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NASA NTRS2011

Mid-Infrared Imaging of Exo-Earths: Impact of Exozodiacal Disk Structures

The characterization of Earth-like extrasolar planets in the mid-infrared is a significant observational challenge that could be tackled by future space-based interferometers. The presence of large amounts of exozodiacal dust around nearby main sequence stars represents however a potential hurdle to obtain mid-infrared spectra of Earth-like planets. Whereas the disk brightness only affects the integration time, the emission of resonant dust structures mixes with the planet signal at the output of the interferometer and could jeopardize the spectroscopic analysis of an Earth-like planet. Fortunately, the high angular resolution provided by space-based interferometry is sufficient to spatially distinguish most of the extended exozodiacal emission from the planetary signal and only the dust located near the planet significantly contributes to the noise level. Considering modeled resonant structures created by Earth-like planets, we address in this talk the role of exozodiacal dust in two different cases: the characterization of Super-Earth planets with single space-based Bracewell interferometers (e.g., the FKSI mission) and the characterization of Earth-like planets with 4-telescope space-based nulling interferometers (e.g., the TPF-I and Darwin projects). In each case, we derive constraints on the disk parameters that can be tolerated without jeopardizing the detection of Earth-like planets

Defrere, Denis↗
NASA NTRS2011

The Origin and Evolution of Interstellar Dust in the Local and High-Redshift Universe

In this talk I will begin by reviewing our current state of knowledge regarding the origin and evolution of dust in the local solar neighborhood. Using chemical evolution models, I will discuss their many different input parameters and their uncertainties. An important consequence of these models is the delayed injection of dust from AGB stars, compared to supernova-condensed dust, into the interstellar medium. I will show that these stellar evolutionary effects on dust composition are manifested in the infrared spectra of local galaxies. The delayed production of dust in AGB stars has also important consequences for the origin of the large amount of dust detected in high-redshift galaxies, when the universe was less that - 1 Gyr old. Supernovae may have been the only viable dust sources in those galaxies. Recent observations of SN1987a show a significant mass of dust in the ejecta of this SN. Is that production rate high enough to account for the observed dust mass in these galaxies? If not, what are the alternative viable sources of dust, and how do they depend on the nature of the galaxy (starburst or AGN) and its star formation history.

Dwek, Eliahu↗
NASA NTRS2011

Wave Forcing of Saturn's Equatorial Oscillation

Ground-based measurements and Cassini data from CIRS thermal-infrared spectra and radio-occultation soundings have characterized the spatial structure and temporal behavior of a 15-year equatorial oscillation in Saturn's stratosphere. The equatorial region displays a vertical pattern of alternating warm and cold anomalies and, concomitantly, easterly and westerly winds relative to the cloud-top winds, with a peak-to-peak amplitude of 200 m/s. Comparison of the Cassini data over a four-year period has established that the pattern of mean zonal winds and temperatures descends at a rate of roughly I scale height over 4 years. This behavior is reminiscent of the equatorial oscillations in Earth's middle atmosphere. Here the zonal-mean spatial structure and descending pattern are driven by the absorption of vertically propagating waves. The maximum excursions in the pattern of easterly and westerly winds is determined by the limits of the zonal phase velocities of the waves. Here we report on the characterization of the waves seen in the temperature profiles retrieved from the Cassini radio-occultation soundings. The equatorial profiles exhibit a complex pattern of wavelike structure with dimensions one pressure scale height and smaller. We combine a spectral decomposition with a WKBJ analysis, where the vertical wavelength is assumed to vary slowly with the ambient static stability and doppler-shifted phase velocity of the wave. Use of the temperature and zonal wind maps from CIRS makes this approach viable. On Earth, the wave forcing associated with the equatorial oscillations generates secondary meridional circulations that affect the mean flow and planetary wave ducting well away from the equator. This may relate to the triggering of the recently reported mid-latitude storms on Saturn.

Flasar, F. M.↗
NASA NTRS2012

Origins of GEMS Grains

Interplanetary dust particles (IDPs) collected in the Earth s stratosphere contain high abundances of submicrometer amorphous silicates known as GEMS grains. From their birth as condensates in the outflows of oxygen-rich evolved stars, processing in interstellar space, and incorporation into disks around new stars, amorphous silicates predominate in most astrophysical environments. Amorphous silicates were a major building block of our Solar System and are prominent in infrared spectra of comets. Anhydrous interplanetary dust particles (IDPs) thought to derive from comets contain abundant amorphous silicates known as GEMS (glass with embedded metal and sulfides) grains. GEMS grains have been proposed to be isotopically and chemically homogenized interstellar amorphous silicate dust. We evaluated this hypothesis through coordinated chemical and isotopic analyses of GEMS grains in a suite of IDPs to constrain their origins. GEMS grains show order of magnitude variations in Mg, Fe, Ca, and S abundances. GEMS grains do not match the average element abundances inferred for ISM dust containing on average, too little Mg, Fe, and Ca, and too much S. GEMS grains have complementary compositions to the crystalline components in IDPs suggesting that they formed from the same reservoir. We did not observe any unequivocal microstructural or chemical evidence that GEMS grains experienced prolonged exposure to radiation. We identified four GEMS grains having O isotopic compositions that point to origins in red giant branch or asymptotic giant branch stars and supernovae. Based on their O isotopic compositions, we estimate that 1-6% of GEMS grains are surviving circumstellar grains. The remaining 94-99% of GEMS grains have O isotopic compositions that are indistinguishable from terrestrial materials and carbonaceous chondrites. These isotopically solar GEMS grains either formed in the Solar System or were completely homogenized in the interstellar medium (ISM). However, the chemical compositions of GEMS grains are extremely heterogeneous and seem to rule out this possibility. Based on their solar isotopic compositions and their non-solar elemental compositions we propose that most GEMS grains formed in the nebula as late-stage non-equilibrium condensates.

Messenger, S.↗
NASA NTRS2012

Thermal Behaviour of Unusual Local-Scale Surface Features on Vesta

On Vesta, the region of the infrared spectrum beyond approximately 3.5 micrometers is dominated by the thermal emission of the asteroid's surface, which can be used to determine surface temperature by means of temperature-retrieval algorithms. The thermal behavior of areas of unusual albedo seen at the local scale can be related to physical properties that can provide information about the origin of those materials. Dawn's Visible and Infrared Mapping Spectrometer (VIR) hyperspectral cubes are used to retrieve surface temperatures, with high accuracy as long as temperatures are greater than 180 K. Data acquired in the Survey phase (23 July through 29 August 2011) show several unusual surface features: 1) high-albedo (bright) and low-albedo (dark) material deposits, 2) spectrally distinct ejecta, 3) regions suggesting finer-grained materials. Some of the unusual dark and bright features were re-observed by VIR in the subsequent High-Altitude Mapping Orbit (HAMO) and Low-Altitude Mapping Orbit (LAMO) phases at increased pixel resolution. To calculate surface temperatures, we applied a Bayesian approach to nonlinear inversion based on the Kirchhoff law and the Planck function. These results were cross-checked through application of alternative methods. Here we present temperature maps of several local-scale features that were observed by Dawn under different illumination conditions and different local solar times. Some bright terrains have an overall albedo in the visible as much as 40% brighter than surrounding areas. Data from the IR channel of VIR show that bright regions generally correspond to regions with lower thermal emission, i.e. lower temperature, while dark regions correspond to areas with higher thermal emission, i.e. higher temperature. This behavior confirms that many of the dark appearances in the VIS mainly reflect albedo variations. In particular, it is shown that during maximum daily insolation, dark features in the equatorial region may rise to temperatures greater than 270 K. However, individual features may show different thermal behaviours, as a result of differences in composition and/or structure (e.g, average grain size of the surface regolith, porosity, etc.). To complement the temperature and near-infrared emissivity derived from the infrared spectra, a separate work is devoted to calculate thermal inertia and other thermal properties using theoretical models which solve the heat equation for airless bodies, and model the distribution of temperatures due to surface roughness variations.

Tosi, F.↗
NASA NTRS2012

Enhanced-Adhesion Multi-Walled Carbon Nanotubes on Titanium Substrates for Stray Light Control

Carbon nanotubes previously grown on silicon have extremely low reflectance, making them a good candidate for stray light suppression. Silicon, however, is not a good structural material for stray light components such as tubes, stops, and baffles. Titanium is a good structural material and can tolerate the 700 C nanotube growth process. The ability to grow carbon nanotubes on a titanium substrate that are ten times blacker than the current NASA state-of-the-art paints in the visible to near infrared spectra has been achieved. This innovation will allow significant improvement of stray light performance in scientific instruments or any other optical system. This innovation is a refinement of the utilization of multiwalled carbon nano tubes for stray light suppression in spaceflight instruments. The innovation is a process to make the surface darker and improve the adhesion to the substrate, improving robustness for spaceflight use. Bright objects such as clouds or ice scatter light off of instrument structures and components and make it difficult to see dim objects in Earth observations. A darker material to suppress this stray light has multiple benefits to these observations, including enabling scientific observations not currently possible, increasing observational efficiencies in high-contrast scenes, and simplifying instruments and lowering their cost by utilizing fewer stray light components and achieving equivalent performance. The prior art was to use commercially available black paint, which resulted in approximately 4% of the light being reflected (hemispherical reflectance or total integrated scatter, or TIS). Use of multiwalled carbon nanotubes on titanium components such as baffles, entrance aperture, tubes, and stops, can decrease this scattered light by a factor of ten per bounce over the 200-nm to 2,500-nm wavelength range. This can improve system stray light performance by orders of magnitude. The purpose of the innovation is to provide an enhanced stray light control capability by making a blacker surface treatment for typical stray light control components. Since baffles, stops, and tubes used in scientific observations often undergo loads such as vibration, it was critical to develop this surface treatment on structural materials. The innovation is to optimize the carbon nanotube growth for titanium, which is a strong, lightweight structural material suitable for spaceflight use. The titanium substrate carbon nanotubes are more robust than those grown on silicon and allow for easier utilization. They are darker than current surface treatments over larger angles and larger wavelength range. The primary advantage of titanium substrate is that it is a good structural material, and not as brittle as silicon.

Hagopian, John↗
NASA NTRS2012

Descent with Modification: Thermal Reactions of Subsurface H2O2 of Relevance to Icy Satellites and Other Small Bodies

Laboratory experiments have demonstrated that magnetospheric radiation in the Jovian system drives reaction chemistry in ices at temperatures relevant to Europa and other icy satellites. Similarly, cosmic radiation (mainly protons) acting on cometary and interstellar ices can promote extensive chemical change. Among the products that have been identified in irradiated H20-ice is hydrogen peroxide (H202), which has been observed on Europa and is suspected on other worlds. Although the infrared spectra and radiation chemistry of H2O2-containing ices are well documented, the thermally-induced solid-phase chemistry of H2O2 is largely unknown. Therefore, in this presentation we report new laboratory results on reactions at 50 - 130 K in ices containing H2O2 and other molecules, both in the presence and absence of H2O. As an example of our results, we find that warming H2O + H2O2 + SO2 ices promotes SO2 oxidation to SO4(2-). We suspect that such redox chemistry may explain some of the observations related to the presence and distribution of H2O2 across Europa's surface as well as the lack of H2O2 on Ganymede and Callisto. If other molecules prove to be just as reactive with frozen H2O2 then it may explain why H2O2 has been absent from surfaces of many of the small icy bodies that are known to be exposed to ionizing radiation. Our results also have implications for the survival of H2O2 as it descends towards a subsurface ocean on Europa.

Hudson, Reggie L.↗
NASA NTRS2012

Infrared Spectral Studies of the Thermally-Driven Chemistry Present on Icy Satellites

Remote sensing of Jupiters icy satellites has revealed that even though their surfaces arc composed mostly of water ice, molecules such as SO2, CO2, H2O2. O2, and O3 also are present. On Europa, a high radiation flux is believed to play a role in the formation of many of the minor species detected, and numerous laboratory studies have been devoted to explore this hypothesis. In this presentation we will discuss some of our recent research on another alteration pathway, thermally-driven chemical reactions, which are also important for understanding the chemical evolution of Europa's surface and sub-surface ices. We will focus on the infrared spectra of and reactions between H2O, SO2 and H2O2, at 80 - 130 K.

Loeffler, Mark J.↗
NASA NTRS2012

Using Apollo Sites and Soils to Compositionally Ground Truth Diviner Lunar Radiometer Observations

Apollo landing sites and returned soils afford us a unique opportunity to "ground truth" Diviner Lunar Radiometer compositional observations, which are the first global, high resolution , thermal infrared measurements of an airless body. The Moon is the most accessible member of the most abundant class of solar system objects, which includes Mercury, asteroids, and icy satellites. And the Apollo samples returned from the Moon are the only extraterrestrial samples with known spatial context. Here we compare Diviner observations of Apollo landing sites and compositional and spectral laboratory measurements of returned Apollo soils. Diviner, onboard NASA's Lunar Reconnaissance Orbiter, has three spectral channels near 8 micron that were designed to characterize the mid-infrared emissivity maximum known as the Christiansen feature (CF), a well-studied indicator of silicate mineralogy. It has been observed that thermal infrared spectra measured in simulated lunar environment (SLE) are significantly altered from spectra measured under terrestrial or martian conditions, with enhanced CF contrast and shifted CF position relative to other spectral features. Therefore only thermal emission experiments conducted in SLE are directly comparable to Diviner data. With known compositions, Apollo landing sites and soils are important calibration points for the Diviner dataset, which includes all six Apollo sites at approximately 200 m spatial resolution. Differences in measured CFs caused by composition and space weathering are apparent in Diviner data. Analyses of Diviner observations and SLE measurements for a range of Apollo soils show good agreement, while comparisons to thermal reflectance measurements under ambient conditions do not agree well, which underscores the need for SLE measurements and validates our measurement technique. Diviner observations of Apollo landing sites are also correlated with geochemical measurements of Apollo soils from the Lunar Sample Compendium. In particular, the correlations between CF and FeO and AI203 are very strong, owing to the dependence on the feldspar-mafic ratio. Our analyses suggest that Diviner data may offer an independent measure of soil iron content from the existing optical and gamma-ray spectrometer datasets.

Greenhagen, Benjamin T.↗
NASA NTRS2012

Observing Campaign for Potential Deep Impact Flyby Target 163249 (2002 GT)

The Deep Impact spacecraft is currently on course for a Jan. 4, 2020 flyby of the sub-kilometer near-Earth asteroid 163249 (2002 GT). The re-targeting will be complete with a final small maneuver scheduled for Oct. 4, 2012. 2002 GT, which is also designated as a Potentially Hazardous Asteroid (PHA), has a well-determined orbit and is approx 800 m in diameter (H=18.3). Little more is known about the nature of this object, but in mid-2013 it will pass near the Earth, affording an exceptional opportunity for ground-based characterization. At this apparition 2002 GT will be in range of Arecibo. In addition to Doppler measurements, radar delay observations with precisions of a few microseconds are expected and have a good chance of revealing whether the system is binary or not. The asteroid will be brighter than 16th mag., which will facilitate a host of observations at a variety of wavelengths. Light curve measurements across a wide range of viewing perspectives will reveal the rotation rate and ultimately lead to strong constraints on the shape and pole orientation. Visible and infrared spectra will constrain the mineralogy, taxonomy, albedo and size. Along with the radar observations, optical astrometry will further constrain the orbit, both to facilitate terminal guidance operations and to potentially reveal nongravitational forces acting on the asteroid. Coordinating all of these observations will be a significant task and we encourage interested observers to collaborate in this effort. The 2013 apparition of 2002 GT represents a unique opportunity to characterize a potential flyby target, which will aid interpretation of the high-resolution flyby imagery and aid planning and development of the flyby imaging sequence. The knowledge gained from this flyby will be highly relevant to the human exploration program at NASA, which desires more information on the physical characteristics of sub-kilometer near-Earth asteroids.

Pittichova, Jana↗
NASA NTRS2012

Thermal Reactions of H2O2 on Icy Satellites and Small Bodies: Descent with Modification?

Magnetospheric radiation drives surface and near-surface chemistry on Europa, but below a few meters Europa's chemistry is hidden from direct observation . As an example, surface radiation chemistry converts H2O and SO2 into H2O2 and (SO4)(sup 2-), respectively, and these species will be transported downward for possible thermally-driven reactions. However, while the infrared spectra and radiation chemistry of H2O2-containing ices are well documented, this molecule's thermally-induced solid-phase chemistry has seldom been studied. Here we report new results on thermal reactions in H2O + H2O2 + SO2 ices at 50 - 130 K. As an example of our results, we find that warming H2O + H2O2 + SO2 ices promotes SO2 oxidation to (SO4)(sup 2-). These results have implications for the survival of H2O2 as it descends, with modification, towards a subsurface ocean on Europa. We suspect that such redox chemistry may explain some of the observations related to the presence and distribution of H2O2 across Europa's surface as well as the lack of H2O2 on Ganymede and Callisto.

Hudson, Reggie L.↗
NASA NTRS2012

The Origin and Evolution of Interstellar Dust in the Local and High-redshift Universe

In this talk I will begin by reviewing our current state of knowledge regarding the origin and evolution of dust in the local solar neighborhood. using chemical evolution models, I will discuss their many different input parameters and their uncertainties. An important consequence of these models is the delayed injection of dust from AGB stars, compared to supernova-condensed dust, into the interstellar medium. I will show that these stellar evolutionary effects on dust composition are manifested in the infrared spectra of local galaxies. The delayed production of dust in AGB stars has also important consequences for the origin of the large amount of dust detected in high-redshift galaxies, when the universe was less that approx. 1 Gyr old. Supernovae may have been the only viable dust sources in those galaxies. Recent observations of sN1987a show a significant mass of dust in the ejecta of this SN. Is that production rate high enough to account for the observed dust mass in these galaxies? If not, what are the alternative viable sources of dust, and how do they depend on the nature of the galaxy (starburst or AGN) and its star formation history .

Dwek, Eliahu↗
NASA NTRS2013

Insights into Collisional between Small Bodies: Comparison of Impacted Magnesium-rich Minerals

Impacts are sustained by comets and asteroids throughout their lives, especially early in the Solar system's history, as described by the Nice model. Identifying observable properties that may be altered due to impacts can lead to a better understanding their collisional histories. Here, we investigate spectral effects and physical shock features observed in infrared spectra and Transmission Electron Microscope (TEM) images, respectively, of magnesium-rich minerals subjected to shock through impact experiments. Samples of magnesium-rich forsterite (Mg2SiO4, olivine), orthoenstatite (Mg2SiO3, pyroxene), diopside (MgCaSi2O6, monoclinic pyroxene), and magnesite (MgCO3, carbonate) were impacted at speeds of 2.4 km/s, 2.6 km/s and 2.8 km/s. Impact experiments were conducted in the Johnson Space Center Experimental Impact Laboratory using the vertical gun. Clear signatures are observed in both the mid-IR spectra (shift in wavelengths of the spectral peaks and relative amplitude changes) of all minerals except magnesite, and in TEM images (planar dislocations) of both the forsterite and orthoenstatite samples. Further discussion on forsterite and enstatite analyses can be found in Jensen et al., this meeting.

Lederer, Susan M.↗
NASA NTRS2013

Vertical Distribution of Dust and Water Ice Aerosols from CRISM Limb-geometry Observations

[1] Near-infrared spectra taken in a limb-viewing geometry by the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) on board the Mars Reconnaissance Orbiter provide a useful tool for probing atmospheric structure. Specifically, the observed radiance as a function of wavelength and height above the limb enables the vertical distribution of both dust and water ice aerosols to be retrieved. More than a dozen sets of CRISM limb observations have been taken so far providing pole-to-pole cross sections, spanning more than a full Martian year. Radiative transfer modeling is used to model the observations taking into account multiple scattering from aerosols and the spherical geometry of the limb observations. Both dust and water ice vertical profiles often show a significant vertical structure for nearly all seasons and latitudes that is not consistent with the well-mixed or Conrath-v assumptions that have often been used in the past for describing aerosol vertical profiles for retrieval and modeling purposes. Significant variations are seen in the retrieved vertical profiles of dust and water ice aerosol as a function of season. Dust typically extends to higher altitudes (approx. 40-50km) during the perihelion season than during the aphelion season (<20km), and the Hellas region consistently shows more dust mixed to higher altitudes than other locations. Detached water ice clouds are common, and water ice aerosols are observed to cap the dust layer in all seasons.

Atmosphere↗
NASA NTRS2014

Inferred Variable FeO Content in Medium-sized Lunar Pyroclastic Deposits from LRO Diviner Data

Lunar pyroclastic deposits (LPDs) are low albedo features that mantle underlying terrain (Gaddis et al. 1985). They are high priority targets for science and exploration as they are believed to originate from and therefore reflect the composition of the deep lunar interior (NRC, 2011). They are also the best potential resource of oxygen out of any Apollo samples (Allen et al. 1996). Historically, LPDs have been divided into regional versus local categories (Gaddis et al. 2003). The large (>1000 km2 area) regional deposits are deeply sourced (>400 km deep) and result from fire fountaining. Small (<1000 km2) local deposits are thought to result from Vulcanian eruptions in which magma is slowly emplaced beneath the surface until enough volatiles exsolve and the high pressure causes an explosion. Bennett et al. (2013) identified a local deposit (674 km2 area) that may have resulted from both Vulcanian activity and fire fountaining. This deposit potentially represents a new intermediate class of LPDs that straddles the interface between the two formation mechanisms. The deposit also exhibits the highest inferred FeO wt.% of any known lunar glass. In this work we investigate the inferred FeO abundances of other medium-sized deposits to characterize this potential new class of deposits and understand the magnitude of variations in inferred FeO among pyroclastic deposits. We use the method of Greenhagen et al. (2010) to calculate the wavelength of the Christiansen Feature (CF) from Lunar Reconnaissance Orbiter Diviner Lunar Radiometer instrument thermal-infrared observations for four medium-sized deposits. From the CF values, we estimate each deposit's FeO abundance using the method of Allen et al. (2012). The four LPDs that we examined (Oppenheimer South, Beer, Cleomedes, and J. Herschel) all have average CF values from 8.22-8.28 microns, corresponding to FeO abundances of approx. 10-15 wt.%. All of these values are within the range and uncertainties of FeO abundances measured in Apollo samples. As previously identified, the Oppenheimer South deposit exhibits an area of enhanced CF values (8.49 microns) that, if the methods of Allen et al. (2012) can be extrapolated, correspond to a highest observed approx. 30 wt.% FeO. Moon Mineralogy Mapper near-infrared spectra indicate that this area is glass-rich as opposed to olivine-rich. While we are still investigating the nature of the high CF wavelength in Oppenheimer South, spatially-resolved observations there and (to a smaller degree) in our other study sites, shows that FeO wt.% can vary within LPDs. Thus, obtaining only the average FeO abundance over a large area may not be adequate to understand global variation. The magnitude of Oppenheimer South's CF variability, if due to actual surface variations rather than calibration artifacts or spectral mixing, could indicate that it is a unique deposit and not part of a new mid-sized class of deposits. The higher value could be a result of its location within the South Pole Aitken Basin and exsolution of more deeply sourced magma due to the thin crust there.

Bennett, K. A.↗
NASA NTRS2012

Mixing of Dust and NH3 Observed Globally over Anthropogenic Dust Sources

The global distribution of dust column burden derived from MODIS Deep Blue aerosol products is compared to NH3 column burden retrieved from IASI infrared spectra. We found similarities in their spatial distributions, in particular their hot spots are often collocated over croplands and to a lesser extent pastures. Globally, we found 22% of dust burden collocated with NH3, with only 1% difference between land-use databases. This confirms the importance of anthropogenic dust from agriculture. Regionally, the Indian subcontinent has the highest amount of dust mixed with NH3 (26 %), mostly over cropland and during the pre-monsoon season. North Africa represents 50% of total dust burden but accounts for only 4% of mixed dust, which is found over croplands and pastures in Sahel and the coastal region of the Mediterranean. In order to evaluate the radiative effect of this mixing on dust optical properties, we derive the mass extinction efficiency for various mixtures of dust and NH3, using AERONET sunphotometers data. We found that for dusty days the coarse mode mass extinction efficiency decreases from 0.62 to 0.48 square meters per gram as NH3 burden increases from 0 to 40 milligrams per square meter. The fine mode extinction efficiency, ranging from 4 to 16 square mters per gram, does not appear to depend on NH3 concentration or relative humidity but rather on mineralogical composition and mixing with other aerosols. Our results imply that a significant amount of dust is already mixed with ammonium salt before its long range transport. This in turn will affect dust lifetime, and its interactions with radiation and cloud properties

dust sources↗
NASA NTRS2012

Spatial and Temporal Variations in Titan's Surface Temperatures from Cassini CIRS Observations

We report a wide-ranging study of Titan's surface temperatures by analysis of the Moon's outgoing radiance through a spectral window in the thermal infrared at 19 mm (530/cm) characterized by lower atmospheric opacity. We begin by modeling Cassini Composite Infrared Spectrometer (CIRS) far infrared spectra collected in the period 2004-2010, using a radiative transfer forward model combined with a non-linear optimal estimation inversion method. At low-latitudes, we agree with the HASI near-surface temperature of about 94 K at 101S (Fulchignoni et al., 2005). We find a systematic decrease from the equator toward the poles, hemispherically asymmetric, of approx. 1 K at 60 deg. south and approx. 3 K at 60 deg. north, in general agreement with a previous analysis of CIRS data and with Voyager results from the previous northern winter. Subdividing the available database, corresponding to about one Titan season, into 3 consecutive periods, small seasonal changes of up to 2 K at 60 deg N became noticeable in the results. In addition, clear evidence of diurnal variations of the surface temperatures near the equator are observed for the first time: we find a trend of slowly increasing temperature from the morning to the early afternoon and a faster decrease during the night. The diurnal change is approx. 1.5 K, in agreement with model predictions for a surface with a thermal inertia between 300 and 600 J/ sq. m s (exp -1/2) / K. These results provide important constraints on coupled surface-atmosphere models of Titan's meteorology and atmospheric dynamic.

titan↗
NASA NTRS2013

The Unexpectedly Bright Comet C-2012 F6 (Lemmon) Unveiled at Near-Infrared Wavelengths

We acquired near-infrared spectra of the Oort cloud comet C/2012 F6 (Lemmon) at three different heliocentric distances (R h) during the comet's 2013 perihelion passage, providing a comprehensive measure of the outgassing behavior of parent volatiles and cosmogonic indicators. Our observations were performed pre-perihelion at R h = 1.2 AU with CRIRES (on 2013 February 2 and 4), and post-perihelion at R h = 0.75 AU with CSHELL (on March 31 and April 1) and R h = 1.74 AU with NIRSPEC (on June 20). We detected 10 volatile species (H2O, OH* prompt emission, C2H6, CH3OH, H2CO, HCN, CO, CH4, NH3, and NH2), and obtained upper limits for two others (C2H2 and HDO). One-dimensional spatial profiles displayed different distributions for some volatiles, confirming either the existence of polar and apolar ices, or of chemically distinct active vents in the nucleus. The ortho-para ratio for water was 3.31 +/- 0.33 (weighted mean of CRIRES and NIRSPEC results), implying a spin temperature >37 K at the 95% confidence limit. Our (3σ) upper limit for HDO corresponds to D/H < 2.45 × 10-3 (i.e., <16 Vienna Standard Mean Ocean Water, VSMOW). At R h = 1.2 AU (CRIRES), the production rate for water was Q(H2O) = 1.9 +/- 0.1 × 1029 s-1 and its rotational temperature was T rot ~ 69 K. At R h = 0.75 AU (CSHELL), we measured Q(H2O) = 4.6 +/- 0.6 × 1029 s-1 and T rot = 80 K on March 31, and 6.6 +/- 0.9 × 1029 s-1 and T rot = 100 K on April 1. At R h = 1.74 AU (NIRSPEC), we obtained Q(H2O) = 1.1 +/- 0.1 × 1029 s-1 and T rot ~ 50 K. The measured volatile abundance ratios classify comet C/2012 F6 as rather depleted in C2H6 and CH3OH, while HCN, CH4, and CO displayed abundances close to their median values found among comets. H2CO was the only volatile showing a relative enhancement. The relative paucity of C2H6 and CH3OH (with respect to H2O) suggests formation within warm regions of the nebula. However, the normal abundance of HCN and hypervolatiles CH4 and CO, and the enhancement of H2CO, may indicate a possible heterogeneous nucleus of comet C/2012 F6 (Lemmon), possibly as a result of radial mixing within the protoplanetary disk

C/2012 F6↗