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At least 811 records · Page 45

Large balancing areas and dispersed renewable investment enhance grid flexibility in a renewable-dominant power system in China

Renewable energy is poised to play a major role in achieving China's carbon neutrality goal by 2060; however, reliability and flexibility is a big concern of a renewable-dominant power system. Various strategies of enhancing flexibility are under discussion to ensure the reliability of such a system, but no detailed quantitative analysis has been reported yet in China. We combine the advantages of a capacity expansion model, SWITCH-China, with a production simulation model, PLEXOS, and analyze flexibility options under different scenarios of a renewable-dominant power system in China. We find that a larger balancing area offers direct flexibility benefits. Regional balancing could reduce the renewable curtailment rate by 5-7%, compared with a provincial balancing strategy. National balancing could further reduce the power cost by about 16%. However, retrofitting coal power plants for flexible operation would only improve the system flexibility marginally.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Response to “how robust are reductions in modeled estimates from GTAP-BIO of the indirect land use change induced by conventional biofuels?”

Malins et al. (2020) recently published "How robust are reductions in modeled estimates from GTAP-BIO of the indirect land use change induced by conventional biofuels?", provided their narrative from the model improvements in GTAP-BIO over time, made several critical points regarding this model, and argued that the implemented improvements in this model tended to decrease Induce Land Use Changes (ILUC) emissions. Furthermore, they also provided several critical points regarding the Carbon Calculator for Land Use Change from Biofuels Production (CCLUB) emissions model. In this response to Malins et al. we address these critiques point-by-point by providing our detailed responses to key issues: 1) the GTAP-BIO model and its improvements over time; 2) the inclusion of cropland pasture in the model; 3) the observed land use changes in the US that have been the bases for improvements in GTAP-BIO model, 4) the time trends in corn price and yield to challenge the concept of the yield to price response; 5) some sources of land intensification in crop production; 6) the FAO notifications with respect to the comparison between harvested area and arable land; and 7) the GTAP-BIO results for multiple cropping. We also provided responses to Malins et al. critical points regarding the CCLUB emissions model. We hope that this response letter will open more constructive discussion among the LUC modeling community to remain focused on the big picture regarding agriculture's role as a very effective GHG mitigation tool that can shape the new policies to govern the production and consumption of biofuels.

09 BIOMASS FUELS↗

Learning functional priors and posteriors from data and physics

In this work, we develop a new Bayesian framework based on deep neural networks to be able to extrapolate in space-time using historical data and to quantify uncertainties arising from both noisy and gappy data in physical problems. Specifically, the proposed approach has two stages: (1) prior learning and (2) posterior estimation. At the first stage, we employ the physics-informed Generative Adversarial Networks (PI-GAN) to learn a functional prior either from a prescribed function distribution, e.g., Gaussian process, or from historical data and physics. At the second stage, we employ the Hamiltonian Monte Carlo (HMC) method to estimate the posterior in the latent space of PI-GANs. In addition, we use two different approaches to encode the physics: (1) automatic differentiation, used in the physicsinformed neural networks (PINNs) for scenarios with explicitly known partial differential equations (PDEs), and (2) operator regression using the deep operator network (DeepONet) for PDE-agnostic scenarios. We then test the proposed method for (1) meta-learning for one-dimensional regression, and forward/inverse PDE problems (combined with PINNs); (2) PDE-agnostic physical problems (combined with DeepONet), e.g., fractional diffusion as well as saturated stochastic (100-dimensional) flows in heterogeneous porous media; and (3) spatial-temporal regression problems, i.e., inference of a marine riser displacement field using experimental data from the Norwegian Deepwater Programme (NDP). The results demonstrate that the proposed approach can provide accurate predictions as well as uncertainty quantification given very limited scattered and noisy data, since historical data could be available to provide informative priors. In summary, the proposed method is capable of learning flexible functional priors, e.g., both Gaussian and non-Gaussian process, and can be readily extended to big data problems by enabling mini-batch training using stochastic HMC or normalizing flows since the latent space is generally characterized as low dimensional.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

An advanced low-cost cathode composed of graphene-coated Na 2.4 Fe 1.8 (SO 4 ) 3 nanograins in a 3D graphene network for ultra-stable sodium storage

Iron-based electrodes have attracted great attention for sodium storage because of the distinct cost effectiveness. However, exploring suitable iron-based electrodes with high power density and long duration remains a big challenge. Herein, a spray-drying strategy is adopted to construct graphene-coated Na 2.4 Fe 1.8 (SO 4 ) 3 nanograins in a 3D graphene microsphere network. The unique structural and compositional advantages endow these electrodes to exhibit outstanding electrochemical properties with remarkable rate performance and long cycle life. Additionally, mechanism analyses further explain the outstanding electrochemical properties from the structural aspect.

25 ENERGY STORAGE↗

Development of a multi-layer canopy model for E3SM Land Model with support for heterogeneous computing

The vertical structure of vegetation canopies creates micro-climates. However, the land components of most Earth System Models, including the Energy Exascale Earth System Model (E3SM), typically neglect vertical canopy structure by using a single layer big-leaf representation to simulate water, CO 2 , and energy exchanges between the land and the atmosphere. In this study, we developed a Multi-Layer Canopy Model for the E3SM Land Model to resolve the micro-climate created by vegetation canopies. The model developed in this study re-implements the CLM-ml_v1 to support heterogeneous computing architectures consisting of CPUs and GPUs and includes three additional optimization-based stomatal conductance models. The use of Portable, Extensible Toolkit for Scientific Computation provides a speedup of 25–50 times on a GPU relative to a CPU. The numerical implementation of the model was verified against CLM-ml_v1 for a month-long simulation using data from the Ameriflux US-University of Michigan Biological Station site. Model structural uncertainty was explored by performing control simulations for five stomatal conductance models that exclude and include the control of plant hydrodynamics (PHD) on photosynthesis. The bias in simulated sensible and latent heat fluxes was lower when PHD was accounted for in the model. Additionally, six idealized simulations were performed to study the impact of three environmental variables (i.e. air temperature, atmospheric CO 2 , and soil moisture) on canopy processes (i.e. net CO 2 assimilation, leaf temperature, and leaf water potential). Increasing air temperature reduced net CO 2 assimilation and increased air temperature. Net CO 2 assimilation increased at higher atmospheric CO 2 , while decreasing soil moisture resulted in lower leaf water potential.

54 ENVIRONMENTAL SCIENCES↗

Locus coeruleus catecholamines link neuroticism and vulnerability to tau pathology in aging

Higher neuroticism is a risk factor for Alzheimer's disease (AD), and is implicated in disordered stress responses. The locus coeruleus (LC)-catecholamine system is activated during perceived threat and is a centerpiece of developing models of the pathophysiology of AD, as it is the first brain region to develop abnormal tau. We examined relationships among the "Big 5" personality traits, LC catecholamine synthesis capacity measured with [ 18 F]Fluoro-m-tyrosine PET, and tau burden measured with [ 18 F]Flortaucipir PET in cognitively normal older adults (n = 47). β-amyloid (Aβ) status was determined using [ 11 C]Pittsburgh compound B PET (n = 14 Aβ positive). Lower LC catecholamine synthesis capacity was associated with higher neuroticism, more depressive symptoms as measured by the Geriatric Depression Scale, and higher amygdala tau-PET binding. Exploratory analyses with other personality traits revealed that low trait conscientiousness was also related to both lower LC catecholamine synthesis capacity, and more depressive symptoms. A significant indirect path linked both high neuroticism and low conscientiousness to greater amygdala tau burden via their mutual association with low LC catecholamine synthesis capacity. Together, these findings reveal LC catecholamine synthesis capacity to be a promising marker of affective health and pathology burden in aging, and identifies candidate neurobiological mechanisms for the effect of personality on increased vulnerability to dementia.

59 BASIC BIOLOGICAL SCIENCES↗

Performance of 8 × 8 × 32 and 10 × 10 × 32 mm 3 CdZnTe position-sensitive virtual Frisch-grid detectors for high-energy gamma ray cameras

CdZnTe (CZT) crystals with thicknesses up to 20 mm and diameters up to 75 mm have become available from Redlen Technologies, Inc. for making large-volume gamma-ray detectors. The modified growth and optimized annealing conditions allowed Redlen to minimize the dark current and improve the uniformity of CZT crystals. Two detector designs, pixelated (H3D) and position-sensitive virtual Frisch-grid (VFG), have greatly benefitted from the availability of such big crystals. Encouraging results from testing of 40×40×15 mm 3 pixelated detectors were recently reported by the University of Michigan. In this work, we evaluated the spectroscopic properties of 8×8×32 and 10×10×32 mm 3 crystals configured as position-sensitive VFG detectors. Both digitized waveforms and an analog ASIC were used to read and process the signals from the detectors and test their spectral- and spatial-resolution. The VFG design provides the flexibility to scale-up the dimensions of the detectors for the desired efficiency, while the position information allows for correcting the detectors' response non-uniformity caused by crystal defects and devices geometry, thereby reducing the instrument cost and making them more feasible for emerging applications in gamma-ray astronomy, nonproliferation, portal screening and nuclear safeguards, where large detector arrays are often required.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Characterization of shale using Helium and Argon at high pressures

In order to estimate the shale gas in place and the eventual recovery during shale gas operations, one of the key requirements is to accurately characterize the shale’s petrophysical and transport properties such as porosity, permeability, diffusivity, and storage capacity. Despite the many efforts reported in the technical literature aiming to provide an improved understanding of the complex pore structures and the associated fluid flow in gas shales, complete characterization of organic-rich shale samples still poses a big challenge. Here, we have characterized mass transfer and sorption in shale at different length scales using Helium (He) and Argon (Ar) as probe gases. Thermogravimetric analysis (TGA) with a shale cube of ~1 cm 3 in size and gas expansion experiments with a full-diameter core (3.5” in diameter) were used to measure sorption kinetics/isotherms and mass transfer, respectively. Both samples are from the same depth/location in the Marcellus shale formation. The TGA steady-state technique was initially used to generate excess sorption isotherms for Ar, while dynamic TGA experiments were used to study its sorption kinetics. The TGA experiments demonstrate that Ar, which has a similar sorption potential as Methane, but is generally assumed to be inert, adsorbs onto the surfaces of the mesoporous and microporous regions of the shale samples according to a Langmuir-type behavior. Helium expansion experiments, on the full-diameter core, were used to measure the overall porosity, on the basis that He is a non-sorbing and inert gas as compared to Ar. The He expansion experiments, furthermore, allow us to delineate the mass transfer of gas across the inherent hierarchy of pore sizes, including macropores (macro- and microcracks), mesopores and micropores. Similar expansion experiments were also performed with Ar to study the combined impact of mass transfer and sorption. A triple-porosity model (TPM) was utilized to interpret the He expansion experiments with the shale core and to extract (estimate) relevant transport parameters. We report and compare here the diffusivities and permeabilities of the whole core for both He and Ar, as calculated from the modeling and fitting of the experimental data. On the premise that the shale cube is representative of the matrix region of the core, the Ar sorption kinetics from the cube experiments were subsequently combined with the transport parameters extracted from the He experiments to predict the behavior of the Ar expansion test with the full-diameter core. An excellent agreement is observed between the model predictions and the experimental data. The experimental observations and their interpretation indicate that one must be cautious when using Ar to estimate the true porosity and permeability of shales. In addition, we demonstrate that He and Ar probe gases, when used in tandem, can be employed effectively as a tool to characterize shales in terms of mass transfer and sorption dynamics across scales.

04 OIL SHALES AND TAR SANDS↗

Causal horizons, geodesic completeness and stability in slow contraction cosmology

We show that cosmological models with a semi-infinite phase of slow contraction (ekpyrosis) possess a combination of properties that can address several fundamental problems in cosmology, otherwise faced in contracting de Sitter phases or standard big bang expansion. In particular, flat or open slow contraction admits a stable past attractor that asymptotes to Minkowski space and is past geodesically complete, as well as a stable, flat, homogeneous, and isotropic future attractor with negligible Weyl curvature (and, therefore, negligible gravitational entropy). In bouncing cosmologies, this contracting attractor is terminated by a smooth, non-singular bounce that transforms the attractor properties at the end of contraction into the initial conditions for the subsequent expanding phase. Cosmologies incorporating a slow contraction phase have no particle horizon and therefore avoid the causal horizon problem. The past Minkowski attractor also generates an initial spectrum of vacuum-like quantum fluctuations on all wavelengths. Moreover, because the averaged expansion rate along past-directed geodesics is non-positive, models incorporating a semi-infinite phase of slow contraction also evade the Borde–Guth–Vilenkin theorem. By contrast, contracting de Sitter space possesses a finite particle horizon and becomes unstable in the presence of scalar fields, matter, or radiation.

Cosmology and Nongalactic Astrophysics (astro-ph.C↗

Cosmological constraints on dark matter interactions with ordinary matter

Dark matter interactions with electrons or protons during the early Universe leave imprints on the cosmic microwave background and the matter power spectrum, and can be probed through cosmological and astrophysical observations. These interactions lead to momentum and heat exchange between the ordinary and dark matter components, which in turn results in a transfer of pressure from the ordinary to the dark matter. Here, we explore these interactions using a diverse suite of data: cosmic microwave background anisotropies, baryon acoustic oscillations, the Lyman-α forest, and the abundance of Milky-Way subhalos. We derive constraints using model-independent parameterizations of the dark matter–electron and dark matter–proton interaction cross sections and map these constraints onto concrete dark matter models. Our constraints are complementary to other probes of dark matter interactions with ordinary matter, such as direct detection, big bang nucleosynthesis, various astrophysical systems, and accelerator-based experiments. They exclude sufficiently large cross sections for a large range of dark matter masses, which cannot be accessed by direct-detection experiments due to the overburden from the Earth’s atmosphere or crust.

79 ASTRONOMY AND ASTROPHYSICS↗

Indirect methods in nuclear astrophysics with relativistic radioactive beams

Reactions with radioactive nuclear beams at relativistic energies have opened new doors to clarify the mechanisms of stellar evolution and cataclysmic events involving stars and during the big bang epoch. Numerous nuclear reactions of astrophysical interest cannot be assessed directly in laboratory experiments. Ironically, some of the information needed to describe such reactions, at extremely low energies (e.g., keVs), can only be studied on Earth by using relativistic collisions between heavy ions at GeV energies. In this contribution, we make a short review of experiments with relativistic radioactive beams and of the theoretical methods needed to understand the physics of stars, adding to the knowledge inferred from astronomical observations. We continue by introducing a more detailed description of how the use of relativistic radioactive beams can help to solve astrophysical puzzles and several successful experimental methods. State-of-the-art theories are discussed at some length with the purpose of helping us understand the experimental results reported. The review is not complete and we have focused most of it to traditional methods aiming at the determination of the equation of state of symmetric and asymmetric nuclear matter and the role of the symmetry energy. Whenever possible, under the limitations of our present understanding of experimental data and theory, we try to pinpoint the information still missing to further understand how stars evolve, explode, and how their internal structure might be. We try to convey the idea that in order to improve microscopic theories for many-body calculations, nuclear structure, nuclear reactions, and astrophysics, and in order to constrain and allow for convergence of our understanding of stars, we still need considerable improvements in terms of accuracy of experiments and the development of new and dedicated nuclear facilities to study relativistic reactions with radioactive beams.

79 ASTRONOMY AND ASTROPHYSICS↗

On the uncertainty of estimating photovoltaic soiling using nearby soiling data

The accumulation of dust on the surface of photovoltaic modules can reduce their performance and affect the cost competitiveness of this technology. This phenomenon is known as soiling and can be mitigated through appropriate corrective and/or preventive actions. In order to maximize its effectiveness, it is important to plan the soiling mitigation strategy even before the PV system is operational. This is typically done through a nearest neighbor approach, by estimating soiling using data from the nearest operational photovoltaic system. This work focuses on understanding the uncertainty related to this practice. For this purpose, the semi-variance function is used to study the dissimilarity between the soiling losses of two locations in California depending on their distance. The results show that, when the soiling loss at a nearby system is used to estimate soiling of a site, the uncertainty can be approximated to increase linearly at a rate of 0.08-0.10%/km up to 60 or 80 km. After this distance, the use of a nearest neighbor approach is no longer justified, as it produces an uncertainty as big as the average soiling loss of the sites in the dataset used in this study. In some conditions, uncertainties > 0% are found also for sites located within 25 km, meaning that even close-by systems might soil differently.

14 SOLAR ENERGY↗

An Ab initio based OH initiated oxidation kinetics of glycerol carbonate: A promising biofuel component

The global energy demand is steadily increasing because of the population explosion and economic growth. Fossil fuels supply around 85 % of global primary energy demand. On one hand, fulfilling the increasing energy demands is a big challenge for the next few decades. On the other hand, the continued burning of fossil fuels leads to higher CO2 emissions, severely impacting global warming. Therefore, the policymakers vow to shift from conventional fuels to renewable resources for economic, environmental, and future energy security reasons. In this context, biofuels from lignocellulosic biomass and/or carbon-neutral fuels produced in the sustainable carbon cycle can close the carbon cycle and reach net zero-carbon emission. Recently, glycerol carbonate has been proposed as a promising fuel or fuel additive for future sustainability. Therefore, we investigated the hydrogen abstraction reactions of glycerol carbonate (GC) by OH radicals using high-level ab initio and variational transition state theory calculations. We mapped out the potential energy surface using the CCSD(T)/cc-pV(D, T)Z//MP2/cc-pVTZ level of theory. Here we used the ab initio parameters to obtain the site-specific rate coefficients by employing the variational transition state theory. We observed that every hydrogen atom in GC displays a unique reactivity with OH radicals. We derived branching ratio of each channel that are difficult to access experimentally. The overall rate coefficients exhibit a strong non-Arrhenius behaviour, which can be represented as: $k^{CVT/SCT}_{ov}$ (T) = 3.39 x 10 -20 x T 2.659 x e$\frac{-750.0 Jmol^{-1}}{RT}$ $\frac{cm^{3}}{molecule s}$ This is the first reported rate data for the glycerol carbonate and OH radicals reaction.

09 BIOMASS FUELS↗

Additive manufacturing of highly dense anisotropic Nd–Fe–B bonded magnets

Extrusion based big area additive manufacturing process is utilized for fabrication of dense anisotropic bonded magnets. High loading fraction (≥70 vol%) of magnequench anisotropic Nd–Fe–B powder in nylon is used for preparing anisotropic bonded magnets. A higher energy product of ~143.2 kJ/m 3 is obtained for the post printed magnetic field aligned at 1 Tesla. These findings make an important step towards the fabrication of gap magnets with energy product between ferrite and Nd–Fe–B sintered magnets. Finally, printed bonded magnets exhibited better thermal stability, mechanical properties and superior magnetic properties compared to commercial injection molded magnets.

36 MATERIALS SCIENCE↗

The energy footprint of automotive electronic sensors

We discuss how Information and communication technologies (ICT) have emerged as one of the leading technologies to reduce global emissions, particularly in the mobility sector. Automotive electronics, such as sensors/actuators and microcontrollers (commonly known as electronic control units (ECU) which control one or more of the electrical systems or subsystems in a vehicle), play a key role in ICT. Sensors/actuators are key in electronic ICT devices, starting with the data collection and data communication with the internet. The latest two big trends of electrification and automation in vehicles, are projected to increase the use of worldwide automotive sensors from 7.5 billion units in 2017 to 11.0 billion units by the year 2024. A representative state-of-the art automotive sensor system, (i.e., an ultrasonic backup system), including the ECUs controlling the vehicle electrical systems/subsystems, has been considered to estimate the energy footprint in terms of manufacturing and operational energy of global automotive sensors use. A widely used life cycle energy assessment method (i.e., cumulative energy demand) was used as both direct and indirect (including the extraction, manufacturing, and disposal of the raw and auxiliary materials) energy use can be considered for the energy footprint estimation. The embodied manufacturing energy impacts of the system was estimated to be 559 MJ/system, compared to the 417 MJ/system for lifetime system power and additional gasoline use. The share of purchased energy to the embodied energy where the upstream energy isn't included in the former case, is less than 10% and ~ 85% for the component manufacturing and vehicle operation energy uses, respectively. As the purpose of this ultrasonic backup system is to prevent rear crashes, an estimated 1.0 MJ/system is avoided from reduced lifetime vehicular repairs (from an estimated 11% chance of requiring a rear bumper replacement). While all of this is small compared to the overall automotive manufacturing and use energy, the 11 billion automotive sensors expected to be produced in 2024 could require 1540 PJ for manufacturing and those sensors would require an additional 780–1150 PJ for lifetime energy use.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Revealing aggregation of non-fullerene acceptors in intermixed phase by ultraviolet-visible absorption spectroscopy

Non-fullerene acceptor (NFA) aggregation is crucial in determining bulk-heterojunction (BHJ) organic photovoltaic (OPV) performance. However, it is still a big challenge to characterize the nanostructure of NFAs in the disordered donor-acceptor intermixed phase. Here, we demonstrate a method to characterize NFA aggregation and composition in the intermixed phase by measuring NFA concentration-dependent ultraviolet-visible (UV-vis) absorption spectroscopy of BHJ films. In various polymer:NFA films, an absorption shift as a function of increasing molecular concentration (ASIMC) phenomenon is observed, and different NFA aggregation behaviors can be distinguished. The ASIMC method was then applied to study the influence of processing conditions on the NFA concentration in the intermixed phase of devices to establish a correlation with device efficiency. The current work provides a feasible tool to study the nanostructure of NFAs in the complex polymer matrix and to understand the variations in the NFA concentration in the intermixed phase under non-equilibrium conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Engineered extracellular vesicle mimetics from macrophage promotes hair growth in mice and promotes human hair follicle growth

Recent studies clearly show that cell-derived extracellular vesicles (EVs, including exosomes) can promote hair growth. However, large-scale production of EVs remains a big hurdle. Recently, extracellular vesicle mimetics (EMs) engineered by extrusion through various membranes are emerging as a complementary approach for large-scale production. In this study, to investigate their ability to induce hair growth, we generated macrophage-engineered EMs (MAC-EMs) that activated the human dermal papilla (DP) cells in vitro. MAC-EMs intradermally injected into the skin of C57BL/6 mice were retained for up to 72 h. Microscopy imaging revealed that MAC-EMs were predominately internalized into hair follicles. The MAC-EMs treatment induced hair regrowth in mice and hair shaft elongation in a human hair follicle, suggesting the potential of MAC-EMs as an alternative to EVs to overcome clinical limitation.

60 APPLIED LIFE SCIENCES↗

The radioactive nuclei 26 Al and 60 Fe in the Cosmos and in the solar system

The cosmic evolution of the chemical elements from the Big Bang to the present time is driven by nuclear fusion reactions inside stars and stellar explosions. A cycle of matter recurrently re-processes metal-enriched stellar ejecta into the next generation of stars. The study of cosmic nucleosynthesis and this matter cycle requires the understanding of the physics of nuclear reactions, of the conditions at which the nuclear reactions are activated inside the stars and stellar explosions, of the stellar ejection mechanisms through winds and explosions, and of the transport of the ejecta towards the next cycle, from hot plasma to cold, star-forming gas. Due to the long timescales of stellar evolution, and because of the infrequent occurrence of stellar explosions, observational studies are challenging, as they have biases in time and space as well as different sensitivities related to the various astronomical methods. Here, we describe in detail the astrophysical and nuclear-physical processes involved in creating two radioactive isotopes useful in such studies, 26 Al and 60 Fe. Due to their radioactive lifetime of the order of a million years, these isotopes are suitable to characterise simultaneously the processes of nuclear fusion reactions and of interstellar transport. We describe and discuss the nuclear reactions involved in the production and destruction of 26 Al and 60 Fe, the key characteristics of the stellar sites of their nucleosynthesis and their interstellar journey after ejection from the nucleosynthesis sites. This allows us to connect the theoretical astrophysical aspects to the variety of astronomical messengers presented here, from stardust and cosmic-ray composition measurements, through observation of γ rays produced by radioactivity, to material deposited in deep-sea ocean crusts and to the inferred composition of the first solids that have formed in the Solar System. We show that considering measurements of the isotopic ratio of 26 Al to 60 Fe eliminate some of the unknowns when interpreting astronomical results, and discuss the lessons learned from these two isotopes on cosmic chemical evolution. This review paper has emerged from an ISSI-BJ Team project in 2017–2019, bringing together nuclear physicists, astronomers, and astrophysicists in this inter-disciplinary discussion.

79 ASTRONOMY AND ASTROPHYSICS↗