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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 811 records · Page 45
All sourcesNASA NTRSDOE OSTI
NASA NTRS2017

United Kingdom Infrared Telescope's Spectrograph Observations of Human-Made Space Objects

Presented here are the results of the United Kingdom Infrared Telescope (UKIRT) spectral observations of human-made space objects taken from 2014 to 2015. The data collected using the UIST infrared spectrograph cover the wavelength range 0.7-2.5 micrometers. Overall, data were collected on 18 different orbiting objects at or near the geosynchronous (GEO) regime. Thirteen of the objects are spacecraft, one is a rocket body, and four are cataloged as debris pieces. The remotely collected data are compared to the laboratory-collected reflectance data on typical spacecraft materials; thereby general materials are identified but not specific types. These results highlight the usefulness of observations in the infrared by focusing on features from hydrocarbons and silicon. The spacecraft show distinct features due to the presence of solar panels. Signature variations between rocket bodies, due to the presence of various metals and paints on their surfaces, show a clear distinction from those objects with solar panels, demonstrating that one can distinguish most spacecraft from rocket bodies through infrared spectrum analysis. Finally, the debris pieces tend to show featureless, dark spectra. These results show that the laboratory data in its current state give excellent indications as to the nature of the surface materials on the objects. Further telescopic data collection and model updates to include more materials, noise, surface roughness, and material degradation are necessary to make better assessments of orbital object material types. A comparison conducted between objects observed previously with the NASA Infrared Telescope Facility (IRTF) shows similar materials and trends from the two telescopes and from the two distinct data sets. However, based on the current state of the model, infrared spectroscopic data are adequate to classify objects in GEO as spacecraft, rocket bodies, or debris.

Buckalew, Brent↗
NASA NTRS2021

Pyrolysis Rate and Yield Strength Reduction Incarbon Fiber and Glass Fiber Composites Underreentry Heating Conditions

The behavior of composite materials, specifically carbon fiber reinforced plastic (CFRP) and glass fiber reinforced plastic (GFRP), under reentry conditions poses a problem for space debris reentry risk modeling. Since these materials pyrolyze rather than melt and their different components demise at different rates, modeling their destruction to determine ground impact risk is complex. Modern spacecraft are using these materials in ever-greater quantities owing to their superior strength-to-weight characteristics, and this has required that the orbital debris community improve its understanding of how these materials demise on reentry. The NASA Orbital Debris Program Office undertook an extensive test campaign to better understand the rate at which several types of GFRP and CFRP materials pyrolyze under reentry heating conditions and how that pyrolysis affects the ultimate strength of the material. GFRP with a polyester resin (G10/FR-4) and CFRP with epoxy, cyanate ester, vinyl ester, and phenolic resins were tested. The test campaign was carried out at the Inductively Coupled Plasma (ICP) Torch Facility at the University of Texas at Austin. Because the ICP facility operates in a shirt-sleeve environment, test samples can be changed within seconds or minutes, allowing many samples to be tested in a short period. Two heat flux rates, 20 W/m2 and 30W/m2, and two oxygen concentration conditions, 0% and 2% of atmospheric, were applied to all five types of material. To measure both the char rate and the effect of pyrolysis on the ultimate material strength, two types of test were carried out for each material: a char rate test on a ~10 mm thick sample of material and an in-situ bending stress test of a ~2 mm thick sample of material. Measurements of the char rate showed very similar average pyrolysis front velocity in epoxy resin CFRP as in G10 at 3.6 mm/min and 3.4 mm/min, respectively. However, the total mass loss rate in theG10 was nearly double that of the CFRP at 3.8 g/min and 2.2 g/min, respectively. This result represented a slow ablation rate of carbon fibers in the CFRP at the temperatures encountered in low Earth orbit reentry and a comparatively rapid removal of the glass fibers in G10 due to melting and spallation. Pyrolysis front velocity was more significantly affected by the type of plastic than the type of fiber, with the cyanate ester CFRP samples displaying an average pyrolysis front velocity of only 1.9 mm/min. Similarly, the effect of thermal exposure on the ultimate strength of the material depended heavily on the type of plastic and very little on the type of fiber in the material. Epoxy, vinyl ester, and polyester resins all behaved very similarly, with complete structural failure at between 400 J/g and 600 J/g of specific absorbed heat. Phenolic and cyanate ester resins, on the other hand, displayed a change in structural properties that was only barely measurable with the current apparatus even after the maximum exposure time tested. These data are being incorporated into a numerical model of the ablation and demise of composite materials that will be used to more accurately calculate the ground casualty risk of future spacecraft.

Benton R. Greene↗
NASA NTRS2017

United Kingdom Infrared Telescope's Spectrograph Observations of Human-Made Space Objects

Presented here are the results of the United Kingdom Infrared Telescope (UKIRT) spectral observations of human-made space objects taken from 2014 to 2015. The data collected using the UKIRT 1-5 micron Imager Spectrometer (UIST) cover the wavelength range 0.7-2.5 micrometers. Overall, data were collected on 18 different orbiting objects at or near geosynchronous orbit (GEO). Two of the objects are controlled spacecraft, twelve are non-controlled spacecraft, one is a rocket body, and three are cataloged as debris. The remotely collected data are compared to the laboratory-collected reflectance data on typical spacecraft materials; thereby general materials are identified but not specific types. These results highlight the usefulness of observations in the infrared by focusing on features from hydrocarbons and silicon. The spacecraft, both the controlled and non-controlled, show distinct features due to the presence of solar panels whereas the rocket bodies do not. Signature variations between rocket bodies, due to the presence of various metals and paints on their surfaces, show a clear distinction from those objects with solar panels, demonstrating that one can distinguish most spacecraft from rocket bodies through infrared spectrum analysis. Finally, the debris pieces tend to show featureless, dark spectra. These results show that the laboratory data in its current state give well-correlated indications as to the nature of the surface materials on the objects. Further telescopic data collection and model updates to include noise, surface roughness, and material degradation are necessary to make better assessments of orbital object material types. A comparison conducted between objects observed previously with the NASA Infrared Telescope Facility (IRTF) shows similar materials and trends from the two telescopes and different times. However, based on the current state of the model, infrared spectroscopic data are adequate to classify objects in GEO as spacecraft, rocket bodies, or debris.

Buckalew, Brent↗
NASA NTRS1989

Chemical, isotopic and mineralogical evidence for the origin of matrix in ordinary chondrites

Results are presented of a combined chemical, isotopic, and mineralogical study of fine-grained opaque matrix material from a type-3 ordinary chondrite Allan Hills A77299. It was found that the matrix of this chondrite (in contrast to chondrules) shows no siderophile element depletions and is remarkably unfractionated relative to CI chondrites. It was also found that the matrix lump has a unique oxygen isotopic composition which lies below the terrestrial fractionation line and differs markedly from the composition of fine-grained matrix lumps and chondrule rims from Semarkona chondrules (Grossman and Wasson, 1987; Grossman et al., 1987); the mineralogy and textures of the matrix lump (which consists of rare angular grains of pyroxene and olivine embedded within a ground-mass of rounded fine-grained olivines), as well as its major element composition, are typical of matrix material of other type-3 chondrites studied. It is concluded that the matrix lump in these chondrites consists largely of material that formed by annealing of amorphous presolar dust or nebular condensates.

Brearley, Adrian J.↗
DOE OSTI2021

Removing or preventing dry etch-induced damage in Al/In/GaN films by photoelectrochemical etching

A method comprises providing a substrate comprising an n-type Al/In/GaN semiconductor material. A surface of the substrate is dry-etched to form a trench therein and cause dry-etch damage to remain on the surface. The surface of the substrate is immersed in an electrolyte solution and illuminated with above bandgap light having a wavelength that generates electron-hole pairs in the n-type Al/In/GaN semiconductor material, thereby photoelectrochemically etching the surface to remove at least a portion of the dry-etch damage.

Monavarian, Morteza↗
DOE OSTI2023

Removing or preventing dry etch-induced damage in Al/In/GaN films by photoelectrochemical etching

A method comprises providing a substrate comprising an n-type Al/In/GaN semiconductor material. A surface of the substrate is dry-etched to form a trench therein and cause dry-etch damage to remain on the surface. The surface of the substrate is immersed in an electrolyte solution and illuminated with above bandgap light having a wavelength that generates electron-hole pairs in the n-type Al/In/GaN semiconductor material, thereby photoelectrochemically etching the surface to remove at least a portion of the dry-etch damage.

Monavarian, Morteza↗
DOE OSTI2020

Revealing Reaction Pathways of Collective Substituted Iron Fluoride Electrode for Lithium Ion Batteries

Metal fluorides present a high redox potential among the conversion-type compounds, which make them specially work as cathode materials of lithium ion batteries. To mitigate the notorious cycling instability of conversion-type materials, substitutions of anion and cation have been proposed but the role of foreign elements in reaction pathway is not fully evaluated. In this work, we explored the lithiation pathway of a rutile-Fe 0.9 Co 0.1 OF cathode with multimodal analysis, including ex situ and in situ transmission electron microscopy and synchrotron X-ray techniques. Our work revealed a prolonged intercalation–extrusion–cation disordering process during phase transformations from the rutile phase to rocksalt phase, which microscopically corresponds to topotactic rearrangement of Fe/Co–O/F octahedra. During this process, the diffusion channels of lithium transformed from 3D to 2D while the corner-sharing octahedron changed to edge-sharing octahedron. DFT calculations indicate that the Co and O cosubstitution of the Fe 0.9 Co 0.1 OF cathode can improve its structural stability by stabilizing the thermodynamic semistable phases and reducing the thermodynamic potentials. We anticipate that our study will inspire further explorations on untraditional intercalation systems for secondary battery applications.

25 ENERGY STORAGE↗
NASA NTRS1986

Summary of tower designs for large horizontal axis wind turbines

Towers for large horizontal axis wind turbines, machines with a rotor axis height above 30 meters and rated at more than 500 kW, have varied in configuration, materials of construction, type of construction, height, and stiffness. For example, the U.S. large HAWTs have utilized steel truss type towers and free-standing steel cylindrical towers. In Europe, the trend has been to use only free-standing and guyed cylindrical towers, but both steel and reinforced concrete have been used as materials of construction. These variations in materials of construction and type of construction reflect different engineering approaches to the design of cost effective towers for large HAWTs. Tower designs are the NASA/DOE Mod-5B presently being fabricated. Design goals and requirements that influence tower configuration, height and materials are discussed. In particular, experiences with United States large wind turbine towers are elucidated. Finally, current trends in tower designs for large HAWTs are highlighted.

Frederick, G. R.↗
NASA NTRS2011

Connector pin and method

An electrical connector and method includes a connector and a conforming element proximate to or in contact with the mating end of the connector so as to prevent distortion of a matable end. The matable end of the connector may be of a female or male type and may be of a post, tube, blade, pin, or other configuration. An element made of conforming material, for example, an elastomer, epoxy or rubber type material, is configured and positioned in contact with the matable end of the connector, providing support during assembly to prevent distortion of the matable end. The conforming element may be rectangular, wedge, cylindrical, conical, annular, or of another configuration as required to provide support to the connector pin. The conforming element may be fastened with an adhesive to the matable end to further prevent distortion.

Davis, Donald R.↗
DOE OSTI2024

Electrochemical and Chemical Reactivities of Titanium Oxide-Based Materials with a Chloroaluminate Ionic Liquid Electrolyte for Aluminum Batteries

Here, by selecting three different types of electrode materials, we intended to better understand the Al 3+ intercalation chemistry of titanium oxide-based frameworks with an acidic chloroaluminate electrolyte. In agreement with previous reports, we confirmed that the native interstitial sites of anatase TiO 2 are less prone to accommodate Al 3 + than Li + or Na + ions, while introducing cationic vacancies largely increases the electrochemical storage capacity. Upon the first cycle, the highest reversible capacity, up to 277 mAh/g, was obtained for a hydrated layered structure featuring cationic vacancies. Total scattering data showed that the insertion of Al 3+ ions induced a strong distortion of the framework. In addition, combined 27 Al MAS NMR and DFT calculations revealed that in oxy-hydroxylated vacant sites, the coordination mode of Al 3+ ions depends on the arrangement of anions around vacancies inducing the occurrence of 4-, 5-, and 6-fold coordination modes. Further cycling experiments revealed a progressive capacity fading for all electrode materials. Using cyclic voltammetry on the used electrolyte, we evidenced that a partial dissolution has occurred, which is more pronounced for the layered hydrate compound, and that solubilized species are electrochemically active, giving rise to specific signatures in both CVs and galvanostatic experiments. Raman spectroscopy enabled us to characterize these species, which are derived from the Ti-Cl system. The solubilized species, however, eventually precipitated, as shown by a purple deposit observed on the separator and tentatively assigned to TiCl 3 , known to be insoluble in this medium. By providing further information on the Al 3+ intercalation chemistry and a better understanding of the electrochemical and chemical reactivities of electrode materials, this work will enable progress to be made in the development of aluminum-ion batteries.

Al3+-ion insertion chemistry↗
DOE OSTI2022

Designing Cladded Components for High Temperature Nuclear Service: Part I—Analysis Methods

Use of corrosion-resistant cladding can greatly extend the design life of structural components in many advanced reactor systems. However, there are currently no ASME design rules for cladded components to guard against creep-fatigue failure and ratcheting strain accumulation in elevated temperature nuclear service. This paper, presented in two parts, addresses this gap by proposing a design strategy for cladded components that do not require long-term testing of clad materials. The proposed approach relies on approximate design analysis methods for two types of clad materials—a soft clad that creeps much faster than and has lower yield stress than the class A base material and a hard clad that creeps much slower than and has higher yield stress than the class A base material. Part I discusses the approximate analysis strategies for the clad materials—treat a soft clad as perfectly compliant and a hard clad as linear elastic—and Part II develops a complete set of design rules for each of the two types of cladded components. In conclusion, finite element analyses of representative high temperature reactor components show that the proposed design analysis methods can bound the design quantities in soft cladded components and approximate the design quantities in hard cladded components.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
NASA NTRS2015

Infrared Telescope Facility's Spectrograph Observations of Human-Made Space Objects

Presented here are the results of the Infrared Telescope Facility (IRTF) spectral observations of human-made space objects taken from 2006 to 2008. The data collected using the SpeX infrared spectrograph cover the wavelength range 0.7-2.5 micrometers. Overall, data were collected on 20 different orbiting objects at or near the geosynchronous (GEO) regime. Four of the objects were controlled spacecraft, seven were non-controlled spacecraft, five were rocket bodies, and the final four were cataloged as debris pieces. The remotely collected data are compared to the laboratory-collected reflectance data on typical spacecraft materials, thereby general materials are identified but not specific types. These results highlight the usefulness of observations in the infrared by focusing on features from hydrocarbons, silicon, and thermal emission. The spacecraft, both the controlled and non-controlled, show distinct features due to the presence of solar panels, whereas the rocket bodies do not. Signature variations between rocket bodies, due to the presence of various metals and paints on their surfaces, show a clear distinction from those objects with solar panels, demonstrating that one can distinguish most spacecraft from rocket bodies through infrared spectrum analysis. Finally, the debris pieces tend to show featureless, dark spectra. These results show that the laboratory data in its current state give excellent indications as to the nature of the surface materials on the objects. Further telescopic data collection and model updates to include noise, surface roughness, and material degradation are necessary to make better assessments of orbital object material types. However, based on the current state of the comparison between the observations and the laboratory data, infrared spectroscopic data are adequate to classify objects in GEO as spacecraft, rocket bodies, or debris.

Abercromby, K.↗
DOE OSTI2023

An ICME Modeling Framework for Metal Matrix Composites Focusing on Ultrahigh Temperature Matrix Material and Tungsten Carbide Reinforcement Particulate (Final CRADA Report)

Ultra High Temperature Metal Matrix Composites (UHT-MMCs) are of interest to the due to their potential defense and aerospace applications. These materials consist of a metal matrix reinforced with a stiff ceramic or cermet. Based on a preliminary literature survey, this project will focused on a pure titanium (Ti) matrix reinforced with tungsten carbide-cobalt (WC-Co). UHT-MMC technology is still at a nascent stage of development and requires extensive experimental work to optimize the structure and resulting material properties of a particular UHT-MMC material system. An accurate and complete high-performance computing (HPC) model of the Ti/WC-Co material system could greatly accelerate the development and deployment Ti/WC-Co materials by connecting processing parameters to material properties. This type of model could then be used in an integrated computational materials engineering approach to optimize the material structure to achieve a targeted level of performance.

36 MATERIALS SCIENCE↗
NASA NTRS1974

ERTS imagery as a source of environmental information for southern Africa

Southern Africa is faced with a variety of environmental problems that reflect the different states of development of countries in the region. The task of the environmental planner is in many instances complicated by a lack of basic resource information. The acquisition of the necessary data is often impeded by shortage of trained personnel and lack of funds, particularly in developing nations of the region. The range of environmental problems in Southern Africa are described and specific examples are shown of how ERTS type imagery can materially assist in solving these problems. These examples demonstrate that ERTS type data will be of substantial value to both the industrialized and the developing nations of Southern Africa, provided that problems of availability and user education are overcome.

Williamson, D. T.↗
NASA NTRS1993

Impact damage resistance of composite fuselage structure, part 2

The strength of laminated composite materials may be significantly reduced by foreign object impact induced damage. An understanding of the damage state is required in order to predict the behavior of structure under operational loads or to optimize the structural configuration. Types of damage typically induced in laminated materials during an impact event include transverse matrix cracking, delamination, and/or fiber breakage. The details of the damage state and its influence on structural behavior depend on the location of the impact. Damage in the skin may act as a soft inclusion or affect panel stability, while damage occurring over a stiffener may include debonding of the stiffener flange from the skin. An experiment to characterize impact damage resistance of fuselage structure as a function of structural configuration and impact threat was performed. A wide range of variables associated with aircraft fuselage structure such as material type and stiffener geometry (termed, intrinsic variables) and variables related to the operating environment such as impactor mass and diameter (termed, extrinsic variables) were studied using a statistically based design-of-experiments technique. The experimental design resulted in thirty-two different 3-stiffener panels. These configured panels were impacted in various locations with a number of impactor configurations, weights, and energies. The results obtained from an examination of impacts in the skin midbay and hail simulation impacts are documented. The current discussion is a continuation of that work with a focus on nondiscrete characterization of the midbay hail simulation impacts and discrete characterization of impact damage for impacts over the stiffener.

Dost, Ernest F.↗
NASA NTRS2020

Early Ultraviolet Observations of Type IIn Supernovae Constrain the Asphericity of Their Circumstellar Material

We present a survey of the early evolution of 12 Type IIn supernovae (SNe IIn) at ultraviolet and visible light wavelengths. We use this survey to constrain the geometry of the circumstellar material (CSM) surrounding SN IIn explosions, which may shed light on their progenitor diversity. In order to distinguish between aspherical and spherical CSM, we estimate the blackbody radius temporal evolution of the SNe IIn of our sample, following the method introduced by Soumagnac et al. We find that higher-luminosity objects tend to show evidence for aspherical CSM. Depending on whether this correlation is due to physical reasons or to some selection bias, we derive a lower limit between 35% and 66% for the fraction of SNe IIn showing evidence for aspherical CSM. This result suggests that asphericity of the CSM surrounding SNe IIn is common—consistent with data from resolved images of stars undergoing considerable mass loss. It should be taken into account for more realistic modeling of these events.

Maayane T Soumagnac↗
DOE OSTI2025

Polyanion-type iron-based sulfate cathode materials: From fundamental research to industrialization

Sodium-ion batteries (SIBs) with the merits of abundant sodium resources and low cost are considered significant supplements to lithium-ion batteries in large-scale energy storage systems. Among the discovered cathode materials for SIBs, iron-based sulfate materials have attracted widespread attention due to their high operating voltage, superior structural stability, and high safety. Here, in this review, we summarize the research achievements of iron-based sulfate cathode materials in fundamental research, as well as provide a comprehensive overview of its industrialization progress for the first time. Meanwhile, effective modification strategies (including morphology design, hybridization with carbon materials, and construction of heterostructure) and further research directions to boost the sodium storage performance of iron-based sulfate cathode materials are also proposed. This review can provide valuable guidance for developing high-performance iron-based sulfate cathode materials for practical application.

cathode materials↗
DOE OSTI2020

Elastic Single-Ion Conducting Polymer Electrolytes: Toward a Versatile Approach for Intrinsically Stretchable Functional Polymers

Fabrication of stretchable functional polymeric materials usually relies on the physical adhesion between functional components and elastic polymers, while the interfacial resistance is a potential problem. Herein, a versatile approach on the molecular-level intrinsically stretchable polymer materials with defined functionality is reported. The single-ion conducting polymer electrolytes (SICPEs) were employed to demonstrate the proposed concept along with its potential application in stretchable batteries/electronics with improved energy efficiency and prolonged cell lifetime. The obtained membranes exhibit 88–252% elongation before breaking, and the mechanical properties are well adjustable. The galvanostatic test of the assembled cells using the obtained SICPE membrane exhibited a good cycling performance with a capacity retention of 81.5% after 100 cycles. The applicability of a proposed molecular-level design for intrinsically stretchable polymer materials is further demonstrated in other types of stretchable functional materials, including poly(vinylcarbazole)-based semiconducting polymers and poly(ethylene glycol)-based gas separation membranes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗