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At least 811 records · Page 45

Enhancement of oxygen vacancies and solar photocatalytic activity of zinc oxide by incorporation of nonmetal

B-doped ZnO and N-doped ZnO powders have been synthesized by mechanochemical method and characterized by TG-DTA, XRD, SEM-EDX, XPS, UV-visible and photoluminescence (PL) spectra. X-ray diffraction data suggests the hexagonal wurtzite structure for modified ZnO crystallites and the incorporation of nonmetal expands the lattice constants of ZnO. The room temperature PL spectra suggest more number of oxygen vacancies exist in nonmetal-doped ZnO than that of undoped zinc oxide. XPS analysis shows the substitution of some of the O atoms of ZnO by nonmetal atoms. Solar photocatalytic activity of B-doped ZnO, N-doped ZnO and undoped ZnO was compared by means of oxidative photocatalytic degradation (PCD) of Bisphenol A (BPA). B-doped ZnO showed better solar PCD efficiency as compare to N-doped ZnO and undoped ZnO. The PCD of BPA follows first order reaction kinetics. The detail mechanism of PCD of Bisphenol A was proposed with the identification of intermediates such as hydroquinone, benzene-1,2,4-triol and 4-(2-hydroxypropan-2-yl) phenol. - Graphical Abstract: B-doped ZnO and N-doped ZnO synthesized by mechanochemical method were characterized by various techniques. Solar photocatalytic degradation of Bisphenol-A is in the order of B-ZnO>N-ZnO>ZnO. Highlights: Black-Right-Pointing-Pointer B-doped ZnO and N-doped ZnO powders have been synthesized by mechanochemical method. Black-Right-Pointing-Pointer PL spectra suggest oxygen vacancies are in order of B-doped ZnO>N-doped ZnO>ZnO. Black-Right-Pointing-Pointer Solar PCD efficiency is in order of B-doped ZnO>N-doped ZnO>ZnO for Bisphenol A.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Radiation Environment in Free Space and Inside Low-Earth Spacecraft's

There are three main sources of radiation in free space. These are the trapped protons and electrons, solar energetic particles, and the galactic cosmic rays. For human mission to Mars or moon, the trapped protons and electrons are of a minor concern. The flux of trapped particles at a fixed spacecraft altitude, and of galactic cosmic rays, decreases as the solar activity increases; however, the probability of a solar particle event increases as the solar activity increases. As these particles interact with the shielding material of the spacecraft and human body, they produce secondary particles, such as lighter fragments, target fragments, and neutrons. These particles can have far more damaging effect on cells than the primary particles. Thus, the radiation environment is very complex and varies with time. In this paper, we review the sources of charged-particles that contribute significantly to radiation risk to the astronauts, and estimates of exposure for some typical missions, such as Space Shuttle, International Space Station, and a human mission to Mars.

Badhwar, Gautam D.↗

Solar cycle effects on the structure of the electron density profiles in the dayside ionosphere of Venus

Results are presented of observations from the changes in the electron density structure of the dayside ionosphere of Venus that were brought about by changing solar activity. The ionopause height is generally low for values of the solar zenith angle below about 50 deg regardless of the phase in the solar cycle. At solar maximum, and at times of intermediate solar activity, the ionopause height for solar zenith angles greater than about 50 deg is highly variable, ranging from a minimum of about 200 km to a maximum of more than 1000 km. At times of solar minimum the great majority of all ionopause heights for all solar zenith angles are uniformly low, lying between 200 and 300 km. It is argued that the compressed nature of the Venus atmosphere at solar minimum is produced by permeation of the ionosphere by the solar wind magnetic field, which occurs when the solar wind dynamic pressure exceeds the ionospheric plasma pressure.

Kliore, Arvydas J.↗

Drift effects on the galactic cosmic ray modulation

Cosmic ray (CR) modulation is driven by both solar activity and drift effects in the heliosphere, although their role is only qualitatively understood as it is difficult to connect the CR variations to their sources. In order to address this problem, the Empirical Mode Decomposition technique has been applied to the CR intensity, recorded by three neutron monitors at different rigidities (Climax, Rome, and Huancayo-Haleakala (HH)), the sunspot area, as a proxy for solar activity, the heliospheric magnetic field magnitude, directly related to CR propagation, and the tilt angle (TA) of the heliospheric current sheet (HCS), which characterizes drift effects on CRs. A prominent periodicity at ∼six years is detected in all the analyzed CR data sets and it is found to be highly correlated with changes in the HCS inclination at the same timescale. In addition, this variation is found to be responsible for the main features of the CR modulation during periods of low solar activity, such as the flat (peaked) maximum in even (odd) solar cycles. The contribution of the drift effects to the global Galactic CR modulation has been estimated to be between 30% and 35%, depending on the CR particle energy. Nevertheless, the importance of the drift contribution is generally reduced in periods nearing the sunspot maximum. Finally, threshold values of ∼40°, ∼45°, and >55° have been derived for the TA, critical for the CR modulation at the Climax, Rome, and HH rigidity thresholds, respectively.

79 ASTRONOMY AND ASTROPHYSICS↗

MAGNETIC FLUX DENSITY MEASURED IN FAST AND SLOW SOLAR WIND STREAMS

The radial component of the heliospheric magnetic field vector is used to estimate the open magnetic flux density of the Sun. This parameter has been calculated using observations from the Ulysses mission that covered heliolatitudes from 80 Degree-Sign S to 80 Degree-Sign N, from 1990 to 2009 and distances from 1 to 5.4 AU, the Advanced Composition Explorer mission at 1 AU from 1997 to 2010, the OMNI interplanetary database from 1971, and the Helios 1 and 2 missions that covered the distance range from 0.3 to 1 AU. The flux density was found to be much affected by fluctuations in the magnetic field which make its calculated value dependent on heliospheric location, type of solar wind (fast or slow), and the level of solar activity. However, fluctuations are distributed symmetrically perpendicular to the average Parker direction. Therefore, distributions of the field vector in the two-dimensional plane defined by the radial and azimuthal directions in heliospheric coordinates provide a way to reduce the effects of the fluctuations on the measurement of the flux density. This leads to a better defined flux density parameter; the distributions modified by removing the effects of fluctuations then allow a clearer assessment of the dependence of the flux density on heliospheric location, solar wind type, and solar activity. This assessment indicates that the flux density normalized to 1 AU is independent of location and solar wind type (fast or slow). However, there is a residual dependence on solar activity which can be studied using the modified flux density measurements.

79 ASTRONOMY AND ASTROPHYSICS↗

Probabilistic Model for Low Altitude Trapped Proton Fluxes

A new approach is developed for the assessment of low altitude trapped proton fluxes for future space missions. Low altitude fluxes are dependent on solar activity levels due to the resulting heating and cooling of the upper atmosphere. However, solar activity levels cannot be accurately predicted far enough into the future to accommodate typical spacecraft mission planning. Thus, the approach suggested here is to evaluate the trapped proton flux as a function of confidence level for a given mission time period. This is possible because of a recent advance in trapped proton modeling that uses the solar 10.7 cm radio flux, a measure of solar cycle activity, to calculate trapped proton fluxes as a continuous function of time throughout the solar cycle. This trapped proton model is combined with a new statistical description of the 10.7 cm flux to obtain the probabilistic model for low altitude trapped proton fluxes. Results for proton energies ranging from 1.5 to 81.3 MeV are examined as a function of time throughout solar cycle 22 for various orbits. For altitudes below 1000 km, fluxes are significantly higher and energy spectra are significantly harder than those predicted by the AP8 model.

Xapsos, M. A.↗

EVIDENCE FOR GENTLY SLOPING PLASMA DENSITY PROFILES IN THE DEEP CORONA: TYPE III OBSERVATIONS

Type III radio bursts are produced near the local electron plasma frequency f{sub p} and near its harmonic 2f{sub p} by fast electrons ejected from the solar active regions and moving through the corona and solar wind. The coronal bursts have dynamic spectra with frequency rapidly falling with time, the typical duration being about 1-3 s. In the present paper, 37 well-defined coronal type III radio bursts (25-450 MHz) are analyzed. The results obtained substantiate an earlier statement that the dependence of the central frequency of the emission on time can be fitted to a power-law model, f(t) {proportional_to} (t - t{sub 0}){sup -{alpha}}, where {alpha} can be as low as 1. In the case of negligible plasma acceleration and conical flow, it means that the electron number density within about 1 solar radius above the photosphere will decrease as r {sup -2}, like in the solar wind. For the data set chosen, the index {alpha} varies in the range from 0.2 to 7 or bigger, with mean and median values of 1.2 and 0.5, respectively. A surprisingly large fraction of events, 84%, have {alpha} {<=} 1.2. These results provide strong evidence that in the type III source regions the electron number density scales as n(r) {proportional_to} (r - r{sub 0}){sup -{beta}}, with minimum, mean, and median {beta} = 2{alpha} of 0.4, 2.4, and 1.0, respectively. Hence, the typical density profiles are more gently sloping than those given by existing empirical coronal models. Several events are found with a wind-like dependence of burst frequency on time. Smaller power-law indices could result from the effects of non-conical geometry of the plasma flow tubes, deceleration of coronal plasma, and/or the curvature of the magnetic field lines. The last effect is shown to be too weak to explain such low power-law indices. A strong tendency is found for bursts from the same group to have similar power-law indices, thereby favoring the hypothesis that they are usually produced by the same source region.

79 ASTRONOMY AND ASTROPHYSICS↗

How Does the Sun's Spectrum Vary?

Recent observations made by the Spectral Irradiance Monitor (SIM) on the Solar Radiation and Climate Experiment (SORCE) spacecraft suggest that the Sun's visible and infrared spectral irradiance increased from 2004 to 2008, even as the total solar irradiance measured simultaneously by SORCE's Total Irradiance Monitor (TIM) decreased. As well, solar ultraviolet (UV) irradiance decreased 3 to 10 times more than expected from prior observations and model calculations of the known effects of sunspot and facular solar features. Analysis of the SIM spectral irradiance observations during the solar minimum epoch of 2008, when solar activity was essentially invariant, exposes trends in the SIM observations relative to both total solar irradiance and solar activity that are unlikely solar in origin. We suggest that the SIM's radically different solar variability characterization is a consequence of undetected instrument sensitivity drifts, not true solar spectrum changes. It is thus doubtful that simulations of climate and atmospheric change using SIM measurements are indicative of real behavior in the Earth's climate and atmosphere.

Lean, Judith L.↗

Self-consistent simulation of CdTe solar cells with active defects

We demonstrate a self-consistent numerical scheme for simulating an electronic device which contains active defects. As a specific case, we consider copper defects in cadmium telluride solar cells. The presence of copper has been shown experimentally to play a crucial role in predicting device performance. The primary source of this copper is migration away from the back contact during annealing, which likely occurs predominantly along grain boundaries. We introduce a mathematical scheme for simulating this effect in 2D and explain the numerical implementation of the system. Finally, we will give numerical results comparing our results to known 1D simulations to demonstrate the accuracy of the solver and then show results unique to the 2D case.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Solar plages and the vorticity of the earth's atmosphere

Three superimposed epoch analyses of the vorticity area index (VAI) at 500 mbar are described. The analyses used the following definitions of the zero days: (1) the central meridian passage (CMP) of very active solar plages; (2) the occurrence of peak values of the 10.7 cm solar radio flux; and (3) the CMP of active solar plages also accompanied at CMP by sharp rises in 10.7 cm solar radio noise. All three superimposed epoch analyses show a sustained rise in VAI several days before the zero day; the rise continues through the zero day and is followed by a sustained minimum in VAI several days after the zero day. The results suggest that the location of the very active plages play an important role in determining their meteorological influence. It is possible that the initial rise in VAI is caused by enhanced electromagnetic radiation associated with the solar activity, and that the decrease some days later is the result of the geomagnetic storm particle emission that generally follows the zero date.

Olson, R. H.↗

Radiation Measured with Different Dosimeters for ISS-Expedition 18-19/ULF2 on Board International Space Station during Solar Minimum

Radiation field of particles in low Earth orbit (LEO) is mainly composed of galactic cosmic rays (GCR), solar energetic particles and particles in SAA (South Atlantic Anomaly). GCR are modulated by solar activity, at the period of solar minimum activity, GCR intensity is at maximum and the main contributor for space radiation is GCR. At present for space radiation measurements conducted by JSC (Johnson Space Center) SRAG (Space Radiation Analysis Group), the preferred active dosimeter sensitive to all LET (Linear Energy Transfer) is the tissue equivalent proportional counter (TEPC); the preferred passive dosimeters are thermoluminescence dosimeters (TLDs) and optically stimulated luminescence dosimeters (OSLDs) sensitive to low LET as well as CR-39 plastic nuclear track detectors (PNTDs) sensitive to high LET. For the method using passive dosimeters, radiation quantities for all LET can be obtained by combining radiation results measured with TLDs/OSLDs and CR-39 PNTDs. TEPC, TLDs/OSLDs and CR-39 detectors were used to measure the radiation field for the ISS (International Space Station) - Expedition 18-19/ULF2 space mission which was conducted from 15 November 2008 to 31 July 2009 - near the period of the recent solar minimum activity. LET spectra (differential and integral fluence, absorbed dose and dose equivalent) and radiation quantities were measured for positions TEPC, TESS (Temporary Sleeping Station, inside the polyethylene lined sleep station), SM-P 327 and 442 (Service Module - Panel 327 and 442). This paper presents radiation LET spectra measured with TEPC and CR-39 PNTDs and radiation dose measured with TLDs/OSLDs as well as the radiation quantities combined from results measured with passive dosimeters.

Zhou, Dazhuang↗

DMSP Auroral Charging at Solar Cycle 24 Maximum

It has been well established that polar orbiting satellites can experience mild to severe auroral charging levels (on the order of a few hundred volts to few kilovolts negative frame potentials) during solar minimum conditions (Frooninckx and Sojka, 1992; Anderson and Koons, 1996; Anderson, 2012). These same studies have shown a strong reduction in charging during the rising and declining phases of the past few solar cycles with a nearly complete suppression of auroral charging at solar maximum. Recently, we have observed examples of high level charging during the recent approach to Solar Cycle 24 solar maximum conditions not unlike those reported by Frooninckx and Sojka (1992). These observations demonstrate that spacecraft operations during solar maximum cannot be considered safe from auroral charging when solar activity is low. We present a survey of auroral charging events experienced by the Defense Meteorological Satellite Program (DMSP) F16 satellite during Solar Cycle 24 maximum conditions. We summarize the auroral energetic particle environment and the conditions necessary for charging to occur in this environment, we describe how the lower than normal solar activity levels for Solar Cycle 24 maximum conditions are conducive to charging in polar orbits, and we show examples of the more extreme charging events, sometimes exceeding 1 kV, during this time period.

Chandler, Michael↗

DMSP Auroral Charging at Solar Cycle 24 Maximum

It has been well established that polar orbiting satellites can experience mild to severe auroral charging levels (on the order of a few hundred volts to few kilovolts negative frame potentials) during solar minimum conditions. These same studies have shown a strong reduction in charging during the rising and declining phases of the past few solar cycles with a nearly complete suppression of auroral charging at solar maximum. Recently, we have observed examples of high level charging during the recent approach to Solar Cycle 24 solar maximum conditions not unlike those reported by Frooninckx and Sojka. These observations demonstrate that spacecraft operations during solar maximum cannot be considered safe from auroral charging when solar activity is low. We present a survey of auroral charging events experienced by the Defense Meteorological Satellite Program (DMSP) F16 satellite during Solar Cycle 24 maximum conditions. We summarize the auroral energetic particle environment and the conditions necessary for charging to occur in this environment, we describe how the lower than normal solar activity levels for Solar Cycle 24 maximum conditions are conducive to charging in polar orbits, and we show examples of the more extreme charging events, sometimes exceeding 1 kV, during this time period.

Chandler, M.↗

An overview of the solar maximum mission

The Solar Maximum Mission (SMM), devoted to the study of active solar phenomena is expected to be launched in February 1980 and operate throughout the peak of the current maximum of solar activity. The SMM observatory consists of two main sections: the instrument module which houses the solar payload instruments and the Fine Pointing Sun Sensor System, and the Multimission Modular Spacecraft (MMS) which carries the spacecraft subsystem modules. The entire observatory is 4m long and 2.3m in diameter. The SMM will carry a payload of six instruments specifically selected to study the short wavelength and coronal manifestations of flares. These include: gamma ray spectrometer, hard X-ray burst spectrometer, hard-X-ray imaging spectrometer, soft X-ray polychromator, UV spectrometer and polarimeter, coronagraph/polarimeter and solar constant monitoring package which will measure the total solar irradiance to an accuracy of 0.1 percent. Specific scientific objectives will include: chromospheric evaporation, thermalization, electron acceleration and flare build-up. Complementary studies will be made as part of an SMM Guest Investigator Program. The SMM observation program will be operated on a 24 hour cycle.

Chipman, E. C.↗

Use of Apollo 17 Epoch Neutron Spectrum as a Benchmark in Testing LEND Collimated Sensor

The Apollo 17 neutron experiment LPNE provided a unique set of data on production of neutrons in the Lunar soil bombarded by Galactic Cosmic Rays (GCR). It serves as valuable "ground-truth" in the age of orbital remote sensing. We used the neutron data attributed to Apollo 17 epoch as a benchmark for testing the LEND's collimated sensor, as introduced by the geometry of collimator and efficiency of He3 counters. The latter is defined by the size of gas counter and pressure inside it. The intensity and energy spectrum of neutrons escaping the lunar surface are dependent on incident flux of Galactic Cosmic Rays (GCR) whose variability is associated with Solar Cycle and its peculiarities. We obtain first the share of neutrons entering through the field of view of collimator as a fraction of the total neutron flux by using the angular distribution of neutron exiting the Moon described by our Monte Carlo code. We computed next the count rate of the 3He sensor by using the neutron energy spectrum from McKinney et al. [JGR, 2006] and by consider geometry and gas pressure of the LEND sensor. Finally the neutron count rate obtained for the Apollo 17 epoch characterized by intermediate solar activity was adjusted to the LRO epoch characterized by low solar activity. It has been done by taking into account solar modulation potential, which affects the GCR flux, and in turn changes the neutron albedo flux.

Chin, Gordon↗

Passive dosimetry aboard the Mir Orbital Station: internal measurements

Passive radiation dosimeters were exposed aboard the Mir Orbital Station over a substantial portion of the solar cycle in order to measure the change in dose and dose equivalent rates as a function of time. During solar minimum, simultaneous measurements of the radiation environment throughout the habitable volume of the Mir were made using passive dosimeters in order to investigate the effect of localized shielding on dose and dose equivalent. The passive dosimeters consisted of a combination of thermoluminescent detectors to measure absorbed dose and CR-39 PNTDs to measure the linear energy transfer (LET) spectrum from charged particles of LET infinity H2O > or = 5 keV/micrometers. Results from the two detector types were then combined to yield mean total dose rate, mean dose equivalent rate, and average quality factor. Contrary to expectations, both dose and dose equivalent rates measured during May-October 1991 near solar maximum were higher than similar measurements carried out in 1996-1997 during solar minimum. The elevated dose and dose equivalent rates measured in 1991 were probably due to a combination of intense solar activity, including a large solar particle event on 9 June 1991, and the temporary trapped radiation belt created in the slot region by the solar particle event and ensuing magnetic storm of 24 March 1991. During solar minimum, mean dose and dose equivalent rates were found to vary by factors of 1.55 and 1.37, respectively, between different locations through the interior of Mir. More heavily shielded locations tended to yield lower total dose and dose equivalent rates, but higher average quality factor than did more lightly shielding locations. However, other factors such as changes in the immediate shielding environment surrounding a given detector location, changes in the orientation of the Mir relative to its velocity vector, and changes in the altitude of the station also contributed to the variation. Proton and neutron-induced target fragment secondaries, not primary galactic cosmic rays, were found to dominate the LET spectrum above 100 keV/micrometers. This indicates that in low earth orbit, trapped protons in the South Atlantic Anomaly are responsible for the major fraction of the total dose equivalent. c2002 Elsevier Science Ltd. All rights reserved.

NASA Experiment Number 9401620↗

Primary Cosmic Ray and Solar Protons II

During July and August 1961 the energy spectrum of primary cosmic ray protons was investigated in the energy range from 80 to 350 MeV. The observations were made in five high altitude balloon flights at geomagnetic latitudes lambda is greater than 73 degrees N. Solar flare and quiet day spectra were obtained. A comparison of the 1960 and 1961 results leads to the conclusions that, 1. A significant flux of low energy protons is continually present in the primary radiation in the years of high solar activity; 2. This flux decreases with the declining level of solar activity as the galactic cosmic ray flux increases, It is, therefore, suggested that it is of solar origin; 3. The time dependence of the observed proton flux suggests the following alternatives: a) The particles are produced or released more or less continuously by the sun and do not originate only in the large flare events; or b) The particles are produced in individual large solar flares and subsequently stored over long periods of time. This second alternative would require a new and as yet unknown storage mechanism with a characteristic time of about 30 or more days.

BALLOON FLIGHT↗

DOUBLE DYNAMO SIGNATURES IN A GLOBAL MHD SIMULATION AND MEAN-FIELD DYNAMOS

The 11 year solar activity cycle is the most prominent periodic manifestation of the magnetohydrodynamical (MHD) large-scale dynamo operating in the solar interior, yet longer and shorter (quasi-) periodicities are also present. The so-called “quasi-biennial” signal appearing in many proxies of solar activity has been gaining increasing attention since its detection in p -mode frequency shifts, which suggests a subphotospheric origin. A number of candidate mechanisms have been proposed, including beating between co-existing global dynamo modes, dual dynamos operating in spatially separated regions of the solar interior, and Rossby waves driving short-period oscillations in the large-scale solar magnetic field produced by the 11 year activity cycle. In this article, we analyze a global MHD simulation of solar convection producing regular large-scale magnetic cycles, and detect and characterize shorter periodicities developing therein. By constructing kinematic mean-field α {sup 2}Ω dynamo models incorporating the turbulent electromotive force (emf) extracted from that same simulation, we find that dual-dynamo behavior materializes in fairly wide regions of the model’s parameters space. This suggests that the origin of the similar behavior detected in the MHD simulation lies with the joint complexity of the turbulent emf and differential rotation profile, rather that with dynamical interactions such as those mediated by Rossby waves. Analysis of the simulation also reveals that the dual dynamo operating therein leaves a double-period signature in the temperature field, consistent with a dual-period helioseismic signature. Order-of-magnitude estimates for the magnitude of the expected frequency shifts are commensurate with helioseismic measurements. Taken together, our results support the hypothesis that the solar quasi-biennial oscillations are associated with a secondary dynamo process operating in the outer reaches of the solar convection zone.

79 ASTRONOMY AND ASTROPHYSICS↗