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At least 811 records · Page 45
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Studies on aqueous two phase polymer systems useful for partitioning of biological materials

The two phase systems that result when aqueous solutions of dextran and poly(ethylene glycol) (PEG) are mixed above a critical concentration of a few percent provide a useful medium for the separation of biological cell subpopulations via partition between the top, PEG-rich phase and the liquid-liquid phase boundary. Interfacial tensions of such systems have been measured by the rotating drop technique and found to range between 0.1-100 micro-N/m. The tension was found to depend on the length of the tie line describing the system on a phase diagram, via a power law relationship which differed depending on the concentration of Na phosphate buffer present. The electrokinetic properties of drops of one phase suspended in the other were studied for a variety of systems. It was found that the droplet electrophoretic mobility increased monotonically with phosphate concentration and drop diameter but exhibited the opposite sign from that anticipated from phosphate partition measurements. It was possible to take advantage of these electrokinetic properties and dramatically enhance the speed of phase separation through application of relatively small electric fields.

Brooks, D. E.↗
NASA NTRS1983

Charged particle distributions in Jupiter's magnetosphere

In situ data from the Pioneer and Voyager spacecraft, supplemented by earth-based observations and theoretical considerations, are used as the basis for the present quantitative, compact model of the 1 eV-several MeV charged particle distribution in the Jovian magnetosphere. The thermal plasma parameters of convection speed, number density, and characteristic energy, are specified as functions of position for electrons and for the ion species H(+), O(+), O(2+), S(+), S(2+), S(3+), and Na(+). Major features of the magnetic field, thermal plasma, and trapped particle distributions, are modeled and results for each plasma region are compared with observed spectra. Comparisons show that the model represents the data to within a factor of 2 + or - 1, except where time variations are significant. Practical applications of the model to spacecraft near Jupiter are given.

Divine, N.↗
NASA NTRS1983

An analytical and experimental study of zoning in plagioclase

A detailed electron microprobe study has been conducted on natural and experimentally grown zoned plagioclase feldspars. Discontinuous, sector, and oscillatory chemical zoning are observed superimposed on continuous normal or reverse zoning trends. The relative accuracy of 3 element (Na, Ca, K) microprobe traverses was found statistically to be 2 mole percent. Comparison of microprobe data on natural zoned plagioclase with zoned plagioclase grown in controlled experiments has shown that it may be possible to distinguish zonal development resulting from physio-chemical changes to the bulk magma from zoning related to local kinetic control on the growth of individual crystals.

Smith, R. K.↗
NASA NTRS1983

Regolith breccia Allan Hills A81005 - Evidence of lunar origin, and petrography of pristine and nonpristine clasts

It is shown that the ratios of MnO/FeO in pyroxene, texture (abundant brown and swirly glass, which are typical of lunar regolith breccias) and overall composition (approximately 75 percent plagioclase) indicate a lunar origin for the regolith breccia Allan Hills A81005, presumably from an unsampled region of the moon. The rock is found to differ in detail from other regolith samples; for example, it has exceptionally low contents of Na and KREEP. In addition, a pristine clast is found to contain exceptionally coarse augite in comparison with similar Apollo samples. It is found that ALHA81005 is not perceptibly more shocked than typical Apollo regolith breccias. It is concluded that the discovery of this rock on earth strengthens the suggestion that SNC achondrites were derived by impact ejection from Mars.

Warren, P. H.↗
NASA NTRS1983

Neutral interstellar gas in the lower galactic halo

The optical interstellar absorption lines of Ti II, Ca II, Na I, and the 21 cm emission line of H I were observed at high resolution and high detection sensitivity toward none pairs of nearly aligned distant halo stars and foreground disk stars with well determined distances. Analysis of the column densities, velocities, and the directly determined variation of the titanium abundances with z-distance leads to a general picture of the neutral interstellar material in the lower galactic halo. Two types of gas with distinct distribution, kinematics, and abundances are found, a thick, low velocity disk (type I) extending from the plane to well beyond the thin disk of OB stars, and a high velocity, much less strongly depleted gas (type II) observed only at high z-distances, which constitutes at least 24 percent of the mass of the halo gas. The implications of this model for the observed neutral gas are discussed both in terms of the possible origins of the observed gas and in its comparison with quasi stellar object absorption lines. Previously announced in STAR as N82-29246

Albert, C. E.↗
NASA NTRS1984

Deep diode arrays for X-ray detection

Temperature gradient zone melting process was used to form p-n junctions in bulk of high purity silicon wafers. These diodes were patterned to form arrays for X-ray spectrometers. The whole fabrication processes for these X-ray detectors are reviewed in detail. The p-n junctions were evaluated by (1) the dark diode I-V measurements, (2) the diode C sub I - V measurements, and (3) the MOS C-V measurements. The results showed that these junctions were linearly graded in charge distribution with low reverse bias leakage current flowing through them (few nA at -10 volts). The X-ray detection experiments showed that an FWHM of 500 eV was obtained from these diodes with a small bias of just -5 volts (for X-ray source Fe55). A theoretical model was proposed to explain the extra peaks found in the energy spectra and a very interesting point - cross talk effect was pointed out. This might be a solution to the problem of making really high resolution X-ray spectrometers.

Zemel, J. N.↗
NASA NTRS1984

Engineering correlations of variable-property effects on laminar forced convection mass transfer for dilute vapor species and small particles in air

A simple engineering correlation scheme is developed to predict the variable property effects on dilute species laminar forced convection mass transfer applicable to all vapor molecules or Brownian diffusing small particle, covering the surface to mainstream temperature ratio of 0.25 T sub W/T sub e 4. The accuracy of the correlation is checked against rigorous numerical forced convection laminar boundary layer calculations of flat plate and stagnation point flows of air containing trace species of Na, NaCl, NaOH, Na2SO4, K, KCl, KOH, or K2SO4 vapor species or their clusters. For the cases reported here the correlation had an average absolute error of only 1 percent (maximum 13 percent) as compared to an average absolute error of 18 percent (maximum 54 percent) one would have made by using the constant-property results.

Gokoglu, S. A.↗
NASA NTRS1983

Hypervolemia and plasma vasopressin response during water immersion in men

Immersion studies were performed on seven mildly dehydrated male subjects to examine the effect of suppression of plasma vasopressin (PVP) on diuresis in water immersion. The water was kept at close to 34.5 C and the subjects remained in the water for 4 hr after sitting for 2 hr. Na and K levels in the serum and urine were analyzed, as were osmolality, red blood cell count, renin activity, total protein, albumin amounts, hematocrit, and hemoglobin. Plasma volume was monitored from samples drawn at specified intervals during immersion. The plasma volume increased significantly 30 min after immersion, but no PVP was observed. The dehydration induced elevated serum osmotic concentrations. It is concluded that the hydration condition before immersion and the volume of fluid intake during immersion affects the hemodilution during immersion.

Greenleaf, J. E.↗
NASA NTRS1983

Mare glasses from Apollo 17 - Constraints on the moon's bulk composition

Two previously unreported varieties of mare volcanic glass have been discovered in Apollo 17 samples. Twenty-three chemical types of volcanic glass have now been analyzed from the six Apollo landing sites. These volcanic glasses, which may be samples of primary magmas derived from the differentiated lunar mantle, define two linear arrays that seem to reflect regional, if not global, regularities among the source regions of these melts. Additional systematics among these glasses have been used to estimate the bulk composition of the moon. The results suggest that the refractory lithophile elements are present at abundances of 1.7 x chondrites. The silicate portion of the moon appears to have a major-element composition similar to a volatile (Si, Na, K)-depleted, earth's upper mantle. The theory involving an earth-fission origin of the moon can be tested further through trace element analyses on the volcanic glasses, and through determination of the N/Ar-36 ratio and noble gas isotopes from primordial lunar gas trapped within vesicles associated with mare volcanic glass.

Delano, J. W.↗
NASA NTRS1983

The Ne-21 production rate in stony meteorites estimated from Be-10 and other radionuclides

The Be-10 contents of 28 stony meteorites with known Ne-21 contents range from 0.97 to 23 dpm/kg and give an average Ne-21 production rate (P sub 21) of (0.28 + or - 0.02) x 10 to the -8th cu cm STP/g-My for shielding conditions corresponding to Ne-22/Ne-21 = 1.114 in an H-chondrite. This P sub 21 (Be) agrees with others' P sub 21 based on Na-22, Kr-81, and Mn-53, but not an Al-26. Temporal variations in the cosmic ray flux do not explain the disagreement satisfactorily; major errors in the radionuclide half-lives are not indicated. The discrepancy seems rooted in the data selection and the difficulties of making accurate corrections for shielding, chemical composition and other sources of variability.

Moniot, R. K.↗
NASA NTRS1984

The chemical kinetics and thermodynamics of sodium species in oxygen-rich hydrogen flames

Results are presented which, it is claimed, lead to a correction of previous misconceptions over the relative importance and kinetics of NaO2. It is shown that its rapid conversion to NaO and NaOH is such that it can severely perturb the NaOH/Na ratio and produce significant concentration overshoots over that predicted from the balance of the reaction of Na with H2O. This becomes increasingly the case in flames of large O2 concentrations and temperatures below 2500 K; and the corresponding large rate constants for the termolecular formation of the other alkali peroxides imply that similar considerations will be necessary for them. Depending on the rate constants for the exothermic conversions of MO2 to MO or MOH, the steady-state concentrations of MO2 could be more or less significant than for sodium. Owing to numerous reactions that produce these conversions, the MOH species will probably be the dominant species in all cases in oxygen-rich hydrogen or hydrocarbon flames, with MO concentrations at not greater than 1 percent of the bound metal.

Hynes, A. J.↗
NASA NTRS1984

Interstellar absorption lines in the spectrum of supernova Evans in M83 (NGC 5236)

It is pointed out that supernovae in other galaxies create spontaneous opportunities to probe spectroscopically the gaseous material in galactic halos. Because of their brightness, supernovae offer an unparalleled chance to obtain spectra with high wavelength resolution and/or signal-to-noise ratio. The present investigation is concerned with observations of visual interstellar lines in the spectrum of a supernova discovered on July 3, 1983, and identified as Type I. The supernova was located 124 arc sec south and 122 arc sec west of the nucleus of M83. Evidence is obtained that for velocities near that of M83, the line of sight toward the supernova contains a complex array of absorption features of Ca II. In both Ca II and Na I, the absorptions associated with M83 are far more prominent than those halfway through the disk (and halo) of the Milky Way Galaxy. It is felt that many of the displaced velocity components in the M83 system arise from a gaseous halo.

Rodgers, A. W.↗
NASA NTRS1984

Universal binding energy relations in metallic adhesion

Rose, Smith, and Ferrante have discovered scaling relations which map the adhesive binding energy calculated by Ferrante and Smith onto a single universal binding energy curve. These binding energies are calculated for all combinations of Al(111), Zn(0001), Mg(0001), and Na(110) in contact. The scaling involves normalizing the energy by the maximum binding energy and normalizing distances by a suitable combination of Thomas-Fermi screening lengths. Rose et al. have also found that the calculated cohesive energies of K, Ba, Cu, Mo, and Sm scale by similar simple relations, suggesting the universal relation may be more general than for the simple free electron metals for which it was derived. In addition, the scaling length was defined more generally in order to relate it to measurable physical properties. Further this universality can be extended to chemisorption. A simple and yet quite accurate prediction of a zero temperature equation of state (volume as a function of pressure for metals and alloys) is presented. Thermal expansion coefficients and melting temperatures are predicted by simple, analytic expressions, and results compare favorably with experiment for a broad range of metals.

Ferrante, J.↗
NASA NTRS1983

Velocity-changing collisional effects in nonlinear atomic spectroscopy and photon echo decay in gases

A general theory of atomic dipole coherence under the influence of collisional phase changes, inelastic effects and optically active atom velocity changes, including those due to anisotropic interactions is presented. Velocity change effects are obtained in closed form. Line shapes appear as convolutions of standard pressure broadening contours with velocity-change contours. Width and shift parameters for the He-broadened Na D lines at 2 m bar pressure, 380 K are calculated, as are He-induced photon echo decay rates for these lines. Overall agreement with xperiment is reasonably good.

Herman, R. M.↗
NASA NTRS1984

Distances of Local Clouds from Optical Line Observations

The interstellar D-line of Na 1 toward 49 stars were observed in order to determine the distance (125 plus or minus 25 pc) to a cold H 1 cloud. This sheet of gas may be part of the back side of the shell formed by the Loop I supernova.

Crutcher, R. M.↗
NASA NTRS1984

Chondrules in the bishunpur L13 chondrite

Twenty-six chondrules, chondrule fragments or clasts were analyzed. An automated wavelength dispersive instrument with a 90 micrometer beam integrated a series of analyses in traverses across each object. Depending on the size of the cross-sectional area, from 1 to 21 analyses were performed for each bulk analysis. Si, Ti, Al, Cr, Fe, Ni, Mn, Mg, Ca, Na, K and S were determined, and an analyzed augite was used as a secondary standard before and after each set of analyses. The work is part of a study of chondrule rims, interchondrule matrix, chondrules and clasts in unequilibrated ordinary chondrites. Only two of the twenty-six objects analyzed have Ca/Al atomic ratios greater than the ordinary chondritic average of 0.74. The bulk meteorite has a normal Ca/Al ratio, so presumably a Ca-rich, Al-poor component must be present to compensate for chondrules and chlasts. This component is unlikely to be rim or matrix, but may be phosphate associated with metal or sulphide. Na/Al ratios range from 1 to almost zero, but there is no hiatus as in a suite of Manych chondrules and glasses.

Hutchison, R.↗
NASA NTRS1984

Minor elements and cathodoluminescence of Mg-rich olivines from Murchison and Allende carbonaceous meteorites

The morphology and inclusions of individual Mg rich olivine grains from C2 chondrites provide disputed evidence for origin either from a liquid or a vapor. Olivine grains from Murchison (C2) and Allende (C3) meteorites were examined to extend data on Belgica 7904 (C2. Cathodoluminescence revealed the relation of chemical zoning to external shape and inclusions. High precision electron probe analyses of selected spots for Na, Al, P, Ca, Ti, Cr and Mn provided chemical constraints on the source material. From several possible explanations tentative suggestions are for at least two stages: (1) growth of the blue core from a vapor enriched in refractory elements (hence lack of inclusions); and (2) growth of red/dark rim from an unenriched liquid which entrapped the blue core. Mechanical transfer may be involved. The channels and networks are puzzling at this time. Whatever the true explanation, a complex history is needed for a simple mineral, and further study should provide additional restraints on formation of carbonaceous meteorites.

Steele, I. M.↗
NASA NTRS1984

Dynamic thermal episodes in the protosolar nebula: Development of models from observations on CAI's

Evaluation of earlier observations indicated that layered rims on coarse-grained Allende CAI's were possibly the result of partial melting by ablation/drag-heating and reaction of CAI exteriors with a gas or gases of non-solar composition. Bunch and Chang reported the common occurrence of thin, fine-grained, matrix-like bands that at least partially surround rims of CAI's. Although material in these bands in general appears to be similar to matrix, SEM observations show them to be dissimilar in volatile element content, mineral composition, and grain morphology. Moreover, they appear to be related in time of formation with rim development and Na-metasomatism of CAI's. Observations indicate a short-lived but intense heating episode followed by radid cooling as the mechanism responsible for these CAI features.

Bunch, T. E.↗