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CERES Monthly Gridded Single Satellite TOA and Surfaces/Clouds (SFC) data in HDF (CER_SFC_TRMM-PFM-VIRS_Beta4)

The Monthly Gridded TOA/Surface Fluxes and Clouds (SFC) product contains a month of space and time averaged Clouds and the Earth's Radiant Energy System (CERES) data for a single scanner instrument. The SFC is also produced for combinations of scanner instruments. All instantaneous shortwave, longwave, and window fluxes at the Top-of-the-Atmosphere (TOA) and surface from the CERES SSF product for a month are sorted by 1-degree spatial regions and by the local hour of observation. The mean of the instantaneous fluxes for a given region-hour bin is determined and recorded on the SFC along with other flux statistics and scene information. These average fluxes are given for both clear-sky and total-sky scenes. The regional cloud properties are column averaged and are included on the SFC. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1998-01-01; Stop_Date=2000-03-31] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=100] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=1 degree; Horizontal_Resolution_Range=100 km - < 250 km or approximately 1 degree - < 2.5 degrees; Temporal_Resolution=1 hour; Temporal_Resolution_Range=Hourly - < Daily].

NET FLUX↗

CERES Monthly Gridded Single Satellite TOA and Surfaces/Clouds (SFC) data in HDF (CER_SFC_Terra-FM1-MODIS_Edition2A)

The Monthly Gridded TOA/Surface Fluxes and Clouds (SFC) product contains a month of space and time averaged Clouds and the Earth's Radiant Energy System (CERES) data for a single scanner instrument. The SFC is also produced for combinations of scanner instruments. All instantaneous shortwave, longwave, and window fluxes at the Top-of-the-Atmosphere (TOA) and surface from the CERES SSF product for a month are sorted by 1-degree spatial regions and by the local hour of observation. The mean of the instantaneous fluxes for a given region-hour bin is determined and recorded on the SFC along with other flux statistics and scene information. These average fluxes are given for both clear-sky and total-sky scenes. The regional cloud properties are column averaged and are included on the SFC. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1998-01-01; Stop_Date=2003-12-31] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=100] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=1 degree; Horizontal_Resolution_Range=100 km - < 250 km or approximately 1 degree - < 2.5 degrees; Temporal_Resolution=1 hour; Temporal_Resolution_Range=Hourly - < Daily].

LIQUID WATER PATH↗

CERES Monthly Gridded Single Satellite TOA and Surfaces/Clouds (SFC) data in HDF (CER_SFC_Terra-FM2-MODIS_Edition2A)

The Monthly Gridded TOA/Surface Fluxes and Clouds (SFC) product contains a month of space and time averaged Clouds and the Earth's Radiant Energy System (CERES) data for a single scanner instrument. The SFC is also produced for combinations of scanner instruments. All instantaneous shortwave, longwave, and window fluxes at the Top-of-the-Atmosphere (TOA) and surface from the CERES SSF product for a month are sorted by 1-degree spatial regions and by the local hour of observation. The mean of the instantaneous fluxes for a given region-hour bin is determined and recorded on the SFC along with other flux statistics and scene information. These average fluxes are given for both clear-sky and total-sky scenes. The regional cloud properties are column averaged and are included on the SFC. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1998-01-01; Stop_Date=2003-12-31] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=100] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=1 degree; Horizontal_Resolution_Range=100 km - < 250 km or approximately 1 degree - < 2.5 degrees; Temporal_Resolution=1 hour; Temporal_Resolution_Range=Hourly - < Daily].

ICE PARTICLE DIAMETER↗

CERES Monthly Gridded Single Satellite TOA and Surfaces/Clouds (SFC) data in HDF (CER_SFC_Terra-FM1-MODIS_Edition2B)

The Monthly Gridded TOA/Surface Fluxes and Clouds (SFC) product contains a month of space and time averaged Clouds and the Earth's Radiant Energy System (CERES) data for a single scanner instrument. The SFC is also produced for combinations of scanner instruments. All instantaneous shortwave, longwave, and window fluxes at the Top-of-the-Atmosphere (TOA) and surface from the CERES SSF product for a month are sorted by 1-degree spatial regions and by the local hour of observation. The mean of the instantaneous fluxes for a given region-hour bin is determined and recorded on the SFC along with other flux statistics and scene information. These average fluxes are given for both clear-sky and total-sky scenes. The regional cloud properties are column averaged and are included on the SFC. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1998-01-01; Stop_Date=2003-10-31] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=100] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=1 degree; Horizontal_Resolution_Range=100 km - < 250 km or approximately 1 degree - < 2.5 degrees; Temporal_Resolution=1 hour; Temporal_Resolution_Range=Hourly - < Daily].

CLEAR-SKY ALBEDO↗

CERES Monthly Gridded Single Satellite TOA and Surfaces/Clouds (SFC) data in HDF (CER_SFC_Terra-FM2-MODIS_Edition2B)

The Monthly Gridded TOA/Surface Fluxes and Clouds (SFC) product contains a month of space and time averaged Clouds and the Earth's Radiant Energy System (CERES) data for a single scanner instrument. The SFC is also produced for combinations of scanner instruments. All instantaneous shortwave, longwave, and window fluxes at the Top-of-the-Atmosphere (TOA) and surface from the CERES SSF product for a month are sorted by 1-degree spatial regions and by the local hour of observation. The mean of the instantaneous fluxes for a given region-hour bin is determined and recorded on the SFC along with other flux statistics and scene information. These average fluxes are given for both clear-sky and total-sky scenes. The regional cloud properties are column averaged and are included on the SFC. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1998-01-01; Stop_Date=2003-10-31] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=100] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=1 degree; Horizontal_Resolution_Range=100 km - < 250 km or approximately 1 degree - < 2.5 degrees; Temporal_Resolution=1 hour; Temporal_Resolution_Range=Hourly - < Daily].

CLOUD INFRARED EMISSIVITY↗

CERES Monthly Gridded Single Satellite TOA and Surfaces/Clouds (SFC) data in HDF (CER_SFC_Terra-FM1-MODIS_Edition2C)

The Monthly Gridded TOA/Surface Fluxes and Clouds (SFC) product contains a month of space and time averaged Clouds and the Earth's Radiant Energy System (CERES) data for a single scanner instrument. The SFC is also produced for combinations of scanner instruments. All instantaneous shortwave, longwave, and window fluxes at the Top-of-the-Atmosphere (TOA) and surface from the CERES SSF product for a month are sorted by 1-degree spatial regions and by the local hour of observation. The mean of the instantaneous fluxes for a given region-hour bin is determined and recorded on the SFC along with other flux statistics and scene information. These average fluxes are given for both clear-sky and total-sky scenes. The regional cloud properties are column averaged and are included on the SFC. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1998-01-01; Stop_Date=2005-12-31] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=100] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=1 degree; Horizontal_Resolution_Range=100 km - < 250 km or approximately 1 degree - < 2.5 degrees; Temporal_Resolution=1 hour; Temporal_Resolution_Range=Hourly - < Daily].

EOSDIS↗

CERES Monthly Gridded Single Satellite TOA and Surfaces/Clouds (SFC) data in HDF (CER_SFC_Terra-FM2-MODIS_Edition2C)

The Monthly Gridded TOA/Surface Fluxes and Clouds (SFC) product contains a month of space and time averaged Clouds and the Earth's Radiant Energy System (CERES) data for a single scanner instrument. The SFC is also produced for combinations of scanner instruments. All instantaneous shortwave, longwave, and window fluxes at the Top-of-the-Atmosphere (TOA) and surface from the CERES SSF product for a month are sorted by 1-degree spatial regions and by the local hour of observation. The mean of the instantaneous fluxes for a given region-hour bin is determined and recorded on the SFC along with other flux statistics and scene information. These average fluxes are given for both clear-sky and total-sky scenes. The regional cloud properties are column averaged and are included on the SFC. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1998-01-01; Stop_Date=2005-12-31] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=100] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=1 degree; Horizontal_Resolution_Range=100 km - < 250 km or approximately 1 degree - < 2.5 degrees; Temporal_Resolution=1 hour; Temporal_Resolution_Range=Hourly - < Daily].

CLEAR-SKY ALBEDO↗

CERES Monthly Gridded Single Satellite TOA and Surfaces/Clouds(SFC) data in HDF (CER_SFC_Aqua-FM3-MODIS_Edition1B)

The Monthly Gridded TOA/Surface Fluxes and Clouds (SFC) product contains a month of space and time averaged Clouds and the Earth's Radiant Energy System (CERES) data for a single scanner instrument. The SFC is also produced for combinations of scanner instruments. All instantaneous shortwave, longwave, and window fluxes at the Top-of-the-Atmosphere (TOA) and surface from the CERES SSF product for a month are sorted by 1-degree spatial regions and by the local hour of observation. The mean of the instantaneous fluxes for a given region-hour bin is determined and recorded on the SFC along with other flux statistics and scene information. These average fluxes are given for both clear-sky and total-sky scenes. The regional cloud properties are column averaged and are included on the SFC. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1998-01-01; Stop_Date=2005-03-31] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=100] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=1 degree; Horizontal_Resolution_Range=100 km - < 250 km or approximately 1 degree - < 2.5 degrees; Temporal_Resolution=1 hour; Temporal_Resolution_Range=Hourly - < Daily].

CLEAR-SKY ALBEDO↗

CERES Monthly Gridded Single Satellite TOA and Surfaces/Clouds(SFC) data in HDF (CER_SFC_Aqua-FM4-MODIS_Edition1B)

The Monthly Gridded TOA/Surface Fluxes and Clouds (SFC) product contains a month of space and time averaged Clouds and the Earth's Radiant Energy System (CERES) data for a single scanner instrument. The SFC is also produced for combinations of scanner instruments. All instantaneous shortwave, longwave, and window fluxes at the Top-of-the-Atmosphere (TOA) and surface from the CERES SSF product for a month are sorted by 1-degree spatial regions and by the local hour of observation. The mean of the instantaneous fluxes for a given region-hour bin is determined and recorded on the SFC along with other flux statistics and scene information. These average fluxes are given for both clear-sky and total-sky scenes. The regional cloud properties are column averaged and are included on the SFC. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1998-01-01; Stop_Date=2005-03-31] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=100] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=1 degree; Horizontal_Resolution_Range=100 km - < 250 km or approximately 1 degree - < 2.5 degrees; Temporal_Resolution=1 hour; Temporal_Resolution_Range=Hourly - < Daily].

CLEAR-SKY LONGWAVE FLUX↗

CERES Monthly Gridded Single Satellite TOA and Surfaces/Clouds (SFC) data in HDF (CER_SFC_Aqua-FM3-MODIS_Edition2A)

The Monthly Gridded TOA/Surface Fluxes and Clouds (SFC) product contains a month of space and time averaged Clouds and the Earth's Radiant Energy System (CERES) data for a single scanner instrument. The SFC is also produced for combinations of scanner instruments. All instantaneous shortwave, longwave, and window fluxes at the Top-of-the-Atmosphere (TOA) and surface from the CERES SSF product for a month are sorted by 1-degree spatial regions and by the local hour of observation. The mean of the instantaneous fluxes for a given region-hour bin is determined and recorded on the SFC along with other flux statistics and scene information. These average fluxes are given for both clear-sky and total-sky scenes. The regional cloud properties are column averaged and are included on the SFC. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1998-01-01; Stop_Date=2005-12-31] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=100] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=1 degree; Horizontal_Resolution_Range=100 km - < 250 km or approximately 1 degree - < 2.5 degrees; Temporal_Resolution=1 hour; Temporal_Resolution_Range=Hourly - < Daily].

CLOUD INFRARED EMISSIVITY↗

CERES Monthly Gridded Single Satellite TOA and Surfaces/Clouds (SFC) data in HDF (CER_SFC_Aqua-FM4-MODIS_Edition2A)

The Monthly Gridded TOA/Surface Fluxes and Clouds (SFC) product contains a month of space and time averaged Clouds and the Earth's Radiant Energy System (CERES) data for a single scanner instrument. The SFC is also produced for combinations of scanner instruments. All instantaneous shortwave, longwave, and window fluxes at the Top-of-the-Atmosphere (TOA) and surface from the CERES SSF product for a month are sorted by 1-degree spatial regions and by the local hour of observation. The mean of the instantaneous fluxes for a given region-hour bin is determined and recorded on the SFC along with other flux statistics and scene information. These average fluxes are given for both clear-sky and total-sky scenes. The regional cloud properties are column averaged and are included on the SFC. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1998-01-01; Stop_Date=2005-03-31] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=100] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=1 degree; Horizontal_Resolution_Range=100 km - < 250 km or approximately 1 degree - < 2.5 degrees; Temporal_Resolution=1 hour; Temporal_Resolution_Range=Hourly - < Daily].

CLOUD INFRARED EMISSIVITY↗

A Historic View of Solar Coronal Mass Ejections (CMEs)

We present a historic overview of CME observations, ending with concepts for future measurement capabilities. One of the first detections of what we now call a CME was provided by instrumentation on OSO-7 and reported by Tousey (1973); but the phrase "corona) mass ejection" was coined after the Skylab/ATM coronagraph detected dozens of the transients over its nine month observing run (e.g., Munro et al., 1979). Pre-discovery identification of likely CMEs were then reported in historic eclipse photographs and drawings (e.g., Eddy, 1974; Cliver, 1989). Multi-year observations followed with groundbased MLSO MK3/4 coronagraph (1980-present), and spacebased missions: Solwind (1979-1985), SMM (1980-1989), SOHO LASCO/EIT (1996-present), SMEI (2003-present), and STEREO SECCHI (2006-present). The Spartan 201 coronagraph flew in space multiple times. The influential Gosling (1993) "solar flare myth" manuscript identified CMEs as the cause of the most severe geomagnetic storms, thus cementing their importance in Sun-Earth connection studies. A new window into CMEs was opened with the launch of SOHO in 1995 when the UVCS spectrometer began returning plasma diagnostics of a significant number of events (e.g., Ciaravella et al., 2006). What about the future for CME research? Statistical properties of the UVCS CME observations are forthcoming; the STEREO mission should continue to return views of CMEs from unique vantage points; and the recent launch of SDO should provide new insights into the small spatial scale dynamics of activity associated with CMEs. Several new observing techniques have been demonstrated at total eclipses, and inclusion on spacebased platforms in the future could also prove valuable for understanding CMEs. A common element of several recent proposals is to image the white-light corona with extremely high spatial resolution. The momentary glimpses of the corona during total solar eclipses have shown fine structure that is not captured by global models, and dynamics of these structured elements may be important to resolve the question of CME initiation.

SaintCyr, Orville C.↗

The CheMin XRD on the Mars Science Laboratory Rover Curiosity: Construction, Operation, and Quantitative Mineralogical Results from the Surface of Mars

The Mars Science Laboratory mission was launched from Cape Canaveral, Florida on Nov. 26, 2011 and landed in Gale crater, Mars on Aug. 6, 2012. MSL's mission is to identify and characterize ancient "habitable" environments on Mars. MSL's precision landing system placed the Curiosity rover within 2 km of the center of its 20 X 6 km landing ellipse, next to Gale's central mound, a 5,000 meter high pile of laminated sediment which may contain 1 billion years of Mars history. Curiosity carries with it a full suite of analytical instruments, including the CheMin X-ray diffractometer, the first XRD flown in space. CheMin is essentially a transmission X-ray pinhole camera. A fine-focus Co source and collimator transmits a 50μm beam through a powdered sample held between X-ray transparent plastic windows. The sample holder is shaken by a piezoelectric actuator such that the powder flows like a liquid, each grain passing in random orientation through the beam over time. Forward-diffracted and fluoresced X-ray photons from the sample are detected by an X-ray sensitive Charge Coupled Device (CCD) operated in single photon counting mode. When operated in this way, both the x,y position and the energy of each photon are detected. The resulting energy-selected Co Kalpha Debye-Scherrer pattern is used to determine the identities and amounts of minerals present via Rietveld refinement, and a histogram of all X-ray events constitutes an X-ray fluorescence analysis of the sample.The key role that definitive mineralogy plays in understanding the Martian surface is a consequence of the fact that minerals are thermodynamic phases, having known and specific ranges of temperature, pressure and composition within which they are stable. More than simple compositional analysis, definitive mineralogical analysis can provide information about pressure/temperature conditions of formation, past climate, water activity and the like. Definitive mineralogical analyses are necessary to establish the origin or provenance of a sample. The search for evidence of extant or extinct life on Mars will initially be a search for evidence of present or past conditions supportive of life (e.g., evidence of water), not for life itself.Results of the first 1,000 sols (Mars days) will be discussed, including the discovery of the first habitable environment on Mars.

CheMin↗

Proton-induced noise in digicons

The Space Telescope, which carries four Digicons, will pass several times per day through a low-altitude portion of the radiation belt called the South Atlantic Anomaly. This is expected to create interference in what is otherwise anticipated to be a noise-free device. Two essential components of the Digicon, the semiconductor diode array and the UV transmitting window, generate noise when subjected to medium-energy proton radiation, a primary component of the belt. These trapped protons, having energies ranging from 2 to 400 Mev and fluences at the Digicon up to 4,000 P+/sec-sq cm, pass through both the window and the diode array, depositing energy in each. In order to evaluate the effect of these protons, engineering test models of Digicon tubes to be flown on the High Resolution Spectrograph were irradiated with low-flux monoenergetic proton beams at the University of Maryland cyclotron. Electron-hole pairs produced by the protons passing through the diodes or the surrounding bulk caused a background count rate. This is the result of holes diffusing over a distance of many diode spacings, causing counts to be triggered simultaneously in the output circuits of several adjacent diodes. Pulse-height spectra of these proton-induced counts indicate that most of the bulk-related counts overlap the single photoelectron peak. A geometrical model will be presented of the charge collection characteristics of the diode array that accounts for most of the observed effects.

Smith, L. C.↗

Approaches for effective negative pressure isolation space control to minimize airborne transmission of contaminants in residential homes

Controlling airborne transmission of contaminants including respired viruses such as SARS-CoV-2 is necessary to protect occupants living in the same house with a contagious person. The effectiveness of interventions requiring minor efforts that create a negative pressure isolation zone (IZ) for a contagious person has yet to be systematically tested for residential homes. In this study, ASHRAE Standard 170, which offers guidance for negative pressure isolation space control in healthcare facilities, was used in developing practical and attainable recommendations for residential single-family homes. The relative effectiveness of several control strategies was evaluated through experimentally conducting 17 different test cases in a manufactured single-family house laboratory. These cases were designed based on various heating, ventilation and air-conditioning (HVAC) operating scenarios, intervention measures including closing the IZ door and/or sealing over supply and return air grilles in the IZ, and utilization of bathroom exhaust or portable window fans for pressure control. Four out of 17 test cases were identified as having the potential for strong containment with adequate depressurization in the IZ. The most effective IZ depressurization was achieved through continuously operating the exhaust fan in the bathroom attached to the IZ, by installing a portable window fan that extracted air out of the IZ, and a portable room air conditioner with the AC unit exhaust duct installed in one of the IZ windows.

Construction & Building Technology↗

Time and Laser Ranging: A Window of Opportunity for Geodesy, Navigation and Metrology

Recent progress in the domain of time and frequency (T/F) standards requires important improvements of existing time distribution links. Among these, the accuracy of time transfer is actually an important part of the concerns in order to establish and maintain time & space references from ground and/or space facilities. Several time transfers by laser link projects have been carried out over the past 10 years with numerous scientific and metrological objectives. Satellite Laser ranging (SLR) has proven to be a fundamental tool, offering a straightforward, conceptually simple, highly accurate and unambiguous observable. Depending on the mission, LR is used to transmit time over two-way or one-way distances from 500 to several millions of km. The following missions and their objectives employed this technique: European Laser Timing (ELT) at 450 km, Time Transfer by Laser Link (T2L2) at 1,336 km, Laser Time Transfer (LTT) at 36,000 km, Lunar Reconnaissance Orbiter (LRO) at 350,000 km, and MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) at tens of million km. This article describes the synergy between SLR and T/F technologies developed on the ground and in space and as well as the state of the art of their exploitation. The performance and sources of limitation of such space missions are analyzed. It shows that current and future challenges lie in the improvement of the time accuracy and stability of the time for ground geodetic observatories. The role of the next generation of SLR systems is emphasized both in space and at ground level, from the point of view of GGOS and valuable exploitation of the synergy between time synchronization, ranging and data transfer.

P. Exertier↗

Sleep, Circadian Rhythms, and Performance During Space Shuttle Missions

Sleep and circadian rhythms may be disturbed during spaceflight, and these disturbances can affect crewmembers' performance during waking hours. The mechanisms underlying sleep and circadian rhythm disturbances in space are not well understood, and effective countermeasures are not yet available. We investigated sleep, circadian rhythms, cognitive performance, and light-dark cycles in five astronauts prior to, during, and after the 16-day STS-90 mission and the IO-day STS-95 mission. The efficacy of low-dose, alternative-night, oral melatonin administration as a countermeasure for sleep disturbances was evaluated. During these missions, scheduled rest activity cycles were 20-35 minutes shorter than 24 hours. Light levels on the middeck and in the Spacelab were very low; whereas on the flight deck (which has several windows), they were highly variable. Circadian rhythm abnormalities were observed. During the second half of the missions, the rhythm of urinary cortisol appeared to be delayed relative to the sleep-wake schedule. Performance during wakefulness was impaired. Astronauts slept only about 6.5 hours per day, and subjective sleep quality was lower in space. No beneficial effects of melatonin (0.3 mg administered prior to sleep episodes on alternate nights) were observed. A surprising finding was a marked increase in rapid eye movement (REM) sleep upon return to Earth. We conclude that these Space Shuttle missions were associated with circadian rhythm disturbances, sleep loss, decrements in neurobehavioral performance, and alterations in REM sleep homeostasis. Shorter than 24-hour rest-activity schedules and exposure to light-dark cycles inadequate for optimal circadian synchronization may have contributed to these disturbances.

Neri, David F.↗

High field electron paramagnetic resonance spectroscopy under ultrahigh vacuum conditions—A multipurpose machine to study paramagnetic species on well defined single crystal surfaces

A new ultrahigh vacuum (UHV) electron paramagnetic resonance (EPR) spectrometer operating at 94 GHz to investigate paramagnetic centers on single crystal surfaces is described. It is particularly designed to study paramagnetic centers on well-defined model catalysts using epitaxial thin oxide films grown on metal single crystals. The EPR setup is based on a commercial Bruker E600 spectrometer, which is adapted to ultrahigh vacuum conditions using a home made Fabry Perot resonator. The key idea of the resonator is to use the planar metal single crystal required to grow the single crystalline oxide films as one of the mirrors of the resonator. EPR spectroscopy is solely sensitive to paramagnetic species, which are typically minority species in such a system. Hence, additional experimental characterization tools are required to allow for a comprehensive investigation of the surface. The apparatus includes a preparation chamber hosting equipment, which is required to prepare supported model catalysts. In addition, surface characterization tools such as low energy electron diffraction (LEED)/Auger spectroscopy, temperature programmed desorption (TPD), and infrared reflection absorption spectroscopy (IRAS) are available to characterize the surfaces. A second chamber used to perform EPR spectroscopy at 94 GHz has a room temperature scanning tunneling microscope attached to it, which allows for real space structural characterization. The heart of the UHV adaptation of the EPR experiment is the sealing of the Fabry-Perot resonator against atmosphere. To this end it is possible to use a thin sapphire window glued to the backside of the coupling orifice of the Fabry Perot resonator. With the help of a variety of stabilization measures reducing vibrations as well as thermal drift it is possible to accumulate data for a time span, which is for low temperature measurements only limited by the amount of liquid helium. Test measurements show that the system can detect paramagnetic species with a density of approximately 5 × 10{sup 11} spins/cm{sup 2}, which is comparable to the limit obtained for the presently available UHV-EPR spectrometer operating at 10 GHz (X-band). Investigation of electron trapped centers in MgO(001) films shows that the increased resolution offered by the experiments at W-band allows to identify new paramagnetic species, that cannot be differentiated with the currently available methodology.

36 MATERIALS SCIENCE↗