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At least 811 records · Page 45

The electronic structure and second-order nonlinear optical properties of donor-acceptor acetylenes - A detailed investigation of structure-property relationships

A series of donor-acceptor acetylene compounds was synthesized in which systematic changes in both the conjugation length and the donor-acceptor strength were made. The effect of these structural changes on the spectroscopic and electronic properties of the molecules and, ultimately, on the measured second-order molecular hyperpolarizabilities (beta) was investigated. It was found that increases in the donor-acceptor strength resulted in increases in the magnitude of beta. For this class of molecules, the increase is dominated by the energy of the intramolecular charge-transfer transition, while factors such as the ground to excited-state dipole moment change and the transition-moment integral are much less important. Increasing the conjugation length from one to two acetylene linkers did not result in an increase in the value of beta; however, beta increased sharply in going from two acetylenes to three. This increase is attributed to the superposition of several nearly isoenergetic excited states.

Stiegman, A. E.↗

Second harmonic conversion in cubic silicon carbide at 1.06 micron

This letter describes second harmonic conversion in cubic silicon carbide (beta-SiC) at a wavelength of 1.06 micron. Epitaxial layers of beta-SiC formed by vapor phase growth on silicon are indeed birefringent, and thus phase matchable. Phase-matched films of beta-SiC have respectable conversion efficiencies even in the presence of adsorption at 532 nm. The measured value of the effective second order nonlinear susceptibility for beta-SiC is chi super (2) eff = 1.05 +/- 0.3 x 10 exp -9 esu.

Harris, G. L.↗

Electronic considerations for externally segmented germanium detectors

The dominant background source for germanium gamma ray detector spectrometers used for some astrophysics observations is internal beta decay. Externally segmented germanium gamma ray coaxial detectors can identify beta decay by localizing the event. Energetic gamma rays interact in the germanium detector by multiple Compton interactions while beta decay is a local process. In order to recognize the difference between gamma rays and beta decay events, the external electrode (outside of detector) is electrically partitioned. The instrumentation of these external segments and the consequence with respect to the spectrometer energy signal is examined.

Madden, N. W.↗

Occultation of a compact radio source by Venus

The position of Venus in the radio reference frame was measured on the basis of an observation of an occultation of the compact radio source P0507 + 17 by Venus on July 19, 1988. By comparing model light curves to the observed light curves for both ingress and egress, the frame-tie offsets Delta(lambda) and Delta(beta) (ecliptic longitude and latitude) were determined. The solution for both Delta(lambda) and Delta(beta) gave results consistent with zero offsets, but with an error of about 0.2 arcsec. The egress light curve alone yielded higher accuracy for a linear combination of Delta(lambda) and Delta(beta): Delta(lambda) + 0.51 Delta(beta) = 0.026 +/-0.04 arcsec.

Linfield, R. P.↗

Solving modal equations of motion with initial conditions using MSC/NASTRAN DMAP. Part 1: Implementing exact mode superposition

Within the MSC/NASTRAN DMAP (Direct Matrix Abstraction Program) module TRD1, solving physical (coupled) or modal (uncoupled) transient equations of motion is performed using the Newmark-Beta or mode superposition algorithms, respectively. For equations of motion with initial conditions, only the Newmark-Beta integration routine has been available in MSC/NASTRAN solution sequences for solving physical systems and in custom DMAP sequences or alters for solving modal systems. In some cases, one difficulty with using the Newmark-Beta method is that the process of selecting suitable integration time steps for obtaining acceptable results is lengthy. In addition, when very small step sizes are required, a large amount of time can be spent integrating the equations of motion. For certain aerospace applications, a significant time savings can be realized when the equations of motion are solved using an exact integration routine instead of the Newmark-Beta numerical algorithm. In order to solve modal equations of motion with initial conditions and take advantage of efficiencies gained when using uncoupled solution algorithms (like that within TRD1), an exact mode superposition method using MSC/NASTRAN DMAP has been developed and successfully implemented as an enhancement to an existing coupled loads methodology at the NASA Lewis Research Center.

Abdallah, Ayman A.↗

Hot corrosion of the B2 nickel aluminides

The hot corrosion behavior of the B2 nickel aluminides was studied to determine the inherent hot corrosion resistance of the beta nickel aluminides and to develop a mechanism for the hot corrosion of the beta nickel aluminides. The effects of the prior processing of the material, small additions of zirconium, stoichiometry of the materials, and preoxidation of the samples were also examined. Additions of 2, 5, and 15 w/o chromium were used to determine the effect of chromium on the hot corrosion of the beta nickel aluminides and the minimum amount of chromium necessary for good hot corrosion resistance. The results indicate that the beta nickel aluminides have inferior inherent hot corrosion resistance despite their excellent oxidation resistance. Prior processing and zirconium additions had no discernible effect on the hot corrosion resistance of the alloys. Preoxidation extended the incubation period of the alloys only a few hours and was not considered to be an effective means of stopping hot corrosion. Stoichiometry was a major factor in determining the hot corrosion resistance of the alloys with the higher aluminum alloys having a definitely superior hot corrosion resistance. The addition of chromium to the alloys stopped the hot corrosion attack in the alloys tested. From a variety of experimental results, a complex hot corrosion mechanism was proposed. During the early stages of the hot corrosion of these alloys the corrosion is dominated by a local sulphidation/oxidation form of attack. During the intermediate stages of the hot corrosion, the aluminum depletion at the surface leads to a change in the oxidation mechanism from a protective external alumina layer to a mixed nickel-aluminum spinel and nickel oxide that can occur both externally and internally. The material undergoes extensive cracking during the later portions of the hot corrosion.

Ellis, David L.↗

Extinction and scattering in the Orion Nebula - Comparison of optical and VLA 21 centimeter studies

We have compared VLA 21 cm continuum maps of M42 with extinction-corrected H-beta images and found that much of M42 has an excess of H-beta surface brightness. This is interpreted as reflection by particles lying close to the principal ionization front. Comparison of column densities of H I near M42 and extinction (C(H-beta)) indicates an excellent area-by-area correlation, establishing that most of the extinction in M42 arises in the neutral lid that lies on the near side of the nebula. A more quantitative comparison of (C(H-beta)) and N(H I), the column density, is consistent with this conclusion and indicates a dust scattering cross section per hydrogen atom that is similar to the value for the general interstellar medium. The usual model for extinction in the Trapezium region is that it occurs very near the stars and produces an anomalous reddening curve through modification of the nature or size distribution of the particles. These new results question the basic assumptions and conclusions of that model.

O'Dell, C. R.↗

Drift Kelvin-Helmholtz instabilities in space plasmas

Drift Kelvin-Helmholtz instabilities of a finite-beta plasma in equilibrium electric and magnetic fields which are perpendicular to each other are studied using two fluid equations. Three types of these instabilities are considered including the magnetosonic instability of a finite beta-homogeneous plasma, the electrostatic drift instability of an inhomogeneous low-beta plasma, and the magneto-acoustic instability of a high-beta inhomogeneous isothermal plasma. It is shown that the electric field has either stabilizing or destabilizing effect depending on conditions under consideration.

Sharma, Avadhesh C.↗

Flat sheet metal girders with very thin metal web. Part II : sheet metal girders with spars resistant to bending - oblique uprights - stiffness

Noting that the stiffness of the girder increases very rapidly as Beta increases, the result can be summed up as follows: When the cross stress preponderates in one direction and when the web plate is to be given the dimensions commensurate to its stresses, it is advisable (regardless of any ensuing structural difficulties) to set the uprights at about Beta = 120 degrees, thereby lowering the weight of the plate wall 15 percent (in contrast to Beta = 90 degrees), and raising the stiffness 55 percent. But, when the cross stresses alternate and are approximately of the same intensity in both directions, or, if the web plate thickness is determined by other structural reasons, then Beta = 90 degrees should be chosen.

Wagner, Herbert↗

Parametric instabilities of a large-amplitude circularly polarized Alfven wave - Linear growth in two-dimensional geometries

The growth of parametric instabilities, which may lead to the development of a turbulent cascade, is studied using an MHD code that permits nonlinear couplings in the parallel direction to the ambient magnetic field and one perpendicular direction. Compressibility is included in the form of a polytropic equation of state. Parametric instabilities associated with a parallel-propagating decay instability are found to dominate the low-beta case. An obliquely propagating filamentationlike instability dominates the high-beta case. The nonlinear growth of the nth harmonic of a daughter wave growing as a factor of n times the fundamental's growth rate is found in both cases. Nonlinear saturation is caused by the parallel decay instability in the low-beta case and by the oblique filamentationlike instability in the high-beta case.

Ghosh, S.↗

IRAS sky survey atlas: Explanatory supplement

This Explanatory Supplement accompanies the IRAS Sky Survey Atlas (ISSA) and the ISSA Reject Set. The first ISSA release in 1991 covers completely the high ecliptic latitude sky, absolute value of beta is greater than 50 deg, with some coverage down to the absolute value of beta approx. equal to 40 deg. The second ISSA release in 1992 covers ecliptic latitudes of 50 deg greater than the absolute value of beta greater than 20 deg, with some coverage down to the absolute value of beta approx. equal to 13 deg. The remaining fields covering latitudes within 20 deg of the ecliptic plane are of reduced quality compared to the rest of the ISSA fields and therefore are released as a separate IPAC product, the ISSA Reject Set. The reduced quality is due to contamination by zodiacal emission residuals. Special care should be taken when using the ISSA Reject images. In addition to information on the ISSA images, some information is provided in this Explanatory Supplement on the IRAS Zodiacal History File (ZOHF), Version 3.0, which was described in the December 1988 release memo. The data described in this Supplement are available at the National Space Science Data Center (NSSDC) at the Goddard Space Flight Center. The interested reader is referred to the NSSDC for access to the IRAS Sky Survey Atlas (ISSA).

Wheelock, S. L.↗

Implementation of a Single-Stage-To-Orbit (SSTO) model for stability and control analysis

Three NASA centers: Marshall Space Flight Center (MSFC), Langley Research Center (LaRC), and Johnson Space Center (JSC) are currently involved in studying a family of single-stage- and two-stage-to-orbit (SSTO/TSTO) vehicles to serve as the next generation space transportation system (STS). A rocketed winged-body is the current focus. The configuration (WB001) is a vertically-launched, horizontally-landing system with circular cross-section. Preliminary aerodynamic data was generated by LaRC and is a combination of wind-tunnel data, empirical methods, and Aerodynamic Preliminary Analysis System-(APAS) generated values. JSC's efforts involve descent trajectory design, stability analysis, and flight control system synthesis. Analysis of WB001's static stability indicates instability in 'tuck' (C(sub mu) less than 0: Mach = 0.30, alpha greater than 3.25 deg; Mach = 0.60, alpha greater than 8.04), an unstable dihedral effects (C(sub l(beta)) greater than 0: Mach = 30,alpha less than 12 deg.; Mach = 0.60, alpha less than 10.00 deg.), and, most significantly, an unstable weathercock stability derivative, C(sub n(beta)), at all angles of attack and subsonic Mach numbers. Longitudinal trim solutions for Mach = 0.30 and 0.60 indicate flight path angle possibilities ranging from around 12 (M = 0.30) to slightly over 20 degrees at Mach = 0.60. Trim angles of attack increase from 6.24 at Mach 0.60 and 10,000 feet to 17.7 deg. at Mach 0.30, sea-level. Lateral trim was attempted for a design cross-wind of 25.0 knots. The current vehicle aerodynamic and geometric characteristics will only yield a lateral trim solution at impractical tip-fin deflections (approximately equal to 43 deg.) and bank angles (21 deg.). A study of the lateral control surfaces, tip-fin controllers for WB001, indicate increased surface area would help address these instabilities, particularly the deficiency in C(sub n(beta)), but obviously at the expense of increased vehicle weight. Growth factors of approximately 7 were determined using a design C(sub n(beta)) of 0.100/radian (approximate subsonic values for the orbiter).

Ingalls, Stephen A.↗

Parameter degeneracy in models of the quadruple lens system Q2237+0305

The geometry of the quadruple lens system Q2237+0305 is modeled with a simple astigmatic lens: a power-law mass distribution: m approximately r(exp beta) with an external shear gamma. The image positions can be reproduced with an accuracy better than 0.01 arcsec for any 0.0 less than or = beta less than or = 1.85 and the corresponding value of gamma = 0.1385-0.0689 beta. This is a factor of approximately 4 more precise than what can be achieved by the best constant stellar mass/L lens models. The image intensity ratios and the time delay ratios are almost constant along our one parameter family of models, but the total magnification varies from 8 to greater than 1000, and the maximum time delay (between leading image B and trailing image C) for H(sub 0) of 75 km/s (Mpc) varies from more than 20 h to about 1.5 h, while beta increases from 0.0 to 1.85.

Wambsganss, Joachim↗

Testing the gravitational instability hypothesis?

We challenge a widely accepted assumption of observational cosmology: that successful reconstruction of observed galaxy density fields from measured galaxy velocity fields (or vice versa), using the methods of gravitational instability theory, implies that the observed large-scale structures and large-scale flows were produced by the action of gravity. This assumption is false, in that there exist nongravitational theories that pass the reconstruction tests and gravitational theories with certain forms of biased galaxy formation that fail them. Gravitational instability theory predicts specific correlations between large-scale velocity and mass density fields, but the same correlations arise in any model where (a) structures in the galaxy distribution grow from homogeneous initial conditions in a way that satisfies the continuity equation, and (b) the present-day velocity field is irrotational and proportional to the time-averaged velocity field. We demonstrate these assertions using analytical arguments and N-body simulations. If large-scale structure is formed by gravitational instability, then the ratio of the galaxy density contrast to the divergence of the velocity field yields an estimate of the density parameter Omega (or, more generally, an estimate of beta identically equal to Omega(exp 0.6)/b, where b is an assumed constant of proportionality between galaxy and mass density fluctuations. In nongravitational scenarios, the values of Omega or beta estimated in this way may fail to represent the true cosmological values. However, even if nongravitational forces initiate and shape the growth of structure, gravitationally induced accelerations can dominate the velocity field at late times, long after the action of any nongravitational impulses. The estimated beta approaches the true value in such cases, and in our numerical simulations the estimated beta values are reasonably accurate for both gravitational and nongravitational models. Reconstruction tests that show correlations between galaxy density and velocity fields can rule out some physically interesting models of large-scale structure. In particular, successful reconstructions constrain the nature of any bias between the galaxy and mass distributions, since processes that modulate the efficiency of galaxy formation on large scales in a way that violates the continuity equation also produce a mismatch between the observed galaxy density and the density inferred from the peculiar velocity field. We obtain successful reconstructions for a gravitational model with peaks biasing, but we also show examples of gravitational and nongravitational models that fail reconstruction tests because of more complicated modulations of galaxy formation.

Babul, Arif↗

The broad emission line and continuum variations of Seyfert galaxies. 2: Broad-line region structure and kinematics

Spectroscopic observations of 13 Seyfert 1 galaxies made from 1979 to 1984 at Palomar and Steward Observatories were analyzed for H beta line profile variations. Significant profile changes were detected in five galaxies. These variations are often associated with changes in continuum and/or H beta strength, suggesting a causal connection between variations in the continuum source and changes in emission-line profiles. Moreover, the overall strength of H beta line flux variations is strongly correlated with line width in the far wings, whereas no such correlation was found in the line core. This finding is consistent with previous observations (Shuder 1982) which suggest that higher velocity gas lies closer to the central continuum source, since this inner gas would be expected to track variations more closely. In each of the five galaxies in which H beta line profile variations were detected, particularly NGC 5548 and Mrk 6, only two distinct line profile shapes were observed. Since intermediate profile types were not detected, the transition from one type to the other must occur rapidly (within a few months). These rapid line profile variations are thus consistent with numerous other studies which strongly point to a small broad-line region (BLR) size in Seyfert galaxies. Observational models of BLR kinematics and structure for each of the galaxies in the present sample are presented. Line asymmetries suggest that radial motions exist in the BLRs of most of these objects. Chaotic motions also appear to be quite common. However, evidence for rotational motion was observed in only one case. A model that is consistent with the majority of this sample incorporates both radial and chaotic motions combined with some form of external obscuration such as an optically and geometrically thick torus.

Rosenblatt, Edward I.↗

Steps toward determination of the size and structure of the broad-line region in active galactic nuclei. 6: Variability of NGC 3783 from ground-based data

The Seyfert 1 galaxy NGC 3783 was intensely monitored in several bands between 1991 December and 1992 August. This paper presents the results from the ground-based observations in the optical and near-IR bands, which complement the data set formed by the International Ultraviolet Explorer (IUE) spectra, discussed elsewhere. Spectroscopic and photometric data from several observatories were combined in order to obtain well-sampled light curves of the continuum and of H(beta). During the campaign the source underwent significant variability. The light curves of the optical continuum and of H(beta) display strong similarities to those obtained with the IUE. The near-IR flux did not vary significantly except for a slight increase at the end of the campaign. The cross-correlation analysis shows that the variations of the optical continuum have a lag of 1 day or less with respect to those of the UV continuum, with an uncertainty of is less than or equal to 4 days. The integrated flux of H(beta) varies with a delay of about 8 days. These results confirm that (1) the continuum variations occur simultaneously or with a very small lag across the entire UV-optical range, as in the Seyfert galaxy NGC 5548; and (2) the emission lines of NGC 3783 respond to ionizing continuum variations with less delay than those of NGC 5548. As observed in NGC 5548, the lag of H(beta) with respect to the continuum is greater than those of the high-ionization lines.

Stirpe, G. M.↗

Search for important weak interaction nuclei in presupernova evolution

A search is made for the most important electron captures and beta-decays after core silicon burning in massive stars. A nuclear statistical equilibrium code is used to compute isotopic abundances. Electron capture and beta-decay rates are estimated for the 150 most abundant isotopes in a simplified fashion which generally includes the strongest transitions. These estimates are made for nuclei in the fp-shell and use techniques similar to Fuller, Fowler, & Newman (1982a), and are compared to them. The general behavior of the rate of change of Y(sub e) is examined. These methods are then used to follow a typical stellar trajectory, seeking the most important weak interactions during the formation of the iron core. Ranked lists of nuclei are given, to prioritize more detailed studies on individual nuclei. Beta-decays are found to ben an important modification to the evolution below the rate of change of Y(sub e) approx. = 0.46 as the core approaches a state of dynamic equilibrium between electron captures and beta-decays.

Aufderheide, Maurice B.↗

The Sun as a probe of varying G

In order to explore the ability of helioseismology and features of solar models to test the constancy of the gravitational constant G during the last 4.5 Gyr of solar evolution, we have constructed a grid of evolutionary sequences for solar models under the assumptions that G varies with time, and have explored the sensitivity of their nonradial acoustic mode oscillation spectra to G variability. All final models satisfy the standard constraints for the present Sun and, except for the variation in G, were constructed under the assumptions of a standard solar model. When compared with the observed solar p-mode spectrum, our models definitely rule out beta greater than 0.4 and beta less than -0.4, where G(t) proportional to t(exp -beta) over the last 4.5 Gyr. These limits can be tightened to rule out absolute value of beta greater than 0 (0.1) by the use of other solar observables. For nonmonotonic variation in G this suggests that long-timescale variations greater than 0 (5%) in G are ruled out over the last 4.5 Gyr. Future prospects for improving the sensitivity of helioseismic tests of a varying G are also discussed. Finally, we explore the sensitivity of the predicted solar neutrino flux to varying G.

Demarque, P.↗