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At least 811 records · Page 45

Thermomechanical Fatigue Damage/Failure Mechanisms in SCS-6/Timetal 21S [0/90](Sub S) Composite

The thermomechanical fatigue (TMF) deformation, damage, and life behaviors of SCS6/Timetal 21S (0/90)s were investigated under zero-tension conditions. In-phase (IP) and out-of-phase (OP) loadings were investigated with a temperature cycle from 150 to 650 deg C. An advanced TMF test technique was used to quantify mechanically damage progression. The technique incorporated explicit measurements of the macroscopic (1) isothermal static moduli at the temperature extremes of the TMF cycle and (2) coefficient of thermal expansion (CTE) as functions of the TMF cycles. The importance of thermal property degradation and its relevance to accurate post-test data analysis and interpretation is briefly addressed. Extensive fractography and metallography were conducted on specimens from failed and interrupted tests to characterize the extent of damage at the microstructure level. Fatigue life results indicated trends analogous to those established for similar unidirectional(0) reinforced titanium matrix composite systems. High stress IP and mid to low stress OP loading conditions were life-limiting in comparison to maximum temperature isothermal conditions. Dominant damage mechanisms changed with cycle type. Damage resulting from IP TMF conditions produced measurable decreases in static moduli but only minimal changes in the CTE. Metallography on interrupted and failed specimens revealed extensive (0) fiber cracking with sparse matrix damage. No surface initiated matrix cracks were present. Comparable OP TMF conditions initiated environment enhanced surface cracking and matrix cracking initiated at (90) fiber/matrix (F/M) interfaces. Notable static moduli and CTE degradations were measured. Fractography and metallography revealed that the transverse cracks originating from the surface and (90) F/M interfaces tended to converge and coalesce at the (0) fibers.

Castelli, Michael G.↗

Characterization of Metal Matrix Composites

Experimental methods were developed, adapted, and applied to the characterization of a metal matrix composite system, namely, silicon carbide/aluminim (SCS-2/6061 Al), and its constituents. The silicon carbide fiber was characterized by determining its modulus, strength, and coefficient of thermal expansion. The aluminum matrix was characterized thermomechanically up to 399 C (750 F) at two strain rates. The unidirectional SiC/Al composite was characterized mechanically under longitudinal, transverse, and in-plane shear loading up to 399 C (750 F). Isothermal and non-isothermal creep behavior was also measured. The applicability of a proposed set of multifactor thermoviscoplastic nonlinear constitutive relations and a computer code was investigated. Agreement between predictions and experimental results was shown in a few cases. The elastoplastic thermomechanical behavior of the composite was also described by a number of new analytical models developed or adapted for the material system studied. These models include the rule of mixtures, composite cylinder model with various thermoelastoplastic analyses and a model based on average field theory. In most cases satisfactory agreement was demonstrated between analytical predictions and experimental results for the cases of stress-strain behavior and thermal deformation behavior at different temperatures. In addition, some models yielded detailed three-dimensional stress distributions in the constituents within the composite.

Daniel, I. M.↗

Application of an Energy-Based Life Prediction Model to Bithermal and Thermomechanical Fatigue

The inelastic hysteresis energy applied to the material in a cycle is used as the basis for predicting nonisothermal fatigue life of a wrought cobalt-base superalloy, Haynes 188, from isothermal fatigue data. Damage functions that account for hold-time effects and time-dependent environmental phenomena such as oxidation and hot corrosion are proposed in terms of the inelastic hysteresis energy per cycle. The proposed damage functions are used to predict the bithermal and thermomechanical fatigue lives of Haynes 188 between 316 and 760 C from isothermal fatigue data. Predicted fatigue lives of all but two of the nonisothermal tests are within a factor of 1.5 of the experimentally observed lives.

Radhakrishnan, V. M.↗

Transport phenomena in the micropores of plug-type phase separators

This study numerically investigates the transport phenomena within and across a porous-plug phase separator. The effect of temperature differential across a single pore and of the sidewall boundary conditions, i.e., isothermal or linear thermal gradient, are presented and discussed. The effects are quantified in terms of the evaporation mass flux across the boundary and the mean surface temperature. A two-dimensional finite element model is used to solve the continuity, momentum, and energy equations for the liquid. Temperature differentials across the pore interface of 1.0, and 1.5 K are examined and their effect on evaporation flux and mean surface temperature is shown. For isothermal side boundary conditions, the evaporation flux across the pore is directly proportional and linear with Delta T. For the case of an imposed linear thermal gradient on the side boundaries, Biot numbers of 0.0, 0.15, and 0.5 are examined. The most significant effect of Biot number is to lower the overall surface temperature and evaporation flux.

Fazah, M. M.↗

Electric field effects on a near-critical fluid in microgravity

The effects of an electric field on a sample of SF6 fluid in the vicinity of the liquid-vapor critical point is studied. The isothermal increase of the density of a near-critical sample as a function of the applied electric field was measured. In agreement with theory, this electrostriction effect diverges near the critical point as the isothermal compressibility diverges. Also as expected, turning on the electric field in the presence of density gradients can induce flow within the fluid, in a way analogous to turning on gravity. These effects were observed in a microgravity environment by using the Critical Point Facility which flew onboard the Space Shuttle Columbia in July 1994 as part of the Second International Microgravity Laboratory Mission. Both visual and interferometric images of two separate sample cells were obtained by means of video downlink. The interferometric images provided quantitative information about the density distribution throughout the sample. The electric field was generated by applying 500 Volts to a fine wire passing through the critical fluid.

Zimmerli, G.↗

Mapping the dark matter in the NGC 5044 group with ROSAT: Evidence for a nearly homogeneous cooling flow with a cooling wake

The NGC 5044 group of galaxies was observed by the ROSAT Position Sensitive Proportional Counter (PSPC) for 30 ks during its reduced pointed phase (1991 July). Due to the relatively cool gas temperature in the group (kT = 0.98 +/- 0.02 keV) and the excellent photon statistics (65,000 net counts), we are able to determine precisely a number of fundamental properties of the group within 250 kpc of the central galaxy. In particular, we present model-independent measurements of the total gravitating mass, the temperature and abundance profiles of the gas, and the mass accretion rate. Between 60 and 250 kpc, the gas is nearly isothermal with T varies as r(exp (-0.13 +/- 0.03)). The total gravitating mass of the group can be unambiguously determined from the observed density and temperature profiles of the gas using the equation of hydrostatic equilibrium. Within 250 kpc, the gravitating mass is 1.6 x 10(exp 13) solar mass, yielding a mass-to-light ratio of 130 solar mass/solar luminosity. The baryons (gas and stars) comprise 12% of the total mass within this radius. At small radii, the temperature clearly increases outward and attains a maximum value at 60 kpc. The positive temperature gradient in the center of the group confirms the existence of a cooling flow. The cooling flow region extends well beyond the temperature maximum with a cooling radius between 100 and 150 kpc. There are two distinct regions in the cooling flow separated by the temperature maximum. In the outer region, the gas is nearly isothermal with a unifor m Fe abundance of approximately 80% solar, the flow is nearly homogeneous with dot-M= 20 to 25 solar mass/year, the X-ray contours are spherically symmetric, and rho(sub gas) varies as r(exp -1.6). In the inner region, the temperature profile has a positive gradient, the mass accretion rate decreases rapidly inward, the gas density profile is steeper, and the X-ray image shows some substrucutre. NGC 5044 is offset from the centroid of the outer X-ray contours indicating that the central galaxy may have a residual velocity with respect to the center of the group potential. There is also a linear X-ray feature with an extent of approximately 30 kpc with one end coincident with NGC 5044. The X-ray emission from this feature is softer than the ambient gas. We interpret this feature as a 'cooling wake' formed by the accreting gas as it is gravitationally focused into the wake of NGC 5044. One of the most surprising results of our PSPC observation is the discovery of a nearly homogeneous cooling flow. Prior results concerning the mass accretion profile in cooling flows indicate that dot-M varies as r. This relation implies that significant mass deposition occurs at large radii which generates an inhomogeneous flow. The mass accretion rate in the NGC 5044 group is essentially a constant beyond 40 kpc (well within the cooling radius). Significant mass deposition (a declining dot-M) does not commence until the gas accretes to within 40 kpc of the group center where the radiative cooling time is approximately equals 10(exp 9) year. Th is radius also corresponds to the temperature maximum, the break in gas density profile, and the onset of structure in the X-ray image. A Hubble constant of H(sub 0) = 50 km/sec/Mpc is used throughout the paper.

David, Laurence P.↗

Factors affecting the estimate of primary production from space

Remote sensing of primary production in the euphotic zone has been based mostly on visible-band and water-leaving radiance measured with the coastal zone color scanner. There are some robust, simple relationships for calculating integral production based on surface measurements, but they also require knowledge for photoadaptive parameters such as maximum photosynthesis which currently cannot be obtained from spave. A 17,000-station data set is used to show that space-based estimates of maximum photosynthesis could improve predictions of psi, the water column light utiliztion index, which is an important term in many primary productivity models. Temperature is also examined as a factor for predicting hydrographic structure and primary production. A simple model is used to relate temperature and maximum photosynthesis; the model incorporates (1) the positive relationship between maximum photosynthesis and temperature and (2) the strongly negative relationship between temperature and nitrate in the ocean (which directly affects maximum growth rates via nitrogen limitation). Since these two factors relate to carbon and nitrogen, 'balanced carbon/nitrogen assimilation' was calculated using the Redfield ratio, It is expected that the relationship between maximum balanced carbon assimilation versus temperature is concave-down, with the peak dependent on nitrate uptake kinetics, temperature-nitrate relationships,a nd the carbon chlorophyll ration. These predictions were compared with the sea truth data. The minimum turnover time for nitrate was also calculated using this approach. Lastly, sea surface temperature gradients were used to predict the slope of isotherms (a proxy for the slope of isopycnals in many waters). Sea truth data show that at size scales of several hundred kilometers, surface temperature gradients can provide information on the slope of isotherms in the top 200 m of the water column. This is directly relevant to the supply of nutrients into the surface mixed layer, which is useful for predicting integral biomass and primary production.

Balch, W. M.↗

Internal velocity and mass distributions in simulated clusters of galaxies for a variety of cosmogonic models

The mass and velocity distributions in the outskirts (0.5-3.0/h Mpc) of simulated clusters of galaxies are examined for a suite of cosmogonic models (two Omega(sub 0) = 1 and two Omega(sub 0) = 0.2 models) utilizing large-scale particle-mesh (PM) simulations. Through a series of model computations, designed to isolate the different effects, we find that both Omega(sub 0) and P(sub k) (lambda less than or = 16/h Mpc) are important to the mass distributions in clusters of galaxies. There is a correlation between power, P(sub k), and density profiles of massive clusters; more power tends to point to the direction of a stronger correlation between alpha and M(r less than 1.5/h Mpc); i.e., massive clusters being relatively extended and small mass clusters being relatively concentrated. A lower Omega(sub 0) universe tends to produce relatively concentrated massive clusters and relatively extended small mass clusters compared to their counterparts in a higher Omega(sub 0) model with the same power. Models with little (initial) small-scale power, such as the hot dark matter (HDM) model, produce more extended mass distributions than the isothermal distribution for most of the mass clusters. But the cold dark matter (CDM) models show mass distributions of most of the clusters more concentrated than the isothermal distribution. X-ray and gravitational lensing observations are beginning providing useful information on the mass distribution in and around clusters; some interesting constraints on Omega(sub 0) and/or the (initial) power of the density fluctuations on scales lambda less than or = 16/h Mpc (where linear extrapolation is invalid) can be obtained when larger observational data sets, such as the Sloan Digital Sky Survey, become available.

Cen, Renyue↗

Troilite formation kinetics and growth mechanism in the solar nebula

Troilite formation via the reaction Fe(s) + H2S(g) + H2(g) is the major mechanism for S retention in grains in the solar nebula. Thermodynamic calculations predict that troilite condenses from a solar composition gas. We present experimental results on the kinetics and growth of troilite crystals on Fe metal at temperature (450-650 C) and composition (50-1000 ppm H2S in H2) conditions similar to those in the solar nebula. The fraction of Fe reacted (based on gravimetric data) is plotted at 450, 505, 575, and 650 C. The thickness change of unreacted iron (measured by optical microscopy) is plotted at 575 and 650 C vs. time. the weight change per unit area varies as the square root of time at the lower temperatures and varies linearly with time at the highest temperature. The growth behavior along the lower isotherms is due to diffusion. This behavior suggests sulfide diffusion to the metal-sulfide interface and suggests Fe(2+) diffusion to the sulfide-gas interface. The reaction along the highest isotherm appears to be interface controlled. The formation of troilite crystals is a rapid process forming measurable layers in a few hours. The crystalgrowth is complicated. Initially there are intergrowths of troilite into the pure Fe metal. As the reaction progresses two distinct layers of troilite crystals form. One is in contact with the Fe metal and consists of small randomly oriented crystals with pore space between them. The outermost layer contains large crystals that are all oriented in the same direction. The intergrowth layer is much smaller at 650 C than at 575 C. This suggest that FeS nucleation is inhibited at the higher temperature, accounting for the initially slower reaction rate. Once nucleated, the reaction kinetics are apparently controlled by the growth of the crystals at the interface.

Lauretta, D. S.↗

New production in the warm waters of the tropical Pacific Ocean

The average depth-integrated rate of new production in the tropical Pacific Ocean was estimated from a calculation of horizontal and vertical nitrate balance over the region enclosed by the climatological 26 C isotherm. The net turbulent flux of nitrate into the region was computed in terms of the climatological net surface heat flux and the nitrate-temperature relationship at the base of the 26 C isotherm. The net advective transport of nitrate into the region was estimated using the mean nitrate distribution obtained from the analysis of historical data and previous results of a general circulation model of the tropical Pacific. The rate of new production resulting from vertical turbulent fluxes of nitrate was found to be similar in magnitude to that due to advective transport. Most (about 75%) of the advective input of nitrate was due to the horizontal transport of nutrient-rich water from the eastern equatorial region rather than from equatorial upwelling. An average rate of new production of 14.5 - 16 g C/sq m/yr was found for the warm waters of the tropical Pacific region. These values are in good agreement with previous estimates for this region and are almost five times less than is estimated for the eastern equatorial Pacific, where most of the nutrient upwelling occurs.

Pena, M. Angelica↗

Solar wind plasma electron parameters based on aligned observations by ICE and Ulysses

During November-December 1991, the International Cometary Explorer (ICE) and Ulysses spacecraft were aligned in solar longitude, with an angular offset as small as 1 deg and a radial offset of 3.8 to 4.0 AU. Both spacecraft carry spectrometers which measure the thermal and suprathermal solar wind electron distributions. During the alignment interval, both spacecraft encountered the declining phase of a high-speed solar wind stream, representing unshocked plasma. We use the aligned observations from ICE and Ulysses to characterized the radial gradients in core and halo electron temperature, relative halo density, and heat flux, as well as the core and total polytropic indices. The thermal properties of the core vary widely in a range from isothermal to adiabatic, while the halo is more nearly isothermal. The halo density falls off more steeply for higher density plasma, and the electron heat flux gradient indicates constant or decreasing distribution skewness.

Phillips, J. L.↗

A study of cooling flows in poor clusters of galaxies

We observed three poor clusters with central dominant galaxies (AWM 4, MKW 4, and MKW 3's) using the Position Sensitive Proportional Counter on the ROSAT X-ray satellite. The images reveal smooth, symmetrical X-ray emission filling the cluster with a sharp peak on each central galaxy. The cluster surface brightness profiles can be decomposed using superposed King models for the central galaxy and the intracluster medium. The King model parameters for the cluster portions are consistent with previous observations of these clusters. The newly measured King model parameters for the central galaxies are typical of the X-ray surface brightness distributions of isolated elliptical galaxies. Spatially resolved temperature measurements in annular rings throughout the clusters show a nearly isothermal profile. Temperatures are consistent with previously measured values, but are much better determined. There is no significant drop in temperature noted in the innermost bins where cooling flows are likely to be present, nor is any excess absorption by cold gas required. All cold gas columns are consistent with galactic foreground absorption. We derive mass profiles for the clusters assuming both isothermal temperature profiles and cooling flow models with constant mass flow rates. Our results are consistent with previous Einstein IPC observations by Kriss, Cioffi, & Canizares, but extend the mass profiles out to 1 Mpc in these poor clusters.

Kriss, Gerard A.↗

An Axial-Torsional, Thermomechanical Fatigue Testing Technique

A technique for conducting strain-controlled, thermomechanical, axial-torsional fatigue tests on thin-walled tubular specimens was developed. Three waveforms of loading, namely, the axial strain waveform, the engineering shear strain waveform, and the temperature waveform were required in these tests. The phasing relationships between the mechanical strain waveforms and the temperature and axial strain waveforms were used to define a set of four axial-torsional, thermomechanical fatigue (AT-TMF) tests. Real-time test control (3 channels) and data acquisition (a minimum of 7 channels) were performed with a software program written in C language and executed on a personal computer. The AT-TMF testing technique was used to investigate the axial-torsional thermomechanical fatigue behavior of a cobalt-base superalloy, Haynes 188. The maximum and minimum temperatures selected for the AT-TMF tests were 760 and 316 C, respectively. Details of the testing system, calibration of the dynamic temperature profile of the thin-walled tubular specimen, thermal strain compensation technique, and test control and data acquisition schemes, are reported. The isothermal, axial, torsional, and in- and out-of-phase axial-torsional fatigue behaviors of Haynes 188 at 316 and 760 C were characterized in previous investigations. The cyclic deformation and fatigue behaviors of Haynes 188 in AT-TMF tests are compared to the previously reported isothermal axial-torsional behavior of this superalloy at the maximum and minimum temperatures.

Kalluri, Sreeramesh↗

Evaluation of HAN-TEAN Stabilizers using Microcalorimetry

HAN-TEAN (hydroxylammonium nitrate - triethanolammonium nitrate - in water) is being considered for various propellant applications. This propellant has advantages in terms of insensitivity to impact and fire, low vapor pressure and environmentally benign reaction products. One office concerns with HAN-TEAN is its stability and shelf-life, especially when contaminated with trace metals. Stabilizer systems, consisting of anti-oxidants and/or chealating agents were investigated for their ability to control the decomposition of HAN-TEAN. Isothermal microcalorimetry, an ultrasensitive heat measurement technique, was used to monitor the decomposition of HANTEAN at near ambient temperatures. Isothermal microcalorimetry measures the heat flow from a reaction vessel into a surrounding heat sink. Microcalorimetry is approximately 1,000 times more sensitive than accelerating rate calorimetry (ARC) or differential scanning calorimetry (DSC) for measuring heat flow. Samples of HAN-TEAN containing the stabilizers were spiked with 50 ppm iron and the heat evolution monitored for a period of at least 30 days. Ten stabilizer combinations were tested and the rates of HAN-TEAN decomposition were lowered by 74 to 95 percent in the presence of iron.

Hornung, Steven D.↗

High-Pressure Equation of State for Partially Ionic Solids

Recently, we showed that the cohesive energy of partially ionic solids may be characterized by a two-term energy relationship consisting of a Coulomb term arising from the valence-charge transfer delta Z between the atoms, and a scaled universal energy function E(sup *)(a(sup *)), which accounts for the partially covalent character of the bond and for the repulsion between the atomic cores for small R; a(sup *) is a scaled length. Normalized cohesive-energy curves of alkali halide crystals and of Ti and Ag halide crystals were obtained, and the cohesive-energy-curve parameters were used to generate theoretical equation-of-state (EOS) curves for the Li, Na, K, Cs, and Ag halides. Good agreement was obtained with the experimental isothermal compression curves over a wide pressure range (0-90 kbar). In this paper we verify that the cohesive-energy relationship is valid for divalent partially ionic solids; physically reasonable charge-transfer values (1.80 less than delta Z less than 2.0) are obtained for MgO, CaO, and CaS. Next, EOS curves for LiF, NaF, Nal, CsCl, Csl, MgO, CaO, and CaS are generated in terms of the cohesive-energy parameters. These EOS's yield excellent fits to experimental isothermal-compression data and to shock-wave data to very high pressures (P(sub max)= 250-1350 kbar).

Schlosser, Herbert↗

Development of a Rational Modeling Approach for the Design, and Optimization of the Multifiltration Unit

This thesis includes the development and verification of an adsorption model for analysis and optimization of the adsorption processes within the International Space Station multifiltration beds. The fixed bed adsorption model includes multicomponent equilibrium and both external and intraparticle mass transfer resistances. Single solute isotherm parameters were used in the multicomponent equilibrium description to predict the competitive adsorption interactions occurring during the adsorption process. The multicomponent equilibrium description used the Fictive Component Analysis to describe adsorption in unknown background matrices. Multicomponent isotherms were used to validate the multicomponent equilibrium description. Column studies were used to develop and validate external and intraparticle mass transfer parameter correlations for compounds of interest. The fixed bed model was verified using a shower and handwash ersatz water which served as a surrogate to the actual shower and handwash wastewater.

Hand, David W.↗

Orbital Processing of Eutectic Rod-Like Arrays

The eutectic is one of only three solidification classes that exist. The others are isostructural and peritectic-class reactions, respectively. Simplistically, in a binaryeutectic phase diagram, a single liquid phase isothermally decomposes to two solid phases in a cooperative manner. The melting point minimum at the eutectic composition, isothermal solidification temperature, near-isocompositional solidification and refined solidification microstructure lend themselves naturally to such applications as brazing and soldering; industries that eutectic alloys dominate. Interest in direct process control of microstructures has led, more recently, to in-situ eutectic directional solidification with applications in electro-magnetics and electro-optics. In these cases, controlled structural refinement and the high aspect ratio and regularity of the distributed eutectic phases is highly significant to the fabrication and application of these in-situ natural composites. The natural pattern formation and scaling of the dispersed phase on a sub-micron scale has enormous potential application, since fabricating bulk materials on this scale mechanically has proven to be particularly difficult. It is thus of obvious importance to understand the solidification of eutectic materials since they are of great commercial significance. The dominant theory that describes eutectic solidification was derived for diffusion-controlled growth of alloys where both solid eutectic phases solidify metallically, i.e. without faceting at the solidification interface. Both high volume fraction (lamellar) and low volume fraction (rod-like) regular metallic arrays are treated by this theory. Many of the useful solders and brazements, however, and most of the regular in-situ composites are characterized by solidification reactions that are faceted/non-faceted in nature, rather than doubly non-faceted (metallic). Further, diffusion-controlled growth conditions are atypical terrestrially since gravitationally-driven convection is pervasive. As a consequence, it is important to determine whether these faceted/non-faceted composites behave in the same manner as their doubly non-faceted counterparts, particularly in the presence of convection. Prior analytical convective sensitivity testing of this theory predicted insensitivity. Prior experimental testing of this theory offered broad-based agreement between theory and experiment, though most results were for high volume fraction lamellar eutectics that solidified without faceting at the solidification interface. Directional solidification experiments of low volume fraction rod eutectics under damped (microgravity or magnetic field) conditions, however, have demonstrated significant sensitivity, challenging this fundamental theory. More recent theories have been proposed which introduce kinetic undercooling, faceting, fluid shear of the solute redistribution zone and the possibility that the interface composition is not the same as the bulk liquid composition. This program tests the established and proposed analytical theories and addresses the origins of discrepancies between the experimental and analytical results.

Larson, David J., Jr.↗

Magnetic Damping of Solid Solution Semiconductor Alloys

The objective of this study is to: (1) experimentally test the validity of the modeling predictions applicable to the magnetic damping of convective flows in electrically conductive melts as this applies to the bulk growth of solid solution semiconducting materials; and (2) assess the effectiveness of steady magnetic fields in reducing the fluid flows occurring in these materials during processing. To achieve the objectives of this investigation, we are carrying out a comprehensive program in the Bridgman and floating-zone configurations using the solid solution alloy system Ge-Si. This alloy system has been studied extensively in environments that have not simultaneously included both low gravity and an applied magnetic field. Also, all compositions have a high electrical conductivity, and the materials parameters permit reasonable growth rates. An important supporting investigation is determining the role, if any, that thermoelectromagnetic convection (TEMC) plays during growth of these materials in a magnetic field. TEMC has significant implications for the deployment of a Magnetic Damping Furnace in space. This effect will be especially important in solid solutions where the growth interface is, in general, neither isothermal nor isoconcentrational. It could be important in single melting point materials, also, if faceting takes place producing a non-isothermal interface. In conclusion, magnetic fields up to 5 Tesla are sufficient to eliminate time-dependent convection in silicon floating zones and possibly Bridgman growth of Ge-Si alloys. In both cases, steady convection appears to be more significant for mass transport than diffusion, even at 5 Tesla in the geometries used here. These results are corroborated in both growth configurations by calculations.

Szofran, Frank R.↗