Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Using”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 811 records · Page 45
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Evaluation of fuel-borne sodium effects on a DOC-DPF-SCR heavy-duty engine emission control system: Simulation of full-useful life

Here we report that for renewable fuels to displace petroleum, they must be compatible with emissions control devices. Pure biodiesel contains up to 5 ppm Na + K and 5 ppm Ca + Mg metals, which have the potential to degrade diesel emissions control systems. This study aims to address these concerns, identify deactivation mechanisms, and determine if a lower limit is needed. Accelerated aging of a production exhaust system was conducted on an engine test stand over 1001 h using 20% biodiesel blended into ultra-low sulfur diesel (B20) doped with 14 ppm Na. This Na level is equivalent to exposure to Na at the uppermost expected B100 value in a B20 blend for the system full-useful life. During the study, NOx emissions exceeded the engine certification limit of 0.33 g/bhp-hr before the 435,000-mile requirement. Replacing aged diesel oxidation catalyst (DOC), diesel particulate filter (DPF), and selective catalytic reduction (SCR) devices with new degreened parts showed that each device contributed equally to the NOx increase. Following this systems-based evaluation, a detailed investigation of the individual components was completed. Na was determined to have minimal impact on DOC activity. For this system, it is estimated that B20-Na resulted in 50% more ash into the DPF. However, the Na did not diffuse into the cordierite DPF nor degrade its mechanical properties. The SCR degradation was found to be caused by a small amount of precious group metals (PGM) contamination that increased NH3 oxidation, and lowered NOx reduction. Therefore, we determined that the primary effect of Na in this study is through increased ash in the DPF rather than deactivation of the catalytic activity.

42 ENGINEERING↗
DOE OSTI2011

Assessing regional scale predictions of aerosols, marine stratocumulus, and their interactions during VOCALS-REx using WRF-Chem

This study assesses the ability of the recent chemistry version (v3.3) of the Weather Research and Forecasting (WRF-Chem) model to simulate boundary layer structure, aerosols, stratocumulus clouds, and energy fluxes over the Southeast Pacific Ocean. Measurements from the VAMOS Ocean-Cloud-Atmosphere-Land Study Regional Experiment (VOCALS-REx) and satellite retrievals (i.e., products from the MODerate resolution Imaging Spectroradiometer (MODIS), Clouds and Earth's Radiant Energy System (CERES), and GOES-10) are used for this assessment. The Morrison double-moment microphysics scheme is newly coupled with interactive aerosols in the model. The 31-day (15 October-16 November 2008) WRF-Chem simulation with aerosol-cloud interactions (AERO hereafter) is also compared to a simulation (MET hereafter) with fixed cloud droplet number concentrations in the microphysics scheme and simplified cloud and aerosol treatments in the radiation scheme. The well-simulated aerosol quantities (aerosol number, mass composition and optical properties), and the inclusion of full aerosol-cloud couplings lead to significant improvements in many features of the simulated stratocumulus clouds: cloud optical properties and microphysical properties such as cloud top effective radius, cloud water path, and cloud optical thickness. In addition to accounting for the aerosol direct and semi-direct effects, these improvements feed back to the simulation of boundary-layer characteristics and energy budgets. Particularly, inclusion of interactive aerosols in AERO strengthens the temperature and humidity gradients within the capping inversion layer and lowers the marine boundary layer (MBL) depth by 130 m from that of the MET simulation. These differences are associated with weaker entrainment and stronger mean subsidence at the top of the MBL in AERO. Mean top-of-atmosphere outgoing shortwave fluxes, surface latent heat, and surface downwelling longwave fluxes are in better agreement with observations in AERO, compared to the MET simulation. Nevertheless, biases in some of the simulated meteorological quantities (e.g., MBL temperature and humidity) and aerosol quantities (e.g., underestimations of accumulation mode aerosol number) might affect simulated stratocumulus and energy fluxes over the Southeastern Pacific, and require further investigation. The well-simulated timing and outflow patterns of polluted and clean episodes demonstrate the model's ability to capture daily/synoptic scale variations of aerosol and cloud properties, and suggest that the model is suitable for studying atmospheric processes associated with pollution outflow over the ocean. The overall performance of the regional model in simulating mesoscale clouds and boundary layer properties is encouraging and suggests that reproducing gradients of aerosol and cloud droplet concentrations and coupling cloud-aerosol-radiation processes are important when simulating marine stratocumulus over the Southeast Pacific.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Evaluating the feasibility of using downwind methods to quantify point source oil and gas emissions using continuously monitoring fence-line sensors

The dependable reporting of methane (CH 4 ) emissions from point sources, such as fugitive leaks from oil and gas infrastructure, is important for profit maximization (retaining more hydrocarbons), evaluating climate impacts, assessing CH 4 fees for regulatory programs, and validating CH 4 intensity in differentiated gas programs. Currently, there are disagreements between emissions reported by different quantification techniques for the same sources. It has been suggested that downwind CH 4 quantification methods using CH 4 measurements on the fence line of production facilities could be used to generate emission estimates from oil and gas operations at the site level, but it is currently unclear how accurate the quantified emissions are. To investigate the accuracy of downwind methods, this study uses fence-line simulated data collected during controlled-release experiments as input for a non-standard closed-path eddy covariance (EC), the Gaussian plume inverse model (GPIM), and the backward Lagrangian stochastic (bLs) model in a range of atmospheric conditions. This study's EC attempt was unsuccessful due to data collection and instrumentation issues, resulting in invalid results characterized by underestimated emissions, large negative fluxes, and cospectra/ogives that deviated from their ideal shapes. Consequently, the EC results could not be compared with the GPIM and bLS model. The bLs model demonstrated the highest accuracy for single-release single-point emissions, though it exhibited greater uncertainty than GPIM under multi-release conditions. Across the GPIM and bLs model, the most reliable quantification was achieved with 15 min averaging and a narrow 5° wind sector range. Although EC was limited in this context, future studies should consider employing a standard EC system and further optimizing GPIM and bLs approaches – particularly for complex multi-source scenarios – to enhance quantification accuracy and reduce uncertainty.

03 NATURAL GAS↗
DOE OSTI2016

Investigating the impact of land-use land-cover change on Indian summer monsoon daily rainfall and temperature during 1951–2005 using a regional climate model

Daily moderate rainfall events, which constitute a major portion of seasonal summer monsoon rainfall over central India, have decreased significantly during the period 1951 through 2005. On the other hand, mean and extreme near-surface daily temperature during the monsoon season have increased by a maximum of 1–1.5 °C. Using simulations made with a high-resolution regional climate model (RegCM4) and prescribed land cover of years 1950 and 2005, it is demonstrated that part of the changes in moderate rainfall events and temperature have been caused by land-use/land-cover change (LULCC), which is mostly anthropogenic. Model simulations show that the increase in seasonal mean and extreme temperature over central India coincides with the region of decrease in forest and increase in crop cover. Our results also show that LULCC alone causes warming in the extremes of daily mean and maximum temperatures by a maximum of 1–1.2 °C, which is comparable with the observed increasing trend in the extremes. Decrease in forest cover and simultaneous increase in crops not only reduces the evapotranspiration over land and large-scale convective instability, but also contributes toward decrease in moisture convergence through reduced surface roughness. These factors act together in reducing significantly the moderate rainfall events and the amount of rainfall in that category over central India. Additionally, the model simulations are repeated by removing the warming trend in sea surface temperatures over the Indian Ocean. As a result, enhanced warming at the surface and greater decrease in moderate rainfall events over central India compared to the earlier set of simulations are noticed. Results from these additional experiments corroborate our initial findings and confirm the contribution of LULCC in the decrease in moderate rainfall events and increase in daily mean and extreme temperature over India. Therefore, this study demonstrates the important implications of LULCC over India during the monsoon season. Although, the regional climate model helps in better resolving land–atmosphere feedbacks over the Indian region, the inferences do depend on the fidelity of the model in capturing the features of Indian monsoon realistically. Lastly, it is proposed that similar studies using a suite of climate models will further enrich our understanding about the role of LULCC in the Indian monsoon climate.

58 GEOSCIENCES↗
DOE OSTI2011

Kinetics of Separations of Volatile Fluorides from Used Fuel Using NF3

The study of the fluorination of UO2 with various fluorinating agents using thermogravimetric analysis (TGA) is well documented. Additional research has examined the fluorination of other metals and metal oxides. Seeing the possible benefit of using analogous fluorination technologies to affect separations in used nuclear fuel, we have expanded the existing research to an investigation of the reaction of NF3 with UO2 and NpO2. The conversion fractions gathered from experimental results have been compared with those predicted by existing models for various rate-limiting phenomena.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2015

Discomfort glare with complex fenestration systems and the impact on energy use when using daylighting control

Glare is a frequent issue in highly glazed buildings. A modelling approach is presented that uses discomfort glare probability and discomfort glare index as metrics to determine occupants’ behaviour. A glare control algorithm that actuated an interior shade for glare protection based on the predicted perception was implemented in a building simulation program. A reference case with a state-of-the-art base glazing was compared to the same glazing but with five different complex fenestration systems, i.e., exterior shades. The windows with exterior shades showed significant variations in glare frequencies. Energy use intensity in a prototypical office building with daylighting controls was greatly influenced for the systems with frequent glare occurrence. While the base glazing could benefit from glare control, some of the exterior shades showed significantly greater energy use when discomfort glare-based operation of interior shades was considered.

Hoffmann, Sabine↗
DOE OSTI2015

USING TIME VARIANT VOLTAGE TO CALCULATE ENERGY CONSUMPTION AND POWER USE OF BUILDING SYSTEMS

Buildings are the main consumers of electricity across the world. However, in the research and studies related to building performance assessment, the focus has been on evaluating the energy efficiency of buildings whereas the instantaneous power efficiency has been overlooked as an important aspect of total energy consumption. As a result, we never developed adequate models that capture both thermal and electrical characteristics (e.g., voltage) of building systems to assess the impact of variations in the power system and emerging technologies of the smart grid on buildings energy and power performance and vice versa. This paper argues that the power performance of buildings as a function of electrical parameters should be evaluated in addition to systems’ mechanical and thermal behavior. The main advantage of capturing electrical behavior of building load is to better understand instantaneous power consumption and more importantly to control it. Voltage is one of the electrical parameters that can be used to describe load. Hence, voltage dependent power models are constructed in this work and they are coupled with existing thermal energy models. Lack of models that describe electrical behavior of systems also adds to the uncertainty of energy consumption calculations carried out in building energy simulation tools such as EnergyPlus, a common building energy modeling and simulation tool. To integrate voltage-dependent power models with thermal models, the thermal cycle (operation mode) of each system was fed into the voltage-based electrical model. Energy consumption of systems used in this study were simulated using EnergyPlus. Simulated results were then compared with estimated and measured power data. The mean square error (MSE) between simulated, estimated, and measured values were calculated. Results indicate that estimated power has lower MSE when compared with measured data than simulated results. Results discussed in this paper will illustrate the significance of enhancing building energy models with electrical characteristics. This would support different studies such as those related to modernization of the power system that require micro scale building-grid interaction, evaluating building energy efficiency with power efficiency considerations, and also design and control decisions that rely on accuracy of building energy simulation results.

Makhmalbaf, Atefe↗
DOE OSTI2018

Classification of multispectral or hyperspectral satellite imagery using clustering of sparse approximations on sparse representations in learned dictionaries obtained using efficient convolutional sparse coding

An approach for land cover classification, seasonal and yearly change detection and monitoring, and identification of changes in man-made features may use a clustering of sparse approximations (CoSA) on sparse representations in learned dictionaries. The learned dictionaries may be derived using efficient convolutional sparse coding to build multispectral or hyperspectral, multiresolution dictionaries that are adapted to regional satellite image data. Sparse image representations of images over the learned dictionaries may be used to perform unsupervised k-means clustering into land cover categories. The clustering process behaves as a classifier in detecting real variability. This approach may combine spectral and spatial textural characteristics to detect geologic, vegetative, hydrologic, and man-made features, as well as changes in these features over time.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Additive manufacturing methods using aluminum-rare earth alloys and products made using such methods

Described herein are additive manufacturing methods and products made using such methods. The alloy compositions described herein are specifically selected for the additive manufacturing methods and provide products that exhibit superior mechanical properties as compared to their cast counterparts. Using the compositions and methods described herein, products that do not exhibit substantial coarsening, such as at elevated temperatures, can be obtained. The products further exhibit uniform microstructures along the print axis, thus contributing to improved strength and performance. Additives also can be used in the alloys described herein.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Additive manufacturing methods using aluminum-rare earth alloys and products made using such methods

Described herein are additive manufacturing methods and products made using such methods. The alloy compositions described herein are specifically selected for the additive manufacturing methods and provide products that exhibit superior mechanical properties as compared to their cast counterparts. Using the compositions and methods described herein, products that do not exhibit substantial coarsening, such as at elevated temperatures, can be obtained. The products further exhibit uniform microstructures along the print axis, thus contributing to improved strength and performance. Additives also can be used in the alloys described herein.

Plotkowski, Alex J.↗
DOE OSTI2023

Feasibility Analysis for the Use of Retrofitted Air-Conditioners Using Thermal Energy Storage (TES) for High Ambient Temperature (HAT) Countries

In high ambient temperature (HAT) countries, summer temperatures exceed 35℃, degrading the performance of air-conditioning systems and straining power grids. In this paper, a feasibility analysis was conducted to investigate potential savings during the peak using latent Thermal Energy Storage (TES) at near room phase-change temperatures, replacing condensers, thus, minimizing temperature lifts. Weather data, building loads, and baseline air-conditioning systems data were gathered for Dubai. A transient vapor-compression model in Modelica was used to compare the COP, total power input and cooling capacity of the air-conditioner at peak hours when ambient temperatures range between 35 – 45 ⁰C versus the TES-Phase-Change Material (PCM) melting temperatures from 22 – 28⁰C. The results indicate that the TES-PCM can enhance the system COP at the peak by a factor 1.4 and 2 for during for outdoor temperatures of 35 – 40⁰C, and 40 – 45⁰C, respectively. Lower melting temperature PCMs were able to reduce the required power input by 30-50%, with more savings occurring at higher temperature days. On the other hand, higher temperature PCMs enhancements were minimal especially at outdoor ambient temperatures ranging between 35 – 40⁰C. Improvements to the cooling capacity range from 8 – 18 % for the outdoor temperature range of 35 – 45 ⁰C. An economic analysis was conducted to find the potential saving in utility costs for 30%, 60%, and 90% of the space cooling demands of Dubai, and find the trade-off points between utility savings and cost of PCM-TES implementation. If the peak loads are to be shifted by 6 hours daily, the percentage utility savings for the city is 18%. Using estimated costs of the PCM-TES, ranging from $200-500/kWh, the daily load shifting hours were estimated to range from 4 hours at the lowest cost systems to 2.5 hours at the highest costs.

25 ENERGY STORAGE↗
DOE OSTI2019

Using the American Time-Use Survey for Travel-Behavior Research

This presentation, by Venu Garikapati of the National Renewable Energy Laboratory, provides information about the American Time Use Survey (ATUS), which was conducted by the U.S. Bureau of Labor Statistics and the U.S. Census Bureau. The presentation will also cover examples on utilizing time use data for understanding travel patterns.

25 ENERGY STORAGE↗
DOE OSTI2012

Oriented Growth of Al2O3:ZnO Nanolaminates for Use as Electron-Selective Electrodes in Inverted Polymer Solar Cells

Atomic layer deposition is used to synthesize Al{sub 2}O{sub 3}:ZnO(1:x) nanolaminates with the number of deposition cycles, x, ranging from 5 to 30 for evaluation as optically transparent, electron-selective electrodes in polymer-based inverted solar cells. Al{sub 2}O{sub 3}:ZnO(1:20) nanolaminates are found to exhibit the highest values of electrical conductivity (1.2 x 10{sup 3} S cm{sup 01}; more than six times higher than for neat ZnO films), while retaining a high optical transmittance ({>=}80% in the visible region) and a low work function (4.0 eV). Such attractive performance is attributed to the structure (ZnO crystal size and crystal alignment) and doping level of this intermediate Al{sub 2}O{sub 3}:ZnO film composition. Polymer-based inverted solar cells using poly(3-hexylthiophene) (P3HT):phenyl-C{sub 61}-butyric acid methyl ester (PCBM) mixtures in the active layer and Al{sub 2}O{sub 3}:ZnO(1:20) nanolaminates as transparent electron-selective electrodes exhibit a power conversion efficiency of 3% under simulated AM 1.5 G, 100 mW cm{sup -2} illumination.

14 SOLAR ENERGY↗
DOE OSTI2015

The impact of off-site land use energy intensity on the overall life cycle land use energy intensity for utility-scale solar electricity generation technologies

Estimates of the amount of land used for a defined amount of utility-scale electricity generation in the solar power industry, referred to as solar land use energy intensity (LUEI), are important to decision makers for evaluating the environmental impact of energy technology choices. In general, solar energy tends to have a larger on-site LUEI than that of fossil fuels because the energy generated per square meter of power plant area is much lower. Unfortunately, there are few studies that quantify the off-site LUEI for utility-scale solar energy, and of those that do, they share common methodologies and data sets. As such, in this study, we develop a new method for calculating the off-site LUEI for utility-scale solar energy for three different technologies: silicon photovoltaic (Si-PV), cadmium-telluride (CdTe) PV, and parabolic trough concentrated solar thermal. Our results indicate that the off-site LUEI is most likely 1% or less of the on-site LUEI for each technology. Although our results have some inherent uncertainties, they fall within an order of magnitude of other estimates in the literature.

14 SOLAR ENERGY↗
DOE OSTI2024

Reducing stomatal density by expression of a synthetic epidermal patterning factor increases leaf intrinsic water use efficiency and reduces plant water use in a C4 crop

Abstract Enhancing crop water use efficiency (WUE) is a key target trait for climatic resilience and expanding cultivation on marginal lands. Engineering lower stomatal density to reduce stomatal conductance (gs) has improved WUE in multiple C3 crop species. However, reducing gs in C3 species often reduces photosynthetic carbon gain. A different response is expected in C4 plants because they possess specialized anatomy and biochemistry which concentrates CO2 at the site of fixation. This modifies the relationship of photosynthesis (AN) with intracellular CO2 concentration (ci), such that photosynthesis is CO2 saturated and reductions in gs are unlikely to limit AN. To test this hypothesis, genetic strategies were investigated to reduce stomatal density in the C4 crop sorghum. Constitutive expression of a synthetic epidermal patterning factor (EPF) transgenic allele in sorghum led to reduced stomatal densities, reduced gs, reduced plant water use, and avoidance of stress during a period of water deprivation. In addition, moderate reduction in stomatal density did not increase stomatal limitation to AN. However, these positive outcomes were associated with negative pleiotropic effects on reproductive development and photosynthetic capacity. Avoiding pleiotropy by targeting expression of the transgene to specific tissues could provide a pathway to improved agronomic outcomes.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2012

Study of surface cleaning methods and pyrolysis temperatures on nanostructured carbon films using x-ray photoelectron spectroscopy

Nanostructured carbon (ns-C) films fabricated by stabilization and pyrolysis of diblock copolymers are of interest for a variety of electrical/electronic applications due to their chemical inertness, high-temperature insensitivity, very high surface area, and tunable electrical resistivity over a wide range [Kulkarni et al., Synth. Met. 159, 177 (2009)]. Because of their high porosity and associated high specific surface area, controlled surface cleaning studies are important for fabricating electronic devices from these films. In this study, quantification of surface composition and surface cleaning studies on ns-C films synthesized by carbonization of diblock copolymers of polyacrylonitrile-b-poly(n-butyl acrylate) at two different temperatures were carried out. X-ray photoelectron spectroscopy was used for elemental analysis and to determine the efficacy of various surface cleaning methods for ns-C films and to examine the polymer residues in the films. The in-situ surface cleaning methods included HF vapor treatment, vacuum annealing, and exposure to UV-ozone. Quantitative analysis of high-resolution XPS scans showed 11 at. % nitrogen was present in the films pyrolyzed at 600 Degree-Sign C, suggesting incomplete denitrogenation of the copolymer films. The nitrogen atomic concentration decreased significantly for films pyrolyzed at 900 Degree-Sign C confirming extensive denitrogenation at that temperature. Furthermore, quantitative analysis of nitrogen subpeaks indicated higher loss of nitrogen atoms residing at the edge of graphitic clusters relative to that of nitrogen atoms within the graphitic clusters, suggesting higher graphitization with increasing pyrolysis temperature. Of the surface cleaning methods investigated, in-situ annealing of the films at 300 Degree-Sign C for 40 min was found to be the most efficacious in removing adventitious carbon and oxygen impurities from the surface.

36 MATERIALS SCIENCE↗