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Electric Vehicle Charging Demand in the Chicago Metropolitan Area through 2030

This report outlines the collaborative efforts between Argonne National Laboratory and Exelon in advancing the Agent-Based Transportation Energy Analysis Model (ATEAM). Aligning with ComEd’s beneficial electrification plan, this study developed eight scenarios to access the temporal and spatial distribution of charging load and demand stemming from the widespread adoption of battery electric vehicles (BEV) adoption, augmented public charging infrastructure deployment, and increased multi-unit dwelling (MUD) charging availability. Enhancements to the ATEAM model encompassed the simulation of multiple days of travel behavior, estimation of total public charging infrastructure needs, user interface refinements, and output tracking at both vehicle and charging station levels. The total electricity consumption for residential and public charging to support over 800,000 BEVs in Chicago in 2029 is projected at approximately 10.2 GWh. Enhanced MUD home charging accessibility (70%) amplifies the home charging load in the study area by 1.5% compared to the baseline scenario (10%). The widespread adoption of BEVs reduces peak charging loads, owing to their inclusion across households with diverse income levels, thus fostering a more dispersed charging activity pattern. However, widespread BEV adoption increases the peak home charging load in areas with lower median household incomes, reflecting a higher BEV concentration in these locales and, subsequently, heightened peak charging demands. In the Widespread BEV adoption scenario, fewer census tracts exhibit elevated peak loads for combined home and public charging, indicating a more even distribution of charging demand across the study area. Predominantly, peak loads for combined charging—both home and public— occur between 2 p.m. and 10 p.m. across all scenarios, encompassing the majority of census tracts.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Results From Mars Show Electrostatic Charging of the Mars Pathfinder Sojourner Rover

Indirect evidence (dust accumulation) has been obtained indicating that the Mars Pathfinder rover, Sojourner, experienced electrostatic charging on Mars. Lander camera images of the Sojourner rover provide distinctive evidence of dust accumulation on rover wheels during traverses, turns, and crabbing maneuvers. The sol 22 (22nd Martian "day" after Pathfinder landed) end-of-day image clearly shows fine red dust concentrated around the wheel edges with additional accumulation in the wheel hubs. A sol 41 image of the rover near the rock "Wedge" (see the next image) shows a more uniform coating of dust on the wheel drive surfaces with accumulation in the hubs similar to that in the previous image. In the sol 41 image, note particularly the loss of black-white contrast on the Wheel Abrasion Experiment strips (center wheel). This loss of contrast was also seen when dust accumulated on test wheels in the laboratory. We believe that this accumulation occurred because the Martian surface dust consists of clay-sized particles, similar to those detected by Viking, which have become electrically charged. By adhering to the wheels, the charged dust carries a net nonzero charge to the rover, raising its electrical potential relative to its surroundings. Similar charging behavior was routinely observed in an experimental facility at the NASA Lewis Research Center, where a Sojourner wheel was driven in a simulated Martian surface environment. There, as the wheel moved and accumulated dust (see the following image), electrical potentials in excess of 100 V (relative to the chamber ground) were detected by a capacitively coupled electrostatic probe located 4 mm from the wheel surface. The measured wheel capacitance was approximately 80 picofarads (pF), and the calculated charge, 8 x 10(exp -9) coulombs (C). Voltage differences of 100 V and greater are believed sufficient to produce Paschen electrical discharge in the Martian atmosphere. With an accumulated net charge of 8 x 10(exp -9) C, and average arc time of 1 msec, arcs can also occur with estimated arc currents approaching 10 milliamperes (mA). Discharges of this magnitude could interfere with the operation of sensitive electrical or electronic elements and logic circuits. Sojourner rover wheel tested in laboratory before launch to Mars. Before launch, we believed that the dust would become triboelectrically charged as it was moved about and compacted by the rover wheels. In all cases observed in the laboratory, the test wheel charged positively, and the wheel tracks charged negatively. Dust samples removed from the laboratory wheel averaged a few ones to tens of micrometers in size (clay size). Coarser grains were left behind in the wheel track. On Mars, grain size estimates of 2 to 10 mm were derived for the Martian surface materials from the Viking Gas Exchange Experiment. These size estimates approximately match the laboratory samples. Our tentative conclusion for the Sojourner observations is that fine clay-sized particles acquired an electrostatic charge during rover traverses and adhered to the rover wheels, carrying electrical charge to the rover. Since the Sojourner rover carried no instruments to measure this mission's onboard electrical charge, confirmatory measurements from future rover missions on Mars are desirable so that the physical and electrical properties of the Martian surface dust can be characterized. Sojourner was protected by discharge points, and Faraday cages were placed around sensitive electronics. But larger systems than Sojourner are being contemplated for missions to the Martian surface in the foreseeable future. The design of such systems will require a detailed knowledge of how they will interact with their environment. Validated environmental interaction models and guidelines for the Martian surface must be developed so that design engineers can test new ideas prior to cutting hardware. These models and guidelines cannot be validated without actual flighata. Electrical charging of vehicles and, one day, astronauts moving across the Martian surface may have moderate to severe consequences if large potential differences develop. The observations from Sojourner point to just such a possibility. It is desirable to quantify these results. The various lander/rover missions being planned for the upcoming decade provide the means for doing so. They should, therefore, carry instruments that will not only measure vehicle charging but characterize all the natural and induced electrical phenomena occurring in the environment and assess their impact on future missions.

Kolecki, Joseph C.↗

Improved Control of Charging Voltage for Li-Ion Battery

The protocol for charging a lithium-ion battery would be modified, according to a proposal, to compensate for the internal voltage drop (charging current internal resistance of the battery). The essence of the modification is to provide for measurement of the internal voltage drop and to increase the terminal-voltage setting by the amount of the internal voltage drop. Ordinarily, a lithium-ion battery is charged at constant current until its terminal voltage attains a set value equal to the nominal full-charge potential. The set value is chosen carefully so as not to exceed the lithium-plating potential, because plated lithium in metallic form constitutes a hazard. When the battery is charged at low temperature, the internal voltage drop is considerable because the electrical conductivity of the battery electrolyte is low at low temperature. Charging the battery at high current at any temperature also gives rise to a high internal voltage drop. In some cases, the internal voltage drop can be as high as 1 volt per cell. Because the voltage available for charging is less than the terminal voltage by the amount of the internal voltage drop, the battery is not fully charged (see figure), even when the terminal voltage reaches the set value. In the modified protocol, the charging current would be periodically interrupted so that the zero-current battery-terminal voltage indicative of the state of charge could be measured. The terminal voltage would also be measured at full charging current. The difference between the full-current and zero-current voltages would equal the internal voltage drop. The set value of terminal voltage would then be increased beyond the nominal full-charge potential by the amount of the internal voltage drop. This adjustment would be performed repeatedly, in real time, so that the voltage setting would track variations in the internal voltage drop to afford full charge without risk of lithium plating. If the charging current and voltage settings were controlled by a computer, then this method of charge control could readily be implemented in software.

Timmerman, Paul↗

Implementation of Charged Particle Behavior in Discrete Element Method (DEM) Simulations

Lunar landers will agitate the surface of the Moon with an exhaust plume during descent which will, due to the particulate nature of the lunar regolith, loosen and eject grains from the surface. This ejection is not only coupled with the charged plume gas, but also results in significant particle-particle interactions. Settling of these grains after plume effects have subsided takes much longer than expected in a ballistic trajectory. The prevailing hypothesis attributes this behavior to the accumulated charge on the particles. We are thus developing a discrete element method (DEM) approach to explore these charged particle interactions on the lunar surface. The Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) Improved for General Granular and Granular Heat Transfer Simulations (LIGGGHTS) software package provides a DEM modeling framework for granular interactions. It includes many complexities such as non-spherical particle shapes, cohesion and frictional forces, and heat transfer, but has no provision for inter-particle electrostatic forces and charge transfer that are important to examine in the lunar environment. In this work, a standard Coulomb potential and a Yukawa potential are integrated into the LIGGGHTS framework to provide a basis for particle-particle electrostatic interactions, as well as a gravitational potential to enable inter-grain gravitational interactions. A preliminary approach to charge transfer between grains incorporating properties such as work function and electrical conductivity to the library of available material characteristics will be presented. Several scenarios have been simulated that include charged particle interactions within a diffuse granular gas, settling of charged grains into a regolith bed, sliding of granular material along an incline, and vibration of settled grains to produce a behavior similar to fluidization. There are numerous challenges to incorporate realistic interactions between complex lunar particles. Currently, grains are modeled to behave as if the entirety of the charge acts at the center of mass, such as conductors with spherical symmetry and insulators with homogeneously distributed charge. We are developing improvements that will include the use of non-spherical particle geometries, as well as reasonable approximations of insulating/dielectric materials that have non-uniform charge distributions. The cases simulated thus far will be examined in a relevant environment within a vacuum chamber to validate the simulations. These simulations will be bounded by experiments utilizing high-speed camera observations of the motion for validation. The grains in the experiment will exchange charge during their motion and this can be quantified by collection within a charge measurement device such as a Faraday cup. Such a device may be modeled within the software by defining an integration region and computing the contained charge as a function of simulation time, allowing for side-by-side comparison of simulated and measured bulk charging results. Any differences will be reconciled by updating the mathematical mechanisms described within the simulation suite. Successfully combining results from experiments within a relevant environment into the LIGGGHTS framework will improve modeling of the charged grain dynamics experienced on the Moon to provide insights into dust behavior for future lunar exploration missions.

Electrostatics↗

Shadow of charged wormholes in Einstein–Maxwell–dilaton theory

The study of shadow is quite prominent nowadays because of the ongoing Event Horizon Telescope{sup 1} observations. We construct the shadow images of charged wormholes in Einstein–Maxwell–dilaton (EMD) theory. The spacetime metric of the charged wormholes contains three charges: magnetic charge P, electric charge Q, and dilaton charge Σ. We evaluate the photon geodesics around the charged wormholes. We also calculate the effective potential and discuss its behavior with angular momentum L and different values of charges P, Q, and Σ. A study of the shadow of charged wormholes reveals that the shadow has an effect of the charges P and Q. The radius of the shadow increases with the magnetic charge P as well as the electric charge Q. We also find that the dilaton charge does not affect the shadow of the charged wormholes.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Estimating the electric vehicle charging demand of multi-unit dwelling residents in the United States

Abstract Early battery electric vehicle (EV) adopters can access home chargers for reliable charging. As the EV market grows, residents of multi-unit dwellings (MUDs) may face barriers in owning EVs and charging them without garage or parking availability. To investigate the mechanisms that can bridge existing disparities in home charging and station deployment, we characterized the travel behavior of MUD residents and estimated their EV residential charging demand. This study classifies the travel patterns of MUD residents by fusing trip diary data from the National Household Travel Survey and housing features from the American Housing Survey. A hierarchical agglomerative clustering method was used to cluster apartment complex residents’ travel profiles, considering attributes such as dwell time, daily vehicle miles traveled (VMT), income, and their residences’ US census division. We propose a charging decision model to determine the charging station placement demand in MUDs and the charging energy volume expected to be consumed, assuming that MUD drivers universally operate EVs in urban communities. Numerical experiments were conducted to gain insight into the charging demand of MUD residents in the US. We found that charging availability is indispensable for households that set out to meet 80% state of charge by the end of the day. When maintaining a 20% comfortable state of charge the entire day, the higher the VMT are, the greater the share of charging demand and the greater the energy use in MUD chargers. The upper-income group requires a greater share of MUD charging and greater daily kWh charged because of more VMT.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Atomic charges for modeling metal–organic frameworks: Why and how

Atomic partial charges are parameters of key importance in the simulation of Metal–Organic Frameworks (MOFs), since Coulombic interactions decrease with the distance more slowly than van der Waals interactions. But despite its relevance, there is no method to unambiguously assign charges to each atom, since atomic charges are not quantum observables. There are several methods that allow the calculation of atomic charges, most of them starting from the electronic wavefunction or the electronic density or the system, as obtained with quantum mechanics calculations. In this work, we describe the most common methods employed to calculate atomic charges in MOFs. In order to show the influence that even small variations of structure have on atomic charges, we present the results that we obtained for DMOF-1. We also discuss the effect that small variations of atomic charges have on the predicted structural properties of IRMOF-1. - Graphical abstract: We review the different method with which to calculate atomic partial charges that can be used in force field-based calculations. We also present two examples that illustrate the influence of the geometry on the calculated charges and the influence of the charges on structural properties. - Highlights: • The choice of atomic charges is crucial in modeling adsorption and diffusion in MOFs. • Methods for calculating atomic charges in MOFs are reviewed. • We discuss the influence of the framework geometry on the calculated charges. • We discuss the influence of the framework charges on structural the properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Calculating and Characterizing the Charge Distributions in Solids

Accurate estimation of the partial atomic charges on metal centers is useful for understanding electronic and catalytic properties of materials. However, different methods of calculating these charges may give quite different results; this issue has been more widely studied for molecules than for solids. Here we study the charges on the metal centers of a test set of 18 solids containing transition metals by using density functional theory with several density functionals (PBE, PBE+U, TPSS, revTPSS, HLE17, revM06-L, B3LYP, B3LYP*, and other exchange-modified B3LYP functionals) and four charge models (Bader, Hirshfeld, CM5, and DDEC6). The test set contains 12 systems with nonmagnetic metal centers (eight metal oxides (MO 2 ), two metal sulfides (MS 2 ), and two metal selenides (MSe 2 )) and six ferromagnetic transition metal complexes. Our study shows that, among the four types of charges, Bader charges are the highest and Hirshfeld charges are the lowest for all the systems, regardless of the functional being used. The CM5 charges are bigger than DDEC6 charges for MX 2 with M = Ti or Mo and X = S or Se, but for the other 14 cases they are lower. We found that the most of the systems are sensitive to the Hubbard U parameters in PBE+U and to the percentage X of Hartree–Fock exchange in exchange-modified B3LYP; as we increase U or X, the charges on the metal atoms in MX 2 increase steadily. Testing different density functionals shows charges calculated with higher Hubbard U parameters in PBE+U are comparable to B3LYP (with 20% Hartree–Fock exchange). Among four meta-GGA functionals studied, the charges with HLE17 have the closest agreement with B3LYP. In conclusion, the variation of charges with choice of charge model is greater than the variation with choice of density functional.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Economic Analysis of On-Route Fast Charging for Battery Electric Buses: Case Study in Utah

Battery electric buses (BEBs) are increasingly being embraced by transit agencies as an energy-efficient and emission-free alternative to bus fleets. However, because of the limitations of battery technology, BEBs suffer from limited driving range, great battery cost, and time-consuming charging processes. On-route fast charging technology is gaining popularity as a remedy, reducing battery cost, extending driving range, and reducing charging time. With on-route fast charging, BEBs are as capable as their diesel counterparts in relation to range and operating time. However, transit agencies may have the following concerns about on-route fast charging: 1) on-route fast charging stations require massive capital costs; 2) on-route fast charging may lead to high electricity power demand charges; and 3) charging during peak hours may increase electricity energy charges. This study conducts a quantitative economic analysis of on-route fast charging for BEBs, thereby providing some guidelines for transit agencies. An integrated optimization model is first proposed to determine battery size, charger type, and recharging schedule for a general BEB route. Based on the model, an economic analysis of on-route fast charging is then performed on 10 real-world bus routes and a simplified general bus route with different parameters. The results demonstrate that given the current prices of on-route fast charging stations and batteries, it is always beneficial to install on-route fast charging stations for BEBs. A sensitivity analysis is also conducted to show the impact of potential price reductions of batteries.

Engineering↗

Proposed Modifications to Engineering Design Guidelines Related to Resistivity Measurements and Spacecraft Charging

A key parameter in modeling differential spacecraft charging is the resistivity of insulating materials. This determines how charge will accumulate and redistribute across the spacecraft, as well as the time scale for charge transport and dissipation. Existing spacecraft charging guidelines recommend use of tests and imported resistivity data from handbooks that are based principally upon ASTM methods that are more applicable to classical ground conditions and designed for problems associated with power loss through the dielectric, than for how long charge can be stored on an insulator. These data have been found to underestimate charging effects by one to four orders of magnitude for spacecraft charging applications. A review is presented of methods to measure the resistive of highly insulating materials, including the electrometer-resistance method, the electrometer-constant voltage method, the voltage rate-of-change method and the charge storage method. This is based on joint experimental studies conducted at NASA Jet Propulsion Laboratory and Utah State University to investigate the charge storage method and its relation to spacecraft charging. The different methods are found to be appropriate for different resistivity ranges and for different charging circumstances. A simple physics-based model of these methods allows separation of the polarization current and dark current components from long duration measurements of resistivity over day- to month-long time scales. Model parameters are directly related to the magnitude of charge transfer and storage and the rate of charge transport. The model largely explains the observed differences in resistivity found using the different methods and provides a framework for recommendations for the appropriate test method for spacecraft materials with different resistivities and applications. The proposed changes to the existing engineering guidelines are intended to provide design engineers more appropriate methods for consideration and measurements of resistivity for many typical spacecraft charging scenarios.

Dennison, J. R.↗

Characteristics of Extreme Auroral Charging Events

The highest level spacecraft charging observed in low Earth orbit (LEO) occurs when spacecraft are exposed to energetic auroral electrons. Since auroral charging has been identified as a mechanism responsible for on-orbit anomalies and even possible satellite failures it is important to consider extreme auroral charging events as design and test environments for spacecraft to be used in high inclination LEO orbits. This paper will report on studies of extreme auroral charging events using data from the SSJ/4 and SSJ/5 precipitating electron and ion sensors on the Defense Meteorology Satellite Program (DMSP) satellites. Early studies of DMSP charging to negative potentials ≥100 V focused on statistics of the electron environment responsible for charging. Later statistical studies of auroral charging have generally focused on solar cycle dependence of charging behavior and magnitude of the maximum potential and duration of the charging events. We extend these studies to focus on more detailed investigations of extreme charging event characteristics that are required to evaluate potential threats to spacecraft systems. A collection of example auroral charging events is assembled from the DMSP data set using the criteria that "extreme auroral charging" is defined as periods with spacecraft negative potentials ≥400 V. Specific characteristics to be treated include (but are not limited to) maximum and mean potentials, time history of spacecraft potentials through the events, total charging duration and the time potentials exceed voltage thresholds, frame charging/discharging rates, and information on geographic and geomagnetic latitudes at which the events are observed. Finally, we will comment on the implications of these studies for potential auroral charging risks to the International Space Station.

Minow, Joseph I.↗

International Space Station Spacecraft Charging Environments: Modeling, Measurement and Implications for Future Human Space Flight Programs

Spacecraft charging analysis and migration is an interdisciplinary subject combining aspects of electrostatics, plasma physics, ionizing radiation, and materials science, as well as electronic system electromagnetic interference and compatibility (EMI/EMC) effects. Spacecraft charging hazards are caused by the accumulation of electrical charge on spacecraft and spacecraft components produced by interactions with space plasmas, energetic charged particles, and solar UV photons as well as spacecraft electrical power and propulsion systems operations. Spacecraft charging hazard effects include both hard and soft avionics and electrical power system anomalies and have led to the partial or complete loss of numerous spacecraft. The International Space Station (ISS) orbital altitude and inclination (~400 km and 51.6o) determined the dominant natural environment factors affecting ISS spacecraft charging; high speed flight through the geomagnetic field and electrical power system interaction with the cold, high-density ionospheric plasma. In addition ISS is exposed to energetic auroral electrons at high latitude. In this paper we present the results of ISS spacecraft charging modeling and measurements and compare the measurements with numerical modeling of ISS charging processes. ISS is a large metallic structure and flight through the geomagnetic field at orbital speed dominates ISS charging. Collection of ionospheric electrons by the large 160V PV arrays is the next largest contributor. Charging by auroral electrons is detectable but makes a relatively minor contribution. Finally we report the observation of short duration (~ 1 sec) rapid charging peaks associated with shunt/un-shunt operations of the 160V PV arrays, a phenomena not predicted before flight. ISS spacecraft charging environments are radically different from those encountered at higher altitudes in Earth?s magnetosphere and in cis-Lunar space. We present a brief review of those charging environments and an assessment of the applicability of ISS spacecraft charging management and experience to future human spaceflight programs beyond LEO.

Koontz, Steven L.↗

Permittivity Threshold and Thermodynamics of Integer Charge-Transfer Complexation for an Organic Donor–Acceptor Pair

Molecular or chemical-based charge doping provides a means to change the properties (e.g. conductivity) of a material through a complete or partial transfer of charge between its constituents. Understanding how local material environment impacts this process is thus important for controlling the properties of organic materials. This paper presents spectroscopic investigations of molecular charge transfer interactions between a pair of common charge-doping and -transporting materials (2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane, F4TCNQ, and N,N’-Diphenyl-N-N’-di-p-tolylbenzene-1,4-diamine, MPDA). Equilibrium constants associated with charge transfer were determined for donor-acceptor pairs dissolved in a series of solvents covering a range of values of permittivity. A threshold for highly favorable charge separation was observed to occur at a permittivity of ~8-9, with more and less favorable charge separation observed in solvents of higher and lower permittivity, respectively, but with chloroform (permittivity=4.81) exhibiting an anomalously favorable charge separation. Temperature-dependent studies were undertaken to assess the thermodynamics of charge separation. In 1,2- dichloroethane (permittivity=10.36) and chlorobenzene (permittivity=5.62), charge transfer was observed to be both enthalpically and entropically favorable. Charge separation in chloroform is exothermic and entropically disfavored, indicating that specific, inner-shell solvent-solute interactions stabilize the charge-separated complex and result in a net increase in local solution structure. Furthermore, our results provide insight on how modification to the chemical environment may be utilized to support stable charge transfer for molecular doping applications and requiring only modest changes in local permittivity.

36 MATERIALS SCIENCE↗

Plasma charge injection technology and its application to c-Si solar cells for field-effect passivation

A plasma charge injection technology applicable for field-effect passivation in crystalline silicon solar cells is discussed. The technology uses an inert-gas plasma (helium, argon, N 2 , etc.) as a charge source and a DC bias to extract desired charges from a remote plasma source. A charging model is proposed, and it gives a good guideline to determine a proper charging operation condition for a desired injection charge density. The technology can introduce electric charges into a nitride–oxide or oxide–nitride–oxide passivation stack in a few hundred milliseconds with a charge density equivalent to or higher than that of A l 2 O 3 in a range of 5 × 10 12 to 8 × 10 12 cm -2 . Most-like charge injection mechanisms are discussed for both negative and positive charging. This technology uses a cheap inert-gas plasma which does not cause any parasitic film deposition nor any corrosion inside the chamber during the charging operation and, thus, does not require regular maintenance for chamber cleaning, which leads to a very low cost of ownership. This charging technology is promising for a low-cost alternative to the complex A l 2 O 3 technology. This plasma charge injection can be another important application of the plasma technology among other well-known applications such as dry etching, thin-film deposition, sputtering, etc.

14 SOLAR ENERGY↗

Revenue-Maximizing Shared Parking and Electric Vehicle Charging Management in Multi-Unit Dwellings

In urban areas, searching for parking and electric vehicle (EV) charging can result in cruising, congestion, and environmental externalities. Recognizing the business opportunity of offering private parking and charging infrastructure access within multi-unit dwellings (MUDs) during daytime, we model a shared parking and EV charging management system. We maximize the revenue of MUD charging hubs in mixed land use, catering to public demand. Our approach accounts for the objectives of the two stakeholders involved: a demand model is fitted on the choices of EV charging users, and the supply model optimizes the allocation of parking and charging requests in an MUD parking lot. A binary integer linear programming model for the allocation of parking and charging spaces with a rolling horizon is integrated with matching rules that handle both parking and charging requests. In our numerical experiments in a neighborhood of Chicago, Illinois, we estimate the performance of the MUD parking and charging system with metrics that include revenue, number of matchings, and utilization rates. At any given time, MUDs with lower prices attract more charging requests, particularly those of longer duration, resulting in higher revenue and greater charging utilization. Dynamic pricing facilitates a more equitable distribution of requests; as MUD parking lots reach capacity and their fees increase, other MUDs become more competitive, attracting additional requests. Comparing our method against first-come-first-served and optimal-solution benchmarks, we demonstrate our model’s effectiveness in dynamically managing mixed parking and charging demand in MUD charging hubs.

electric vehicle, multi-unit dwelling, charging in↗

Extreme Fast Charging of Lithium-Ion Battery: Understanding Bottlenecks and Safety Issues

Currently, graphite-based lithium-ion battery (LIB) packs in the electric vehicle (EV) domain can accommodate a charging rate up to 2C, which translates into a 0.5 to 1h recharge time [1-2]. Reducing the recharge time down to 10-15 min range would reduce the gap between the internal combustion engine’s refueling time and EV’s recharge time. Minimizing this gap is seen as attractive to consumers and would eventually enhance the adoption of EVs [1-3]. Significant research activity has been going on globally to understand the scientific limitations associated with high rate charging [4-6]. Extreme fast charging (XFC) of Li-ion batteries can create LIB life and safety issues [1, 7]. Among the issues are shortened battery life and enhanced safety concerns due to potential short creation by Li dendrites [1-2]. The detection and monitoring of Li plating onset and evolution over aging is a significant challenge. In-operando detection schemes to understand the dynamics of Li plating and the role that aging has on Li plating are vital to enable fast charging of specific energy cells. A key to the effort would be understanding the interplay between materials, electrode structure, and use conditions. This presentation will discuss the key bottlenecks of aggressive fast charging (~10 min). In particular, how extreme fast charging impacts individual battery components as well as the overall battery’s performance, life, and safety will be presented in light of experimental results and analysis. The effectiveness and challenges of in-operando electrochemical detection methods in aggressive charging conditions shall also be discussed. References [1] S. Ahmed, I. Bloom, A. N. Jansen, T. R. Tanim, E. J. Dufek, A. Pesaran, A. Burnham, R. B. Carlson, F. Dias, K. Hardy,M. Keyser, C. Kreuzer, A. Markel, A. Meintz, C. Michelbacher, M. Mohanpurkar, P. A. Nelson, D. C. Robertson, D. Scoffield,M. Shirk, T. Stephens, R. Vijayagopal, J. Zhang, Enabling fast charging–A battery technology gap assessment, J Power Sources,367 (2017), 250-262 [2] T.R. Tanim, M. G. Shirk, R. L. Bewley, E. J. Dufek, B. Y. Liaw, Fast charge implications: Pack and cell analysis and comparison,, J Power Sources, 381 (2018) 56-65 [3] N. Lutsey, S. Searle, S. Chambliss, and A. Bandivadekar, Assessment of leading electric vehicle promotion activities inUnited States cities, International Council on Clean Transportation, July 2015 [4] C. Michelbacher, S. Ahmed, I. Bloom, A. Burnham, B. Carlson, F. Dias, E. J. Dufek, A. N Jansen, M. Keyser, A. Markel,A. Meintz, M. Mohanpurkar, A. Pesaran, D. Scoffield, M. Shirk, T. Stephens, T. R. Tanim, R. Vijayagopal, J. Zhang, Enablingfast charging–Introduction and overview, J Power Sources, [5] E-Mobility: New Possibilities with 800-volt charging, Porsche newsroom, https://newsroom.porsche.com/en/technology/porsche-engineering-e-power-electromobility-800-volt-charging-12720.html(accessed Sep 2017) [6] Charging interface initiative e.V. - Industry statement on future charging infrastructure, available at: http://www.charinev.org/fileadmin/Downloads/Papers_and_Regulations/CharIN_industry_statement.pdf(accessed June 2017) [7] T. Waldmann, B. Hogg,M. Kasper, S. Grolleau, C. Couceiro, K. Trad, B. P. Matadi and M. Wohlfahrt-Mehrens, Interplay ofOperational Parameters on Lithium Deposition in Lithium-Ion Cells: Systematic Measurements with Reconstructed 3-ElectrodePouch Full Cells, J. Electrochem. Soc. 163 (7) (2016) A1232-A1238

25 ENERGY STORAGE↗

Cost-Effective and Ecofriendly Plug-In Hybrid Electric Vehicle Charging Management

In this study we explore two charging management schemes for plug-in hybrid electric vehicles (PHEVs). The PHEV drivers and the government were stakeholders who might have preferred different charging control strategies. For the former, a proposed controlled charging scheme minimized the operational cost during PHEV charge-depleting and sustaining modes. For the latter, the research minimized monetized carbon dioxide emissions from electricity generation for the PHEVs charging, as well as tailpipe emissions for the portion of PHEV trips fueled by gasoline. Hourly driving patterns and electricity data were leveraged. Both were representative of each of the eight North American Electric Reliability Corporation regions to examine the results of the proposed schemes. The model accounted for drivers' activity patterns and charging availability spatial and temporal heterogeneity. The optimal charging profiles confirmed the differing nature of the objectives of PHEV drivers and the government; cost-effective charge should occur early in the morning, while ecofriendly charge should be late in the afternoon. Each control's trade-offs between operation cost and emission savings are discussed for each North American Electric Reliability Corporation region. The availability of workplace and public charging was found to affect the optimal charging profiles greatly. Charging control is more efficient for drivers and government when PHEVs have greater electric range.

33 ADVANCED PROPULSION SYSTEMS↗

DC Fast Charging Infrastructure for Electrified Road Trips

To assess DC fast charging station network required for electrified road trips by 2030 in California, a new charging infrastructure simulation tool/model, EVI-Pro (Electric Vehicle Infrastructure Projection) RoadTrip, has been developed. In contrast to the existing EVI-Pro model that is primarily for short-distance travels, EVI-Pro RoadTrip is exclusively focused on road trips (long-distance travels, 100 or miles per day per vehicle). Also, the charging paradigm or strategy is different. EVI-Pro RoadTrip is built upon waypoint charging, in which vehicles are forced to stop to charge or replenish the on-board batteries, along the routes between origins and destinations. On the other hand, EVI-Pro is based on destination charging, in which charging is conducted when vehicles are parked in destinations (e.g., work, home). EVI-Pro RoadTrip takes coordinate-level origin and destination data for road trips (intra-state as well as domestic or international out-of-state) and estimates energy consumption and charging needs along the routes between origins and destinations on a minute-by-minute resolution. Based on charging demands for electrified road trips across the state, the optimal locations of charging stations are determined accounting for preferred land use types (e.g., commercial areas) and station service area (e.g., 5 or less miles). Based on station-by-station charging load profiles, the required number of plugs/connectors is estimated for each station and entire state. By comparing hosting capacity of the electric grid (circuit-level) and the charging load output from EVI-Pro RoadTrip, capacity deficit is also evaluated.

ADVANCED PROPULSION SYSTEMS,ENERGY STORAGE↗