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At least 811 records · Page 45

Environmental Conditions Affecting Global Mesoscale Convective System Occurrence

Abstract The ERA5 environments of mesoscale convective systems (MCSs), tracked from satellite observations, are assessed over a 20-yr period. The use of a large set of MCS tracks allows us to robustly test the sensitivity of the results to factors such as region, latitude, and diurnal cycle. We aim to provide novel information on environments of observed MCSs for assessments of global atmospheric models and to improve their ability to simulate MCSs. Statistical analysis of all tracked MCSs is performed in two complementary ways. First, we investigate the environments when an MCS has occurred at different spatial scales before and after MCS formation. Several environmental variables are found to show marked changes before MCS initiation, particularly over land. The vertically integrated moisture flux convergence shows a robust signal across different regions and when considering MCS initiation diurnal cycle. We also found spatial scale dependence of the environments between 200 and 500 km, providing new evidence of a natural length scale for use with MCS parameterization. In the second analysis, the likelihood of MCS occurrence for given environmental conditions is evaluated, by considering all environments and determining the probability of being in an MCS core or shield region. These are compared to analogous non-MCS environments, allowing discrimination between conditions suitable for MCS and non-MCS occurrence. Three environmental variables are found to be useful predictors of MCS occurrence: total column water vapor, midlevel relative humidity, and total column moisture flux convergence. Such relations could be used as trigger conditions for the parameterization of MCSs, thereby strengthening the dependence of the MCS scheme on the environment. Significance Statement Large storm systems called mesoscale convective systems form across Earth. These are collections of thunderstorms, with associated high-level clouds that produce substantial, lighter rainfall and modulate Earth’s energy balance. They produce hazardous weather conditions, such as floods and high winds, and are responsible for a high percentage of rainfall in many regions globally. We investigate the environmental conditions under which they form, so that we can understand the spatial extent of the environment which is important for their formation, and also where and when the effects of these storms might be felt. The novel information generated here should help improve the representation of these storms in weather and climate models, improving the prediction of rainfall, thunderclouds, and high-level clouds.

54 ENVIRONMENTAL SCIENCES↗

Identifying Basic Factors for Communal Prosperity - Space Technologies are Bridging this Gap

There are many aspects, which are important for maintaining environmentally clean and safe conditions for a healthy and economically self-sufficient community. This problem was somewhat of a lesser concern in earlier days because many communities were small, isolated and solely dependent upon their owners or landlords. Due to an astronomical growth in human population within the last century, extensive use of combustion technologies, and changing environmental conditions has resulted in scarcity of natural resources. In reality, the societal sustainability issues are becoming much more acute and complex. Therefore, the researchers and social scientists are joining forces to address these topics and find solutions to many contentious areas such as public health and diseases, water resources, agriculture production, survivability during and after the natural disasters, energy needs and many others. Forthrightly speaking, there is no canned solution or a methodology to go about solving these issues since the magnitude and complexity of these issues are multi-dimensional and are further inter-locked with other areas. A common sense tells us that we need data, resources and technologies to begin addressing these problems. This is where space observations have provided us with tremendous information and opportunities, which are of great assets to the science, economist, and social scientists. This paper specifically addresses what are critical areas for a successful societal sustainability and growth; and how can we take advantage of multiple sensors and models already in existence. Increasing our knowledge of the home planet, via amplified set of observations, is certainly a right step in a right direction. Furthermore, this is a pre-requisite in understanding multiple hazard phenomena's. This paper further examines various space sensors and observing architectures that can be useful specifically in addressing some of these complex issues. The ultimate goal is to serve the society by providing such valuable information so the decision makers can take full advantage in making timely societal decisions.

Habib, Shahid↗

Multi-Partner Experiment to Test Volcanic-Ash Ingestion by a Jet Engine

A research team of U.S. Government agencies and engine manufacturers are designing an experiment to test volcanic-ash ingestion by a NASA owned F117 engine that was donated by the U.S. Air Force. The experiment is being conducted under the auspices of NASA s Vehicle Integrated Propulsion Research (VIPR) Program and will take place in early 2014 at Edwards AFB in California as an on-ground, on-wing test. The primary objectives are to determine the effect on the engine of several hours of exposure to low to moderate ash concentrations, currently proposed at 1 and 10 mg/m3 and to evaluate the capability of engine health management technologies for detecting these effects. A natural volcanic ash will be used that is representative of distal ash clouds many 100's to approximately 1000 km from a volcanic source i.e., the ash should be composed of fresh glassy particles a few tens of microns in size. The glassy ash particles are expected to soften and become less viscous when exposed to the high temperatures of the combustion chamber, then stick to the nozzle guide vanes of the high-pressure turbine. Numerous observations and measurements of the engine s performance and degradation will be made during the course of the experiment, including borescope and tear-down inspections. While not intended to be sufficient for rigorous certification of engine performance when ash is ingested, the experiment should provide useful information to aircraft manufacturers, airline operators, and military and civil regulators in their efforts to evaluate the range of risks that ash hazards pose to aviation.

Lekki, John↗

Investigation of arc cloud lines

The natural mechanisms that lead to the development of deep convective storms through the integration of radio scan satellite data with research aircraft observations is discussed. The aircraft measurements are designed to provide detailed air motion and thermodynamic data near and in the arc cloud line region at the same time GOES rapid scan data is taken. Inspection of the data indicates: (1) Arc cloud lines are important in both the production of convergence and vorticity, and in the interaction with intense thunderstorms which may act to trigger tornado activity. (2) The lateral extent of the vertical motion field compared to the cloud scale indicates that the main driving force for the initial cloud development along the arc-line is controlled by the thunderstorm outflow(s) interacting with the convectively unstable air of the environment. (3) Arc cloud lines and their associated DSL region can pose extreme hazards to aircraft operations. (4) An arc cloud line's major threat to space shuttle operations lie in its ability to generate new thunderstorm activity along the shuttle glide path.

Purdom, J. F. W.↗

Microbial Risk Assessment

Historically, microbiological spaceflight requirements have been established in a subjective manner based upon expert opinion of both environmental and clinical monitoring results and the incidence of disease. The limited amount of data, especially from long-duration missions, has created very conservative requirements based primarily on the concentration of microorganisms. Periodic reevaluations of new data from later missions have allowed some relaxation of these stringent requirements. However, the requirements remain very conservative and subjective in nature, and the risk of crew illness due to infectious microorganisms is not well defined. The use of modeling techniques for microbial risk has been applied in the food and potable water industries and has exceptional potential for spaceflight applications. From a productivity standpoint, this type of modeling can (1) decrease unnecessary costs and resource usage and (2) prevent inadequate or inappropriate data for health assessment. In addition, a quantitative model has several advantages for risk management and communication. By identifying the variable components of the model and the knowledge associated with each component, this type of modeling can: (1) Systematically identify and close knowledge gaps, (2) Systematically identify acceptable and unacceptable risks, (3) Improve communication with stakeholders as to the reasons for resource use, and (4) Facilitate external scientific approval of the NASA requirements. The modeling of microbial risk involves the evaluation of several key factors including hazard identification, crew exposure assessment, dose-response assessment, and risk characterization. Many of these factors are similar to conditions found on Earth; however, the spaceflight environment is very specialized as the inhabitants live in a small, semi-closed environment that is often dependent on regenerative life support systems. To further complicate modeling efforts, microbial dose-response characteristics may be affected by a potentially dysfunctional crew immune system during a mission. In addition, microbial virulence has been shown to change under certain conditions during spaceflight, further complicating dose-response characterization. An initial study of the applicability of microbial risk assessment techniques was performed using Crew Health Care System (CHeCS) operational data from the International Space Station potable water systems. The risk of infection from potable water was selected as the flight systems and microbial ecology are well defined. This initial study confirmed the feasibility of using microbial risk assessment modeling for spaceflight systems. While no immediate threat was detected, the study identified several medically significant microorganisms that could pose a health risk if uncontrolled. The study also identified several specific knowledge gaps in making a risk assessment and noted that filling these knowledge gaps is essential as the risk estimates may change by orders of magnitude depending on the answers. The current phase of the microbial risk assessment studies focuses on the dose-response relationship of specific infectious agents, focusing on Salmonella enterica Typhimurium, Pseudomonas spp., and Escherichia coli, as their evaluation will provide a better baseline for determining the overall hazard characterization. The organisms were chosen as they either have been isolated on spacecraft or have an identified route of infection during a mission. The characterization will utilize dose-response models selected either from the peer-reviewed literature and/or by using statistical approaches. Development of these modeling and risk assessment techniques will help to optimize flight requirements and to protect the safety, health, and performance of the crew.

Ott, C. M.↗

Evaluation of Risk Acceptance Criteria for Transporting Hazardous Materials

This report reviews and offers recommendations from Sandia National transportation of hazardous materials in the U.S. The risk criteria should be used with the results of a quantitative risk assessment (QRA) in risk acceptance decision-making. The QRA for transportation is fundamentally the same as a fixed facility. However, there are differences in calculations of both the probabilities of occurrence and location of hazards. Involuntary individual fatality risk is recommended to be acceptable for annual probabilities of less than 3 x 10 -7 for any population, including vulnerable populations, and may be considered acceptable at the regulators discretion for non-sensitive/non-vulnerable populations if less than 5 x 10 -5 and demonstrated to be as low as reasonably practicable (ALARP). Societal risk is recommended to be acceptable if the annual frequency of events that would result in N or more fatalities is less than 10 -5 /N events per year and may be considered acceptable at the regulators discretion if less than 10 -3 /N events per year and demonstrated to be ALARP. These criteria should be applied to the societal risk over the entire transportation route, not normalized per-distance. These values are adapted from the National Fire Protection Association (NFPA) 59A, a U.S. and international standard for liquefied natural gas (LNG) facility siting.

54 ENVIRONMENTAL SCIENCES↗

Ignition and subsequent transition to flame spread in a microgravity environment

The fire safety strategy in a spacecraft is (1) to detect any fire as early as possible, (2) to keep any fire as small as possible, and (3) to extinguish any fire as quickly as possible. This suggests that a material which undergoes a momentary, localized ignition might be tolerable but a material which permits a transition to flame spread would significantly increase the fire hazard. Therefore, it is important to understand how the transition from localized ignition to flame spread occurs and what parameters significantly affect the transition. The fundamental processes involved in ignition and flame spread have been extensively studied, but they have been studied separately. Some of the steady state flame models start from ignition to reach a steady state, but since the objective of such a calculation is to obtain the steady state flame spread rate, the calculation through the transition process is made without high accuracy to save computational time. We have studied the transition from a small localized ignition at the center of a thermally thin paper in a microgravity environment. The configuration for that study was axisymmetric, but more general versions of the numerical scheme have been developed by including the effects of a slow, external flow in both two and three dimensions. By exploiting the non-buoyant nature of the flow, it is possible to achieve resolution of fractions of millimeters for 3D flow domains on the order of 10 centimeters. Because the calculations are time dependent, we can study the evolution of multiple flame fronts originating from a localized ignition source. The interaction of these fronts determines whether or not they will eventually achieve steady state spread. Most flame spread studies in microgravity consider two-dimensional flame spread initiated by ignition at one end of a sample strip with or against a slow external flow. In this configuration there is only one flame front. A more realistic scenario involves separate, oppositely directed fronts in two dimensions, or a continuous, radially directed front in three dimensions. We present here some results of both the two and three dimensional codes.

Kashiwagi, Takashi↗

Elimination of NO Pollutant in Semi-enclosed Spaces over Sodium-promoted Cobalt Oxyhydroxide (CoOOH) by Oxidation and Adsorption Mechanism

Low concentrations of NOx accumulated in air in semi-enclosed spaces is a severe health hazard, but its efficient removal at low cost is a grand challenge. A simple method in preparing CoOOH for low-concentration NO removal at room temperature is described here. The samples are synthesized by oxidizing Co(OH)2 to CoOOH with different oxidants (Na2S2O8, O2 and H2O2). Among them, CoOOH prepared by Na2S2O8 (Co-NS) shows remarkable performance for NO abatement, while the samples synthesized by and H2O2 (Co-HO) and O2 (Co-OG) have no apparent NO removal capacity. It is found that the Co-NS material contains a higher concentration of residual Na, which contributes to the decreased crystallinity and increased concentrations of surface active species (Co2+, active oxygen) for NO storage. Following NO storage, the material can be readily regenerated by water washing. The authors from East China University of Science and Technology acknowledge support from National Basic Research Program of China (2013CB933200), National Natural Science Foundation of China (21577035, 21577034), Commission of Science and Technology of Shanghai Municipality (15DZ1205305) and 111 Project (B08021). Aiyong Wang acknowledges the China Scholarship Council for the Joint-Training Scholarship Program with the Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the US DOE under contract DE-AC05-76RL01830. FG is supported by the U.S. DOE/Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office.

NOx abatement, NOx adsorber, ambient temperature, ↗

Safe Maritime Navigation with COLREGS Using Velocity Obstacles

This paper presents a motion planning algorithm for Unmanned Surface Vehicles (USVs) to navigate safely in dynamic, cluttered environments. The proposed algorithm not only addresses Hazard Avoidance (HA) for stationary and moving hazards but also applies the International Regulations for Preventing Collisions at Sea (known as COLREGs). The COLREG rules specify, for example, which vessel is responsible for giving way to the other and to which side of the "stand-on" vessel to maneuver. The three primary COLREG rules were considered in this paper: crossing, overtaking, and head-on situations. For USVs to be safely deployed in environments with other traffic boats, it is imperative that the USV's navigation algorithm obey COLREGs. Note also that if other boats disregard their responsibility under COLREGs, the USV will still apply its HA algorithms to avoid a collision. The proposed approach is based on Velocity Obstacles, which generates a cone-shaped obstacle in the velocity space. Because Velocity Obstacles also specify which side of the obstacle the vehicle will pass during the avoidance maneuver, COLREGs are encoded in the velocity space in a natural way. The algorithm is demonstrated via both simulation and on-water tests.

velocity obstacles↗

Assessing thermal resilience of an assisted living facility during heat waves and cold snaps with power outages

Extreme hot and cold weather events are becoming more frequent, intense, and longer due to climate change. When these events occur coincidentally with power outages, the resulting extreme indoor temperatures pose a severe health hazard for occupants. This study conducted a holistic modeling and analysis of an assisted living facility, where senior residents live, to assess its thermal resilience performance under a six-day heat wave in 2015 and a three-day cold snap in 2021 with power outages. Impacts of 13 energy efficiency measures on thermal resilience and backup power capacity of the facility were evaluated. Three thermal resilience metrics: the SET (standard effective temperature) degree-hours, the Heat Index, and the Hours of Safety, were used and calculated from the EnergyPlus simulation models. Furthermore, major findings are: (1) the facility would suffer from extreme temperatures during the cold and hot events without a power supply, not meeting the passive survivability requirements; (2) most passive envelope measures improve thermal resilience for both hot and cold events, but making the building envelope airtight results in conflicting performance between the hot and cold events; (3) natural ventilation is an effective measure to mitigate summer indoor overheating; and (4) the energy efficiency package can reduce backup power capacity by 19% for the three-day cold snap. It is recommended that building technologies and design strategies be evaluated to consider co-benefits of energy use, thermal resilience, and backup power needs through building energy codes or policies for existing and new buildings, which are transitioning for decarbonization and climate resilience.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Design and Application of Materials for Sequestration and Immobilization of 99 Tc

99 Technetium ( 99 Tc) is a hazardous radionuclide generated by the nuclear industry that poses a serious environmental threat. The wide variation and complex chemistries of nuclear waste streams containing 99 Tc often create unique, site specific challenges when sequestering and immobilizing the waste in a matrix suitable for long-term storage and disposal. Therefore, an effective management plan for 99 Tc containing radioactive waste will likely require a variety of suitable materials/matrices capable of adapting to and addressing these challenges. In this review, we discuss and highlight the key developments for effective removal and immobilization of 99 Tc in inorganic waste forms. Specifically, we review the synthesis, characterization, and application of materials for targeted removal of 99 Tc from (simulated) waste solutions under various experimental conditions. These materials include: i) layered double hydroxides (LDHs), ii) metal-organic frameworks (MOFs), iii) ion-exchange resins (IERs) as well as cationic organic polymers (COPs), and iv) surface modified natural clay materials (SMCMs). Secondly, we discuss some of the major and recent developments towards 99 Tc immobilization in i) glass, ii) cement, and iii) iron mineral waste forms. Finally, we present future challenges that need to be addressed for the design, synthesis, and selection of suitable matrices for the efficient sequestration and immobilization of 99 Tc from targeted wastes. Finally, the purpose of this review is to inspire the researches on the design and application of various suitable materials/matrices for selective removal of 99 Tc present globally in different radioactive wastes and its immobilization in stable/durable waste forms.

36 MATERIALS SCIENCE↗

Building Capacity for Policy-makers in a Virtual Setting: Providing Tools to Analyze Wildfire Smoke Plumes and Their Impacts

The NASA DEVELOP Program conducted 10-week long feasibility projects in a remote work setting, including partnering with The Nature Conservancy’s Washington Chapter and the Puget Sound Clean Air Agency to investigate wildfire smoke from 2000 - 2020 in the Pacific Northwest using satellite-derived data. The team engaged with platforms for collaboration both internally with NASA affiliates and externally with community organizations. Working from multiple states, the team members used a variety of software including Google Meet, Microsoft Teams, and Google Earth Engine to foster communication and work with data in a shared virtual environment. Throughout the project, the team learned that executing the project in a distanced work setting made it easier to reach out to scientists across the country for expertise and guidance. To study changes in air quality resulting from wildfire smoke, the team utilized data from NASA’s Fire Information from Resource Management System (FIRMS) and the ESA’s Sentinel-5 TROPOspheric Monitoring Instrument (TROPOMI). The team created a Google Earth Engine web-based tool, “Plume Hazards and Observations of Emissions by Navigating an Interactive eXplorer” (PHOENIX), to visualize changes in pollutants and aerosol optical depth after fire events. The potential relationship between plume height and fire radiative power was evaluated by using NASA’s Moderate Resolution Imaging Spectroradiometer (MODIS) aboard Aqua and Terra satellites and NASA’s Multi-angle Imaging SpectroRadiometer (MISR) aboard Terra with the MISR INteractive eXplorer (MINX). The PHOENIX smoke assessment tool and science communication infographics will be shared electronically with the partner organizations. Furthermore, the team introduced the partners to MINX and will provide a tailored tutorial that included a recorded video and a written component with a live virtual workshop. These resources build capacity for further research and education on wildfire smoke and air quality within communities.

NASA DEVELOP↗

Selection of the Mars Pathfinder Landing Site

The Mars Pathfinder spacecraft will land on a depositional fan near the mouth of the catastrophic outflow channel, Ares Vallis (19.5 deg N, 32.8 deg W). This site offers the prospect of analyzing a variety of rock types from the ancient cratered highlands, intermediate-age ridged plains, and reworked channel deposits. Analyses of these rocks by Pathfinder instruments will enable first-order scientific questions to be addressed, such as differentiation of the crust, the development of weathering products, and the nature of the early environment, as well as their subsequent evolution on Mars. Constraints imposed by: (1) spacecraft and rover designs (which are robust), (2) entry, descent, and landing, (3) scientific potential at various sites, and (4) safety were important considerations in site selection. Engineering constraints require a 70 km by 200 km smooth, flat (low slopes) area located between 10 deg and 20 deg N that is below 0 km elevation, with average radar reflectivity, little dust, and moderate rock abundance. Three regions on Mars are between 10 deg and 20 deg N and below 0 km elevation: Chryse, Amazonis, and Isidis-Elysitun. Science considerations favor sites at the mouths of outflow channels (grab bag sites offer an assay of rock types on Mars), highland sites (early crustal differentiation and climate), and sites covered with dark (unoxidized) material. Sites are considered safe if they are clearly below 0 km elevation, appear acceptably free of hazards in high-resolution (less than 50 m/pixel) Viking orbiter images and have acceptable reflectivity and roughness at radar wavelengths, thermal inertia, rock abundance, red to violet ratio, and albedo. Recent 3.5-cm wavelength radar observations were used to verify elevation, reflectivity, and roughness within the landing ellipses. Three sites meet all of these criteria: Ares Vallis, Tritonis Lacus, and Isidis. Although Isidis appears to be safer than Tritonis and Ares, the greater scientific potential at Ares Vallis resulted in its selection. Comparisons of the Grand Coulee (channel) and the depositional Ephrata Fan of the Channeled Scabland in eastern Washington, with Ar-es Vallis and its depositional fan also suggest the Ares Vallis landing site is safe and scientifically interesting.

Golombek, M. P.↗

Canonsburg, Pennsylvania, UMTRCA Title I Disposal Site 35 Years Postclosure (1985-2020) - 20288

The DOE Office of Legacy Management (LM) Canonsburg, Pennsylvania, Disposal Site is a former uranium ore-processing site located in the borough of Canonsburg and an important part of US history. For 46 years (1911-1957), the site processed ore, for vanadium, radium and then uranium. Soils and groundwater beneath the site were contaminated by the milling operations. The 15-hectare (37-acre) site is owned by the US government and managed by LM, which serves as the federal land manager and steward of cultural, historical, and natural resources at Cold War legacy sites that have been successfully cleaned up to remedial standards. In 1978 Congress directed DOE to remediate 22 inactive uranium-ore processing sites under the Uranium Mill Tailings Radiation Control Act (UMTRCA), in accordance with standards promulgated by the US Environmental Protection Agency in Title 40 CFR Part 192 (40 (CFR 192). Subpart B of 40 CFR 192 regulates the cleanup of contaminated groundwater at the processing sites. The radioactive materials were encapsulated in US Nuclear Regulatory Commission (NRC)-approved disposal cells, and the NRC general license for UMTRCA Title I sites is established in 10 CFR 40.27. Canonsburg was the first site to be remediated under UMTRCA. From 1983 to 1985, the Canonsburg site underwent cleanup under this US law that provides for the safe and environmentally sound disposal, long-term stabilization, and control of uranium mill tailings in a manner that minimizes or eliminates radiation health hazards to the public. The site is unique in that it is one of only two UMTRCA Title I sites in the eastern half of the United States, the other site being the Burrell, Pennsylvania, Title I Disposal Site, a vicinity property to the Canonsburg site. It has been 35 years since the disposal cell at the Canonsburg site was completed. This paper discusses the many efforts that have been taken to maintain the site and presents some of the lessons learned concerning the long-term care of the site. The discussion includes but is not limited to the following: (1) Preserving site history so the community can better appreciate and understand the site. (2) Community outreach efforts, and the importance of maintaining transparency of environmental monitoring results with the community. (3) Pursuing reuse opportunities that offer the potential for improving the community. (4) Remaining engaged with the local community. (5) Remaining proactive in the long-term care of the site. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The Urban Environmental Monitoring/100 Cities Project: Legacy of the First Phase and Next Steps

The Urban Environmental Monitoring (UEM) project, now known as the 100 Cities Project, at Arizona State University (ASU) is a baseline effort to collect and analyze remotely sensed data for 100 urban centers worldwide. Our overarching goal is to use remote sensing technology to better understand the consequences of rapid urbanization through advanced biophysical measurements, classification methods, and modeling, which can then be used to inform public policy and planning. Urbanization represents one of the most significant alterations that humankind has made to the surface of the earth. In the early 20th century, there were less than 20 cities in the world with populations exceeding 1 million; today, there are more than 400. The consequences of urbanization include the transformation of land surfaces from undisturbed natural environments to land that supports different forms of human activity, including agriculture, residential, commercial, industrial, and infrastructure such as roads and other types of transportation. Each of these land transformations has impacted, to varying degrees, the local climatology, hydrology, geology, and biota that predate human settlement. It is essential that we document, to the best of our ability, the nature of land transformations and the consequences to the existing environment. The focus in the UEM project since its inception has been on rapid urbanization. Rapid urbanization is occurring in hundreds of cities worldwide as population increases and people migrate from rural communities to urban centers in search of employment and a better quality of life. The unintended consequences of rapid urbanization have the potential to cause serious harm to the environment, to human life, and to the resulting built environment because rapid development constrains and rushes decision making. Such rapid decision making can result in poor planning, ineffective policies, and decisions that harm the environment and the quality of human life. Slower, more thought-out, decision making could result in more favorable outcomes. The harm to the environment includes poor air quality, soil erosion, polluted rivers and aquifers, and loss of wildlife habitat. Human life is then threatened because of increased potential for disease spreading, human conflict, environmental hazards, and diminished quality of life. The built environment is potentially threatened when cities are built in areas that can be impacted by events such as hurricanes, tsunamis, earthquakes, fires, and landslides. Our goals include assessing the threat of such events on cities and the people living there.

Stefanov, William L.↗

Techno Economic Analysis for Production of Renewable Natural Gas and Value-Added Chemicals from Forest Biomass Residues (CRADA Final Report)

West Biofuels - in collaboration with the University of California San Diego, the University of California Davis, the National Laboratory of the Rockies (NLR), the Colorado School of Mines’ Center for Hydrate Research, Placer County Air Pollution Control District, the Sierra Business Council, and the Southern California Gas Company (SoCalGas)-will demonstrate an innovative pathway to convert forest biomass to renewable gas (RG). The project, Production of Pipeline Grade Renewable Natural Gas and Value-Added Chemicals from Forest Biomass Residues, will utilize an existing pilot-scale gasification system and data and lessons learned from a lab-scale catalytic reactor design, develop, and demonstrate an integrated pilot-scale RG process with a scaled-up catalytic reactor and hydrate-based gas separation process. This robust and simple process uses a commercial proven gasifier, a commercially available catalyst that can tolerate gas contaminants, and a gas separation process that simplifies the downstream processing. Current testing has shown that the process can yield a large amount of methane rich renewable gas in addition to a mixture of propanol, ethanol and other higher alcohols and the relative amounts can be controlled by shifting the process conditions. This process is novel and groundbreaking because the product mixture of RG and valuable alcohols byproducts makes RG production economically feasible at $\$$12 per million British thermal units (MMBtu) or less using forest biomass from high hazard zones.

09 BIOMASS FUELS↗

Conformal Ablative Thermal Protection System for Planetary and Human Exploration Missions:An Overview of the Technology Maturation Effort

The Office of Chief Technologist, NASA identified the need for research and technology development in part from NASAs Strategic Goal 3.3 of the NASA Strategic Plan to develop and demonstrate the critical technologies that will make NASAs exploration, science, and discovery missions more affordable and more capable. Furthermore, the Game Changing Development Program is a primary avenue to achieve the Agencys 2011 strategic goal to Create the innovative new space technologies for our exploration, science, and economic future. The National Research Council (NRC) Space Technology Roadmaps and Priorities report highlights six challenges and they are: Mass to Surface, Surface Access, Precision Landing, Surface Hazard Detection and Avoidance, Safety and Mission Assurance, and Affordability. In order for NASA to meet these challenges, the report recommends immediate focus on Rigid and Flexible Thermal Protection Systems. Rigid TPS systems such as Avcoat or SLA are honeycomb based and PICA is in the form of tiles. The honeycomb systems are manufactured using techniques that require filling of each (38 cell) by hand, and in a limited amount of time all of the cells must be filled and the heatshield must be cured. The tile systems such as PICA pose a different challenge as the low strain-to-failure and manufacturing size limitations require large number of small tiles with gap-fillers between the tiles. Recent investments in flexible ablative systems have given rise to the potential for conformal ablative TPS. A conformal TPS over a rigid aeroshell has the potential to solve a number of challenges faced by traditional rigid TPS materials. The high strain-to-failure nature of the conformal ablative materials will allow integration of the TPS with the underlying aeroshell structure much easier and enable monolithic-like configuration and larger segments (or parts) to be used. By reducing the overall part count, the cost of installation (based on cost comparisons between blanket and tile materials on shuttle) should be significantly reduced. The conformal ablator design will include a simplified design of seams between gore panels, which should eliminate the need for gap filler design, and should accommodate a wider range of allowable carrier structure imperfections when compared to a rigid material such as PICA.The Conformal TPS development project leverages the past investments made by earlier projects with a goal to develop and deliver a TRL 5 conformal TPS capable of 250 Wcm2 for missions such as MSL or COTS missions. The capabilities goal for the conformal TPS is similar to an MSL design reference mission (250 Wcm2) with matching pressures and shear environments. Both conformal and flexible carbon-felt based materials were successfully tested in stagnation aerothermal environments above 500 Wcm2 under earlier programs. Results on a myriad of materials developed during FY11 were used to determine which materials to start with in FY12. In FY12, the conformal TPS element focused on establishing materials requirements based on MSL-type and COTS Low Earth orbit (LEO) conditions (q 250 Wcm2) to develop and deliver a Conformal Ablative TPS. In FY13, development and refining metrics for mission utilization of conformal ablator technology along with assessment for potential mission stakeholders will be carried out.

Thermal protection materials↗

Space Environment (Natural and Induced)

Considerable effort and improvement have been made in the study of ionizing radiation exposure occurring in various regions of space. Satellites and spacecrafts equipped with innovative instruments are continually refining particle data and providing more accurate information on the ionizing radiation environment. The major problem in accurate spectral definition of ionizing radiation appears to be the detailed energy spectra, especially at high energies, which is important parameter for accurate radiation risk assessment. Magnitude of risks posed by exposure to radiation in future space missions is subject to the accuracies of predictive forecast of event size of SPE, GCR environment, geomagnetic fields, and atmospheric radiation environment. Although heavy ion fragmentations and interactions are adequately resolved through laboratory study and model development, improvements in fragmentation cross sections for the light nuclei produced from HZE nuclei and their laboratory validation are still required to achieve the principal goal of planetary GCR simulation at a critical exposure site. More accurate prediction procedure for ionizing radiation environment can be made with a better understanding of the solar and space physics, fulfillment of required measurements for nuclear/atomic processes, and their validation and verification with spaceflights and heavy ion accelerators experiments. It is certainly true that the continued advancements in solar and space physics combining with physical measurements will strengthen the confidence of future manned exploration of solar system. Advancements in radiobiology will surely give the meaningful radiation hazard assessments for short and long term effects, by which appropriate and effective mitigation measures can be placed to ensure that humans safely live and work in the space, anywhere, anytime.

Kim, Myung-Hee Y.↗