Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “hot pressing”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

800 records · Page 45
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

The X-ray halo of an extremely luminous LSB disk galaxy

We are continuing to refine our upper limit on emission from halo gas in Malin 2. The upper limit is, of course, below the detected flux, but is made more difficult to quantify by the disk and possible AGN sources. We are also exploring spectral and spatial-size constraints to help separate the sources of emission. On the theory side, more recent work on the X-ray halo luminosity from halo gas leftover from galaxy formation has lowered the prediction for disk galaxies (e.g. Toft et al. 2002, MNRAS, 335, 799). While our upper limit is well below the original prediction, refinements in model have moved the theoretical goalposts, so that the observation may be consistent with newer models. A recent theoretical development, which our observations of Malin 2 appear to support, is that a substantial amount of mass can be accreted onto galaxies without being heated at a virial shock. The previous standard theory was that gas accreting into a halo hits a virial shock and is heated to high temperatures, which could produce X-ray halos in massive galaxies. Recent models show that "smooth accretion" of matter bypasses the virial shocking (Murali e t al. 2002, ApJ, 571, 1; Birnboim & Dekel 2003, MNRAS, 345, 349). Additionally, new hydrodynamical simulations of galaxy mergers by UCSC graduate student T. J. Cox show that hot gas halos can be created by gas blown out from the merger, taking up orbital energy of the merging galaxies (Cox et al. 2004, ApJ, 607, L87). If mergers rather than virial shocking are the origin of hot gas halos, the existence of an X-ray halo should depend more on past merger activity than halo mass. Then it makes sense that elliptical galaxies and poor groups with ellipticals, which are probably formed in mergers, have X-ray gas halos; while a giant, quiescent LSB disk galaxy like Malin 2, which has never suffered a major merger, does not have an X-ray halo. While both the observational expectations and theoretical models have changed since we began this project, which has forced us to re-evaluate the goals, we are pressing forward to firm up the observations and put them in context of the current models for X-ray halos of massive galaxies.

Weiner, Benjamin J.↗
NASA NTRS2012

Morphology Of A Hot Prominence Cavity Observed with Hinode/XRT and SDO/AIA

Prominence cavities appear as circularly shaped voids in coronal emission over polarity inversion lines where a prominence channel is straddling the solar limb. The presence of chromospheric material suspended at coronal altitudes is a common but not necessary feature within these cavities. These voids are observed to change shape as a prominence feature rotates around the limb. We use a morphological model projected in cross-sections to fit the cavity emission in Hinode/XRT passbands, and then apply temperature diagnostics to XRT and SDO/AIA data to investigate the thermal structure. We find significant evidence that the prominence cavity is hotter than the corona immediately outside the cavity boundary. This investigation follows upon "Thermal Properties of A Solar Coronal Cavity Observed with the X-ray Telescope on Hinode" by Reeves et al., 2012, ApJ, in press.

Weber, Mark A.↗
NASA NTRS2004

The Mass of the Classical Cepheid S Mus

A FUSE spectrum of the hot companion of the Cepheid S Mus has been obtained, reduced and analysed. Since the determination of the temperature of S Mus B is the prime goal of this program, we have identified two regions in the spectrum which are temperature sensitive in the temperature range of the companion, but which are not overly affected by molecular hydrogen absorption. From comparison of the spectrum with spectra of stars of known temperature, we have determined the temperature of the companion to be 17,000 K. From this a mass has been inferred. Combining this mass with the orbital velocity ratio of the Cepheid and the companion (from the ground-based Cepheid orbit, and HST GHRS echelle observations), the mass of the Cepheid is determined to be 6.0 =/- 0.4 solar masses. The results have been presented at a conference (conference proceedings in press--see attachment).

Sonneborn, George↗
DOE OSTI2023

Sustainable chemistry with plasmonic photocatalysts

There is a pressing global need to increase the use of renewable energy sources and limit greenhouse gas emissions. Towards this goal, highly efficient and molecularly selective chemical processes that operate under mild conditions are critical. Plasmonic photocatalysis uses optically resonant metallic nanoparticles and their resulting plasmonic, electronic, and phononic light-matter interactions to drive chemical reactions. The promise of simultaneous high-efficiency and product-selective reactions with plasmon photocatalysis provides a compelling opportunity to rethink how chemistry is achieved. Plasmonic nanoparticles serve as nanoscale ‘antennas’ that enable strong light–matter interactions, surpassing the light-harvesting capabilities one would expect purely from their size. Complex composite structures, combining engineered light harvesters with more chemically active components, are a focal point of current research endeavors. In this review, we provide an overview of recent advances in plasmonic catalysis. We start with a discussion of the relevant mechanisms in photochemical transformations and explain hot-carrier generation and distributions from several ubiquitous plasmonic antennae. Then we highlight three important types of catalytic processes for sustainable chemistry: ammonia synthesis, hydrogen production and CO 2 reduction. To help elucidate the reaction mechanism, both state-of-art electromagnetic calculations and quantum mechanistic calculations are discussed. This review provides insights to better understand the mechanism of plasmonic photocatalysis with a variety of metallic and composite nanostructures toward designing and controlling improved platforms for green chemistry in the future.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Advanced Autonomous Welding for Refabrication and Follow-On Testing of Previously Irradiated Nuclear Fuel

The performance of follow-on experiments using irradiated nuclear fuel at any point in its lifecycle is a critical step in understanding phenomena and behavior. Transient experiments with high-burnup fuel can deepen the understanding of fuel fragmentation, relocations, and dispersal under loss-of-coolant accidents. An advanced autonomous welding process to refabricate commercial fuel rods inside a hot cell was created and tested to enable flexible experiment approaches on fuels irradiated in commercial and test reactors. Irradiated light water reactor fuel test pins from experiments performed at the Advanced Test Reactor (ATR) at Idaho National Laboratory were used to demonstrate the refabrication process. The welding process was found to be sensitive to welding parameters but flexible such that multiple passes could be performed on the same location until a hermetic weld was obtained. The refabrication of rodlets and successful welds was also found to be sensitive to the preparation of the irradiated cladding and endcaps. Thorough defueling of the fuel at the weld location and proper sizing of the endcaps and backing material mitigated these issues. The use of strategically located heat sinks in contact with the cladding and endcap materials also increased welding and refabrication success. For this work, the test pins were sectioned to remove the original endcaps and fuel was removed from both ends of each rodlet. The reassembly of the rodlets was then completed in four steps, which included the press fitting of new endcaps, the circumferential welding of rodlet endcaps to the cladding, rodlet pressurization in a pressure chamber, and seal welding the rodlet under pressure. The integrity of the refabricated rodlets was then verified via helium leak checking inside a vacuum chamber. The advanced welding system is capable of refabricating rodlets up to 380 mm in length, and repressurizing them up to 15 500 kPa. The refabricated lengths of the rodlets used in this work ranged from 149 to 165 mm and the refabricated fuel stack heights ranged from 70.4 to 79.8 mm. Here, the rodlets were pressurized with argon to an average pressure of 3617 kPa, and the average leak rate after refabrication was 6.7 • 10 -8 cm 3 • s -1 .

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS2009

Pressure-Energized Seal Rings to Better Withstand Flows

Pressure-energized seal rings intended to withstand flows better than do conventional pressure-energized seal rings have been conceived. The concept applies, more specifically, to seal rings used on some valve stems, pistons, and the like. A conventional pressure-energized seal ring generally has a U-shaped cross section and consists of an elastomer or other suitable polymer with an embedded metal energizing spring (see Figure 1). The working fluid from the high-pressure side that one seeks to seal is allowed into the U-shaped cavity, so that the pressure pushes the sides of the seal ring tighter against the gland and body sealing surfaces, thereby increasing the degree of sealing. Unfortunately, when the seal ring is exposed to flow of the working fluid, under some conditions, the flow grabs the lip of the U-shaped cross section and ejects or deforms the seal ring so that, thereafter, a proper seal is not obtained. Figure 2 depicts one of several alternative seal rings according to the present concept. One element of the concept is to modify the U-shaped cross section from that of the corresponding conventional seal ring to eliminate the exposed lip and prevent entry of the working fluid into the U-shaped cavity. Unlike in the conventional seal, pressurized fluid would not push the seal ring directly against the both gland and body sealing surfaces. Instead, the pressure would directly push the seal ring against a gland sealing surface only. In so doing, the pressure would squash the seal ring into a smaller volume bounded by the gland and body sealing surfaces, and would thereby indirectly press the seal ring more tightly against the body sealing surface. To enhance the desired squashing deformation, a spring having an approximately parallelogram cross section would be embedded in the modified U-shaped cavity. As the pressure pushed two corners of the approximate parallelogram closer together along the axis of the seal ring, the other two corners of the approximate parallelogram would be pushed farther apart along a radius of the ring, thereby causing the polymeric ring material to push radially harder against the body sealing surface. From the radially innermost corner of the approximate parallelogram, the spring material would extend radially, then axially into recesses in the seal gland. These extensions would help to restrain the seal ring against ejection. A seat retainer would hold the sealing ring in the gland and form a mechanical compression seal to prevent or at least reduce leakage of pressurized fluid into the cavity behind the seal. However, because there would likely be a little leakage, the cavity behind the seal should be vented to the low pressure side to prevent buildup of pressure in the cavity over time; otherwise, the built-up pressure could cause ejection of the seal ring when the pressure on the high-pressure side was reduced. Polymeric seal-ring materials may not be able to withstand working conditions in applications that involve abrasive and/or hot working fluids. For such applications, all-metal seal rings may be preferred. The bottom part of Figure 2 shows one example of an alternative gland configuration with an all-metal seal ring.

Farner, Bruce↗
DOE OSTI2022

Alternate Methods for Cleaning Zirconium Plate

The United States High Performance Research Reactor Conversion Program identified the need to transition from highly enriched uranium fuel to lowly enriched uranium fuel for high power research and civil reactors. One of the fuel configurations selected for these reactors was a uranium (U) foil alloyed with 10% molybdenum (Mo). The U-10Mo fuel foil was then covered with a zirconium (Zr) interlayer and pressed into an aluminum cladding. Idaho National Laboratory prescribed a need to remove surface oxidation on the Zr prior to bonding it with U-10Mo fuel foil. To determine the best method of oxidation removal, a variety of polishing methods, including hand polishing with a diamond paste or Scotch-Brite™ pads, mechanically wet-polishing with abrasive belts, and chemical etching with hydrofluoric/nitric acid mixtures, were investigated on pre-polished Zircaloy 702 sheets purchased directly from the manufacturer. No change in surface roughness was detected using any of these methods relative to the as-received material. In fact, scanning electron microscopy detected grit from hand polishing with Amplex Grade 30 waste soluble diamond paste and Scotch-Brite™ pads. Visible staining was found, and fluorine detected via X-ray photoelectron spectroscopy on the flash etching samples. These contaminants were not seen on the as-received material. In addition to the need to remove the oxide layer on the Zr prior to co-rolling, there are concerns that the Neolube debonding agent on the co-rolling can may contaminate the Zr surface after co-rolling. The experimental results found that zirconium in contact with Neolube coated steel plates was easily cleaning with ethanol wiping after heat treated and no carbide inclusions remained on the surface. Overall, all cleaning methods tested did not significantly change the surface roughness of the plates or reduce the oxide layer present on the zirconium. Carbon was found on all the samples, before and after cleaning, except for the flash etch samples which detected fluorine instead. The insignificant changes seen in the cleaned plates relative to the as received plates question the need for cleaning prior to rolling. Further investigation in the requirements for cleaning at this step is recommended. Current methods for cleaning the surface after hot rolling with alcohol appear sufficient. After hot rolling, if Neolube does peel off the can and onto the zirconium coated foil surface, a dry abrasive or diamond paste polish is not recommended due to the chance of abrasive being embedded into the surface. However, the ability of an etchant to lift the lubricant off the zirconium surface indicates that a spot etch method could work to clean specific spots where Neolube is present, if the need arises.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS2009

Gratings Fabricated on Flat Surfaces and Reproduced on Non-Flat Substrates

A method has been developed for fabricating gratings on flat substrates, and then reproducing the groove pattern on a curved (concave or convex) substrate and a corresponding grating device. First, surface relief diffraction grating grooves are formed on flat substrates. For example, they may be fabricated using photolithography and reactive ion etching, maskless lithography, holography, or mechanical ruling. Then, an imprint of the grating is made on a deformable substrate, such as plastic, polymer, or other materials using thermoforming, hot or cold embossing, or other methods. Interim stamps using electroforming, or other methods, may be produced for the imprinting process or if the same polarity of the grating image is required. The imprinted, deformable substrate is then attached to a curved, rigid substrate using epoxy or other suitable adhesives. The imprinted surface is facing away from the curved rigid substrate. As an alternative fabrication method, after grating is imprinted on the deformable substrate as described above, the grating may be coated with thin conformal conductive layer (for example, using vacuum deposition of gold). Then the membrane may be mounted over an opening in a pressured vessel in a manner of a membrane on a drum, grating side out. The pressure inside of the vessel may be changed with respect to the ambient pressure to produce concave or convex membrane surface. The shape of the opening may control the type of the surface curvature (for example, a circular opening would create spherical surface, oval opening would create toroidal surface, etc.). After that, well-known electroforming methods may be used to create a replica of the grating on the concave or convex membrane. For example, the pressure vessel assembly may be submerged into an electro-forming solution and negative electric potential applied to the metal coated membrane using an insulated wire. Positive electric potential may be then applied to a nickel or other metal plate submerged into the same solution. Metal ions would transfer from the plate through the solution into the membrane, producing high fidelity metal replica of the grating on the membrane. In one variation, an adhesive may be deposited on the deformable substrate, and then cured without touching the rigid, curved substrate. Edges of the deformable substrate may be attached to the rigid substrate to ensure uniform deformation of the deformable substrate. The assembly may be performed in vacuum, and then taken out to atmospheric pressure conditions to ensure that no air is trapped between the deformable and rigid substrates. Alternatively, a rigid surface with complementary curvature to the rigid substrate may be used to ensure uniform adhesion of the deformable substrate to the rigid substrate. Liquid may be applied to the surface of the deformable substrate to uniformly distribute pressure across its surface during the curing or hardening of the adhesive, or the film may be pressed into the surface using a deformable object or surface. After the attachment is complete, the grooves may be coated with reflective or dielectric layers to improve diffraction efficiency.

Content, David↗