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At least 811 records · Page 45
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Spatial changes in trace element and strontium isotope water chemistry in a temperate river system with application to sturgeon movement

Understanding patterns in trace element concentrations and water quality within river systems provides a foundation to evaluate retrospective movements and habitat use of fish. Because trace elements are incorporated into calcified structures of fishes relative to water concentrations, baseline maps have application for fisheries management, including for rare species such as sturgeons. Therefore, trace elements [strontium (Sr), barium (Ba), manganese (Mn), zinc (Zn), and magnesium (Mg)], strontium isotopes ( 87 Sr/ 86 Sr), dissolved oxygen and salinity were measured in the Pearl River and Lake Pontchartrain watersheds, within Mississippi and Louisiana, USA for application in assessing riverine use by Gulf Sturgeon Acipenser oxyrinchus desotoi. Water samples were collected during the summer-fall period when juvenile Gulf Sturgeon were anticipated to be present and analyzed by solution and multi-collector inductively coupled plasma mass spectrometry. Trace element to calcium (Ca) ratios in Sr, Ba, Zn, and Mg were distinguishable between the upper Pearl River and the Bogue Chitto River tributary, and the upper Pearl River and lower Pearl River. For most trace elements and 87 Sr/ 86 Sr, there was a gradual increase from upper river regions to lower river regions, and large differences between freshwater and saline areas. Lake Pontchartrain watershed rivers were not easily differentiated, but regions of low dissolved oxygen concentrations in the lower reaches suggest available Gulf Sturgeon habitat may be seasonally limited. Therefore, maps of water microchemistry in the Pearl River watershed allow for retrospective analyses of fish watershed use.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

THE COMPOSITION OF INTERSTELLAR GRAINS TOWARD ζ OPHIUCHI: CONSTRAINING THE ELEMENTAL BUDGET NEAR THE DIFFUSE-DENSE CLOUD TRANSITION

We investigate the composition of interstellar grains along the line of sight toward ζ Ophiuchi, a well-studied environment near the diffuse-dense cloud transition. A spectral decomposition analysis of the solid-state absorbers is performed using archival spectroscopic observations from the Spitzer Space Telescope and Infrared Space Observatory. We find strong evidence for the presence of sub-micron-sized amorphous silicate grains, principally comprised of olivine-like composition, with no convincing evidence of H{sub 2}O ice mantles. However, tentative evidence for thick H{sub 2}O ice mantles on large (a ≈ 2.8 μm) grains is presented. Solid-state abundances of elemental Mg, Si, Fe, and O are inferred from our analysis and compared to standard reference abundances. We find that nearly all of the Mg and Si atoms along the line of sight reside in amorphous silicate grains, while a substantial fraction of the elemental Fe resides in compounds other than silicates. Moreover, we find that the total abundance of elemental O is largely inconsistent with the adopted reference abundances, indicating that as much as ∼156 ppm of interstellar O is missing along the line of sight. After taking into account additional limits on the abundance of elemental O in other O-bearing solids, we conclude that any missing reservoir of elemental O must reside on large grains that are nearly opaque to infrared radiation.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Giant Starship Elements Mobilize Accessory Genes in Fungal Genomes

Accessory genes are variably present among members of a species and are a reservoir of adaptive functions. In bacteria, differences in gene distributions among individuals largely result from mobile elements that acquire and disperse accessory genes as cargo. In contrast, the impact of cargo-carrying elements on eukaryotic evolution remains largely unknown. Here, we show that variation in genome content within multiple fungal species is facilitated by Starships, a newly discovered group of massive mobile elements that are 110 kb long on average, share conserved components, and carry diverse arrays of accessory genes. We identified hundreds of Starship-like regions across every major class of filamentous Ascomycetes, including 28 distinct Starships that range from 27 to 393 kb and last shared a common ancestor ca. 400 Ma. Using new long-read assemblies of the plant pathogen Macrophomina phaseolina, we characterize four additional Starships whose activities contribute to standing variation in genome structure and content. One of these elements, Voyager, inserts into 5S rDNA and contains a candidate virulence factor whose increasing copy number has contrasting associations with pathogenic and saprophytic growth, suggesting Voyager’s activity underlies an ecological trade-off. We propose that Starships are eukaryotic analogs of bacterial integrative and conjugative elements based on parallels between their conserved components and may therefore represent the first dedicated agents of active gene transfer in eukaryotes. Our results suggest that Starships have shaped the content and structure of fungal genomes for millions of years and reveal a new concerted route for evolution throughout an entire eukaryotic phylum.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2018

On the Possibility of Delayed Fission of Nuclei in the Region of Superheavy Transuranium Elements

Delayed fission of atomic nuclei was discovered in 1966. It is observed primarily in odd–odd nuclei for which the energy released in beta decay (K capture) is commensurate with the fission barrier in the nucleus formed after this process. Delayed fission was found in four nuclide regions: neutrondeficient isotopes in the Pb region, neutron-deficient isotopes in the Ac and Pa regions, and neutrondeficient and neutron-rich isotopes of transuranium elements. In the wake of investigations into the properties of isotopes of superheavy transuranium elements, numerous calculations were performed in order to determine the masses of new nuclei and to predict their decay properties. Explored and predicted properties of superheavy-element nuclides, where, for some odd–odd nuclei of transuranium elements, the K-capture energy is commensurate with the fission barriers in the corresponding daughter nuclei formed after K capture, are analyzed. Estimates of the delayed-fission probability are presented for some isotopes of elements whose charge number Z ranges from 103 to 107.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2018

Nonlocal and Mixed-Locality Multiscale Finite Element Methods

In many applications the resolution of small-scale heterogeneities remains a significant hurdle to robust and reliable predictive simulations. In particular, while material variability at the mesoscale plays a fundamental role in processes such as material failure, the resolution required to capture mechanisms at this scale is often computationally intractable. Multiscale methods aim to overcome this difficulty through judicious choice of a subscale problem and a robust manner of passing information between scales. One promising approach is the multiscale finite element method, which increases the fidelity of macroscale simulations by solving lower-scale problems that produce enriched multiscale basis functions. Here, in this study, we present the first work toward application of the multiscale finite element method to the nonlocal peridynamic theory of solid mechanics. This is achieved within the context of a discontinuous Galerkin framework that facilitates the description of material discontinuities and does not assume the existence of spatial derivatives. Analysis of the resulting nonlocal multiscale finite element method is achieved using the ambulant Galerkin method, developed here with sufficient generality to allow for application to multiscale finite element methods for both local and nonlocal models that satisfy minimal assumptions. Finally, we conclude with preliminary results on a mixed-locality multiscale finite element method in which a nonlocal model is applied at the fine scale and a local model at the coarse scale.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2019

Nonconforming Mesh Refinement for High-Order Finite Elements

In this study, we propose a general algorithm for nonconforming adaptive mesh refinement (AMR) of unstructured meshes in high-order finite element codes. Our focus is on $h$-refinement with a fixed polynomial order. The algorithm handles triangular, quadrilateral, hexahedral, and prismatic meshes of arbitrarily high-order curvature, for any order finite element space in the de Rham sequence. We present a flexible data structure for meshes with hanging nodes and a general procedure to construct the conforming interpolation operator, both in serial and in parallel. The algorithm and data structure allow anisotropic refinement of tensor product elements in two and three dimensions and support unlimited refinement ratios of adjacent elements. We report numerical experiments verifying the correctness of the algorithms and perform a parallel scaling study to show that we can adapt meshes containing billions of elements and run efficiently on 393,000 parallel tasks. Finally, we illustrate the integration of dynamic AMR into a high-order Lagrangian hydrodynamics solver.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2021

Toward a least-effort principle for evaluating prices of elements as indicators of sustainability

In this article, we explore simplifying mechanisms in materials economics for conceptionally organizing the flows of chemical elements into society. We use the concept of rank, which plays a crucial role in information theory where power laws are involved, and is a useful measure for seeking extremal principles. Borrowing from an analogy to Zipf’s law leads to a power-law relationship between abundance and rank that—pressing the Zipf’s law analogy further—may suggest that the price paid for elemental materials optimizes efficient utilization. Factors such as weight, volume, and moles in the earth's crust or in global mining production of elements are used in our analysis. For this research, 42 elements with price and production data for the year 2010 (a relatively typical year) were considered. We observe that the role of the volume from global mining production dominates in materials economics and indicate that elements such as Te and He should be sold at prices at leas ~ 100–1000 times more than their present price for efficient utilization.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2021

Probabilistic Data Association for Orbital-Element Estimation Using Multistage Expectation–Maximization

Tracking space objects is important for managing space traffic and predicting collisions, but is difficult in part due to data association and orbit model uncertainty. Expectation–maximization (EM) is a commonly used tracking method that has not been widely considered for tracking space objects. The technique consists of iteratively computing data association probabilities with a set of current element estimates, and updating estimates of the elements by solving a nonlinear weighted least-squares regression problem where the weights are the data association probabilities. In this paper, we demonstrate the use of EM for probabilistic data association and orbital-element estimation by applying the technique to simulated data from two angles-only tracking scenarios. In both scenarios, EM provides correct data associations and accurate maximum likelihood estimates of orbital elements. One scenario considers tracking a single object in clutter and quantifies the improvement of the orbital-element estimates and data associations as the detection probability increases. However, standard application of EM requires knowing the number of objects or may fail when a large number of objects are present. To address these issues, this paper employs a multistage version of EM that is applicable when there are a large and possibly unknown number of objects.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2020

Leaching of Rare Earth Elements from Central Appalachian Coal Seam Underclays

Rare earth elements (REE) are necessary for advanced technological and energy applications. To support the emerging need, it is necessary to identify new domestic sources of REE and technologies to separate and recover saleable REE product in a safe and economical manner. Underclay rock associated with Central Appalachian coal seams and prevalent in coal utilization waste products is an alternative source of REE to hard rock ores that are mainly composed of highly refractory REE-bearing minerals. This study utilizes a suite of analytical techniques and benchtop leaching tests to characterize the properties and leachability of the coal seam underclays sampled. Laboratory bench-top and flow-through reactor leaching experiments were conducted on underclay rock powders to produce a pregnant leach solution (PLS) that has relatively low concentrations of gangue elements Al, Si, Fe, and Th and is amenable to further processing steps to recover and produce purified REE product. The leaching method described here uses a chelating agent, the citrate anion, to solubilize elements that are adsorbed, or weakly bonded to the surface of clay minerals or other mineral solid phases in the rock. The citrate PLS produced from leaching specific underclay powders contains relatively higher concentrations of REE and lower concentrations of gangue elements compared to PLS produced from sequential digestion using ammonium sulfate and mineral acids. Citrate solution leaching of underclay produces a PLS with lower concentrations of gangue elements and higher concentrations of REE than achieved with hydrochloric acid or sulfuric acid. The results provide a preliminary assessment of the types of REE-bearing minerals and potential leachability of coal seam underclays from the Central Appalachian basin.

58 GEOSCIENCES↗
NASA NTRS2014

THE SuperTIGER Instrument: Measurement of Elemental Abundances of Ultra-Heavy Galactic Cosmic Rays

The SuperTIGER (Super Trans-Iron Galactic Element Recorder) instrument was developed to measure the abundances of galactic cosmic-ray elements from Ne-10 to Zr-40 with individual element resolution and the high statistics needed to test models of cosmic-ray origins. SuperTIGER also makes exploratory measurements of the abundances of elements with 40 < Z < or = 60 and measures the energy spectra of the more abundant elements for Z < or = 30 from about 0.8 to 10 GeV/nucleon. This instrument is an enlarged and higher resolution version of the earlier TIGER instrument. It was designed to provide the largest geometric acceptance possible and to reach as high an altitude as possible, flying on a standard long-duration 1.11 million cu m balloon. SuperTIGER was launched from Williams Field, McMurdo Station, Antarctica, on 2012 December 8, and made about 2.7 revolutions around the South Pole in 55 days of flight, returning data on over 50 x 10(exp 6) cosmic-ray nuclei with Z > or = 10, including approx.1300 with Z > 29 and approx.60 with Z > 49. Here, we describe the instrument, the methods of charge identification employed, the SuperTIGER balloon flight, and the instrument performance.

abundances↗
NASA NTRS2017

An Assessment of the Icing Blade and the SEA Multi-Element Sensor for Liquid Water Content Calibration of the NASA GRC Icing Research Tunnel

The Icing Research Tunnel at NASA Glenn has recently switched to from using the Icing Blade to using the SEA Multi-Element Sensor (also known as the multi-wire) for its calibration of cloud liquid water content. In order to perform this transition, tests were completed to compare the Multi-Element Sensor to the Icing Blade, particularly with respect to liquid water content, airspeed, and drop size. The two instruments were found to compare well for the majority of Appendix C conditions. However, it was discovered that the Icing Blade under-measures when the conditions approach the Ludlam Limit. This paper also describes data processing procedures for the Multi-Element Sensor in the IRT, including collection efficiency corrections, mounting underneath a splitter plate, and correcting for a jump in the compensation wire power. Further data is presented to describe the repeatability of the IRT with the Multi-Element sensor, health-monitoring checks for the instrument, and a sensing-element configuration comparison.

multi-element sensor↗
NASA NTRSDate not supplied

Mantle Source Mineralogy Inferred from Incompatible Element Ratios in Shergottites

The mineralogy of the martian mantle is a poorly known but vital compositional parameter. In the absence of samples of martian mantle peridotites, the mineralogy has been inferred from bulk composition constrained by a mix of cosmochemical and martian meteoritic constraints. Such a mineralogy reflects the primordial mantle composition, but mantle source regions that differentiated from a magma ocean are not likely to have the same mineralogy as bulk silicate Mars. An alternative approach is to infer source mineralogy of the martian mantle from the analysis of incompatible elements in shergottites. In a recent study, we showed that the general compatibility order of trace lithophile elements in martian mantle is similar to that of MORB mantle, with some exceptions. Compared to MORB mantle, in martian mantle: (1) highly incompatible elements (Th, Nb, Ta and U) are less incompatible relative to La; (2) K is significantly more compatible with respect to other elements; and (3) the HREEs are more compatible. In this study, we calculated effective partition coefficients of trace elements directly from martian igneous meteorites and used this data to infer the source mineralogy of the martian mantle.

Mars↗
DOE OSTI2019

Electromagnetics Simulations with Vector-valued Finite Elements in MOOSE

Vector-valued finite elements have become an essential part of modern electromagnetic (EM) numerical simulation. This talk will describe the development and initial validation of a MOOSE-based EM solver application, ELK (Electromagnetics Library for Kinetics and fluids), that utilizes the recently added vector-valued finite element system. The primary motivation for the development of ELK was to study EM wave propagation in radio-frequency (rf) driven systems, such as those encountered in the study of antenna structures, waveguides, and plasma physics. In simulating these scenarios with traditional scalar-valued finite elements, boundary conditions on tangential field components can sometimes be difficult to define, and field discontinuities encountered with certain geometric or structural features (e.g., abrupt corners and inhomogeneous materials) can often lead to non-physical results. Vector-valued elements can largely mitigate and even eliminate these difficulties. ELK verification and validation efforts thus far have focused on standard wave propagation benchmarks for antennas and waveguides, and the impact of vector-valued elements on the implementation and results of these simulations will be described. Progress using ELK for plasma physics simulation, where inhomogeneous simulation domains are commonplace, will also be discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Additive Manufacturing of Research Reactor Control Elements and Subsequent Neutron Irradiation

Additive manufacturing techniques have made major strides in recent years and are now capable of creating complex components in near-final form. The nuclear industry has many applications with complicated and even unique components that are time consuming, expensive, and more difficult to make using traditional fabrication routes. Modern fabrication techniques possess the potential to reduce fabrication lead-time and costs while increasing quality and efficiency. However, these methods have not been adopted due to the need for strict validation for nuclear applications. Unlike structural components that largely consist of a uniform material, for nuclear reactor core components incorporation of fissile or neutron poison materials inside a cladding becomes necessary. This in turn requires a more complex and flexible manufacturing method to produce these hybrid components. In this study, demonstration of ultrasonic additive manufacturing (UAM) process to produce components resembling research reactor control elements was carried out]. Specifically, the control elements for ORNL's High Flux Isotope Reactor (HFIR) were targeted. These control elements (consisting of an inner cylinder and four outer plates) are placed on the periphery of the circular HFIR core. The control elements consist of Al6061-T6 alloy with a 13-cm-long grey and a 56-cm-long black region, corresponding to 40 wt% of Ta and 30 wt% Eu{sub 2}O{sub 3} (europia) are incorporated along their length. In this study various fabrication parameters for production of aluminum blocks with and without embedded Eu{sub 2}O{sub 3} and Ta bearing compacts were explored. Select optimized specimens we then irradiated inside HFIR for one reactor cycle. The UAM process exploits ultrasonic energy to facilitate solid-state welding of metal foils in contact under pressure. This additive process is carried out in successive layers to build up the material and when coupled with CNC milling, it yields complex 3D components. The milling and subsequent additive steps may be used to embed foreign material into the material undergoing buildup. In this manner fissile or neutron poison elements may be incorporated into the complex structure, though in an inhomogeneous fashion. Multiple Al-6061 blocks were produced by UAM using 25 mm wide by 0.15 mm thick Al-6061-H18 tapes. The mechanical properties of these blocks in the as-fabricated condition was characterized in detail and it was shown that a great degree of anisotropy in the mechanical behavior exists between the direction in the tape plane and the direction perpendicular to the tapes (buildup direction) The latter exhibited reduced modulus and significantly smaller strength. Post production heat treatment appeared to greatly enhance the strength in the buildup direction. Multiple tensile specimens machined per SS-J3 geometry were prepared for irradiation testing. The tensile specimen matrix was set up to enable post irradiation examination of mechanical properties in various directions as well as after heat treatment. A small block with embedded Ta- and Eu{sub 2}O{sub 3}-bearing compacts, three of each kind, was also produced, as demonstrated previously. These compacts were 5.7 mm in diameter and 1.6 mm in height and contained 60 vol Ta or Eu{sub 2}O{sub 3}. The poison-bearing Al-6061 block alongside the tensile bars was loaded into a perforated rabbit (irradiation capsule) for irradiation in HFTK. The perforated rabbit allows penetration of HFIR water coolant into the Interior of the capsule in direct contact with the test specimens. The rabbit was loaded into the flux trap region at the uppermost position in the core. Irradiation temperature was 68 deg. C and fast neutron (E>0.1 MeV) fluence was 10{sup 25} neutrons/m{sup 2}. Currently PIE activities are ongoing that are focused on mechanical testing of irradiated tensile bars and metallographic examination of neutron poison bearing block.

36 MATERIALS SCIENCE↗
DOE OSTI2020

A smooth contact algorithm for the combined finite discrete element method

From its inception, the combined finite discrete element method has used a distributed potential contact force algorithm to resolve interaction between finite elements. The contact interaction algorithm relies on evaluation of the contact force potential field. The problem with existing algorithms is that the potential field introduces artificial numerical non-smoothness in the contact force. This work introduces a smooth potential field based on the finite element topology, and a generalized contact interaction law is constructed on top of the smooth potential field. Further, a number of validation cases for the proposed algorithm, considering different shapes of discrete elements, are presented, and detailed aspects of the proposed contact interaction law are tested with numerical examples.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2017

Modeled Martian subsurface elemental composition measurements with the Probing In situ with Neutron and Gamma ray instrument: Gamma and Neutron Measurements on Mars

Here, the Probing In situ with Neutrons and Gamma rays (PING) instrument is an innovative application of active neutron-induced gamma-ray technology. The objective of PING is to measure the elemental composition of the Martian regolith. As part 2 of a two-part submission, this manuscript presents PING's sensitivities as a function of the Martian regolith depth and PING's uncertainties in the measurements as a function of observation time in passive and active mode. Part 1 of our submission models the associated regolith types. The modeled sensitivities show that in PING's active mode, where both a Pulsed Neutron Generator (PNG) and a Gamma-Ray Spectrometer (GRS) are used, PING can interrogate the material below the rover to about 20 cm due to the penetrating nature of the high-energy neutrons and the resulting secondary gamma rays observed with the GRS. PING is capable of identifying most major and minor rock-forming elements, including H, O, Na, Mn, Mg, Al, Si, P, S, Cl, Cr, K, Ca, Ti, Fe and Th. The modeled uncertainties show that PING's use of a PNG reduces the required observation times by an order of magnitude over a passive operating mode where the PNG is turned off. While the active mode allows for more complete elemental inventories with higher sensitivity, the gamma-ray signatures of some elements are strong enough to detect in passive mode. We show that PING can detect changes in key marker elements and make thermal neutron measurements in about 1 minute that are sensitive to H and Cl.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

Numerical integration in the virtual element method with the scaled boundary cubature scheme

Abstract The virtual element method (VEM) is a stabilized Galerkin method on meshes that consist of arbitrary (convex and nonconvex) polygonal and polyhedral elements. A crucial ingredient in the implementation of low‐ and high‐order VEM is the numerical integration of monomials and nonpolynomial functions over such elements. In this article, we apply the recently proposed scaled boundary cubature (SBC) scheme to compute the weak form integrals in various virtual element formulations over polygonal and polyhedral meshes. In doing so, we demonstrate the flexibility of the approach and the accuracy that it delivers on a broad suite of boundary‐value problems in 2D and 3D over polytopes with affine faces as well as on elements with curved boundaries. In addition, the use of the SBC scheme is exemplified in an enriched Poisson formulation of the VEM in which weakly singular functions are required to be integrated. This study establishes the SBC method as a simple, accurate and efficient integration scheme for use in the VEM.

Chin, Eric B.↗
DOE OSTI2018

A generalized O-element approach for analyzing interface structures

A correct description of interfacial dislocations is critical to the understanding of physical and mechanical properties of the interfaces and their impact on phase transformation and deformation mechanisms. The O-lattice theory provides a general theoretical framework for determining interfacial dislocation structures. However, for systems having an invariant line (IL) or an invariant plane, the O-elements do not always exist in the three-dimensional (3D) space, which impedes the capability of the O-lattice theory to the interfaces in these systems. To determine the dislocation structures in interfaces for which the O-elements do not extend in the 3D space, we introduce a generalized O-element approach by employing the Moore-Penrose pseudoinverse. The generalized O-elements, as the least square solutions to the O-lattice, play a parallel role as that of the ideal O-elements and extend the candidate locations for the coherent regions between dislocations. Worked examples for dislocation structures in both homo-phase and hetero-phase systems are presented. The predicted interface structures are in good agreement with experimental observations and molecular statics (MS)/molecular dynamics (MD) simulations.

36 MATERIALS SCIENCE↗