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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 811 records · Page 45
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

Cryogenic properties of dispersion strengthened copper for high magnetic fields

Cold deformed copper matrix composite conductors, developed for use in the 100 tesla multi-shot pulsed magnet at the National High Magnetic Field Laboratory (NHMFL), have been characterized. The conductors are alumina strengthened copper which is fabricated by cold drawing that introduces high dislocation densities and high internal stresses. Both alumina particles and high density of dislocations provide us with high tensile strength and fatigue endurance. The conductors also have high electrical conductivities because alumina has limited solubility in Cu and dislocations have little scattering effect on conduction electrons. Such a combination of high strength and high conductivity makes it an excellent candidate over other resistive magnet materials. Thus, characterization is carried out by tensile testing and fully reversible fatigue testing. In tensile tests, the material exceeds the design criteria parameters. In the fatigue tests, both the load and displacement were measured and used to control the amplitude of the tests to simulate the various loading conditions in the pulsed magnet which is operated at 77 K in a non-destructive mode. In order to properly simulate the pulsed magnet operation, strain-controlled tests were more suitable than load controlled tests. For the dispersion strengthened coppers, the strengthening mechanism of the aluminum oxide provided better tensile and fatigue properties over convention copper.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Towards Ab-Initio Simulations of Crystalline Defects at the Exascale Using Spectral Quadrature Density Functional Theory

Defects in crystalline solids play a crucial role in determining properties of materials at the nano, meso- and macroscales, such as the coalescence of vacancies at the nanoscale to form voids and prismatic dislocation loops or diffusion and segregation of solutes to nucleate precipitates, phase transitions in magnetic materials via disorder and doping. First principles Density Functional Theory (DFT) simulations can provide a detailed understanding of these phenomena. However, the number of atoms needed to correctly simulate these systems is often beyond the reach of many widely used DFT codes. The aim of this article is to discuss recent advances in first principles modeling of crystal defects using the spectral quadrature method. The spectral quadrature method is linear scaling with respect to the number of atoms, permits spatial coarse-graining, and is capable of simulating non-periodic systems embedded in a bulk environment, which allows the application of appropriate boundary conditions for simulations of crystalline defects. In this article, we discuss the state-of-the-art in ab-initio modeling of large metallic systems of the order of several thousand atoms that are suitable for utilizing exascale computing resourses.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Diverse magnetic phase diagram and anomalous Hall effect in antiferromagnetic LuMn 6⁢ Sn 6

The interactions between conduction electrons and magnetism can significantly enhance the Hall signal, a phenomenon known as the anomalous Hall effect (AHE). While the AHE is generally not expected in antiferromagnets, a large AHE is observed in certain antiferromagnets with noncollinear spin textures and nonvanishing Berry curvature. In this work, we present a rich temperature and magnetic phase diagram with eight distinct magnetic phases for the antiferromagnetic kagome compound LuMn 6 Sn 6 . The Hall effect analysis in LuMn 6 Sn 6 reveals both intriguing physical phenomena and methodological challenges. In the coplanar canted antiferromagnetic phase, we observe an AHE, which likely originates from the intrinsic effects. At low temperatures, upon entering the ferromagnetic phase, the AHE sharply increases and exceeds the conventional limits expected from intrinsic mechanisms. We also demonstrate the limitations of standard experimental methods in extracting the topological contribution to the Hall effect data. In particular, we show that accounting for magnetoresistance anisotropy helps reduce spurious contribution that can mimic topological Hall signals, although it does not fully resolve it. Furthermore, these shortcomings in current approaches in partitioning the Hall response necessitate new tools to interpret transport results in complex magnetic materials such as LuMn 6 Sn 6 .

Anomalous Hall effect↗
DOE OSTI2015

Magnetic and Superconducting Materials at High Pressures

The work concentrates on few important tasks in enabling techniques for search of superconducting compressed hydrogen compounds and pure hydrogen, investigation of mechanisms of high-Tc superconductivity, and exploring new superconducting materials. Along that route we performed several challenging tasks, including discovery of new forms of polyhydrides of alkali metal Na at very high pressures. These experiments help us to establish the experimental environment that will provide important information on the high-pressure properties of hydrogen-rich compounds. Our recent progress in RIXS measurements opens a whole field of strongly correlated 3d materials. We have developed a systematic approach to measure major electronic parameters, like Hubbard energy U, and charge transfer energy Δ, as function of pressure. This technique will enable also RIXS studies of magnetic excitations in iridates and other 5d materials at the L edge, which attract a lot of interest recently. We have developed new magnetic sensing technique based on optically detected magnetic resonance from NV centers in diamond. The technique can be applied to study superconductivity in high-TC materials, to search for magnetic transitions in strongly correlated and itinerant magnetic materials under pressure. Summary of Project Activities; development of high-pressure experimentation platform for exploration of new potential superconductors, metal polyhydrides (including newly discovered alkali metal polyhydrides), and already known superconductors at the limit of static high-pressure techniques; investigation of special classes of superconducting compounds (high-Tc superconductors, new superconducting materials), that may provide new fundamental knowledge and may prove important for application as high-temperature/high-critical parameter superconductors; investigation of the pressure dependence of superconductivity and magnetic/phase transformations in 3d transition metal compounds, including transitions from magnetic to nonmagnetic phases in a broad pressure-temperature range; using X-ray methods including the newly developed RIXS high-pressure technique to explore pressure-tuned electronic excitations in strongly correlated 3d-materials; and advancing transport and magnetic techniques for measurements on small samples at very high pressures in a wide temperature range, with the application of focused ion beam technology and photolithography tailored to the design of microcircuits down to a nanoscale size, thus expanding the horizon in the search for novel physical phenomena at ultrahigh pressures. Apply new optical magnetic sensing techniques with NV- centers in diamond to detect superconductivity and magnetic transitions with unprecedented spatial resolution.

36 MATERIALS SCIENCE↗
DOE OSTI2019

The application of macroscopic flakes for Fe-6.5%Si bulk magnetics with superior magnetic properties

Silicon steel is the most popular crystalline soft magnetic material for motor and transformer applications. The material must be in thin thickness to reduce the eddy current loss. Conventional thin steel sheet manufacturing process starts with cast slab, followed by a series of hot/cold roll process. For transformer, thin sheet is wrapped to form the core; for motor, the sheet is stamped, coated, heat treated, and stacked to form stator/rotor. This process requires the steel to possess sufficient ductility. For Si steel, increasing Si content will improve its electrical and magnetic properties, but it will also lead to embrittlement with 3.5% Si as the limit for the conventional manufacturing processes. Despite poor mechanical properties, high Si steel, especially the one with 6.5% Si, is gaining more attention due to its lower iron loss, higher permeability, and near zero magnetostriction. To address the brittleness problem of the 6.5% Si steel, we developed a novel process, using rapid solidification to prepare thin flakes with high ductility, then using hot press to consolidate the flakes into near net shape bulk sample. The obtained Fe-6.5%Si sample with 0.2 mm thickness exhibits an iron loss of 7.2 W/kg at 400Hz and magnetic flux density of 1 Tesla, and a maximum permeability of 28,400. In addition, various coating materials and processes were investigated as inter-flake insulators for their effect on reducing the eddy current losses for thicker configuration.

Fe-6.5%Si Steel↗
NASA NTRSDate not supplied

Electrifying Aircraft Propulsion: Thermal Issues of Megawatt Scale Power Dense Electric Machines and Material Solutions

Aircraft are the last major mode of transportation to undergo electrification for many reasons, where the underlying reason is the sensitivity of aircraft performance to mass. This sensitivity demands that efficient, megawatt (MW)-scale high specific power density powertrains be developed to impact regional, single aisle and larger aircraft that account for the majority of fuel burn in commercial aviation. Developing MW-scale high specific power electric powertrains (machines, cables/busbars and power electronics) remains a significant challenge. While advanced power semiconductors have enabled higher voltages, densities, and operational frequencies this also leads to passing high current through smaller volumes when considering electric machines and power electronics. This poses significant thermal challenges. This is particularly true for electric machines that strive to surpass 13 kW/kg, which studies have shown to be desirable for electric aircraft propulsion. The necessity of handling high current densities to achieve MW power levels dictates that greater than 10kW of waste heat will be generated. Moreover, most of the heat is generated in the stator winding which is a mixture of electrical conductor (copper or aluminum), potting material, magnet wire (electrical) insulation and high voltage electrical insulation. Although the electrical conductor is a fantastic thermal conductor, it is also the source of the heat (carrying the electrical current) and is thermally isolated by the other materials. Simply letting the machine run at increased temperatures is an attractive idea, however the reality is that most of the suitable electric insulations and potting material candidates are not likely to satisfactorily operate at higher temperatures with reasonable life expectancies. The likelihood of developing new polymers that can satisfy the necessary functions (mechanical and electrical), operate at higher temperatures with acceptable lifetime in the near term is small. This has led the researchers at the NASA Glenn Research Center to examine electrically insulative materials in high power destiny electric machines, their thermal environment, and what solutions are realistic from a materials point of view. This presentation will touch on both the thermal challenges of electric machines and NASA Glenn’s research into material solutions.

Electric Aircraft Propulsion↗
DOE OSTI2021

Nanodevices engineering and spin transport properties of MnBi2Te4 monolayer

Abstract Two-dimensional (2D) magnetic materials are essential for the development of the next-generation spintronic technologies. Recently, layered van der Waals (vdW) compound MnBi 2 Te 4 (MBT) has attracted great interest, and its 2D structure has been reported to host coexisting magnetism and topology. Here, we design several conceptual nanodevices based on MBT monolayer (MBT-ML) and reveal their spin-dependent transport properties by means of the first-principles calculations. The pn -junction diodes and sub-3-nm pin -junction field-effect transistors (FETs) show a strong rectifying effect and a spin filtering effect, with an ideality factor n close to 1 even at a reasonably high temperature. In addition, the pip - and nin -junction FETs give an interesting negative differential resistive (NDR) effect. The gate voltages can tune currents through these FETs in a large range. Furthermore, the MBT-ML has a strong response to light. Our results uncover the multifunctional nature of MBT-ML, pave the road for its applications in diverse next-generation semiconductor spin electric devices.

Chemistry↗
DOE OSTI2012

Nanoscale origins of nonlinear behavior in ferroic thin-films

The nonlinear response of a ferroic to an applied stimulus (e.g. electric field, mechanical stress) is a fundamental characteristic that underpins a number of technologically significant applications[1-3]. It is also the driving feature in numerous physical phenomena, such as interfacial motion[4,5], spin glasses[6], relaxors[7] and phase transitions[8]. In particular, nonlinearity associated with minor hysteresis loops is an extremely useful avenue to explore energy dissipation and losses in such systems. This knowledge is necessary for the design of future materials with enhanced low-field properties. Quantitatively, the macroscopic nonlinear response of ferroic systems at low to mid-range amplitudes of driving fields is given by the phenomenological Rayleigh law[9], first conceived in 1887 for magnetic materials. Yet, the applicability of the Rayleigh law at small length scales has not been extensively studied. Here, we show using a combination of scanning probe techniques and phase field modeling, that nanoscale response appears to follow a non-Rayleigh regime. However, through statistical analysis, we find that a distribution in the individual responses can lead to directly to Rayleigh-like behavior of the strain on a macroscale. The studies shed light on the nanoscale origins of nonlinear behavior in disordered ferroics.

ferroelectric↗
DOE OSTI2014

Magnetic field role on the structure and optical response of photonic crystals based on ferrofluids containing Co{sub 0.25}Zn{sub 0.75}Fe{sub 2}O{sub 4} nanoparticles

Ferrofluids based on magnetic Co{sub 0.25}Zn{sub 0.75}Fe{sub 2}O{sub 4} ferrite nanoparticles were prepared by co-precipitation method from aqueous salt solutions of Co (II), ZnSO{sub 4}, and Fe (III) in an alkaline medium. Ferrofluids placed in an external magnetic field show properties that make them interesting as magneto-controllable soft photonic crystals. Morphological and structural characterizations of the samples were obtained from Scanning Electron Microscopy and Transmission Electron Microscopy studies. Magnetic properties were investigated with the aid of a vibrating sample magnetometer at room temperature. Herein, the Co{sub 0.25}Zn{sub 0.75}Fe{sub 2}O{sub 4} samples showed superparamagnetic behavior, according to hysteresis loop results. Taking in mind that the Co-Zn ferrite hysteresis loop is very small, our magnetic nanoparticles can be considered soft magnetic material with interesting technological applications. In addition, by using the plane-wave expansion method, we studied the photonic band structure of 2D photonic crystals made of ferrofluids with the same nanoparticles. Previous experimental results show that a magnetic field applied perpendicular to the ferrofluid plane agglomerates the magnetic nanoparticles in parallel rods to form a hexagonal 2D photonic crystal. We calculated the photonic band structure of photonic crystals by means of the effective refractive index of the magnetic fluid, basing the study on the Maxwell-Garnett theory, finding that the photonic band structure does not present any band gaps under the action of applied magnetic field strengths used in our experimental conditions.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1982

Magnetic state selection in atomic frequency and time standards

Atomic standards such as those based upon cesium and hydrogen rely upon magnetic state selection to obtain population inversion in the hyperfine transition levels. Use of new design approaches and improved magnetic materials has made it possible to fabricate improved state selectors of small size, and thus the efficiency of utilization of beam flux is greatly improved and the size and weight of the standard is reduced. The sensitivity to magnetic perturbations is also decreased, so that the accuracy and stability of the standard is improved. Several new state selector designs are illustrated and the application to standards utilizing different atomic species is analyzed.

Peters, H. E.↗
NASA NTRS2004

Mapping Weak Crustal Magnetic Fields on Mars with Electron Reflectometry

One of the great surprises of the Mars Global Surveyor (MGS) mission was the discovery of intensely magnetized crust. These magnetic sources are at least ten times stronger than their terrestrial counterparts, probably requiring large volumes of coherently magnetized material, very strong remanence, or both. Perhaps the most intriguing aspect of these fields is their large scale coherence and organization into east-west stripes thousands of kilometers long. The anomalies were almost certainly created by thermoremanent magnetization (TRM) in the presence of a strong Martian dynamo. With few exceptions, the crustal fields are associated with the oldest terrain on Mars. Much of the northern lowlands appears to be non-magnetic, except for the relatively weak north polar anomalies and a few sources adja-cent to the dichotomy boundary, which appear to be associated with strongly magnetized crust south of the boundary. There is clear evidence for impact demagnetization of the Hellas, Argyre, and Isidis basins. Thus, Mars' crustal magnetic fields are among the oldest preserved geologic features on the planet.

Mitchell, D. L.↗
DOE OSTI2019

Preparation and Characterization of Nanocopper Ferrite and Its Green Catalytic Activity in Alcohol Oxidation Reaction

A new type of magnetic material copper ferrite (CuFe{sub 2}O{sub 4}) is successfully manufactured through microwave combustion method. Starch has been tested as a single fuel in this combustion-based synthesis of copper ferrite by using different fuel compositions and equivalence ratios (fuel/oxidant). The formed copper ferrite is characterized by X-ray diffraction analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. Magnetic properties of the prepared copper ferrite are analyzed by vibrating sample magnetometer (VSM). Surface area is measured by the nitrogen adsorption/desorption isotherms. A detailed examination of the morphology of the material in various microwave method-catalyzed processes shows that they provide an optimum catalytic activity due to a combination of lower crystal size and higher activity.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2024

Spin Effects in Low Dimensional Correlated Systems (Final Technical Report)

Our program focuses on the behavior of two-dimensional superconducting systems that have been placed in high magnetic fields and/or in contact with magnetic materials. Our specific research agenda is organized into two separate but related areas. The first is a study of disorder and correlation effects in extremely thin superconducting aluminum, beryllium, and rhenium films that have been subjected to very high magnetic fields. We are particularly interested in understanding how the coupling between the applied field and the electron spins affects the system’s ability to form superconducting state. We now have good evidence that as the electron spins in these superconductors attempt to align to the magnetic field, a new superconducting phase emerges near the critical field transition and that this phase has a significant influence on the character of the transition. Thus, the spin behavior near the transition is much more complex than expected. The second class of systems is proximity structures comprised of superconducting/ferromagnetic (SC/FM) and superconducting/heavy metal (SC/HM) bilayers. We have developed spin-resolved tunneling probes that give us a direct measure of the proximity-induced exchange field in the SC/FM structures, as well as the spin-orbit scattering rate in SC/HM structures. Recently we have demonstrated that the magnitude of the exchange field can be modulated with an external gate, thereby producing a magneto-electric response in the bilayers. We plan to optimize this magneto-electric effect by getting a better understanding of the microscopic mechanism of the interface-induce exchange field, as well as improving the gate barriers and/or the bilayer interface quality. The ultimate goal is to develop a device such as a voltage-controlled superconducting switch or a spin- polarized electron source with a voltage-tunable Zeeman splitting.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Non-hysteretic first-order phase transition with large latent heat and giant low-field magnetocaloric effect

First-order magnetic transitions (FOMTs) with a large discontinuity in magnetization are highly sought in the development of advanced functional magnetic materials. Isosymmetric magnetoelastic FOMTs that do not perturb crystal symmetry are especially rare, and only a handful of material families, almost exclusively transition metal-based, are known to exhibit them. Yet, here we report a surprising isosymmetric FOMT in a rare-earth intermetallic, Eu2In. What makes this transition in Eu 2 In even more remarkable is that it is associated with a large latent heat and an exceptionally high magnetocaloric effect in low magnetic fields, but with tiny lattice discontinuities and negligible hysteresis. Finally, an active role of the Eu-5d and In-4p states and a rather unique electronic structure borne by In to Eu charge transfer, altogether result in an unusual exchange mechanism that both sets the transition in motion and unveils an approach toward developing specific magnetic functionalities ad libitum.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Amplitude mode in the planar triangular antiferromagnet Na 0.9 MnO 2

Amplitude modes arising from symmetry breaking in materials are of broad interest in condensed matter physics. These modes reflect an oscillation in the amplitude of a complex order parameter, yet are typically unstable and decay into oscillations of the order parameter’s phase. This renders stable amplitude modes rare, and exotic effects in quantum antiferromagnets have historically provided a realm for their detection. We report an alternate route to realizing amplitude modes in magnetic materials by demonstrating that an antiferromagnet on a two-dimensional anisotropic triangular lattice (α-Na 0.9 MnO 2 ) exhibits a long-lived, coherent oscillation of its staggered magnetization field. Our results show that geometric frustration of Heisenberg spins with uniaxial single-ion anisotropy can renormalize the interactions of a dense two-dimensional network of moments into largely decoupled, one-dimensional chains that manifest a longitudinally polarized-bound state. This bound state is driven by the Ising-like anisotropy inherent to the Mn 3+ ions of this compound.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Tunable chiral and nematic states in the triple-Q antiferromagnet Co 1/3 TaS 2

Complex spin configurations in magnetic materials, ranging from collinear single-Q to non-coplanar multi-Q states, exhibit rich symmetry and chiral properties. However, their detailed characterization is often hindered by the limited spatial resolution of neutron diffraction techniques. Here we employ magnetic circular dichroism and magnetic linear dichroism to investigate the triangular lattice antiferromagnet Co 1/3 TaS 2 , revealing three-state (Z 3 ) nematicity and also spin chirality across its multi-Q magnetic phases. At intermediate temperatures, the presence of linear dichroism identifies nematicity arising from a single-Q stripe phase, while at high magnetic fields and low temperatures, a phase characterized solely by circular dichroism emerges, signifying a purely chiral non-coplanar triple-Q state. Notably, at low temperatures and small fields, we discover a unique phase where both chirality and nematicity coexist. A theoretical analysis based on a continuous multi-Q manifold captures the emergence of these distinct magnetic phases, as a result of the interplay between four-spin interactions and weak magnetic anisotropy. Additionally, both circular and linear dichroism microscopy spatially resolves the chiral and nematic domains. Our findings establish Co 1/3 TaS 2 as a rare platform hosting diverse multi-Q states with distinct combinations of spin chirality and nematicity while demonstrating the effectiveness of polarized optical techniques in characterizing complex magnetic textures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1987

Magnetic suspension and balance system (MSBS) advanced study.I - System design

A magnetic suspension and balance system is designed to support models of aircraft or other objects in wind tunnels by means of magnetic forces. Major design improvements have been achieved, resulting in reductions of the system size, weight, and cost. These improvements are due to: (1) the use of holmium in the model core to increase its magnetic moment, (2) the use of a powerful new permanent magnet material in the model wings, (3) a new arrangement for the roll coils, and (4) the use of a nonmetallic structure to eliminate eddy current losses. The conceptual design of the holmium core superconductive solenoid and of the new permanent magnet wing assembly is described in detail. The discussion includes comparisons of the pole strengths for different model core magnets, the design of a superconducting solenoid and cryostat, and the analysis of model wing magnetic requirements.

Boom, Roger W.↗
DOE OSTI2017

Cluster-Expansion Model for Complex Quinary Alloys: Application to Alnico Permanent Magnets

An accurate and transferable cluster-expansion model for complex quinary alloys is developed. Lattice Monte Carlo simulation enabled by this cluster-expansion model is used to investigate temperature-dependent atomic structure of alnico alloys, which are considered as promising high-performance non-rare-earth permanent-magnet materials for high-temperature applications. The results of the Monte Carlo simulations are consistent with available experimental data and provide useful insights into phase decomposition, selection, and chemical ordering in alnico. The simulations also reveal a previously unrecognized D 0 3 alloy phase. This phase is very rich in Ni and exhibits very weak magnetization. In conclusion, manipulating the size and location of this phase provides a possible route to improve the magnetic properties of alnico, especially coercivity.

36 MATERIALS SCIENCE↗