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At least 811 records · Page 45

Photoacoustic Optical Properties at UV, VIS, and near IR Wavelengths for Laboratory Generated and Winter Time Ambient Urban Aerosols

We present the laboratory and ambient photoacoustic (PA) measurement of aerosol light absorption coefficients at ultraviolet wavelength (i.e., 355 nm) and compare with measurements at 405, 532, 870, and 1047 nm. Simultaneous measurements of aerosol light scattering coefficients were achieved by the integrating reciprocal nephelometer within the PA's acoustic resonator. Absorption and scattering measurements were carried out for various laboratory generated aerosols, including salt, incense, and kerosene soot to evaluate the instrument calibration and gain insight on the spectral dependence of aerosol light absorption and scattering. Ambient measurements were obtained in Reno, Nevada, between 18 December 2009 and 18 January 2010. The measurement period included days with and without strong ground level temperature inversions, corresponding to highly polluted (freshly emitted aerosols) and relatively clean (aged aerosols) conditions. Particulate matter (PM) concentrations were measured and analyzed with other tracers of traffic emissions. The temperature inversion episodes caused very high concentration of PM (sub 2.5) and PM( sub 10) (particulate matter with aerodynamic diameters less than 2.5 micrometers and 10 micrometers, respectively) and gaseous pollutants: carbon monoxide (CO), nitric oxide (NO), and nitrogen dioxide (NO2). The diurnal change of absorption and scattering coefficients during the polluted (inversion) days increased approximately by a factor of two for all wavelengths compared to the clean days. The spectral variation in aerosol absorption coefficients indicated a significant amount of absorbing aerosol from traffic emissions and residential wood burning. The analysis of single scattering albedo (SSA), Angstrom exponent of absorption (AEA), and Angstrom exponent of scattering (AES) for clean and polluted days provides evidences that the aerosol aging and coating process is suppressed by strong temperature inversion under cloudy conditions. In general, measured UV absorption coefficients were found to be much larger for biomass burning aerosol than for typical ambient aerosols.

absorptivity↗

SO2 Spectroscopy with A Tunable UV Laser

A portion of the fluorescence spectrum of SO2 has been studied using a narrow wavelength doubled dye laser as the exciting source. One purpose of this study is to evaluate the use of SO2 resonance re-emission as a probe of SO2 in the atmosphere. When the SO2 is excited by light at 300.2 nm, for example, a strong reemission peak is observed which is Stokes-shifted from the incident light wavelength by the usual Raman shift (the VI symmetric vibration frequency 1150.5/cm ). The intensity of this peak is sensitive to small changes (.01 nm) in the incident wavelength. Measurements of the N2 quenching and self quenching of this re-emission have been obtained. Preliminary analysis of this data indicates that the quenching is weak but not negligible. The dye laser in our system is pumped by a pulsed N2 laser. Tuning 'and spectral narrowing are accomplished using a telescope-echelle grating combination. In a high power configuration the resulting pulses have a spectral width of about 5 x 10(exp -3) nm and a time duration of about 6 nsec. The echelle grating is rotated by a digital stepping motor, such that each step shifts the wavelength by 6 x 10(exp -4) nm. In addition to the tunable, narrow wavelength uv source and spectral analysis of the consequent re-emission, the system also provides time resolution of the re-emitted light to 6 nsec resolution. This capability is being used to study the lifetime of low pressure S02 fluorescence at different wavelengths and pressures.

Morey, W. W.↗

Initial Technology Assessment for the Large UV-Optical-Infrared (LUVOIR) Mission Concept Study

The NASA Astrophysics Divisions 30-Year Roadmap prioritized a future large-aperture space telescope operating in the ultra-violet-optical-infrared wavelength regime. The Association of Universities for Research in Astronomy envisioned a similar observatory, the High Definition Space Telescope. And a multi-institution group also studied the Advanced Technology Large Aperture Space Telescope. In all three cases, a broad science case is outlined, combining general astrophysics with the search for bio-signatures via direct-imaging and spectroscopic characterization of habitable exo-planets. We present an initial technology assessment that enables such an observatory that is currently being studied for the 2020 Decadal Survey by the Large UV-Optical Infrared (LUVOIR) surveyor Science and Technology Definition Team. We present here the technology prioritization for the 2016 technology cycle and define the required technology capabilities and current state-of-the-art performance. Current, planned, and recommended technology development efforts are also reported.

large aperture↗

The Role of Cloud Contamination, Aerosol Layer Height and Aerosol Model in the Assessment of the OMI Near-UV Retrievals Over the Ocean

Retrievals of aerosol optical depth (AOD) at 388 nm over the ocean from the Ozone Monitoring Instrument (OMI) two-channel near-UV algorithm (OMAERUV) have been compared with independent AOD measurements. The analysis was carried out over the open ocean (OMI and MODerate-resolution Imaging Spectrometer (MODIS) AOD comparisons) and over coastal and island sites (OMI and AERONET, the AErosol RObotic NETwork). Additionally, a research version of the retrieval algorithm (using MODIS and CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) information as constraints) was utilized to evaluate the sensitivity of the retrieval to different assumed aerosol properties. Overall, the comparison resulted in differences (OMI minus independent measurements) within the expected levels of uncertainty for the OMI AOD retrievals (0.1 for AOD less than 0.3, 30% for AOD greater than 0.3). Using examples from case studies with outliers, the reasons that led to the observed differences were examined with specific purpose to determine whether they are related to instrument limitations (i.e., pixel size, calibration) or algorithm assumptions (such as aerosol shape, aerosol height). The analysis confirms that OMAERUV does an adequate job at rejecting cloudy scenes within the instrument's capabilities. There is a residual cloud contamination in OMI pixels with quality flag 0 (the best conditions for aerosol retrieval according to the algorithm), resulting in a bias towards high AODs in OMAERUV. This bias is more pronounced at low concentrations of absorbing aerosols (AOD 388 nm approximately less than 0.5). For higher aerosol loadings, the bias remains within OMI's AOD uncertainties. In pixels where OMAERUV assigned a dust aerosol model, a fraction of them (less than 20 %) had retrieved AODs significantly lower than AERONET and MODIS AODs. In a case study, a detailed examination of the aerosol height from CALIOP and the AODs from MODIS, along with sensitivity tests, was carried out by varying the different assumed parameters in the retrieval (imaginary index of refraction, size distribution, aerosol height, particle shape). It was found that the spherical shape assumption for dust in the current retrieval is the main cause of the underestimate. In addition, it is demonstrated in an example how an incorrect assumption of the aerosol height can lead to an underestimate. Nevertheless, this is not as significant as the effect of particle shape. These findings will be incorporated in a future version of the retrieval algorithm.

aerosols↗

Sugars and Sugar Derivatives in Residues Produced from the UV Irradiation of Astrophysical Ice Analogs

Carbonaceous chondrites contain a large variety of organic compounds of prebiotic interest, which include amino acids, amphiphiles, nucleobases, and sugar derivatives. The presence of these compounds strongly suggests that molecules essential to life can form abiotically under astrophysical conditions. Among the sugar derivatives reported in the Murchison and Murray meteorites, only one sugar (dihydroxyacetone) was found, together with a variety of sugar alcohols and sugar acids containing up to 6 carbon atoms, including sugar acid derivatives of the biological sugars ribose and glucose. On the other hand, laboratory studies on the formation of complex organic molecules from the ultraviolet (UV) irradiation of simulated astrophysical ice mixtures consisting of H2O, CO, CO2, CH3OH, CH4, NH3, etc., at low temperature have been routinely carried out in the past 15 years. These studies have shown that the organic residues recovered at room temperature contain amino acids, amphiphiles, nucleobases, as well as other complex organics, supporting a scenario in which molecules of prebiotic interest can form in extra-terrestrial environments.

Astrochemistry↗

Aluminum Mirror Coatings for UVOIR Telescope Optics Including the Far UV

NASA Cosmic Origins (COR) Program identified the development of high reflectivity mirror coatings for large astronomical telescopes particularly for the far ultra violet (FUV) part of the spectrum as a key technology requiring significant materials research and process development. In this paper we describe the challenges and accomplishments in producing stable high reflectance aluminum mirror coatings with conventional evaporation and advanced Atomic Layer Deposition (ALD) techniques. We present the current status of process development with reflectance of approx. 55 to 80% in the FUV achieved with little or no degradation over a year. Keywords: Large telescope optics, Aluminum mirror, far UV astrophysics, ALD, coating technology development.

large telescope optics↗

Growth and Survival of Perchlorate-Reducing Bacteria in Media Containing Elevated Perchlorate Concentrations and UV-C Conditions

Introduction: The identification of perchlorate (ClO4(-)) on Mars has led to the possibility that complete redox couples are available for microbial metabolism in contemporary surface environments. Perchlorate-reducing bacteria (PRB) utilize ClO4(-) and chlorate (ClO3(-)) as terminal electron acceptors due to the high reduction potential. Additionally, ClO4(-) salts have been suggested as a possible source of brines on Mars and spectral evidence indicates that the hydration of ClO4(-) salts in the regolith of Martian is linked to the surface recurring slope lineae (RSL). For these reasons PRB may serve as analog organisms for possible life on Mars. However, there is very little information on the viability of PRB in aqueous environments that contain high levels of perchlorate Microorganisms on or near the surface of Mars, such as in the RSL, would potentially be exposed to high-salinity and high ultraviolet radiation environments. Under these extreme conditions, microorganisms must possess mechanisms for maintaining continued high genome fidelity. To assess possible microbial viability in contemporary Mars analog environments we are investigating the tolerance of two PRB strains in aqueous conditions under high UV-C conditions and high ClO4(-) concentrations.

Bywaters, K. F.↗

Mission Systems Engineering (MSE) for the Cosmic Evolution Through UV Spectroscopy (CETUS) Space Telescope Concept

The basic objectives of the CETUS mission are to significantly improve our understanding of the evolution of galaxies at a redshift (z) of approximately 1 and to meet the cost constraints (1$B) for a NASA Probe-Class mission. What makes these galaxies so interesting is that their light, which has taken about 7 billion years to reach us, comes from a time when star-formation in the observable universe peaked, and the processes behind this peaking are far from well understood. To accomplish its science goals, CETUS needs to get UV spectra of 105 of these galaxies. To help meet its cost constraints, CETUS will only observe galaxies for which VIS spectra are already available, which means that CETUS has to survey a specific portion of the sky. The combination of the CETUS measurement goals and costs constraints strongly influence the design of virtually every aspect of the mission starting from the telescope and instruments, through to orbit and launch vehicle selection, and including the design of most of the SC Bus sub-systems, such as structure, ACS, power, communications, and thermal control.

Purves, Lloyd R.↗

X-Ray Brightening and UV Fading of Tidal Disruption Event ASASSN-15oi

We present late-time observations by Swift and XMM-Newton of the tidal disruption event (TDE) ASASSN-15oi that reveal that the source brightened in the X-rays by a factor of approximately 10 one year after its discovery, while it faded in the UV (Ultra Violet)/optical by a factor of approximately 100. The XMM-Newton observations measure a soft X-ray blackbody component with kT(sub bb) (blackbody kiloteslas) approximating 45 electronvolts, corresponding to radiation from several gravitational radii of a central approximately 10 (sup 6) solar mass black hole. The last Swift epoch taken almost 600 days after discovery shows that the X-ray source has faded back to its levels during the UV/optical peak. The timescale of the X-ray brightening suggests that the X-ray emission could be coming from delayed accretion through a newly forming debris disk and that the prompt UV/optical emission is from the prior circularization of the disk through stream-stream collisions. The lack of spectral evolution during the X-ray brightening disfavors ionization breakout of a TDE "veiled" by obscuring material. This is the first time a TDE has been shown to have a delayed peak in soft X-rays relative to the UV/optical peak, which may be the first clear signature of the real-time assembly of a nascent accretion disk, and provides strong evidence for the origin of the UV/optical emission from circularization, as opposed to reprocessed emission of accretion radiation.

Gezari, S.↗

Autonomous Inspection of Electrical Transmission Structures with Airborne UV Sensors and Automated Air Traffic Management

This report details test and measurement flights to demonstrate autonomous UAV (Unmanned Aerial Vehicle) inspection of high-voltage electrical transmission structures. A UAV built with commercial, off-the-shelf hardware and software, supplemented with custom sensors and logging software, measured ultraviolet (UV) emissions from a test generator placed on a low-altitude substation and a medium-altitude switching tower. Since corona discharge precedes catastrophic electrical faults on high-voltage structures, detection and geolocation of ultraviolet emissions is needed to develop a UAV-based self-diagnosing power grid. Signal readings from an onboard ultraviolet sensor were validated during flight with a commercial corona camera. Geolocation was accomplished with onboard GPS; the UAV position was logged to a local ground station and transmitted in real time to a NASA server for tracking in the national airspace. The method has practicality and relevance but not adequacy; either improved UAV position determination technology or increased sensor range is needed to enable broad deployment of this method.

Moore, Andrew J.↗

Optical Design for CETUS a Wide-Field 1.5-m Aperture UV Payload Being Studied for a NASA Probe Class Mission Study

As part of a study funded by NASA headquarters, we are developing a probe-class mission concept called the Cosmic Evolution through UV Spectroscopy (CETUS). CETUS includes a 1.5-m aperture diameter telescope with a large field of view (FOV). CETUS includes three scientific instruments: a far ultraviolet (FUV) and near ultraviolet (NUV) imaging camera (CAM); a NUV multiobject spectrograph (MOS); and a dual-channel point/slit spectrograph (PSS) in the Lyman ultraviolet (LUV), FUV, and NUV spectral regions. The large FOV three-mirror anastigmatic (TMA) optical telescope assembly (OTA) simultaneously feeds the three separate scientific instruments. That is, the instruments view separate portions of the TMA image plane, enabling parallel operation by the three instruments. The field viewed by the MOS, whose design is based on an Offner-type spectrographic configuration to provide wide FOV correction, is actively configured to select and isolate numerous field sources using a next-generation micro-shutter array. The two-channel CAM design is also based on an Offner-like configuration. The PSS performs high spectral resolution spectroscopy on unresolved objects over the NUV region with spectral resolving power, R ~ 40,000, in an echelle mode. The PSS also performs long-slit imaging spectroscopy at R ~ 20,000 in the LUV and FUV spectral regions with two aberration-corrected, blazed, holographic gratings used in a Rowland-like configuration. The optical system also includes two fine guidance sensors, and wavefront sensors that sample numerous locations over the full OTA FOV. In-flight wavelength calibration is performed by a wavelength calibration system, and flat-fielding is also performed, both using in-flight calibration sources. We describe the current optical design of CETUS and the major trade studies leading to the design.

space sensors↗

A Cavity-Enhanced UV Absorption Instrument for High-Precision, Fast-Time-Response Ozone Measurements

The NASA Rapid Ozone Experiment (ROZE) is a broadbandcavity-enhanced UV absorption instrument for the detection of in situozone (O3).ROZE uses an incoherent LED light source coupled to a high-finesse optical cavity to achieve an effective pathlength of ~104 m. Due to its high-sensitivity and smalloptical cell volume, ROZE demonstratesa 1𝜎precision of 80 pptv (0.1 s) and 31 pptv (1 s), as well as an 𝑒-fold timeresponseof 50 ms. ROZE can be operated in a range of field environments, including low-and high-altitude research aircraft,and is particularly suited toO3vertical flux measurements usingthe eddy covariance technique.ROZE was successfully integrated aboard the NASA DC-8 aircraft during July–September2019and validated against a well-established chemiluminescence measurement of O3.Aflight within the marine boundary layer also demonstrated flux measurement capabilities, and we observeda mean O3deposition velocityof 0.029 ± 0.005 cm s–1to the ocean surface.The performance characteristics detailed below make ROZE a robust, versatile instrument for fieldmeasurements of O3.

Rapid Ozone Experiment (ROZE)↗

High Resolution UV Spectroscopy of H2 and N2 Applied to Observations of the Planets by Spacecraft

The next generation of high resolution UV imaging Spacecraft are being prepared for studying the airglow and aurora of the Earth, the other terrestrial planets and the Jovian planets. To keep pace with these technological improvements we have developed a laboratory program to provide electron impact collision cross sections of the major molecular planetary gases. This program is described in detail.

Spectroscopy↗

Understanding Atmospheric Absorption Effects on UV Spectra from Sounding Rockets using a Spherical-Shells Model

Our team is working on building and calibrating the FURST sounding rocket, with an expected launch in mid-2023. The goal is to image the most complete and highest resolution UV spectra to date. To do this, preciseradiometric and wavelength calibration techniques have been developed. We describe below our model of O2 atmospheric absorption and couple that with simulated FURST images. With a high-enough SNR, we canestimate our ability to use absorption peaks for calibration, or for back-calculating atmospheric properties. If data is available, this method could be applied to older sounding rocket data to find hidden science.

MSFC, NASA, UAH, CSPAR, FURST, MSU, SHINE, Aeronom↗

Understanding Atmospheric Absorption Effects on UV Spectra from Sounding Rockets using a Spherical-Shells Model

Our team is working on building and calibrating the FURST sounding rocket, with an expected launch in mid-2023. The goal is to image the most complete and highest resolution UV spectra to date. To do this, precise radiometric and wavelength calibration techniques have been developed. We describe below our model of O2 atmospheric absorption and couple that with simulated FURST images. With a high-enough SNR, we can estimate our ability to use absorption peaks for calibration, or for back-calculating atmospheric properties. If data is available, this method could be applied to older sounding rocket data to find hidden science.

MSFC, NASA, UAH, CSPAR, FURST, MSU, SHINE, Aeronom↗

Principal Component-Based Radiative Transfer Model (PCRTM) for Hyperspectral Remote Sensors for UV, VVIS, NIR, IR, and FIR Spectral Regions

Fast and accurate radiative transfer models are needed to efficiently process satellite hyperspectral remote sensors. We have developed a Principal Component-based radiative transfer model (PCRTM) which can simulate TOA radiance or reflectance spectra in the cloudy atmosphere for far IR, IR, NIR, VIS, and UV spectral regions quickly and accurately. Multi-scattering of multiple layers of clouds/aerosols is included in the model. Polarization components can also be calculated. The computation speed is 3 to 4 orders of magnitude faster than MODTRAN5, LBLRTM, and VLIDORT. The PCRTM calculated radiance spectra agree with reference RTM calculated radiance spectra very well (0.03 K in IR and 0.05% in solar). Comparisons of the PCRTM model calculations with observed AIRS, CrIS, IASI, NAST-I, and SCIAMACHY data will be presented. The solar-PCRTM has been developed for CLARREO PathFinder (CPF) and has been extensively used for CPF science algorithms. The PCRTM can also be used for many current and future NASA future missions such as EMIT, SBG, TEMPO, and PACE.

pcrtm↗

Performance of the Dragonfly Mass Spectrometer (DraMS) Programmable UV Laser Source Engineering Test Unit (ETU)

NASA’s Dragonfly mission will sample surface materials from multiple sites on Saturn’s largest moon, Titan, in exploration of its potential for prebiotic chemistry. We report on the performance of our short-pulsed UV laser transmitter, developed for the Dragonfly’s on-board Mass Spectrometer (DraMS). Our engineering test unit (ETU) has completed flight qualification and demonstrated its operational science requirements, such that the final flight unit build can begin. The Titan Hydrocarbon Analysis Nanosecond Optical Source (THANOS) ETU laser produces 266 nm laser pulses at programmable energy levels in order to create high resolution laser desorption mass spectrometry (LDMS) measurements. The laser operates in short bursts of 1-50 pulses, each at < 2 ns pulse width, at a 100 Hz repetition rate. Creating a sealed Titanium unit, capable of operation on the extreme environment of Titan’s surface was a major engineering challenge. The laser successfully demonstrated its ability to meet all operational requirements in terms of pulse energy, beam pointing on target and repeatability even after extensive environmental testing.

Matthew W Mullin↗