish vibration suppression. Several features of Positive Position Feedback make it attractive for the large space structure control environment: The realization of the controller is simple and straightforward. Global stability conditions can be derived which are independent of the dynamical characteristics of the structure being controlled, i.e., all spillover is stabilizing. The method cannot be destabilized by finite actuator dynamics, and the technique is amenable to a strain-based sensing approach. The experiments control the first six bending modes of a cantilever beam, and make use of piezoelectric materials for actuators and sensors, simulating a piezoelectric active-member. The modal damping ratios are increased by factors ranging from 2 to 130.

Fanson, J. L.↗

A mathematical model for predicting cyclic voltammograms of electronically conductive polypyrrole

Polypyrrole is an attractive polymer for use as a high-energy-density secondary battery because of its potential as an inexpensive, lightweight, and noncorrosive electrode material. A mathematical model to simulate cyclic voltammograms for polypyrrole is presented. The model is for a conductive porous electrode film on a rotating disk electrode (RDE) and is used to predict the spatial and time dependence of concentration, overpotential, and stored charge profiles within a polypyrrole film. The model includes both faradic and capacitance charge components in the total current density expression.

Yeu, Taewhan↗

Preliminary study of creep thresholds and thermomechanical response in Haynes 188 at temperatures in the range 649 to 871 C

The following conclusions were drawn from this study of creep thresholds and thermomechanical response: (1) creep threshold can be determined using the latest electrohydraulic test equipment, providing that test durations are short and relatively large accumulations of creep strain are used in defining the threshold; (2) significant creep strains were measured under monotonic loading as stress levels as low as 4 ksi at temperatures predicted for solar receiver service; and (3) the material exhibited creep ratchetting during simulated service cycles, a result not predicted by analysis using current constitutive models for Haynes 188.

Ellis, J. R.↗

Recent advances in engineering science; Proceedings of the A. Cemal Eringen Symposium, University of California, Berkeley, June 20-22, 1988

Various papers on recent advances in engineering science are presented. Some individual topics addressed include: advances in adaptive methods in computational fluid mechanics, mixtures of two medicomorphic materials, computer tests of rubber elasticity, shear bands in isotropic micropolar elastic materials, nonlinear surface wave and resonator effects in magnetostrictive crystals, simulation of electrically enhanced fibrous filtration, plasticity theory of granular materials, dynamics of viscoelastic media with internal oscillators, postcritical behavior of a cantilever bar, boundary value problems in nonlocal elasticity, stability of flexible structures with random parameters, electromagnetic tornadoes in earth's ionosphere and magnetosphere, helicity fluctuations and the energy cascade in turbulence, mechanics of interfacial zones in bonded materials, propagation of a normal shock in a varying area duct, analytical mechanics of fracture and fatigue.

Koh, Severino L.↗