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Templates for Risk Informed Assurance with Curvature Embeddings (TRACE)

We investigate recovery of geometric structure from networks embedded in manifolds with spatially varying curvature, extending the constant-curvature framework of Lubold et al. (2023). Our work supports cascade risk assessment in critical infrastructure through the Templates for Risk-informed Assurance with Curvature Embeddings (TRACE) framework. Simulations on a bi-modal Gaussian surface show that constant-curvature methods yield weighted averages shaped by clique patterns, while hierarchical clustering identifies distinct regimes. Localized estimation, however, reveals boundary contamination in transitional regions. To address heterogeneity, we develop distance metrics for graphs with edge and node features, proving their metric validity, and validate them via deterministic graph generation from canonical tilings. We further propose a diffusion-based anomaly detection approach that treats networks as glued manifolds, using curvature discontinuities to detect structural anomalies. Employing the carré-du-champ operator and scalar curvature, we achieve robust anomaly discrimination, demonstrated on the Singapore Water Treatment (SWaT) dataset with joint network-traffic and sensor features. Integration with TRACE reveals how curvature shapes cascade dynamics: positive curvature impedes, while negative curvature accelerates propagation. This geometric perspective provides interpretable risk metrics and visualization tools for critical infrastructure managers. While full validation remains ongoing, our contributions establish a rigorous foundation for geometric analysis of network resilience and cascade vulnerability.

97 MATHEMATICS AND COMPUTING↗

Boundary layer moisture variability at the Atmospheric Radiation Measurement (ARM) Eastern North Atlantic observatory during marine conditions

Abstract. Boundary layer moisture variability at the Eastern North Atlantic (ENA) site during marine conditions is examined at monthly and daily timescales using 5 years of ground-based observations and output from the European Center for Medium range Weather Forecast (ECMWF) reanalysis model. The annual cycle of the mixed-layer total water budgets is presented to estimate the relative contribution of large-scale advection, local moisture tendency, entrainment, and precipitation to balance the moistening due to surface latent heat flux on monthly timescales. When marine conditions prevail, advection of colder and dry air from the north acts as an important moisture sink (∼ 50 % of the overall budget) during fall and winter driving the seasonality of the budget. Entrainment and precipitation contribute to the drying of the boundary layer (∼ 25 % and ∼ 15 % respectively), and the local change in moisture contributes to a small residual part. On a daily temporal scale, moist and dry mesoscale columns of vapor (∼ 10 km) are analyzed during 10 selected days of precipitating stratocumulus clouds. Adjacent moist and dry columns present distinct mesoscale features that are strongly correlated with clouds and precipitation. Dry columns adjacent to moist columns have more frequent and stronger downdrafts immediately below the cloud base. Moist columns have more frequent updrafts, stronger cloud-top cooling, and higher liquid water path and precipitation compared to the dry columns. This study highlights the complex interaction between large-scale and local processes controlling the boundary layer moisture and the importance of spatial distribution of vapor to support convection and precipitation.

54 ENVIRONMENTAL SCIENCES↗

DSCOVR/EPIC-derived global hourly and daily downward shortwave and photosynthetically active radiation data at 0.1° × 0.1° resolution

Downward shortwave radiation (SW) and photosynthetically active radiation (PAR) play crucial roles in Earth system dynamics. Spaceborne remote sensing techniques provide a unique means for mapping accurate spatiotemporally continuous SW–PAR, globally. However, any individual polar-orbiting or geostationary satellite cannot satisfy the desired high temporal resolution (sub-daily) and global coverage simultaneously, while integrating and fusing multisource data from complementary satellites/sensors is challenging because of co-registration, intercalibration, near real-time data delivery and the effects of discrepancies in orbital geometry. The Earth Polychromatic Imaging Camera (EPIC) on board the Deep Space Climate Observatory (DSCOVR), launched in February 2015, offers an unprecedented possibility to bridge the gap between high temporal resolution and global coverage and characterize the diurnal cycles of SW–PAR globally. In this study, we adopted a suite of well-validated data-driven machine-learning models to generate the first global land products of SW–PAR, from June 2015 to June 2019, based on DSCOVR/EPIC data. The derived products have high temporal resolution (hourly) and medium spatial resolution (0.1°×0.1°), and they include estimates of the direct and diffuse components of SW–PAR. We used independently widely distributed ground station data from the Baseline Surface Radiation Network (BSRN), the Surface Radiation Budget Network (SURFRAD), NOAA's Global Monitoring Division and the U.S. Department of Energy's Atmospheric System Research (ASR) program to evaluate the performance of our products, and we further analyzed and compared the spatiotemporal characteristics of the derived products with the benchmarking Clouds and the Earth's Radiant Energy System Synoptic (CERES) data. We found both the hourly and daily products to be consistent with ground-based observations (e.g., hourly and daily total SWs have low biases of -3.96 and -0.71 W m -2 and root-mean-square errors (RMSEs) of 103.50 and 35.40 W m -2 , respectively). The developed products capture the complex spatiotemporal patterns well and accurately track substantial diurnal, monthly, and seasonal variations in SW–PAR when compared to CERES data. They provide a reliable and valuable alternative for solar photovoltaic applications worldwide and can be used to improve our understanding of the diurnal and seasonal variabilities of the terrestrial water, carbon and energy fluxes at various spatial scales.

54 ENVIRONMENTAL SCIENCES↗

Cosmogenic nuclide and solute flux data from central Cuban rivers emphasize the importance of both physical and chemical mass loss from tropical landscapes

We use 25 new measurements of in situ produced cosmogenic 26 Al and 10 Be in river sand, paired with estimates of dissolved load flux in river water, to characterize the processes and pace of landscape change in central Cuba. Long-term erosion rates inferred from 10 Be concentrations in quartz extracted from central Cuban river sand range from 3.4–189 Mg km –2 yr –1 (mean 59, median 45). Dissolved loads (10–176 Mg km –2 yr –1 ; mean 92, median 97), calculated from stream solute concentrations and modeled runoff, exceed measured cosmogenic- 10 Be-derived erosion rates in 18 of 23 basins. This disparity mandates that in this environment landscape-scale mass loss is not fully represented by the cosmogenic nuclide measurements. The 26 Al / 10 Be ratios are lower than expected for steadystate exposure or erosion in 16 of 24 samples. Depressed 26 Al/ 10 Be ratios occur in many of the basins that have the greatest disparity between dissolved loads (high) and erosion rates inferred from cosmogenic nuclide concentrations (low). Depressed 26 Al/ 10 Be ratios are consistent with the presence of a deep, mixed, regolith layer providing extended storage times on slopes and/or burial and extended storage during fluvial transport. River water chemical analyses indicate that many basins with lower 26 Al/ 10 Be ratios and high 10 Be concentrations are underlain at least in part by evaporitic rocks that rapidly dissolve. Our data show that when assessing mass loss in humid tropical landscapes, accounting for the contribution of rock dissolution at depth is particularly important. In such warm, wet climates, mineral dissolution can occur many meters below the surface, beyond the penetration depth of most cosmic rays and thus the production of most cosmogenic nuclides. Our data suggest the importance of estimating solute fluxes and measuring paired cosmogenic nuclides to better understand the processes and rates of mass transfer at a basin scale.

54 ENVIRONMENTAL SCIENCES↗

Probabilistic estimation of depth-resolved profiles of soil thermal diffusivity from temperature time series

Abstract. Improving the quantification of soil thermal and physical properties is key to achieving a better understanding and prediction of soil hydro-biogeochemical processes and their responses to changes in atmospheric forcing. Obtaining such information at numerous locations and/or over time with conventional soil sampling is challenging. The increasing availability of low-cost, vertically resolved temperature sensor arrays offers promise for improving the estimation of soil thermal properties from temperature time series, and the possible indirect estimation of physical properties. Still, the reliability and limitations of such an approach need to be assessed. In the present study, we develop a parameter estimation approach based on a combination of thermal modeling, sliding time windows, Bayesian inference, and Markov chain Monte Carlo simulation to estimate thermal diffusivity and its uncertainty over time, at numerous locations and at an unprecedented vertical spatial resolution (i.e., down to 5 to 10 cm vertical resolution) from soil temperature time series. We provide the necessary framework to assess under which environmental conditions (soil temperature gradient, fluctuations, and trend), temperature sensor characteristics (bias and level of noise), and deployment geometries (sensor number and position) soil thermal diffusivity can be reliably inferred. We validate the method with synthetic experiments and field studies. The synthetic experiments show that in the presence of median diurnal fluctuations ≥ 1.5 ∘C at 5 cm below the ground surface, temperature gradients > 2 ∘C m−1, and a sliding time window of at least 4 d the proposed method provides reliable depth-resolved thermal diffusivity estimates with percentage errors ≤ 10 % and posterior relative standard deviations ≤ 5 % up to 1 m depth. Reliable thermal diffusivity under such environmental conditions also requires temperature sensors to be spaced precisely (with accuracy to a few millimeters), with a level of noise ≤ 0.02 ∘C, and with a bias defined by a standard deviation ≤ 0.01 ∘C. Finally, the application of the developed approach to field data indicates significant repeatability in results and similarity with independent measurements, as well as promise in using a sliding time window to estimate temporal changes in soil thermal diffusivity, as needed to potentially capture changes in bulk density or water content.

54 ENVIRONMENTAL SCIENCES↗

Important role of stratospheric injection height for the distribution and radiative forcing of smoke aerosol from the 2019–2020 Australian wildfires

More than 1 Tg smoke aerosol was emitted into the atmosphere by the exceptional 2019–2020 southeastern Australian wildfires. Triggered by the extreme fire heat, several deep pyroconvective events carried the smoke directly into the stratosphere. Once there, smoke aerosol remained airborne considerably longer than in lower atmospheric layers. The thick plumes traveled eastward, thereby being distributed across the high and mid-latitudes in the Southern Hemisphere, enhancing the atmospheric opacity. Due to the increased atmospheric lifetime of the smoke plume, its radiative effect increased compared to smoke that remains in lower altitudes. Global models describing aerosol-climate impacts lack adequate descriptions of the emission height of aerosols from intense wildfires. Here, we demonstrate, by a combination of aerosol-climate modeling and lidar observations, the importance of the representation of those high-altitude fire smoke layers for estimating the atmospheric energy budget. Through observation-based input into the simulations, the Australian wildfire emissions by pyroconvection are explicitly prescribed to the lower stratosphere in different scenarios. Based on our simulations, the 2019–2020 Australian fires caused a significant top-of-atmosphere (TOA) hemispheric instantaneous direct radiative forcing signal that reached a magnitude comparable to the radiative forcing induced by anthropogenic absorbing aerosol. Up to +0.50 W m -2 instantaneous direct radiative forcing was modeled at TOA, averaged for the Southern Hemisphere (+0.25 W m -2 globally) from January to March 2020 under all-sky conditions. At the surface, on the other hand, an instantaneous solar radiative forcing of up to -0.81 W m -2 was found for clear-sky conditions, with the respective estimates depending on the model configuration and subject to the model uncertainties in the smoke optical properties. Since extreme wildfires are expected to occur more frequently in the rapidly changing climate, our findings suggest that high-altitude wildfire plumes must be adequately considered in climate projections in order to obtain reasonable estimates of atmospheric energy budget changes.

54 ENVIRONMENTAL SCIENCES↗

Sensitivity of Near-Surface Variables in the RUC Land Surface Model in the Weather Research and Forecasting Model

In this study, we investigate the parametric sensitivity of near-surface variables, such as sensible heat flux, latent heat flux, ground heat flux, hub-height wind speed and land surface temperature, to the parameters used in the Rapid Update Cycle (RUC) land surface model (LSM) during a wintertime and summertime period. The model simulations are compared with observations collected from the second Wind Forecast Improvement Project (WFIP2) field campaign. The results suggest that parameters related to snow/ice and thermal processes can have significant impact on the simulated near-surface variables. Out of the 11 examined parameters, only 6 of them have considerable influences on the model behaviors and explain about 60 ~ 80 % of the estimated total variance of the simulated variables. In addition, the magnitude of the parametric sensitivity varies with season. For instance, parameters associated with snow/ice processes are dominant during the wintertime whereas those associated with thermal processes are more important during the summertime. Furthermore, the impact of the identified parameters on the simulated variables is highly related to the topography. There is a high degree of sensitivity to the parameter values over the slope region. This points out the importance of collecting field observations over steep areas to better quantity the appropriate values of key parameters. Overall, our findings provide a better understanding of the RUC LSM behavior associated with parameter uncertainties and can be used to improve the forecasting skill of land surface processes via calibration of the most uncertain model parameters.

17 WIND ENERGY↗

Interferometric SAR modelling of near surface data to improve geological model in the Surat Basin, Australia

Here we present a study on geophysical inverse modelling for subsurface structural properties of an unconventional hydrocarbon site that was monitored previously by Interferometric Synthetic Aperture Radar (InSAR) technology for surface deformation. A static three-dimensional geomodel along with extracted property maps replicates the depth of each underlying stratigraphic unit and structural feature with the density of each geological layer. We examine the hypothesis that integration of elastic properties of each formation layer with InSAR observations in a stratified elastic medium will lead to a viscoelastic geophysical inverse problem that can be solved to estimate fractional volume change at the reservoir level. Moreover, we examine synthetic scenarios in which the elastic properties of the formations are perturbed before determining the resulting impact on the rate of surface deformation. The results show that although the slope of underlying formations, their density and depth can define the extent and pattern of a deformation signal, their properties have a marginal impact on volumetric change compared to the dense network of shallow depth Coal Seam Gas (CSG) mining wells. Besides, it is also demonstrated that the inversion of InSAR deformation maps can resolve the uncertainties associated with low-resolution seismic interpretation as well as filling the data gaps within seismic acquisitions. A significant contribution of this investigation to the geological basin modelling involves a) introducing a remote and non-invasive technology such as InSAR to improve geophysical mapping of subsurface structures such as faults in areas with sparse or no reflective seismic information, and b) applying a multi-layer viscoelastic geophysical source model for an unconventional hydrocarbon reservoir such as CSG.

58 GEOSCIENCES↗

Distribution Development for Residual Inventory at the New York West Valley Site - 20400

The New York State Energy Research and Development Authority (NYSERDA) is the owner of the Western New York Nuclear Service Center (WNYNSC), a 1,351 ha site located approximately 48 km south of Buffalo, New York. In 1962, Nuclear Fuel Services, Inc. (NFS) entered into Agreements with the Atomic Energy Commission and New York State to construct the first commercial reprocessing plant of nuclear fuel in the United States. NFS, a private company, built and operated the spent fuel reprocessing plant and waste disposal facilities, processing 640 Mg of spent nuclear fuel from 1966 to 1972 under an Atomic Energy Commission license. Nuclear fuel reprocessing operations ended in 1972 and never reopened, leaving behind radioactive and chemical wastes. Operations led to contamination in a number of facilities and locations. Some of that contamination has migrated from waste disposal zones to other layers, formations, and features on and off the WNYNSC. Phase I decommissioning activities are ongoing and involve the removal of a number of areas and structures that have been associated with contamination. The purpose of this work is to outline the approach for characterizing contamination not associated with disposed wastes, contaminated structures, or specific releases. In this work, the term, residual radiological activity, is used to describe environmental contamination that exists subsequent to the completion of Phase I decommissioning activities, that is not associated with disposed wastes, contaminated structures, or specific releases. Contamination from the Site was quantified relative to data that characterize the concentrations of radionuclides that exist in background. Background concentrations are those present in the area but having no influence from Site related activities. The existence of residual radiological activity that is elevated relative to background has the potential to contribute to future risks to human health and the environment. As a consequence, the residual inventory information is used to inform the West Valley Probabilistic Performance Assessment (PPA) model to characterize potential future risks to human health and the environment. The centralized West Valley Data Management System (DMS) was the source of information for the data assembled in this analysis. The DMS is a fairly large compilation consisting of thousands of records from investigation studies, with sample dates ranging from 1990 to present. Samples from monitoring wells, boreholes, geoprobe studies, surface water, surface soils, storm water outfalls, ventilation stack filters, plant and animal tissues, and more are included in the DMS. Results are typically reported in units of activity per unit volume. For the purpose of the analyses presented here, all results were converted into consistent units of pCi per unit volume. Since 1990, data have been collected from various locations across the WNYNSC at different times with varying frequency over the course of several decades. As a consequence, a number of potential issues can arise with respect to the assembly of a dataset that is deemed adequate for the characterization of residual radiological activity. These issues were assessed and resolved to the extent possible through careful consideration of the properties of the distributions. The intent was to use data which characterize the current state of the Site. Radionuclides can be designated to one of several groups depending on their origin. In this work the groups considered were 1) Naturally Occurring Radioactive Material (NORM), 2) fallout, and 3) Other (including power plant, medical research, etc). This grouping is a useful construct with respect to the interpretation of fixed laboratory results. For example, NORM radionuclides that exist within a decay chain should have approximately equivalent distributions of concentrations if they are representative of background conditions. Insights such as these can be used as a check to identify sample results that need to be further investigated or omitted due to issues associated with reported results from fixed laboratory analyses. This type of analysis provided a foundation for the assessment of the adequacy of sample results for use in subsequent components of an assessment. The general process for the assessment of residual radiological contamination at the Site consists of a sequence of several steps. First, for each analyte, several statistical tests were performed to assess the weight of evidence against the null hypothesis that the mean of the distribution of concentrations was equal to zero. If the mean of the distribution of concentrations for a given radionuclide was not found to be greater than zero, then it was removed from consideration as a component of the residual radiological contamination. If there was significant evidence to reject the hypothesis of the mean being equal to zero, the second step was to compare the distribution of the data from the Site to that of the corresponding background. A suite of tests was used to compare the distributions of the site and background data. The results of these tests were collectively used to determine if site data are elevated relative to background. The third step was to develop distributions using a Bayesian framework to characterize the distribution of mean of the increment present above background for each of the radionuclides. The Bayesian model implemented allowed for the comparison of site-specific records to background concentrations to better approximate contamination attributed to the Site. A final screening step was employed for radionuclides that exceed background. This screening step compared 95% upper confidence limits (UCLs) from the increment distribution developed in the previous step to the risk screening levels. This approach yields a list of analytes that were determined to be elevated relative to background.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Onset of cavitation and vapor bubble development over hydrophilic and hydrophobic surfaces

Cavitation, the formation of vapor bubbles as the liquid pressure is reduced below the saturated vapor pressure, often requires a substantial negative relative pressure in a pure liquid. Classical nucleation theory (CNT) provides an estimate for the rate of cavitation but there is often a disconnect between the predictions at the molecular scale compared to observations at the macroscale. We report on mesoscale simulations of cavitation based on many-body dissipative particle dynamics (mDPD), a coarse-grained molecular dynamics (MD), which bridges the two scales. A liquid layer is confined between smooth planar walls at a constant temperature, while the pressure is reduced slowly by expanding the wall-bounded domain. The wetting properties of the liquid are determined by the parameters of the interaction potentials. With hydrophilic walls, homogeneous nucleation is observed in the liquid bulk. As a bubble forms and grows, it creates a strong pressure pulse and oscillations that cause other bubbles that may have formed slightly later to collapse. For a nearly neutral wall with a contact angle close to 90 ° , heterogeneous nucleation occurs at the walls at a smaller negative pressure and generates weaker pressure oscillations. With hydrophobic walls or seed particles, heterogeneous nucleation readily occurs, where fluctuations and the merger of transient surface bubbles are significant.

Science & Technology - Other Topics↗

Correlation of Surface Acoustic Wave (SAW) force myography sensor output with elbow joint torque

Accurate assessment of skeletal muscle forces and net joint torque is essential for preventing fatigue-related injuries, optimizing physical training, and monitoring disease progression in neuromuscular conditions. However, existing joint torque evaluation techniques are hindered by limited portability and high operational costs, confining their use to controlled laboratory or clinical settings. Despite substantial advances in wearable joint torque estimation systems, ongoing challenges such as power constraints, bulky wired setups, and susceptibility to environmental or motion artifacts underscore the urgent need for truly batteryless, wireless solutions deployable in real-world settings. This paper proposes a novel surface acoustic wave (SAW)-based force myography (FMG) system for noninvasive measurement of joint torque, validated against a gold-standard electromechanical dynamometer. The approach uses a single SAW sensor embedded in an armband to detect volumetric biceps brachii changes, with a second-order polynomial mapping sensor output and elbow angle to torque. Seven participants were tested in both isometric (15°–90°) and isokinetic (10°/s and 20°/s) supinated elbow flexion tasks. Under isometric conditions, subject-specific calibration achieved a normalized root-mean-square error (NRMSE) of 13.6% ± 6.0% and R 2 = 0.834 ± 0.180, while a group-level model yielded 14.4% ± 6.8% and 0.808 ± 0.208, respectively. For isokinetic trials, the group model produced an NRMSE of 24.1% ± 6.6% at 10°/s and 24.9% ± 08.9% at 20°/s, highlighting the feasibility of using a single-sensor SAW-FMG setup across different speeds. Because SAW devices support wireless, battery-free operation, the proposed system offers a pathway to portable, real-time monitoring for sports medicine, rehabilitation, and clinical diagnostics.

36 MATERIALS SCIENCE↗

A multi-criteria land suitability assessment of field allocation decisions for switchgrass

With the goal of evaluating biomass resource availability in certain regions in the United States, the Department of Energy, Department of Agriculture, Environmental Protection Agency, national laboratories, and Forest Service research laboratories, together with academic and industry collaborators, performed a resource analysis study, 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy, Volume 1: Economic Availability of Feedstocks, using POLYSYS model to estimate biomass potential. The study provided county- and state-level biomass potential projections, with biomass feedstock production estimates and suitability assessment of lands acreage likely to transition to energy crops. For this analysis, we estimate biomass supply by year 2028, more specifically, lands acreage transition to switchgrass in the Midwest of the United States, across 50 counties in 3 states (Nebraska, Kansas, and Colorado). We propose a multi-criteria site suitability framework, to determine the potential acreage and production for switchgrass, at the field level. Site selection criteria span agronomic and ecosystem services such as previous land cover, crop rotation, soil water holding capacity, crop productivity, field efficiency, topography, soil organic matter, soil leaching propensity, distance to surface water bodies, and soil erosivity. Efficient agricultural field selection for dedicated energy crops field allocation is critical to evaluate biomass resource availability, and it is our position that estimation at the field level would provide a more accurate and useful estimation to support an emerging bioeconomy. Using field suitability scores and county-level assessments, we model land allocation decision for energy crop in the future, estimating the spatial distribution of dynamics of energy crop adoption with priority to fields scoring the highest. Additionally, compared with POLYSYS results from the report mentioned above, our method shows good performance overall, with about 2% and 1.2% of difference in switchgrass acreage allocation and crop production, respectively.

54 ENVIRONMENTAL SCIENCES↗

Unraveling the 2021 Central Tennessee flood event using a hierarchical multi-model inundation modeling framework

Flood prediction systems need hierarchical atmospheric, hydrologic, and hydraulic models to predict rainfall, runoff, streamflow, and floodplain inundation. The accuracy of such systems depends on the error propagation through the modeling chain, sensitivity to input data, and choice of models. In this study, we used multiple precipitation forcings (hindcast and forecast) to drive hydrologic and hydrodynamic models to analyze the impacts of various drivers on the estimates of flood inundation depth and extent. We implement this framework to unravel the August 2021 extreme flooding event that occurred in Central Tennessee, USA. We used two radar-based quantitative precipitation estimates (STAGE4 and MRMS) as well as quantitative precipitation forecasts (QPF) from the National Weather Service Weather Prediction Center (WPC) to drive a series of models in the hierarchical framework, including the Variable Infiltration Capacity (VIC) land surface model, the Routing Application for Parallel Computation of Discharge (RAPID) river routing model, and the AutoRoute and TRITON inundation models. An evaluation with observed high-water marks demonstrates that the framework can reasonably simulate flood inundation. Despite the complex error propagation mechanism of the modeling chain, we show that inundation estimates are most sensitive to rainfall estimates. Most notably, QPF significantly underestimates flood magnitudes and inundations leading to unanticipated severe flooding for all stakeholders involved in the event. Finally, we discuss the implications of the hydrodynamic modeling framework for real-time flood forecasting.

54 ENVIRONMENTAL SCIENCES↗

The contribution of Humboldt Glacier, northern Greenland, to sea-level rise through 2100 constrained by recent observations of speedup and retreat

Abstract. Humboldt Glacier, northern Greenland, has retreated and accelerated through the 21st century, raising concerns that it could be a significant contributor to future sea-level rise. We use a data-constrained ensemble of three-dimensional higher-order ice sheet model simulations to estimate the likely range of sea-level rise from the continued retreat of Humboldt Glacier. We first solve for basal traction using observed ice thickness, bed topography, and ice surface velocity from the year 2007 in a PDE-constrained (partial differential equation) optimization. Next, we impose calving rates to match mean observed retreat rates from winter 2007–2008 to winter 2017–2018 in a transient calibration of the exponent in the power-law basal friction relationship. We find that power-law exponents in the range of 1/7–1/5 – rather than the commonly used 1/3–1 – are necessary to reproduce the observed speedup over this period. We then tune an iceberg calving parameterization based on the von Mises stress yield criterion in another transient-calibration step to approximate both observed ice velocities and terminus position in 2017–2018. Finally, we use the range of basal friction relationship exponents and calving parameter values to generate the ensemble of model simulations from 2007–2100 under three climate forcing scenarios from CMIP5 (two RCP8.5 forcings, Representative Concentration Pathway) and CMIP6 (one SSP5-8.5 forcing, Shared Socioeconomic Pathway). Our simulations predict 5.2–8.7 mm of sea-level rise from Humboldt Glacier, significantly higher than a previous estimate (∼ 3.5 mm) and equivalent to a substantial fraction of the 40–140 mm predicted by ISMIP6 from the whole Greenland Ice Sheet. Our larger future sea-level rise prediction results from the transient calibration of our basal friction law to match the observed speedup, which requires a semi-plastic bed rheology. In many simulations, our model predicts the growth of a sizable ice shelf in the middle of the 21st century. Thus, atmospheric warming could lead to more retreat than predicted here if increased surface melt promotes hydrofracture of the ice shelf. Our data-constrained simulations of Humboldt Glacier underscore the sensitivity of model predictions of Greenland outlet glacier response to warming to choices of basal shear stress and iceberg calving parameterizations. Further, transient calibration of these parameterizations, which has not typically been performed, is necessary to reproduce observed behavior. Current estimates of future sea-level rise from the Greenland Ice Sheet could, therefore, contain significant biases.

54 ENVIRONMENTAL SCIENCES↗

Improving snow albedo modeling in the E3SM land model (version 2.0) and assessing its impacts on snow and surface fluxes over the Tibetan Plateau

With the highest albedo of the land surface, snow plays a vital role in Earth's surface energy budget and water cycle. Snow albedo is primarily controlled by snow grain properties (e.g., size and shape) and light-absorbing particles (LAPs) such as black carbon (BC) and dust. The mixing state of LAPs in snow also has impacts on LAP-induced snow albedo reduction and surface radiative forcing (RF). However, most land surface models assume that snow grain shape is spherical and LAPs are externally mixed with the snow grains. This study improves the snow radiative transfer model in the Energy Exascale Earth System Model version 2.0 (E3SM v2.0) Land Model (ELM v2.0) by considering non-spherical snow grain shapes (i.e., spheroid, hexagonal plate, and Koch snowflake) and internal mixing of dust–snow, and it systematically evaluates the impacts on the surface energy budget and water cycle over the Tibetan Plateau (TP). A series of ELM simulations with different treatments of snow grain shape, mixing state of BC–snow and dust–snow, and sub-grid topographic effects (TOP) on solar radiation are performed. Compared with two remote sensing snow products derived from the Moderate Resolution Imaging Spectroradiometer, the control ELM simulation (ELM_Control) with the default configurations of spherical snow grain shape, internal mixing of BC–snow, external mixing of dust–snow, and without TOP as well as the ELM simulation with new model features (ELM_New) can both capture the overall snow distribution reasonably. Additionally, ELM_New overall shows smaller biases in snow cover fraction than ELM_Control in spring when snowmelt is important for water management. The estimated LAP-induced RF in ELM_New ranges from 0 to 19.3 W m -2 with the area-weighted average value of 1.5 W m -2 that is comparable to the reported values in existing studies. The Koch snowflake shape, among other non-spherical shapes, shows the largest difference from the spherical shape in spring when snow processes related to the surface energy budget and water cycle have high importance. The impacts of the mixing state of LAP in snow are smaller than the shape effects and depend on snow grain shape. Compared to external mixing, internal mixing of LAP–snow can lead to larger snow albedo reduction and snowmelt, which further affect the surface energy budget and water cycle. The individual contributions of non-spherical snow shape, mixing state of LAP–snow, and local topography impacts on the snow and surface fluxes have different signs and magnitudes, and their combined effects may be negative or positive due to complex and nonlinear interactions among the factors. Overall, the changes in net solar radiation in spring due to individual and combined effects range from -28.6 to 16.9 W m -2 and -29.7 to 12.2 W m -2 , respectively. This study advances understanding of the role of snow grain shape and mixing state of LAP–snow in land surface processes and offers guidance for improving snow simulations and RF estimates in Earth system models under climate change.

58 GEOSCIENCES↗

Matching high resolution satellite data and flux tower footprints improves their agreement in photosynthesis estimates

Mapping canopy photosynthesis in both high spatial and temporal resolution is essential for carbon cycle monitoring in heterogeneous areas. However, well established satellites in sun-synchronous orbits such as Sentinel-2, Landsat and MODIS can only provide either high spatial or high temporal resolution but not both. Recently established CubeSat satellite constellations have created an opportunity to overcome this resolution trade-off. In particular, Planet Fusion allows full utilization of the CubeSat data resolution and coverage while maintaining high radiometric quality. In this study, we used the Planet Fusion surface reflectance product to calculate daily, 3-m resolution, gap-free maps of the near-infrared radiation reflected from vegetation (NIRvP). We then evaluated the performance of these NIRvP maps for estimating canopy photosynthesis by comparing with data from a flux tower network in Sacramento-San Joaquin Delta, California, USA. Overall, NIRvP maps captured temporal variations in canopy photosynthesis of individual sites, despite changes in water extent in the wetlands and frequent mowing in the crop fields. When combining data from all sites, however, we found that robust agreement between NIRvP maps and canopy photosynthesis could only be achieved when matching NIRvP maps to the flux tower footprints. In this case of matched footprints, NIRvP maps showed considerably better performance than in situ NIRvP in estimating canopy photosynthesis both for daily sum and data around the time of satellite overpass (R2 = 0.78 vs. 0.60, for maps vs. in situ for the satellite overpass time case). This difference in performance was mostly due to the higher degree of consistency in slopes of NIRvP-canopy photosynthesis relationships across the study sites for flux tower footprint-matched maps. Our results show the importance of matching satellite observations to the flux tower footprint and demonstrate the potential of CubeSat constellation imagery to monitor canopy photosynthesis remotely at high spatio-temporal resolution.

54 ENVIRONMENTAL SCIENCES↗

The structure of the stellar halo of the Andromeda galaxy explored with the NB515 for Subaru/HSC – I. New insights on the stellar halo up to 120 kpc

ABSTRACT We analyse the M31 halo and its substructure within a projected radius of 120 kpc using a combination of Subaru/HSC NB515 and Canada France Hawaii Telescope/MegaCam g and i bands. We succeed in separating M31’s halo stars from foreground contamination with $\sim$90 per cent accuracy by using the surface gravity sensitive NB515 filter. Based on the selected M31 halo stars, we discover three new substructures, which associate with the Giant Southern Stream (GSS) based on their photometric metallicity estimates. We also produce the distance and photometric metallicity estimates for the known substructures. While these quantities for the GSS are reproduced in our study, we find that the north-western stream shows a steeper distance gradient than found in an earlier study, suggesting that it is likely to have formed in an orbit closer to the Milky Way. For two streams in the eastern halo (Stream C and D), we identify distance gradients that had not been resolved. Finally, we investigate the global halo photometric metallicity distribution and surface brightness profile using the NB515-selected halo stars. We find that the surface brightness of the metal-poor and metal-rich halo populations, and the all population can be fitted to a power-law profile with an index of $\alpha =-1.65\pm 0.02$, $-2.82\pm 0.01$, and $-2.44\pm 0.01$, respectively. In contrast to the relative smoothness of the halo profile, its photometric metallicity distribution appears to be spatially non-uniform with non-monotonic trends with radius, suggesting that the halo population had insufficient time to dynamically homogenize the accreted populations.

Ogami, Itsuki (ORCID:0000000182394549)↗

Soil carbon sequestration potential and the identification of hotspots in the Eastern Corn Belt of the United States

Soil carbon sequestration is a significant CO 2 mitigation strategy but precise assessments of sequestration require spatially explicit modeling of potential changes in soil organic carbon (SOC) in response to soil, climate, land condition and management interactions. We assessed the SOC sequestration potential of the Eastern Corn Belt (ECB) in the USA (Indiana, Kentucky, Maryland, Michigan, Ohio, Pennsylvania, and West Virginia) in response to the adoption of conservation farming practices and land use change (pasture and forestation) using the SOCRATES model. Input data was provided through an intersection of the STATSGO, National Land Cover Database and a PRISM climate surface. At the end of the 20th century, the 15.3 Mha of cropped soils in the ECB contained 632 Tg C, an estimated reduction of 52% since the introduction of agriculture in the mid-1800s. Complete adoption of no-tillage practices on Prime Cropland would potentially recover 147 Tg SOC over 20 years, whereas a continuation of conventional tillage would produce a loss of 35 Tg SOC. Sequestration hotspots (> 500 Gg increase in SOC) under no-tillage cover 2.3 Mha providing 28 Tg C over 20 years. The conversion of Marginal (non-Prime) agricultural lands to Forests would yield an additional 13 Tg C in SOC and 381 Tg C in aboveground biomass. The rehabilitation of Minelands to Forest would yield an additional 4 Tg C in SOC and 42 Tg C in biomass. Here, opportunities to sequester C in the ECB via tillage and reforestation are substantial and should be incorporated into regional and national climate change mitigation strategies.

59 BASIC BIOLOGICAL SCIENCES↗