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At least 811 records · Page 45

A new method for operating a continuous flow diffusion chamber to investigate immersion freezing: assessment and performance study

Glaciation in mixed-phase clouds predominately occurs through the immersion freezing mode where ice nucleating particles (INPs) immersed within supercooled droplets induce nucleation of ice. Currently, model representations of this process are a large source of uncertainty in simulating cloud radiative properties, and to constrain these estimates, continuous flow diffusion chamber (CFDC)-style INP devices are commonly used to assess the immersion freezing efficiencies of INPs. In this study, a new approach was explored to operating such an ice chamber that provides maximum activation of particles without droplet breakthrough and correction factor ambiguity to obtain high-quality INP measurements in a manner that has not been demonstrated as possible previously. The conditioning section of the chamber was maintained at ~ –20 °C and water relative humidity (RH w ) ~ 113 % conditions to maximize the droplet activation, and the droplets were supercooled with an independently temperature-controlled nucleation section at a steady cooling rate (0.5 °C min –1 ) to induce the freezing of droplets and evaporation of unfrozen droplets. The performance of the modified ice chamber was evaluated using four INP species: K-feldspar, illite-NX, Argentinian soil dust, and airborne arable dust that had shown ice nucleation over a wide span of supercooled temperatures. Dry dispersed and size-selected K-feldspar particles were generated in the laboratory. Illite-NX and soil dust particles were sampled during the second phase of the Fifth International Ice Nucleation Workshop (FIN-02) campaign, and airborne arable dust particles were sampled from the aerosol inlet located on the rooftop of the laboratory. The measured ice nucleation efficiencies of model aerosols with a surface active site density (n s ) metric were higher, but mostly agreed within one order of magnitude compared to literature results.

54 ENVIRONMENTAL SCIENCES↗

Reactive transport modeling for supporting climate resilience at groundwater contamination sites

Abstract. Climate resilience is an emerging issue at contaminated sites and hazardous waste sites, since projected climate shifts (e.g., increased/decreased precipitation) and extreme events (e.g., flooding, drought) could affect ongoing remediation or closure strategies. In this study, we develop a reactive transport model (Amanzi) for radionuclides (uranium, tritium, and others) and evaluate how different scenarios under climate change will influence the contaminant plume conditions and groundwater well concentrations. We demonstrate our approach using a two-dimensional (2D) reactive transport model for the Savannah River Site F-Area, including mineral reaction and sorption processes. Different recharge scenarios are considered by perturbing the infiltration rate from the base case as well as considering cap-failure and climate projection scenarios. We also evaluate the uranium and nitrate concentration ratios between scenarios and the base case to isolate the sorption effects with changing recharge rates. The modeling results indicate that the competing effects of dilution and remobilization significantly influence pH, thus changing the sorption of uranium. At the maximum concentration on the breakthrough curve, higher aqueous uranium concentration implies that sorption is reduced with lower pH due to remobilization. To better evaluate the climate change impacts in the future, we develop the workflow to include the downscaled CMIP5 (Coupled Model Intercomparison Project) climate projection data in the reactive transport model and evaluate how residual contamination evolves through 2100 under four climate Representative Concentration Pathway (RCP) scenarios. The integration of climate modeling data and hydrogeochemistry models enables us to quantify the climate change impacts, assess which impacts need to be planned for, and therefore assist climate resiliency efforts and help guide site management.

54 ENVIRONMENTAL SCIENCES↗

Biochar alters hydraulic conductivity and impacts nutrient leaching in two agricultural soils

Biochar is purported to provide agricultural benefits when added to the soil, through changes in saturated hydraulic conductivity (K sat ) and increased nutrient retention through chemical or physical means. Despite increased interest and investigation, there remains uncertainty regarding the ability of biochar to deliver these agronomic benefits due to differences in biochar feedstock, production method, production temperature, and soil texture. In this project, a suite of experiments was carried out using biochars of diverse feedstocks and production temperatures, in order to determine the biochar parameters which may optimize agricultural benefits. Sorption experiments were performed with seven distinct biochars to determine sorption efficiencies for ammonium and nitrate. Only one biochar effectively retained nitrate, while all biochars bound ammonium. The three biochars with the highest binding capacities (produced from almond shell at 500 and 800 °C (AS500 and AS800) and softwood at 500 °C (SW500)) were chosen for column experiments. Biochars were amended to a sandy loam and a silt loam at 0 % and 2 % (w/w), and K sat was measured. Biochars reduced K sat in both soils by 64 %–80 %, with the exception of AS800, which increased K sat by 98 % in the silt loam. Breakthrough curves for nitrate and ammonium, as well as leachate nutrient concentration, were also measured in the sandy loam columns. All biochars significantly decreased the quantity of ammonium in the leachate, by 22 % to 78 %, and slowed its movement through the soil profile. Ammonium retention was linked to high cation exchange capacity and a high oxygen-to-carbon ratio, indicating that the primary control of ammonium retention in biochar-amended soils is the chemical affinity between biochar surfaces and ammonium. Biochars had little to no effect on the timing of nitrate release, and only SW500 decreased total quantity, by 27 % to 36 %. The ability of biochar to retain nitrate may be linked to high micropore specific surface area, suggesting a physical entrapment rather than a chemical binding. Together, this work sheds new light on the combined chemical and physical means by which biochar may alter soils to impact nutrient leaching and hydraulic conductivity for agricultural production.

54 ENVIRONMENTAL SCIENCES↗

Scout Benchmark Scenarios for U.S. Building Energy and CO2 Emissions to 2050

Overview and Intended Use Cases: These scenarios establish a range of futures for U.S. buildings sector energy use and CO2 emissions to 2050 using Scout (scout.energy.gov), a reproducible and granular model of U.S. building energy use, emissions, and consumer costs developed by the U.S. national labs for the U.S. Department of Energy's Building Technologies Office (BTO). Scout benchmark scenario data are suitable for the following example use cases: setting high-level policy goals for the U.S. buildings sector to 2050 (e.g., X% building CO2 emissions reductions vs. 2005 levels by 2030, Y% reductions vs. 2005 levels by 2050); exploring the effects of key dynamics driving U.S. buildings sector energy and CO2 emissions to 2050 that could be affected by policy levers (e.g., raising minimum technology performance levels; accelerating electrification and/or retrofit rates; introducing breakthrough technologies to the market); determining priority segments (regions, building types, and end use/technology types) and sequencing of U.S. buildings sector energy and CO2 emissions reductions to 2050 under a given set of assumptions; and/or identifying the energy and emissions impacts or cost effectiveness of specific technologies or operational approaches of interest—in isolation or after considering competition with other measures in a scenario portfolio. Scenario Summary: A total of 8 scenarios explore the effects of changes across both the demand- and supply-side of building energy use on annual U.S. building energy use and CO2 emissions from 2022–2050. Scenarios are organized into three groups representing low, moderate, and best-case potentials for building decarbonization, respectively.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Intertwined States at Finite Temperatures in the Hubbard Model

We report significant advances in numerical techniques have enabled recent breakthroughs in the study of various properties of the Hubbard model - a seemingly simple, yet complex model of correlated electrons that has been a focus of study for more than half a century. In particular, it captures the essence of strong correlations, and is believed to possess various emergent, low energy states and collective excitations characteristic of cuprate high-temperature superconducting materials. While a thorough review of all activity is not possible here, we have focused the discussion on our recent work using unbiased, numerically exact, “brute force”, finite temperature quantum Monte Carlo methods. Our various studies reveal a rich variety of quantum liquid crystal phases, and complementary transport properties, which answer some questions, but certainly raise others concerning “strange metal” behavior and the ultimate fate of quasiparticles in the Hubbard model.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Development of the Saturn Space Vehicle

The Saturn launch vehicle program has become a major element in our national space effort within little more than 3 years. At the beginning of the program, in 1958, various Saturn configurations were planned to lift instrumented payloads of 20,000 to 40,000 lb. into Earth orbit. As research and development progressed, it became apparent that the vehicle design approach had far more potential than anticipated that it was, in fact, a breakthrough into a new class of heavy launch vehicles. Thus, within the space of a few years, it was possible to consider even more advanced missions. In addition to placing multiton payloads in orbit, we can seriously conceive sending over 90,000 lb. of instruments on escape missions, using advanced Saturn-class vehicles. With these vehicles, we plan to accomplish lunar reconnaissance and manned lunar landings scheduled for the latter part of this decade. Likewise, these vehicles will permit flight tests of advanced nuclear power plants and stages.

SATURN LAUNCH VEHICLE↗

Use of nonwettable membranes for water transfer

Transfer of water through nonwettable vinyl fluoride membranes has two unique features - /1/ very low water transfer rates can be held constant by holding temperature and solute concentrations constant, /2/ the pressure gradient against which water is transported is limited only by solution breakthrough or membrane strength.

Hausch, H. G.↗

Nonvolatile read/write memory element - A concept

Memory, with limited number of programming cycles, is achieved by using verticle, fusible links in series with oxide breakthrough elements. Memory elements are fabricated with integrated circuit technology and are ideal for low power digital computer application.

Cricchi, J. R.↗

Large-scale terrestrial solar cell power generation cost: A preliminary assessment

A cost study was made to assess the potential of the large-scale use of solar cell power for terrestrial applications. The incentive is the attraction of a zero-pollution source of power for wide-scale use. Unlike many other concepts for low-pollution power generation, even thermal pollution is avoided since only the incident solar flux is utilized. To provide a basis for comparison and a perspective for evaluation, the pertinent technology was treated in two categories: current and optimistic. Factors considered were solar cells, array assembly, power conditioning, site preparation, buildings, maintenance, and operation. The capital investment was assumed to be amortized over 30 years. The useful life of the solar cell array was assumed to be 10 years, and the cases of zero and 50-percent performance deg-radation were considered. Land costs, taxes, and profits were not included in this study because it was found too difficult to provide good generalized estimates of these items. On the basis of the factors considered, it is shown that even for optimistic projections of technology, electric power from large-sclae terrestrial use of solar cells is approximately two to three orders of magnitude more costly than current electric power generation from either fossil or nuclear fuel powerplants. For solar cell power generation to be a viable competitor on a cost basis, technological breakthroughs would be required in both solar cell and array fabrication and in site preparation.

Spakowski, A. E.↗

Expendable Second Stage Reusable Space Shuttle Booster. Volume 10: Technology Requirements

Technology requirements for the expendable second stage of the space shuttle booster system are discussed. The primary objective of the expendable second stage (ESS) program is to define a low-cost system for placing large payloads, such as the space station or reusable nuclear shuttle, into low earth orbit. The proposed concept is to utilize a modified Saturn 5 second stage (S-2) in conjunction with the space shuttle reusable booster. The ESS retains the major S-2 structure, modified for attachment to the space shuttle booster, and incorporates both Saturn and shuttle developed propulsion and avionics hardware. No major technology breakthroughs are required to develop this ESS system. Technology application and implementation efforts in selected areas, however, should be conducted in support of the ESS detail design and development phase. The selected ESS system incorporates recovery of propulsion and avionics hardware by the shuttle orbiter for ESS reuse to minimize cost.

Source record↗

Development of a Thick-film Silicon Ribbon Growth Technique for Application to Large-area Solar Cells and Arrays

A new technique is described for growth of large-area silicon ribbons. This technique is an edge-defined, film-fed growth process by which single crystals can be grown having a shape controlled by the outside dimensions of a shaping die, growth taking place from an extremely thin film of liquid fed by capillary action from a crucible below. The material from which the die is fabricated is very critical to the process. The die must be wet by the silicon, but adverse impurities must not be introduced into the silicon, and the die must not become degraded by the molten silicon. A breakthrough in die fabrication that has allowed the growth of silicon ribbons having dimensions of 1 cm by 30 cm with a thickness of 0.7 mm is described. The implications of this significant advancement with respect to development of photovoltaic solar arrays for wide-scale terrestrial solar-to-electric energy conversion systems are discussed.

Berman, P. A.↗

Overall evaluation of ERTS imagery for cartographic application

The author has identified the following significant results. The apparently successful fitting of a plane coordinate (UTM) grid to an ERTS-1 bulk image represents a breakthrough of potential economic importance. If such results continue to be attained it means that ERTS-1 imagery even in bulk form can be reproduced as planimetric image maps that meet National Map Accuracy Standards up to the 1:250,000 scale. Such maps permit positions of image points to be geodetically defined to within 75 meters (rms). Previous efforts to map with ERTS-1 images resulted in errors approaching 300 meters (rms).

Colvocoresses, A. P.↗

Galactic background maps at 3.93 and 6.55 MHz

The Radio Astronomy Explorer Satellite (RAE-1), its hardware and its data processing are discussed. The data from the prime mapping antenna are discussed with emphasis on the problems involved in reducing the data. Particular attention is drawn to two problems - receiver instability and ground breakthrough - and their influence on the data. Galactic background maps of the nonthermal radiation at 3.93 and 6.55 MHz are produced. It is demonstrated that the positional uncertainity of the maps is about 20 deg. The maps at 3.93 and 6.55 MHz are compared to two ground based maps made at higher frequencies that are smoothed to the larger RAE antenna patterns.

Novaco, J. C.↗

Automated land-use mapping from spacecraft data

The author has identified the following significant results. In response to the need for a faster, more economical means of producing land use maps, this study evaluated the suitability of using ERTS-1 computer compatible tape (CCT) data as a basis for automatic mapping. Significant findings are: (1) automatic classification accuracy greater than 90% is achieved on categories of deep and shallow water, tended grass, rangeland, extractive (bare earth), urban, forest land, and nonforested wet lands; (2) computer-generated printouts by target class provide a quantitative measure of land use; and (3) the generation of map overlays showing land use from ERTS-1 CCTs offers a significant breakthrough in the rate at which land use maps are generated. Rather than uncorrected classified imagery or computer line printer outputs, the processing results in geometrically-corrected computer-driven pen drawing of land categories, drawn on a transparent material at a scale specified by the operator. These map overlays are economically produced and provide an efficient means of rapidly updating maps showing land use.

Chase, P. E.↗

Apogee motor rocketry reliability improvements

Since 1963, solid-propellant apogee motors have been placing satellites into geosynchronous orbits. Major technological breakthroughs are not required to satisfy future mission requirements; however, there is a need to improve reliability to enhance cost effectiveness. A summary of results and conclusions derived from a review of missions, where failure of a solid motor was inferred, and from a correlation of system factors with failures are reported. Highlights of a solid motor diagnostic instrumentation study are presented. Finally, recommendations are provided for areas of future apogee motor upgrade, which will increase project cost effectiveness by reducing the potential for future flight failures.

Behm, J.↗

Polarization studies of planetary atmospheres

Studies are considered of the planets Venus, Earth, Mars, Jupiter, Saturn, Uranus, and Neptune. The era of precise planetary polarimetry began with the work of Lyot (1929). The investigations in this field were continued by Dollfus (1957), who added detailed studies of planetary regions. A new breakthrough came with the availability of photoemissive detectors, which led to extensive measurements of the wavelength dependence of the polarization of planets. Two very recent developments have been the inclusion of photoelectric polarimeters on planetary space probes and the development of precise polarimeters for the measurement of elliptical polarization.

Coffeen, D. L.↗

Apogee motor rocketry reliability improvements

Since 1963, solid propellant apogee motors have been placing satellites into geosynchronous orbits. Major technological breakthroughs are not required to satisfy future mission requirements; however, there is a need to improve reliability to enhance cost effectiveness. Several management test options are discussed. A summary of results and conclusions derived from review of missions, where failure of a solid motor was inferred, and correlation of system factors with failures are reported. Highlights of a solid motor diagnostic instrumentation study are presented. Finally, recommendations are provided for areas of future apogee motor upgrade, which will increase project cost effectiveness by reducing the potential for future flight failures.

Behm, J.↗